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2018 IEEE 7th World Conference on Photovoltaic Energy Conversion (WCPEC) (A Joint Conference of 45th IEEE PVSC, 28th PVSEC & 34th EU PVSEC)最新文献

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Reduction of Thermal Caused Extra Light Induced Degradation by Redefined Regeneration Conditions 通过重新定义再生条件减少热引起的额外光诱导降解
Chun-Ping Lin, Kuo-Yi Yen, Jun-Rui Huang, Sean H. T. Chen
The regeneration process is a method for boronoxygen defects passivation by using heat and illumination, and its benefits have been demonstrated for efficiently reducing light induced degradation (LID) on P-type cells. It is widely used for solving LID issue on p-type PERC cells in recent year. In this paper, post-heating was used to understand the thermal influence on regenerated cells. Comparison between cell with and without regeneration process, the post-heating caused extra LID (2%) in regenerated cells is much higher than that (0.5%) in as-fired cells. The difference of extra LID between as-fired and regenerated cells indicates that the post-heating results in defect state transition from regenerated state to annealed state in regenerated cells. Based on this phenomenon, the LID test must take the impact of latent heat after regeneration process such as subsequent module process into consideration. Therefore, the regeneration process windows of temperature and light intensity need to be redefined when post-heating is introduced after regeneration process. The result of process window redefinition shows that the regeneration conditions of 1.4C suns light intensity can reduce the post-heating caused extra LID about 0.8% as compared with the regeneration conditions of 1C suns light intensity, and LID has no significant change as temperature of regeneration condition in a range from 225 °C to 275 °C. Additionally, cells with regeneration condition of 175 °C have low as regenerated efficiency, and the LID of cells with regeneration treatment at 300 °C is higher than that of cells treated with lower temperatures.
再生过程是一种利用热和光照进行硼氧缺陷钝化的方法,其优点已被证明可以有效地减少p型电池的光诱导降解(LID)。近年来,它被广泛用于解决p型PERC电池的LID问题。本文采用后加热的方法来了解热对再生细胞的影响。经过和未经过再生处理的细胞比较,再生细胞的后加热产生的额外LID(2%)远高于未经过再生处理的细胞(0.5%)。煅烧和再生电池的额外LID差异表明,后加热导致再生电池的缺陷状态从再生状态转变为退火状态。基于这一现象,LID试验必须考虑再生过程后潜热的影响,如后续模块过程。因此,在再生过程后引入后加热时,需要重新定义温度和光强的再生过程窗口。工艺窗口重新定义结果表明,与1C太阳光强的再生条件相比,1.4C太阳光强的再生条件可减少后加热造成的额外LID约0.8%,并且在225℃~ 275℃范围内,LID随再生条件温度变化不显著。175℃再生条件下细胞的再生效率较低,300℃再生条件下细胞的LID高于低温条件下细胞的LID。
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引用次数: 0
Optimization of Optical Performance and Dust Removal Efficiency of Electrodynamic Screen (EDS) Films for Improving Energy-Yield of Solar Collectors 提高太阳能集热器产能率的EDS薄膜光学性能和除尘效率优化研究
A. Bernard, Ricci la Centra, Eric Argentieri, Ryan S. Eriksen, S. Garner, M. Horenstein, M. Mazumder
Silver nanowire (AgNW) electrodes of the Electrodynamic Screen (EDS) aim at restoring the output power lost due to soiling and ensure minimal loss in transmission efficiency when retrofitted on the PV modules. Experiments are done to improve the robustness of electrodes by incorporating zinc oxide (ZnO) layers in electrode structure. Alternatively, the use of a protective clear polymer overcoat over the entire design aims to increase the stability and durability of the silver nanowires in the electrodes. Hybrid ink is also developed by using silver nanospheres to increase conductivity of electrodes. New designs of electrode geometry and structure to increase efficiency of EDS operation are discussed.
