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2018 IEEE 7th World Conference on Photovoltaic Energy Conversion (WCPEC) (A Joint Conference of 45th IEEE PVSC, 28th PVSEC & 34th EU PVSEC)最新文献

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Characterizing high-mobility indium zinc oxide for the front transparent conductive oxide layer in silicon heterojunction solar cells 用于硅异质结太阳能电池前透明导电氧化层的高迁移率氧化铟锌的表征
D. Quispe, Syeda Mohsin, A. Leilaeioun, Z. Holman
Silicon heterojunction solar cells have a front transparent conductive oxide (TCO) layer serving an optical and electrical role to mitigate free carrier absorption and sheet resistance. A common optimization problem is the trade-off between fill factor and short-circuit current density when adjusting the carrier concentration of the TCO material. One way to circumvent this problem is to find high-mobility TCO materials and we contribute by performing a characterization of indium zinc oxide. We found that an optimum sample has a high-mobility of about 50 cm2/Vs with a sheet resistance of about 30- $40 Omega /mathrm {sq}$. For the same sample, absorbance in the infrared wavelength range can be 1–3%.
硅异质结太阳能电池具有前端透明导电氧化物(TCO)层,用于光学和电学作用,以减轻自由载流子吸收和片材电阻。在调整TCO材料载流子浓度时,一个常见的优化问题是填充系数和短路电流密度之间的权衡。规避这个问题的一种方法是找到高迁移率的TCO材料,我们通过对氧化锌铟进行表征来做出贡献。我们发现最佳样品具有约50 cm2/Vs的高迁移率,片电阻约为30- $40 Omega / mathm {sq}$。对于同一样品,红外波长范围内的吸光度可达1-3%。
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引用次数: 0
Impact of substrate thickness on the surface passivation in high performance n-type solar cells 衬底厚度对高性能n型太阳能电池表面钝化的影响
A. Augusto, P. Balaji, J. Karas, S. Bowden
Recently, silicon solar cells surpassed 26% efficiency. This was a result of remarkable low surface saturation current density and high short-circuit current provided by the SHJ-IBC architecture. In this paper we study the contribution of the different recombination mechanisms to shape the voltage at open-circuit and maximum power for different solar cell thicknesses. We demonstrate thinner cells are required to increase further the efficiency toward the intrinsic limit, as voltage increases and bulk lifetime dependence decreases. Open-circuit voltages over 760 mV were experimental confirmed on 50 μm-thick SHJ structures, leading to bandgap-voltage offsets of 0.349V.
最近,硅太阳能电池的效率超过了26%。这是由于SHJ-IBC结构提供了显著的低表面饱和电流密度和高短路电流。在本文中,我们研究了不同的复合机制对不同太阳能电池厚度的开路电压和最大功率的贡献。我们证明,随着电压的增加和体积寿命依赖性的降低,需要更薄的电池来进一步提高效率,达到固有极限。在50 μm厚的SHJ结构上,实验证实开路电压大于760 mV,导致带隙电压偏移0.349V。
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引用次数: 7
Power Estimation of Photovoltaic System using 4 and 5-parameter Solar Cell Models under Real Outdoor Conditions 真实室外条件下基于4参数和5参数太阳能电池模型的光伏系统功率估计
Manish Kumar, Arun Kumar
Solar photovoltaic systems are widely used to generate electricity from solar energy but the reliability and efficiency of PV systems are always of serious concern due to intermittent nature of solar radiation. The performance of the photovoltaic system depends upon various factors like type of solar PV technology used, irradiance, module temperature, wind speed, ambient temperature and other outdoor environmental conditions. The main objective of the study is to identify a suitable solar cell model for power prediction of a PV system for a location of interest and validate the results experimentally. A single diode model with 4 and 5-parameters is used for modeling of PV arrays. A hybrid approach of analytical and numerical methods has been utilized to identify the accurate parameters of solar cell model. The instantaneous output power is predicted by considering the effects of irradiance and module temperature on the power generation. The predicted power by both the 4 and 5-parameters models are compared and validated using an experimental PV system. The average percentage difference error between measured and predicted output power values for the 5-parameter model is 4.95% and 4-parameter model is 5.16%. The output power predicted using 5-parameter model is found to be much closer to measured values.
