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2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)最新文献

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Orthovanadate-Based Nanoparticles: Differences in Functional Activity of Cancer and Hematopoietic Stem Cells 基于正钒酸盐的纳米颗粒:癌症和造血干细胞功能活性的差异
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568604
A. Goltsev, N. Babenko, M. Bondarovych, T. Dubrava, Yuliia Gaevska, V. Klochkov
This research comparatively studies the influence of different concentrations of spherical gadolinium-yttrium orthovanadate nanoparticles (GdYEuVO4) on a functional potential of Ehrlich carcinoma cancer and hematopoietic stem cells of healthy animals. Confocal microscopy data indicate the ability of nanoparticles at a concentration of 0.87 and 1.3 g / L to visualize the cells of tumor and those of healthy bone marrow; however, the intensity of their accumulation in myelokaryocytes was significantly lower than in Ehrlich carcinoma cells. It was shown that nanoparticles in both concentrations had the ability to inhibit the functional potential of both transformed and hematopoietic stem cells, but in the latter this was observed to a much lesser extent. Nanoparticles at a concentration of 1.3 g / L maximally reduced the metabolic activity of Ehrlich carcinoma cells and promoted an inhibition of tumor growth, while slightly altering the functional potential of hematopoietic stem cells.
本研究比较研究了不同浓度的球形钒酸钆钇纳米颗粒(gdyuvo4)对健康动物埃利希癌和造血干细胞功能电位的影响。共聚焦显微镜数据表明,浓度分别为0.87和1.3 g / L的纳米颗粒能够显示肿瘤细胞和健康骨髓细胞;然而,它们在骨髓细胞中的积累强度明显低于在埃利希癌细胞中的积累强度。研究表明,两种浓度的纳米颗粒都有抑制转化干细胞和造血干细胞功能潜能的能力,但在造血干细胞中,这种抑制程度要小得多。浓度为1.3 g / L的纳米颗粒最大限度地降低了埃利希癌细胞的代谢活性,促进了肿瘤生长的抑制,同时轻微改变了造血干细胞的功能潜能。
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引用次数: 0
LSPR Tuning by Variable Morphology of Gold Nanoshells 金纳米壳的可变形貌LSPR调谐
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568515
P. Demydov, V. Lytvyn, A. Lopatynskyi, I. I. Hudzenko, V. Chegel
In this work, a complex time resolved study of gold nanoshell synthesis using silver-gold galvanic replacement reaction was carried out. Sequential extraction of the synthesis fragments on each stage of the nanoshells preparation allowed us to obtain a series of nanostructures, each one with its own unique geometrical and optical properties. Nanostructures that were isolated on the initial synthesis stages are mostly bimetallic spherical formations, which transform into solid nanoshells on the last stage of the reaction and further into spheroidal assemblies of separate nanostructures. Step by step research of nanostructures at each stage shows the ability of smooth LSPR spectrum nano tuning in the range from 400 to 720 nm.
本文对银-金电取代反应合成金纳米壳进行了复杂时间分辨研究。在纳米壳制备的每个阶段对合成片段进行顺序提取,使我们能够获得一系列纳米结构,每个纳米结构都具有自己独特的几何和光学性质。在初始合成阶段分离的纳米结构大多为双金属球形结构,在反应的最后阶段转变为固体纳米壳,并进一步转变为独立纳米结构的球形组装体。对每个阶段的纳米结构的逐步研究表明,LSPR光谱在400 ~ 720 nm范围内具有平滑的纳米调谐能力。
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引用次数: 0
Effect of Ion Bombardment and Deposition Temperature on Intrinsic Stress and Growth Rate of DLC 离子轰击和沉积温度对DLC本征应力和生长速率的影响
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568620
A. Kalinichenko, V. Strel’nitskij
Within the framework of the model of the nonlocal thermoelastic peak of the low-energy ion, the formation of intrinsic stress in the DLC deposited from the flow of $C^{+}$ ions of the filtered vacuum arc plasma is theoretically investigated. The dependence of intrinsic stress on the bias potential is determined at different deposition temperatures for the cases of constant and pulse potentials. It is shown that in both cases considered, the stresses decrease with the increase in the deposition temperature. The influence of the filling parameter in the mode of pulse potential on the behavior of intrinsic stresses at different bias potentials is investigated. The results of calculation the sputtering coefficients of the DLC depending on the potential at different angles of incidence of ions are presented. The influence of the sputtering process on the growth rate of DLC in the cases of DC-mode and mode of pulse potential is analyzed.
