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Types, composition and diagenetic evolution of authigenic clay minerals in argillaceous limestone of sepiolite-bearing strata: A case study of Mao-1 Member of Middle Permian Maokou Formation, eastern Sichuan Basin, SW China 含海泡石地层霰粒灰岩中自生粘土矿物的类型、组成和成岩演化:中国西南部四川盆地东部中二叠统茅口组茅-1层的个案研究
Q1 ENERGY & FUELS Pub Date : 2024-04-01 DOI: 10.1016/S1876-3804(24)60028-5
Jinmin SONG , Jiarui WANG , Shugen LIU , Zhiwu LI , Ping LUO , Qingchun JIANG , Xin JIN , Di YANG , Shipeng HUANG , Jianping FAN , Yuehao YE , Junke WANG , Haoshuang DENG , Bin WANG , Jiaxin GUO
<div><p>The types, occurrence and composition of authigenic clay minerals in argillaceous limestone of sepiolite-bearing strata of the first member of the Middle Permian Maokou Formation (Mao-1 Member) in eastern Sichuan Basin were investigated through outcrop section measurement, core observation, thin section identification, argon ion polishing, X-ray diffraction, scanning electron microscope, energy spectrum analysis and laser ablation-inductively coupled plasma-mass spectrometry. The diagenetic evolution sequence of clay minerals was clarified, and the sedimentary-diagenetic evolution model of clay minerals was established. The results show that authigenic sepiolite minerals were precipitated in the Si<sup>4+</sup> and Mg<sup>2+</sup>-rich cool aragonite sea and sepiolite-bearing strata were formed in the Mao-1 Member. During burial diagenesis, authigenic clay minerals undergo two possible evolution sequences. First, from the early diagenetic stage A to the middle diagenetic stage A<sub>1</sub>, the sepiolite kept stable in the shallow-buried environment lack of Al<sup>3+</sup>. It began to transform into stevensite in the middle diagenetic stage A<sub>2</sub>, and then evolved into disordered talc in the middle diagenetic stage B<sub>1</sub> and finally into talc in the period from the middle diagenetic stage B<sub>2</sub> to the late diagenetic stage. Thus, the primary diagenetic evolution sequence of authigenic clay minerals, i.e. sepiolite–stevensite–disordered talc–talc, was formed in the Mao-1 Member. Second, in the early diagenetic stage A, as Al<sup>3+</sup> carried by the storm and upwelling currents was involved in the diagenetic process, trace of sepiolite started to evolve into smectite, and a part of smectite turned into chlorite. From the early diagenetic stage B to the middle diagenesis stage A<sub>1</sub>, a part of smectite evolved to illite/smectite mixed layer (I/S). The I/S evolved initially into illite from the middle diagenesis stage A<sub>2</sub> to the middle diagenesis stage B<sub>2</sub>, and then totally into illite in the late diagenesis stage. Thus, the secondary diagenetic evolution sequence of authigenic clay minerals, i.e. sepiolite–smectite–chlorite/illite, was formed in the Mao-1 Member. The types and evolution of authigenic clay minerals in argillaceous limestone of sepiolite-bearing strata are significant for petroleum geology in two aspects. First, sepiolite can adsorb and accumulate a large amount of organic matters, thereby effectively improving the quality and hydrocarbon generation potential of the source rocks of the Mao-1 Member. Second, the evolution from sepiolite to talc is accompanied by the formation of numerous organic matter pores and clay shrinkage pores/fractures, as well as the releasing of the Mg<sup>2+</sup>-rich diagenetic fluid, which allows for the dolomitization of limestone within or around the sag. As a result, the new assemblages of self-generation and self-accumulation, and lower/