太阳能光伏发电系统被广泛应用于太阳能发电,但由于太阳辐射的间歇性,光伏系统的可靠性和效率一直是人们关注的问题。光伏系统的性能取决于各种因素,如所使用的太阳能光伏技术类型、辐照度、组件温度、风速、环境温度和其他室外环境条件。该研究的主要目的是确定一个合适的太阳能电池模型,用于光伏系统的功率预测,并通过实验验证结果。采用4参数和5参数的单二极管模型对光伏阵列进行建模。采用解析法和数值法相结合的方法对太阳能电池模型参数进行了精确辨识。考虑辐照度和组件温度对发电的影响,预测了瞬时输出功率。通过实验光伏系统对4参数模型和5参数模型的预测功率进行了比较和验证。5参数模型的输出功率实测值与预测值的平均百分比差误差为4.95%,4参数模型的输出功率实测值与预测值的平均百分比差误差为5.16%。使用五参数模型预测的输出功率更接近实测值。
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引用次数: 8
Accelerating Solar For Decelerating Climate Change In Time 加速太阳活动,及时减缓气候变化
A. Lagaaij
Any serious climate change model shows the extreme risks to life, food and habitat were we to continue on current ways of making electricity, heat and transportation by combusting fossil fuels. The question for humanity is if the energy from the sun can become a benign alternative in time. Solar energy is now 2.5% of electricity worldwide. How quickly can it grow to 70% for electricity and heating? We are entering a new regime where the trinity electric vehicles, solar energy and storage will spiral upwards. Can solar bend the Keeling curve down in time for CO2 to not become disastrous? How can all solar energy actors act in greater symphony to be in time?
任何严重的气候变化模型都表明,如果我们继续以目前的方式通过燃烧化石燃料来发电、供热和运输,生命、食物和栖息地将面临极大的风险。人类面临的问题是,来自太阳的能量能否及时成为一种良性的替代品。太阳能目前占全球电力的2.5%。电力和供暖的比例能多快增长到70% ?我们正在进入电动汽车、太阳能和储能三位一体将螺旋式上升的新局面。太阳能能否及时使基林曲线向下弯曲,使二氧化碳不至于变成灾难性的?所有的太阳能演员如何才能在更大的交响乐中及时行动?
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引用次数: 1
Solid-state infrared-to-visible upconversion for sub-bandgap sensitization of photovoltaics 用于光电器件亚带隙敏化的固态红外-可见光上转换
L. Nienhaus, Nadav Geva, Juan‐Pablo Correa‐Baena, Mengfei Wu, S. Wieghold, V. Bulović, T. Voorhis, M. Baldo, T. Buonassisi, M. Bawendi
By harvesting sub-bandgap photons, we have a path to overcome the Shockley-Queisser limit in photovoltaics (PVs). We investigate semiconductor nanocrystal (NC) sensitized upconversion via triplet-triplet annihilation (TTA) in organic semiconductors (OSCs). Since this process relies on optically inactive triplet states in the OSCs, we utilize PbS NCs to directly sensitize the triplet state via energy transfer. This is possible due to the strong spin-orbit coupling in PbS NCs, resulting in rapid spin-dephasing of the exciton. Current technology allows for upconversion of light with a photon energy above $sim 1.1$ eV. However, while internal efficiencies are rapidly improving, the low external device efficiencies render them impractical for applications, as devices are based on a single monolayer of NCs. Our results show simply increasing the PbS NC film thickness does not show improvement in the efficiency due to poor exciton transport between PbS NCs. Here, we present a new strategy to increase the external upconversion efficiency by utilizing thin tinbased halide perovskites as the absorbing layer. Resonant energy transfer from the perovskite to the PbS NCs allows for subsequent sensitization of the triplet state in rubrene.