电动力屏(EDS)的银纳米线(AgNW)电极旨在恢复因污染而损失的输出功率,并确保在改装光伏组件时将传输效率的损失降到最低。通过在电极结构中加入氧化锌层来提高电极的鲁棒性。另外,在整个设计上使用一层保护性的透明聚合物涂层,旨在提高电极中银纳米线的稳定性和耐久性。利用银纳米球来提高电极导电性的混合墨水也被开发出来。讨论了提高能谱仪工作效率的电极几何和结构的新设计。
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引用次数: 1
Ultraviolet fluorescence of ethylene-vinyl acetate in photovoltaic modules as estimation tool for yellowing and power loss 光伏组件中乙烯-醋酸乙烯酯的紫外荧光作为发黄和功率损失的估计工具
Arnaud Morlier, M. Siebert, I. Kunze, S. Blankemeyer, M. Köntges
The potential of ultraviolet (UV) fluorescence as a field technique for photovoltaic module defect detection was demonstrated recently. Here we study the formation rate of the fluorophores in module encapsulating material under UV illumination. We observe a correlation between the decrease in visible light transmission of the encapsulant and UV fluorescence intensity. This correlation allows estimating the yellowing-induced power loss via fluorescence measurements.
近年来,紫外荧光技术在光伏组件缺陷检测领域的应用得到了广泛的应用。本文研究了紫外光照射下模块封装材料中荧光团的形成速率。我们观察到包封剂可见光透射率的降低与紫外线荧光强度之间存在相关性。这种相关性可以通过荧光测量来估计发黄引起的功率损失。
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引用次数: 12
Comparison of Line Scan Luminescence Imaging Techniques for Defect Characterisation in Crystalline Silicon Solar Modules 晶体硅太阳能组件缺陷表征的线扫描发光成像技术比较
Iskra Zafirovska, M. Juhl, T. Trupke
Luminescence inspection of modules is currently being adopted as a standard practice in the photovoltaic industry. This paper presents a comparison of electroluminescence and photoluminescence imaging on industrial crystalline silicon modules, employed with a line scan system. We find that specific defects appear differently in the two techniques due to the difference in excitation method. Line scan photoluminescence images enable differentiation of series resistance defects from recombination defects and can identify the presence of encapsulant discolouration. Line scan electroluminescence images allow defects that prevent majority carrier transport to be evaluated. The use of both techniques enables robust defect characterisation.
组件发光检测目前已成为光伏行业的标准做法。本文介绍了用线扫描系统对工业晶体硅组件进行电致发光和光致发光成像的比较。我们发现,由于激励方式的不同,两种技术中出现的具体缺陷有所不同。线扫描光致发光图像能够区分串联电阻缺陷和复合缺陷,并能识别封装剂变色的存在。线扫描电致发光图像允许缺陷,防止大多数载流子传输进行评估。使用这两种技术可以实现健壮的缺陷表征。
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引用次数: 5
Improved Phosphorus Emitter Passivation using Chemically Grown SiO2 Layer for Industrial-sized Selective Emitter PERC 用化学生长SiO2层改进工业尺寸选择性发射极PERC的磷发射极钝化
Supawan Joonwichien, Y. Kida, M. Moriya, S. Utsunomiya, K. Shirasawa, H. Takato
We demonstrate the improvement of phosphorus emitter passivation for an industrial-sized passivated emitter and rear cell (PERC) with selective emitter (SE) structure using a method of nitric acid oxidation of silicon (NAOS) to form ultrathin SiO2layer. The results clearly show a significant impact of the presence of NAOS-SiO2 above emitters on all I-V parameters of PERCsWe observed an increase in the opencircuit voltage (Voc), and theshort-circuit current density(Jsc) along with strong improvements in the internal quantum efficiency (IQE) for short-wavelength photons. These improvements can be ascribed to the high level of chemical passivation, as clearly shown by a reduced interface trap density (Dit), and it is due to the less Shockley-Read-Hall recombination. The results presented here suggest that NAOS surface pretreatment is a very promising technology to improve the level of chemical passivation and thereby enhancing the industrialsized PERC performance.
