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2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)最新文献

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Paraffin Wax Enhanced with Carbon Nanostructures as Phase Change Materials: Preparation and Thermal Conductivity Measurement 碳纳米结构增强石蜡相变材料的制备及热导率测量
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568522
V. Zhelezny, O. Khliyeva, A. Nikulin, N. Lapardin, D. Ivchenko, Elena Palomo del Barrio
Synthesize routes of paraffin wax (PW) dopped by carbon nanostructures (fullerene C60 and multi-wall carbon nanotube) as the phase change materials (PCM) with enhanced thermophysical properties have been discussed. Thermal conductivity of prepared composite PCMs in the solid and liquid states was measured. No any meaningful increase of thermal conductivity for PW dopped with carbon nanotubes was observed. However, significant enhancement (up to two times) was found for the thermal conductivity of the PW containing C60 in the solid phase. At the same time, an influence of C60 on the thermal conductivity of PW in liquid phase was insignificant.
讨论了掺杂碳纳米结构(富勒烯C60和多壁碳纳米管)作为相变材料(PCM)的合成路线。测定了制备的复合PCMs在固态和液态下的导热系数。掺杂碳纳米管的PW导热系数没有明显提高。然而,发现在固相中含有C60的PW的导热性显著增强(高达两倍)。同时,C60对PW液相导热系数的影响不显著。
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引用次数: 7
Morphology of Nanocrystaline Calcifications of Ovarian Tumors 卵巢肿瘤纳米晶钙化的形态学研究
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568609
R. Chyzhma, A. Piddubnyi, A. Stepanenko, S. Danilchenko, R. Moskalenko
This paper is devoted to morphology, microstructure, phase and elemental composition of pathological crystalline inclusions in malignant ovarian neoplasms. It was found that pathological minerals are represented by calcium apatite with different levels of crystallinity. The transmission electron microscopy in combination with electron microdiffraction has shown some structural and morphological features of ovarian apatite crystals, which were not detected by other methods. According to transmission electron microscopy, the crystalline particles of calcifications are polydisperse (of different sizes) and the range of their sizes can be quite large.
本文对卵巢恶性肿瘤病理结晶包涵体的形态、微观结构、物相及元素组成进行了研究。病理矿物以不同结晶度的磷灰石钙为代表。透射电镜结合电子显微衍射显示了卵巢磷灰石晶体的一些结构和形态特征,这些特征是其他方法无法检测到的。通过透射电镜观察,钙化的结晶颗粒是多分散的(大小不一),其大小范围可以相当大。
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引用次数: 0
Magnetic Force Microscopy of Brain Microtubules 脑微管磁力显微镜
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568538
P. Mikheenko
Being biological object, microtubules attract significant attention in physics, since it is believed that they are responsible for quantum processing of information in the brain. There were, however, no direct experiments checking such a statement. Recently, strong advancement in quantum computing took place utilizing properties of superconductors at low temperatures. Following this progress, it was proposed that brain microtubules are superconducting at room temperature allowing quantum processing of information. Moreover, the evidence of room-temperature superconductivity in brain slices containing microtubules was obtained by electrical transport measurements, and even specific scenario of quantum processing in the microtubules has been suggested. These results, however, are not yet accepted by the scientific community as there are no known attempts to reproduce them. Another step in proving superconductivity would be confirming ideal diamagnetism of microtubules, since ideal diamagnetism is more fundamental property of superconductivity than perfect conductivity, some features of which were seen indirectly, or the existence of energy gap, which was already confirmed by the transport measurements. Here brain microtubules are examined by the magnetic force microscopy. The evidence of strong diamagnetism and its sensitivity to the water content in the microtubules is obtained. This gives another strong argument in favor of the concept suggesting superconductivity-based quantum processing of information in living organisms.