通过收集亚带隙光子,我们有了克服光伏(pv)中的Shockley-Queisser限制的途径。我们研究了在有机半导体(OSCs)中通过三重态-三重态湮灭(TTA)的半导体纳米晶体(NC)敏化上转换。由于这一过程依赖于osc中的光学非活性三重态,我们利用PbS nc通过能量转移直接敏化三重态。这是可能的,因为在PbS nc中有很强的自旋轨道耦合,导致激子的快速自旋减相。目前的技术允许光子能量高于1.1 eV的光上转换。然而,虽然内部效率正在迅速提高,但由于设备基于单层nc,外部设备的低效率使得它们在应用中不切实际。我们的研究结果表明,由于激子在PbS NC之间传输不良,简单地增加PbS NC膜厚度并没有显示出效率的提高。本文提出了一种利用薄的锡基卤化物钙钛矿作为吸收层来提高外部上转换效率的新策略。从钙钛矿到PbS NCs的共振能量转移允许rubrene中三重态的后续敏化。
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引用次数: 2
Post-Deposition Recrystallization of Chloride Treated Cu(In x Ga (1-x)) Se 2 Thin-Film Solar Cells 氯处理Cu(In x Ga (1-x)) Se 2薄膜太阳能电池沉积后的再结晶
Elizabeth Palmiotti, Sina Soltanmohammad, A. Rockett, G. Rajan, S. Karki, Benjamin Belfore, S. Marsillac
Conditions promoting the recrystallization of CuIn(1-x) Se2 (CIGS) deposited by co-evaporation at 350°C were studied. Cu-rich and Cu-poor CIGS samples were annealed at 400°C and 550°C for 1 hour in the presence of alkali halide, In3Cl,Cu2Cl, SeCl4, and Se vapors. Increases in grain size of greater than 10x were observed with In3Cl with Se, Cu2Cl with and without Se, and SeCl4 at 550°C. Smaller magnitude grain size increases resulted at 400°C. Film composition was influenced by the vapors present with In3Cl enhancing the In content and Cu2{Cl enhancing the Cu content. Based on XRD analysis, the In3Cl+Se treatment best preserves the CIGS structure while resulting in a large amount of grain growth.
研究了350℃共蒸发沉积CuIn(1-x) Se2 (CIGS)再结晶的促进条件。富cu和贫cu的CIGS样品在400°C和550°C下,在卤化物、In3Cl、Cu2Cl、sec4和Se蒸气存在下退火1小时。在550°C时,加入含Se的In3Cl、含Se和不含Se的Cu2Cl和secr4,晶粒尺寸增加了10倍以上。在400℃时,晶粒尺寸增加幅度较小。In3Cl提高了In含量,Cu2{Cl提高了Cu含量,影响了膜的组成。XRD分析表明,In3Cl+Se处理能较好地保留CIGS结构,同时使晶粒大量长大。
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引用次数: 6
Optimization Methodology for Reconfigurable PV Modules 可重构光伏组件的优化方法
P. Manganiello, Pavlos Bosmalis, M. Baka, E. Voroshazi, D. Soudris, F. Catthoor, J. Szlufcik, J. Poortmans
Reconfigurable photovoltaic modules represent an effective solution to improve PV system resilience to partial shading. Indeed, the availability of different configurations increases energy generation under non-uniform conditions. However, the additional components that are active under uniform conditions lead to higher losses compared to equivalent static solutions. This paper presents a methodology for the design of optimized reconfigurable PV modules, balancing losses under uniform conditions and gain under partial shading. First, feasible reconfigurable module instantiations are selected given some design constraints. Then, the search space is further reduced by taking into account the typical operating conditions of the module. Finally, the best module layouts are chosen based on performance consideration. Results for a specific case study are presented to show the feasibility of the proposed methodology.
可重构光伏组件是提高光伏系统对部分遮阳的弹性的有效解决方案。事实上,不同配置的可用性增加了非均匀条件下的能量产生。然而,与等效静态解决方案相比,在均匀条件下活跃的额外组件会导致更高的损耗。本文提出了一种优化可重构光伏模块的设计方法,平衡均匀条件下的损失和部分遮阳条件下的增益。首先,在给定设计约束条件下选择可行的可重构模块实例。然后,考虑到模块的典型工作条件,进一步缩小了搜索空间。最后,基于性能考虑选择最佳模块布局。一个具体的案例研究结果显示了所提出的方法的可行性。
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引用次数: 0
Lightweight Monolithic Microcell CPV for Space 用于太空的轻量级单片微单元CPV
Christian J. Ruud, J. Price, Brent Fisher, Baoming Wang, N. Giebink
Concentrating photovoltaics (CPV) can increase the efficiency and reduce the cost of photovoltaic power in space. We introduce a new monolithic, ultrathin, and lightweight CPV paradigm based on a transfer-printed microscale solar cell array. In our reflective design, the microcell array is embedded in a radiation-tolerant glass optic that delivers 83% optical efficiency with a $pm mathbf{77} ^{circ}$ acceptance angle at $32 times$ geometric gain. The system is $<1$ mm thick and capable of achieving a specific power density of 352 W/kg using state-of-the-art triple junction microcells.