我们展示了采用硝酸氧化硅(NAOS)形成超薄sio2层的方法,改进了具有选择性发射极(SE)结构的工业尺寸钝化发射极和后电池(PERC)的磷发射极钝化。结果清楚地表明,NAOS-SiO2的存在对percs的所有I-V参数都有显著的影响,我们观察到闭合电压(Voc)和短路电流密度(Jsc)的增加,以及短波长的光子的内部量子效率(IQE)的显著提高。这些改进可以归因于高水平的化学钝化,正如界面陷阱密度(Dit)的降低所清楚表明的那样,这是由于较少的肖克利-里德-霍尔复合。研究结果表明,NAOS表面预处理是一种非常有前途的技术,可以提高化学钝化水平,从而提高工业化PERC的性能。
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引用次数: 1
Mitigation of Crack Formation During Thermo-Mechanical Delamination of CdTe Solar Cells CdTe太阳能电池热-机械分层过程中裂纹形成的减缓
D. McGott, C. Wolden, M. Reese
Controlled thermo-mechanical delamination of thin-film solar cells offers a promising approach to drastically improve flexibility and specific power (power-to-weight ratio). However, the issue of film cracking during the delamination process must first be addressed. Here, we examine the causes of cracking during and after delamination, where it is found that cracking is heavily influenced by the material properties of the stressor layer used to induce delamination and the glass substrate that the solar cell is grown on. We then present several ways to reduce cracking during the delamination process.
薄膜太阳能电池的受控热机械分层提供了一种有前途的方法,可以大幅提高灵活性和比功率(功率重量比)。然而,在分层过程中,薄膜开裂的问题必须首先解决。在这里,我们研究了在分层期间和分层后开裂的原因,发现开裂在很大程度上受到用于诱导分层的应力源层和太阳能电池生长的玻璃基板的材料特性的影响。然后,我们提出了几种方法来减少开裂在分层过程中。
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引用次数: 0
Decoupled textures for broadband absorption enhancement beyond Lambertian light trapping limit in thin-film silicon-based solar cells 薄膜硅基太阳能电池中超越朗伯氏光捕获极限的宽带吸收增强解耦结构
R. Vismara, N. P. Dane Linssen, K. X. Wang, S. Fan, O. Isabella, M. Zeman
We present a modelling study of thin silicon based solar cells endowed with periodic and decoupled front/back textures. After careful optimization, the proposed device models exhibit absorption beyond the Lambertian light trapping limit for a wide range of light angles of incidence. The advanced light management scheme is applied to (nano)crystalline silicon solar cells, where the benefits of texturing the absorber rather than the supporting layers is clear and to barium (di)silicide solar cells, which could achieve an implied photocurrent densityof41.1 mA/cm2 for a thickness of only 2 $mu$m.
我们提出了一种具有周期性和去耦前/后纹理的薄硅基太阳能电池的建模研究。经过仔细的优化,所提出的器件模型在大范围的入射角下表现出超过朗伯光捕获极限的吸收。先进的光管理方案应用于(纳米)晶体硅太阳能电池,其中纹理化吸收层而不是支撑层的好处是清楚的,以及(二)硅化钡太阳能电池,它可以实现41.1 mA/cm2的隐含光电流密度,厚度仅为2 $mu$m。
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引用次数: 0
Slow minority carrier trapping and de-trapping in Czochralski silicon: Influence of thermal donors and the doping density chzochralski硅中缓慢的少数载流子捕获和释放:热供体和掺杂密度的影响
M. Siriwardhana, D. Macdonald, F. Heinz, F. Rougieux
The trapping characteristics of defects related to thermal donors have been studied with transient photoconductance measurements in Cz monocrystalline silicon wafers. The samples were annealed for various lengths of time to create a range of thermal donor concentrations. The de-trapping time constant was measured using photoconductance decay after the illumination is turned off. In order to obtain an estimate of the de-trapping time constants, the measurements were fitted with exponential terms. We find that the de-trapping time constant is inversely related to the concentration of thermal donors, while trapping is not observed in samples without thermal donors.
利用瞬态光导测量技术研究了Cz单晶硅片中与热供体有关的缺陷的俘获特性。样品被退火不同长度的时间,以产生一系列的热供体浓度。在关闭光照后,利用光导衰减测量了脱陷时间常数。为了得到解陷时间常数的估计,测量结果用指数项拟合。我们发现去捕获时间常数与热供体的浓度成反比,而在没有热供体的样品中没有观察到捕获。
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引用次数: 3
Exploration of copper-free ZnTe buffer layers for CdTe-based solar cells cdte基太阳能电池中无铜ZnTe缓冲层的探索
Yegor Samoilenko, C. Wolden
Development of copper-free ZnTe buffer layers for CdTe-based solar cells is an important avenue for improving stability. Group V elements offer a path towards that goal. This work explores two group V elements, phosphorous and antimony, as candidates for making copper-free p-type ZnTe buffer layer using thermal evaporation. It is found that incorporation of both elements into ZnTe film can easily be done. In addition, as deposited ZnTe films are Te-rich and Cd1-x Znx Te alloys form upon co-evaporation of ZnTe and Cd3P2, improving crystallinity and stoichiometry of the film. Activation of P poses a challenge, while ZnTe films with Sb produced good sheet resistance values.