微管作为生物学对象,在物理学中引起了极大的关注,因为人们认为它们负责大脑中信息的量子处理。然而,没有直接的实验来验证这种说法。最近,利用超导体在低温下的特性,量子计算取得了很大的进展。根据这一进展,有人提出,大脑微管在室温下是超导的,允许信息的量子处理。此外,通过电输运测量获得了含有微管的脑切片室温超导性的证据,甚至提出了微管中量子处理的具体场景。然而,这些结果还没有被科学界所接受,因为目前还没有人试图重现它们。证明超导性的另一个步骤是确认微管的理想抗磁性,因为理想抗磁性是超导性的更基本的性质,而完美的导电性的一些特征是间接看到的,或者能量间隙的存在,这已经被输运测量证实了。这里用磁力显微镜检查脑微管。结果表明,微管具有很强的抗磁性和对微管中含水量的敏感性。这给了另一个强有力的论据,支持这一概念,即生物体中基于超导的信息量子处理。
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引用次数: 1
Enhancing Properties of TiZrHfNbTa Alloy by Surface Layers Nanostructuring Using Cryogenic Ultrasonic Impact Treatment 低温超声冲击处理增强TiZrHfNbTa合金表面纳米结构性能
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568529
B. Mordyuk, N. Khripta, V. Odnosum, S. Kedrovsky, Liguo Zhao, D. Lesyk
A multicomponent Ti28 Zr29 Hf28 Nb5 Ta10 alloy was subjected to ultrasonic impact treatment (UIT) carried out in the air (at room temperature) and in liquid nitrogen (at cryogenic temperature). X-ray diffraction (XRD) analysis shows that the UIT-induced severe plastic deformation did not change the single-bcc structure but results in a significant increase of dislocation density, grain refinement (the XRD-assessed grain size decreases down to ~25 nm after cryo-UIT), and formation of compressive residual stresses. Indentation tests show that the surface nanostructuring leads to the ~30% increase in the instrumental hardness of the cryo-UIT processed specimen (HIT ~5.4 GPa) and to a slight increase in elastic modulus (E ~90.5 GPa). The UIT processes also led to an increase in the corrosion potential and a decrease in the corrosion current density indicating the enhanced corrosion resistance in 0.9 NaCl physiological solution. The nanostructured surface was shown to experience uniform dissolution and quicker formation of the protective oxide layer.
对一种多组分Ti28 Zr29 Hf28 Nb5 Ta10合金进行了空气(室温)和液氮(低温)超声冲击处理(UIT)。x射线衍射(XRD)分析表明,低温加热引起的严重塑性变形并未改变单bcc结构,但导致位错密度显著增加,晶粒细化(低温加热后XRD评估的晶粒尺寸降至~25 nm),并形成压缩残余应力。压痕试验表明,表面纳米化使低温uit加工试样的仪器硬度提高了约30% (HIT ~5.4 GPa),弹性模量略有增加(E ~90.5 GPa)。腐蚀电位升高,腐蚀电流密度降低,表明在0.9 NaCl生理溶液中的耐蚀性增强。纳米结构表面具有均匀溶解和快速形成氧化保护层的特点。
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引用次数: 0
A New Method for Determining the Quality of Bionanocomposite Layers of Chicken Eggshells 一种测定鸡蛋壳生物复合层质量的新方法
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568392
R. Dolbanosova, V. Loboda, T. Chernyavska, O. Bordunova, Y. Shchepetilnikov, V. Opara, Y. Samokhina, O. Chernenko, V. Chivanov
A new method for determining the quality of the shell of edible and hatching eggs of hens has been developed. The method is based on thermal programmed desorption-mass spectrometry (TPD-MS), which consists in study kinetic parameters of carbon dioxide release from a 0,5 – 5 mkg eggshell sample during a linear temperature rise in vacuumed quartz tubes by electron impact ionization mass spectrometer with subsequent mathematical processing of obtained thermograms (curves “signal intensity carbon dioxide vs temperature”). Analysis of the thermograms makes it possible to sorting of hatching and laying hen eggs according to quality indicators, which closely correlate with indicators of density and peculiarities of microstructure of biocrystalline layers of eggshells of incubation and laying eggs. These data allow us to make conclusions about the suitability of certain batches of eggs to further technological operations
本文提出了一种测定母鸡食用蛋和孵蛋蛋壳质量的新方法。该方法基于热程序解吸-质谱法(TPD-MS),利用电子冲击电离质谱仪研究真空石英管内线性升温过程中0.5 ~ 5 mkg蛋壳样品二氧化碳释放的动力学参数,并对所得热图(“信号强度二氧化碳与温度”曲线)进行数学处理。热像图的分析可以根据质量指标对孵蛋蛋进行分类,而质量指标与孵蛋蛋蛋壳生物结晶层的密度指标和微观结构特征密切相关。这些数据使我们能够对某些批次的卵子是否适合进一步的技术操作作出结论
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引用次数: 0
Anti-Corrosion Properties of Ions Modified Zeolite 离子改性沸石的防腐性能
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568524
M. Danyliak, O. Khlopyk, I. Zin, S. Korniy, M. Holovchuk
Environmentally friendly corrosion inhibitors were obtained by liquid-phase ion exchange modification of zeolite with zinc, calcium and manganese cations. The surface morphology and chemical composition of modified zeolites were determined by scanning electron microscopy and energy dispersion spectroscopy analyzes. It was established that the structure of ion-exchange modified zeolites is homogeneous with a particle size of 2-4 $mu mathrm{m}$. It was shown that using of modified zeolites increases the corrosion resistance of the aluminum alloy in 0.1% NaCl solution. The Zn-zeolite had highest anti-corrosion effectiveness. Gradual release of the inhibitory components from zeolites provides long-term protection of metal constructions.