在低能离子非局域热弹性峰模型的框架下,从理论上研究了过滤后的真空电弧等离子体中$C^{+}$离子流动沉积DLC中本征应力的形成。在恒定电位和脉冲电位情况下,测定了不同沉积温度下的本征应力对偏置电位的依赖关系。结果表明,在这两种情况下,应力随沉积温度的升高而减小。研究了脉冲电位模式下填充参数对不同偏置电位下本征应力行为的影响。给出了不同离子入射角下DLC溅射系数随电势变化的计算结果。分析了在直流模式和脉冲电位模式下溅射工艺对DLC生长速率的影响。
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引用次数: 0
Ti6Al4V Scaffolds with Alkali Activated Surfaces for Tissue Engineering 组织工程用碱活化表面Ti6Al4V支架
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568619
Y. Husak, Kateryna Zaitseva, A. Turlybekuly, K. Diedkova, M. Sliusarenko, Illya Yanko, S. Kyrylenko, A. Pogrebnjak, W. Simka, M. Pogorielov
Osteocompatibility of orthopedic implants can be enhanced by surface bioactivation and by providing biomimetic architecture. Selective laser melting (SLM) is used to produce scaffold materials with ameliorated topology to meet the requirements of the load-bearing function of a bone tissue. Both macro- and micro levels were considered to achieve these goals. Mineralization of the implant surfaces improves cell attachment and spreading. Treatment of Ti6Al4V implant with sodium hydroxide resulted in a titanate surface layer with well-developed nanostructure. Additional surface treatment can be used to improve the biological properties of the SLM-fabricated porous scaffolds.
骨科植入物的骨相容性可以通过表面生物活化和提供仿生结构来增强。为了满足骨组织承载功能的要求,采用选择性激光熔化(SLM)技术制备了拓扑结构改进的支架材料。为实现这些目标,从宏观和微观两个层面进行了考虑。种植体表面的矿化改善了细胞的附着和扩散。用氢氧化钠处理Ti6Al4V植入体后,钛酸盐表面层具有良好的纳米结构。附加的表面处理可用于改善slm制备的多孔支架的生物学性能。
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引用次数: 0
Modified Polypropylene Fibrous Nonwoven Materials 改性聚丙烯纤维非织造材料
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568574
K. Avdeeva, A. Shumskaya, Zh. B. Ignatovich, A. Rogachev, V. Agabekov, M. Yarmolenko, Aleksey Mikhalko, Nataliya Dudchik, A. Oleynik
Polymer nonwoven materials based on polypropylene are the basis for the creation of protective medical masks. Modification of the filter layers has been performed by electron-beam deposition from the active gas phase formed by the electron-beam dispersion of PTFE. The filtration efficiency was investigated by two indicators: the PFE with a diameter of 2.5 $mu$m (PM2.5), BFE in accordance with GOST R 58396-2019 for three-layer combinations of nonwovens, the inner layer of which had a modified coating. An increase in the filtration efficiency for both indicators was observed for all samples, which is associated with physicochemical changes of the surface of the active layer.
以聚丙烯为基础的高分子非织造材料是制造防护医用口罩的基础。利用聚四氟乙烯的电子束色散形成的活性气相进行电子束沉积,对滤层进行了改性。通过两项指标考察过滤效率:直径为2.5 μ m (PM2.5)的PFE和符合GOST R 58396-2019的三层非织造布组合的BFE,内层有改性涂层。两种指标的过滤效率在所有样品中都有所提高,这与活性层表面的物理化学变化有关。
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引用次数: 0
Regularities of Obtaining Silver Nanoparticles in the Presence of Polyvinylpyrrolidone 聚乙烯吡咯烷酮存在下制备纳米银的规律
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568511
G. Dudok, N. Semenyuk, Kh. V. Kysil, I. Ilkiv, V. Skorokhoda
The influence of technological factors on the regularities of obtaining silver nanoparticles using polyvinylpyrrolidone as a reducing agent and stabilizer has been studied. The chemistry of the reaction of silver obtaining by the reduction reaction with polyvinylpyrrolidone has been proposed. The mechanism of chemical reaction of silver nanoparticles obtaining in the presence of polyvinylpyrrolidone has been proposed. The formation of silver nanoparticles was confirmed by UV spectroscopy and transmission electron microscopy. The effect of temperature, ratio and reagents concentration on the kinetics of silver ions reduction has been established. Particles with a smaller diameter are formed in the case of the use of PVP with a higher molecular weight. Silver-containing composites in the form of porous blocks and films were synthesized and their antibacterial and antifungal properties were investigated. Developed porous composites are recommended to be used in medicine as osteoplastic to replace damaged bone tissue.