聚光光伏(CPV)可以提高空间光伏发电效率,降低空间光伏发电成本。我们介绍了一种基于转移印刷微型太阳能电池阵列的新型单片、超薄、轻量化CPV范式。在我们的反射设计中,微单元阵列嵌入在耐辐射玻璃光学器件中,具有83%的光学效率和$pm mathbf{77} ^{circ}$接收角,几何增益$32 倍$。该系统厚度小于1毫米,使用最先进的三结微电池,能够实现352 W/kg的比功率密度。
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引用次数: 5
GaP/Si Heterojunction Solar Cells: An Interface, Doping and Morphology Study GaP/Si异质结太阳能电池:界面、掺杂和形态研究
R. Saive, Hal S. Emmer, Christopher T. Chen, Chaomin Zhang, C. Honsberg, H. Atwater
We report on an study of the GaP/Si interface for application in silicon heterojunction solar cells. We analyzed the band alignment using X-ray photoelectron spectroscopy (XPS) and cross-sectional Kelvin probe force microscopy (x-KPFM). Our measurements show a high conduction band offset (0.9 eV) leading to a barrier in electron extraction which we microscopically resolved via x-KPFM. XPS reveals the presence of Si-Ga bonds which explains the observed interface dipole that leads to low open circuit voltage and low fill factor in GaP/Si heterojunction solar cells. Furthermore, we investigated the electronic and morphologic changes in GaP upon Si and Mg doping.
本文报道了一种应用于硅异质结太阳能电池的GaP/Si界面的研究。我们使用x射线光电子能谱(XPS)和截面开尔文探针力显微镜(x-KPFM)分析了带对准。我们的测量结果显示,高导带偏移(0.9 eV)导致电子萃取中的屏障,我们通过x-KPFM进行了微观分解。XPS揭示了Si- ga键的存在,这解释了在GaP/Si异质结太阳能电池中观察到的导致低开路电压和低填充因子的界面偶极子。此外,我们还研究了Si和Mg掺杂后GaP的电子和形态变化。
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引用次数: 1
Towards 90% Bifaciality for p-Type Cz-Si Solar Cells by Adaption of Industrial PERC Processes 采用工业PERC工艺实现p型Cz-Si太阳能电池90%双面性
E. Lohmüller, Sabrina Lohmüller (née Werner), M. Norouzi, P. Saint‐Cast, J. Weber, Sebastian B. Meier, A. Wolf
We demonstrate a bifaciality of 88.0% for 6-inch bifacial p-type Cz-Si passivated emitter and rear cells (biPERC) and increase their rear side energy conversion efficiency to 18.0% by minor adaptions in the fabrication sequence. We utilize the “pPassDop” concept on the cells’ rear side that applies an aluminum oxide and a boron-doped silicon nitride (SiNX:B layer stack for simultaneous passivation and doping source. Laser doping forms the local p-doped back surface field regions for these biPERL solar cells. Screen-printed silver-aluminum metallization contacts these regions. We also demonstrate the compatibility of the laser doping approach with conventional (undoped) SiNX capping layer to fabricate biPERL devices with screen-printed contacts.
我们证明了6英寸双面p型Cz-Si钝化发射极和后电池(biPERC)的双面性为88.0%,并且通过对制造顺序的轻微调整将其后侧能量转换效率提高到18.0%。我们在电池背面采用“pPassDop”概念,采用氧化铝和硼掺杂氮化硅(SiNX:B)层堆叠同时钝化和掺杂源。激光掺杂形成了双倍率太阳能电池的局部p掺杂后表面场区。丝网印刷银铝金属化接触这些区域。我们还证明了激光掺杂方法与传统的(未掺杂的)SiNX封盖层的兼容性,以制造具有丝网印刷触点的双perl器件。
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引用次数: 4
期刊
2018 IEEE 7th World Conference on Photovoltaic Energy Conversion (WCPEC) (A Joint Conference of 45th IEEE PVSC, 28th PVSEC & 34th EU PVSEC)
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