采用锌、钙、锰阳离子对沸石进行液相离子交换改性,制备了环保型缓蚀剂。通过扫描电镜和能谱分析对改性沸石的表面形貌和化学成分进行了测定。结果表明,离子交换改性沸石结构均匀,粒径为2 ~ 4 $mu mathrm{m}$。结果表明,改性沸石的加入提高了铝合金在0.1% NaCl溶液中的耐蚀性。锌分子筛的防腐效果最好。沸石中抑制成分的逐渐释放为金属结构提供了长期的保护。
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引用次数: 0
Simulation of Radial Distribution Functions and Internal Energy of Carbon Disulfide Film Sandwiched Between Diamond Surfaces 金刚石表面夹心二硫化碳膜径向分布函数及内能的模拟
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568548
D. Boyko, A. Khomenko, Natalya Kotliar, Ya.V. Khyzhnya, P. Trofymenko
Molecular dynamics simulation of ultrathin carbon disulfide film confined between atomically flat stiff diamond plates is exposed. While calculating the radial distribution functions, we specify three site-site distribution functions that are possible to measure experimentally: gCC,gCS and gSS. Films with one and two molecular layers are detailed and TIP4P model is applied for carbon disulfide molecules. The radial distribution function is also calculated as a function of the load on the substrate. Internal energy is calculated, for one-layer film with a zero load, such a dependency is irregular with considerable fluctuations. For a higher value of load, periodic spikes are observed. Similar spikes are inherent in experiments when the film is in a solid-like state and they are characteristic to the stick-slip friction. In general, the pattern of the studied model is in agreement with the experiments with simple fluids from spherical molecules.
研究了原子平面硬金刚石板间超薄二硫化碳薄膜的分子动力学模拟。在计算径向分布函数时,我们指定了三个可以实验测量的站点-站点分布函数:gCC,gCS和gSS。对一层和两层分子膜进行了详细分析,并对二硫化碳分子应用了TIP4P模型。径向分布函数也计算为基板上载荷的函数。计算了内能,对于具有零载荷的单层薄膜,这种依赖关系是不规则的,有相当大的波动。对于较高的负载值,可以观察到周期性尖峰。在实验中,当膜处于固体状态时,类似的尖峰是固有的,它们是粘滑摩擦的特征。总的来说,所研究的模型的模式与球形分子简单流体的实验是一致的。
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引用次数: 1
Photocatalytic Activity of P25-TiO2 Modified with Yttrium Oxide Towards Ciprofloxacin 氧化钇修饰P25-TiO2对环丙沙星的光催化活性
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568624
Karashchuk Olha, Kutuzova Anastasiya, Dontsova Tetiana
The article considers the effect of modification of commercial material P25-TiO2 with yttrium oxide and the effect of the modifier nature on the photocatalytic activity towards ciprofloxacin. TiO2 modification with yttrium oxide enhances the degree of antibiotic degradation. Increase in modifier content affects the photoactivity of TiO2 ambiguously: when yttrium chloride is used as a precursor, photoactivity increases; when yttrium nitrate is used – photoactivity decreases. Additional use of an oxidant (H2O2) significantly increases (more than 2 times) efficiency of the photocatalytic process. It has been found that at low concentrations of antibiotic aqueous solution (up to $10 mathrm{mg/dm^{3}}$), its photodegradation over TiO2 modified with yttrium oxide reaches 100%. However, in case of high concentrations of ciprofloxacin (up to $50 mathrm{mg/dm^{3}}$), complete degradation of the antibiotic is observed only when the combination of TiO2 modified with yttrium oxide and oxidant H2O2 is utilized in the photocatalytic process.