研究了工艺因素对以聚乙烯吡咯烷酮为还原剂和稳定剂制备纳米银的规律的影响。提出了聚乙烯吡咯烷酮还原制银反应的化学性质。提出了在聚乙烯吡咯烷酮存在下制备纳米银的化学反应机理。通过紫外光谱和透射电镜证实了银纳米颗粒的形成。确定了温度、配比和试剂浓度对银离子还原动力学的影响。在使用分子量较高的PVP的情况下,形成直径较小的颗粒。合成了多孔块和薄膜形式的含银复合材料,并对其抗菌和抗真菌性能进行了研究。开发的多孔复合材料被推荐用于医学上作为骨成形术来替代受损的骨组织。
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引用次数: 2
Quantization Conductivity of Surface Electrons over Superfluid Helium at the Charged Substrate Channels 超流氦表面电子在带电衬底通道上的量子化电导率
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568517
V. A. Nikolaenko, A. Smorodin, S. Sokolov
The carry features of a quasi-one-dimensional surface electrons (Q1D-SEs) over the superfluid helium at the charged profiled substrate is investigated by the transport method. Substrate is row the optical fiber segments. The experiments carried out in temperature range 1.5 K-0.6 K at electron densities up to 109 cm-2. According a phase diagram “electron gas - Wigner crystal” research performed in the electron gas region at temperature higher the Fermi energy and at electron density far “quantum melting». The substrate electrostatic model in the electric field demonstrates the potential modulation in the cross section lets to charge the fiber tops increasing thereby the Q1D-SE potential well. The surface electrons motion satisfies the quantization condition in view both the temperature and the electron relaxation time. Lower of some temperature the conductivity is a steps-like and it differential is a peaks-like simile to the electron states density with the peak distance according energy spectrum. Pronounced steps at lowering temperature can be caused the electron density redistribution on the energy levels and the SEs thermo-activation motion near the channel bounders.
用输运方法研究了准一维表面电子(q1d - se)在带电型衬底超流氦上的携带特性。衬底是排在光纤段的。实验在1.5 K-0.6 K温度范围内进行,电子密度高达109 cm-2。根据相图“电子气-维格纳晶体”的研究,在温度高于费米能量的电子气区和电子密度远为“量子熔化”的电子气区进行了研究。电场中的衬底静电模型表明,截面上的电位调制使光纤顶部带电,从而增加了Q1D-SE电位。考虑到温度和电子弛豫时间,表面电子运动满足量子化条件。在某一温度较低时,电导率呈阶梯状,其差值与电子态密度呈峰状,随能谱的峰距而变化。降低温度的显著步骤可引起电子密度在能级上的重新分布和通道边界附近的SEs热活化运动。
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引用次数: 0
Electrodeposition of Binary and Ternary Rhenium Alloys 二、三元铼合金的电沉积
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568569
Yu. S. Yapontseva, T. Maltseva, V. Kublanovsky
This work presents a comparative analysis of the chemical and phase composition, current efficiency, and microhardness of binary and ternary electrolytic CoRe and CoWRe alloys, deposited from two types of electrolytes: acidic citrate and alkaline citrate-pyrophosphate ones. It has been shown that the use of electrolytes of various complexes compositions makes it possible to vary the amount of rhenium in the coatings over a wide range (12 – 59 at.%). Ternary CoWRe alloys contain 4 – 9 at.% of tungsten, and they are deposited with higher current efficiency (up to 86%) than binary alloys. By selecting the composition of the electrolyte and the electrolysis mode, it is possible to regulate not only the chemical composition but also the structure of the coatings and to obtain X-ray amorphous or crystalline alloys, depending on the task.