开发用于cdte基太阳能电池的无铜ZnTe缓冲层是提高电池稳定性的重要途径。V组元素提供了实现这一目标的途径。本研究探索了两种V族元素,磷和锑,作为热蒸发制备无铜p型ZnTe缓冲层的候选元素。发现这两种元素都可以很容易地结合到ZnTe薄膜中。此外,由于沉积的ZnTe薄膜富含Te,并且通过ZnTe和Cd3P2的共蒸发形成Cd1-x Znx Te合金,从而提高了薄膜的结晶度和化学计量学。P的活化是一个挑战,而含有Sb的ZnTe薄膜产生了良好的片电阻值。
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引用次数: 0
Carrier injection from amorphous silicon into crystalline silicon determined with photoluminescence 用光致发光法测定从非晶硅注入晶体硅的载流子
A. Paduthol, M. Juhl, G. Nogay, P. Löper, A. Ingenito, T. Trupke
Intrinsic amorphous silicon provides excellent surface passivation on crystalline silicon. It has previously been shown, that carriers that are photo generated in the amorphous silicon can be efficiently electronically injected into the crystalline silicon. A method to quantify the efficiency of such carrier injection using the spectral response of photoluminescence has recently been demonstrated. As this is a contactless method, it can be applied to incomplete device structures. Here we, use this technique to measure partially processed heterojunction devices with different capping layers to quantify their impact on the carrier injection efficiency. Silicon nitride capping on amorphous silicon is shown to have minimum impact on the high carrier injection efficiency of the amorphous layer whereas phosphorus doped amorphous capping layers on the other hand were seen to have a strong effect on the carrier injection efficiency.
本征非晶硅为晶体硅提供了良好的表面钝化效果。以前已经证明,在非晶硅中光生成的载流子可以有效地电子注入到晶体硅中。最近已经证明了一种利用光致发光光谱响应来量化这种载流子注入效率的方法。由于这是一种非接触式方法,因此可以应用于不完整的器件结构。在这里,我们使用这种技术来测量具有不同封盖层的部分加工异质结器件,以量化它们对载流子注入效率的影响。氮化硅盖层对非晶层载流子注入效率的影响最小,而磷掺杂的非晶盖层对载流子注入效率的影响很大。
{"title":"Carrier injection from amorphous silicon into crystalline silicon determined with photoluminescence","authors":"A. Paduthol, M. Juhl, G. Nogay, P. Löper, A. Ingenito, T. Trupke","doi":"10.1109/PVSC.2018.8547295","DOIUrl":"https://doi.org/10.1109/PVSC.2018.8547295","url":null,"abstract":"Intrinsic amorphous silicon provides excellent surface passivation on crystalline silicon. It has previously been shown, that carriers that are photo generated in the amorphous silicon can be efficiently electronically injected into the crystalline silicon. A method to quantify the efficiency of such carrier injection using the spectral response of photoluminescence has recently been demonstrated. As this is a contactless method, it can be applied to incomplete device structures. Here we, use this technique to measure partially processed heterojunction devices with different capping layers to quantify their impact on the carrier injection efficiency. Silicon nitride capping on amorphous silicon is shown to have minimum impact on the high carrier injection efficiency of the amorphous layer whereas phosphorus doped amorphous capping layers on the other hand were seen to have a strong effect on the carrier injection efficiency.","PeriodicalId":6558,"journal":{"name":"2018 IEEE 7th World Conference on Photovoltaic Energy Conversion (WCPEC) (A Joint Conference of 45th IEEE PVSC, 28th PVSEC & 34th EU PVSEC)","volume":"59 6 1","pages":"3746-3750"},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77761693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
2018 IEEE 7th World Conference on Photovoltaic Energy Conversion (WCPEC) (A Joint Conference of 45th IEEE PVSC, 28th PVSEC & 34th EU PVSEC)
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