本文研究了用氧化钇对商品材料P25-TiO2进行改性的效果,以及改性剂性质对其对环丙沙星光催化活性的影响。用氧化钇修饰TiO2提高了抗生素的降解程度。改性剂含量的增加对TiO2光活性的影响是模糊的:当使用氯化钇作为前体时,光活性增加;当使用硝酸钇时,光活性降低。额外使用氧化剂(H2O2)可显著提高光催化过程的效率(超过2倍)。研究发现,在低浓度的抗生素水溶液中(高达$10 mathm {mg/dm^{3}}$),其在氧化钇修饰的TiO2上的光降解达到100%。然而,在环丙沙星浓度较高的情况下(高达$50 mathm {mg/dm^{3}}$),只有在光催化过程中利用氧化钇修饰的TiO2与氧化剂H2O2的组合才能观察到抗生素的完全降解。
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引用次数: 0
Plasma Nitriding of Stainless Steel in Non-Self-Sustained Gas Discharge with Hollow Anode and Pulsed Bias 不锈钢在空心阳极脉冲偏压非自持气体放电中的等离子体氮化
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568391
I. Misiruk, O. Tymoshenko, A. Taran, S. Romaniuk, I. Garkusha, G. Nikolaychuk
Results on plasma nitriding of AISI 430 stainless steel samples have been presented. The nitriding process has been carried out in nitrogen plasma of non-self-sustained gas discharge with hollow anode in Bulat type device with pulsed biasing mode and repetition frequency 50 kHz. The phase composition of the obtained coatings was analyzed via X-ray diffraction (XRD). The surface morphology was monitored by scanning electron microscopy (SEM) whereas chemical composition was examined by using energy dispersive X-ray analysis (EDX). Vickers hardness was used as criteria to determine the diffusion zone thickness and the boundary to the steel base.
介绍了aisi430不锈钢样品的等离子渗氮试验结果。在脉冲偏置模式、重复频率为50 kHz的Bulat型装置中,在空心阳极非自燃气体放电氮等离子体中进行了氮化过程。通过x射线衍射(XRD)分析了涂层的相组成。利用扫描电子显微镜(SEM)监测表面形貌,并用能量色散x射线分析(EDX)检测化学成分。采用维氏硬度作为判定扩散区厚度和与钢基体边界的标准。
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引用次数: 0
Formation of Nanoparticles and Polymer Films in RF Gas-Discharge Plasma in Acetylene 乙炔中射频气体放电等离子体中纳米粒子和聚合物薄膜的形成
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568603
V. Lisovskiy, S. Dudin, A. Minenkov, S. Bogatyrenko, P. Platonov
The aim of this work was to study nanoparticles that are formed in the plasma volume of a radio-frequency capacitive discharge in acetylene. The particles partially penetrate into the polymer film on the electrodes, and partially increase in size, and then fall on the tube wall. It is shown that even when deposited on vertically located electrodes, the polymer film contains nanoparticles with diameter of about 10 nm. In the plasma volume, nanoparticles can grow up to several hundred nanometers in diameter and then fall on the wall of the discharge tube. An analysis of the emission spectra showed that only hydrogen lines and a weak CH band (431 nm) are observed in a burning rf discharge in acetylene. A polymer film deposited on the tube wall effectively absorbs radiation lines in the blue part of the spectrum, while lines in the red and infrared parts of the spectrum are weakly absorbed.
这项工作的目的是研究在乙炔中射频电容放电的等离子体体积中形成的纳米颗粒。颗粒部分渗透到电极上的聚合物膜中,部分尺寸增大,然后落在管壁上。结果表明,即使沉积在垂直位置的电极上,聚合物薄膜也含有直径约为10纳米的纳米颗粒。在等离子体体积中,纳米颗粒的直径可以长到几百纳米,然后落在放电管的壁上。发射光谱分析表明,在乙炔燃烧的射频放电中,只观察到氢谱线和弱CH波段(431 nm)。沉积在管壁上的聚合物薄膜有效地吸收光谱蓝色部分的辐射线,而光谱红色和红外部分的线则被弱吸收。
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引用次数: 1
期刊
2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)
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