本文比较分析了由酸性柠檬酸盐和碱性柠檬酸盐焦磷酸盐两种电解质沉积的二元和三元电解CoRe和CoRe合金的化学成分、物相组成、电流效率和显微硬度。已经表明,使用各种配合物组成的电解质可以在很宽的范围内(12 - 59at .%)改变涂层中铼的含量。三元core合金含有4 - 9at。它们的电流效率比二元合金高(高达86%)。通过选择电解液的成分和电解方式,不仅可以调节化学成分,还可以调节涂层的结构,并根据任务获得x射线非晶或结晶合金。
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引用次数: 0
Terahertz-Frequency Signal Source Based on an Array of Synchronized Antiferromagnetic Spin Hall Oscillators 基于同步反铁磁自旋霍尔振荡器阵列的太赫兹频率信号源
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568573
Oleh Shtanko, O. Prokopenko
Terahertz-frequency (TF) signals have a great potential for applications in medicine, security, communications, etc., but many of these applications require the development of compact, reliable and rather powerful sources of coherent TF signals, which are able to operate in the absence of cryogenic temperatures, strong bias magnetic fields and large bias voltages. One of the promising types of such sources can be a source utilizing an array of synchronized antiferromagnetic (AFM) spin Hall oscillators (SHOs). In this paper we theoretically and numerically study electrodynamic properties of a TF source based on a high-quality dielectric resonator with embedded current-biased mutually synchronized AFM SHOs, where an AFM layer of each SHO is made of a canted AFM with non-zero net magnetization. Since the location of AFM SHOs inside the resonator has influence on the excitation conditions of resonator’s oscillation modes, we study an impact of AFM SHO array spatial configuration on the performance of considered TF source and find optimum spatial configuration of the SHOs array for different excited E- and H-modes. The obtained results could be important for the development of novel micro- and nano-scale TF signal sources based on antiferromagnets.
太赫兹频率(TF)信号在医学、安全、通信等领域具有巨大的应用潜力,但其中许多应用需要开发紧凑、可靠和相当强大的相干TF信号源,这些信号源能够在没有低温、强偏置磁场和大偏置电压的情况下工作。其中一种很有前途的光源是利用同步反铁磁(AFM)自旋霍尔振荡器(SHOs)阵列的光源。本文从理论上和数值上研究了基于高质量介质谐振器的TF源的电动力学特性,该谐振器内置电流偏置相互同步的AFM SHOs,其中每个SHO的AFM层由非零净磁化的倾斜AFM制成。由于AFM SHO在谐振腔内的位置会影响谐振腔振荡模式的激发条件,因此我们研究了AFM SHO阵列空间构型对所考虑的TF源性能的影响,并找到了不同激发E-模式和h -模式下SHOs阵列的最佳空间构型。所得结果对开发基于反铁磁体的新型微纳米级TF信号源具有重要意义。
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引用次数: 0
Comparative Optic Studies of Cobalt-Based Layered Double Hydroxides with Nitrate and Carbonate Anions and CoII/A1III ratio n = 2, 3, 4 含硝酸盐和碳酸盐阴离子的钴基层状双氢氧化物及CoII/A1III比值n = 2,3,4的光学比较研究
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568631
Y. Pashkevich, Vladimir Gnezdiov, D. Vieira, R. Babkin, Irina M. Lukienko, J. Vieira, D. Wulferding, P. Lemmens, A. Salak
The variations of Raman and optic absorption spectra of Co-Al layered double hydroxides (LDH) intercalated with nitrate and carbonate anions have been studied as a function of the $Co^{2+}/A1^{3+}$ ratio. It was revealed from the comparative analysis of the hydrogen bond frequencies in Raman spectra and the phonon repetition lines in optic absorption spectra that the increasing $Co^{2+}/A1^{3+}$ ratio results in an enhancement of the anion exchange ability in nitrate LDH and in a suppression of the ability in carbonate LDH.
研究了Co^{2+}/A1^{3+}$比值对Co- al层状双氢氧化物(LDH)拉曼光谱和光吸收光谱的影响。通过对拉曼光谱中氢键频率和光吸收光谱中声子重复谱的对比分析发现,增大$Co^{2+}/A1^{3+}$比值,硝酸LDH中的阴离子交换能力增强,而碳酸盐LDH中的阴离子交换能力受到抑制。
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引用次数: 0
期刊
2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)
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