通过外露剖面测量、岩心观察、薄片鉴定、氩离子抛光、X射线衍射、扫描电镜、能谱分析和激光烧蚀-电感耦合等离子体质谱等手段,研究了四川盆地东部中二叠统茅口组(茅-1组)含绢云母地层中箭石灰岩自生粘土矿物的类型、发生和组成。明确了粘土矿物的成因演化序列,建立了粘土矿物的沉积-成因演化模型。结果表明,自生海泡石矿物是在富含Si4+和Mg2+的冷文石海中沉淀的,含海泡石地层形成于毛-1组。在埋藏成因过程中,自生粘土矿物可能经历两个演化序列。首先,从早期成因阶段 A 到中期成因阶段 A1,海泡石在缺乏 Al3+ 的浅埋环境中保持稳定。在成岩中期 A2 阶段,它开始转变为铁闪石,然后在成岩中期 B1 阶段演变为无序滑石,最后在成岩中期 B2 阶段至成岩晚期演变为滑石。因此,自生粘土矿物的主要成因演化序列,即海泡石-闪长岩-无序滑石-滑石,是在毛-1 成员中形成的。其次,在成岩早期 A 阶段,由于风暴潮和上升流携带的 Al3+ 参与了成岩过程,微量的海泡石开始演化为闪长岩,部分闪长岩转化为绿泥石。从早期成因阶段 B 到中期成因阶段 A1,部分直闪石演化为伊利石/直闪石混合层(I/S)。从成岩中期 A2 到成岩中期 B2,I/S 初步演化为伊利石,然后在成岩晚期完全演化为伊利石。因此,自生粘土矿物的次生成因演化序列,即海泡石-直闪石-绿泥石/伊利石,是在毛-1 成员中形成的。含海泡石地层的霰石灰岩中自生粘土矿物的类型和演化在两个方面对石油地质具有重要意义。首先,海泡石可吸附和积聚大量有机质,从而有效地提高毛一构造源岩的质量和生烃潜力。其次,从海泡石到滑石的演化过程中,伴随着大量有机质孔隙和粘土收缩孔隙/裂隙的形成,以及富含 Mg2+ 的成岩流体的释放,使弧坑内部或周围的石灰岩白云石化。因此,在中二叠世形成了自生与自积、下/侧源与上/侧储层的新组合,提高了油气积累效率。
{"title":"Types, composition and diagenetic evolution of authigenic clay minerals in argillaceous limestone of sepiolite-bearing strata: A case study of Mao-1 Member of Middle Permian Maokou Formation, eastern Sichuan Basin, SW China","authors":"Jinmin SONG ,&nbsp;Jiarui WANG ,&nbsp;Shugen LIU ,&nbsp;Zhiwu LI ,&nbsp;Ping LUO ,&nbsp;Qingchun JIANG ,&nbsp;Xin JIN ,&nbsp;Di YANG ,&nbsp;Shipeng HUANG ,&nbsp;Jianping FAN ,&nbsp;Yuehao YE ,&nbsp;Junke WANG ,&nbsp;Haoshuang DENG ,&nbsp;Bin WANG ,&nbsp;Jiaxin GUO","doi":"10.1016/S1876-3804(24)60028-5","DOIUrl":"https://doi.org/10.1016/S1876-3804(24)60028-5","url":null,"abstract":"&lt;div&gt;&lt;p&gt;The types, occurrence and composition of authigenic clay minerals in argillaceous limestone of sepiolite-bearing strata of the first member of the Middle Permian Maokou Formation (Mao-1 Member) in eastern Sichuan Basin were investigated through outcrop section measurement, core observation, thin section identification, argon ion polishing, X-ray diffraction, scanning electron microscope, energy spectrum analysis and laser ablation-inductively coupled plasma-mass spectrometry. The diagenetic evolution sequence of clay minerals was clarified, and the sedimentary-diagenetic evolution model of clay minerals was established. The results show that authigenic sepiolite minerals were precipitated in the Si&lt;sup&gt;4+&lt;/sup&gt; and Mg&lt;sup&gt;2+&lt;/sup&gt;-rich cool aragonite sea and sepiolite-bearing strata were formed in the Mao-1 Member. During burial diagenesis, authigenic clay minerals undergo two possible evolution sequences. First, from the early diagenetic stage A to the middle diagenetic stage A&lt;sub&gt;1&lt;/sub&gt;, the sepiolite kept stable in the shallow-buried environment lack of Al&lt;sup&gt;3+&lt;/sup&gt;. It began to transform into stevensite in the middle diagenetic stage A&lt;sub&gt;2&lt;/sub&gt;, and then evolved into disordered talc in the middle diagenetic stage B&lt;sub&gt;1&lt;/sub&gt; and finally into talc in the period from the middle diagenetic stage B&lt;sub&gt;2&lt;/sub&gt; to the late diagenetic stage. Thus, the primary diagenetic evolution sequence of authigenic clay minerals, i.e. sepiolite–stevensite–disordered talc–talc, was formed in the Mao-1 Member. Second, in the early diagenetic stage A, as Al&lt;sup&gt;3+&lt;/sup&gt; carried by the storm and upwelling currents was involved in the diagenetic process, trace of sepiolite started to evolve into smectite, and a part of smectite turned into chlorite. From the early diagenetic stage B to the middle diagenesis stage A&lt;sub&gt;1&lt;/sub&gt;, a part of smectite evolved to illite/smectite mixed layer (I/S). The I/S evolved initially into illite from the middle diagenesis stage A&lt;sub&gt;2&lt;/sub&gt; to the middle diagenesis stage B&lt;sub&gt;2&lt;/sub&gt;, and then totally into illite in the late diagenesis stage. Thus, the secondary diagenetic evolution sequence of authigenic clay minerals, i.e. sepiolite–smectite–chlorite/illite, was formed in the Mao-1 Member. The types and evolution of authigenic clay minerals in argillaceous limestone of sepiolite-bearing strata are significant for petroleum geology in two aspects. First, sepiolite can adsorb and accumulate a large amount of organic matters, thereby effectively improving the quality and hydrocarbon generation potential of the source rocks of the Mao-1 Member. Second, the evolution from sepiolite to talc is accompanied by the formation of numerous organic matter pores and clay shrinkage pores/fractures, as well as the releasing of the Mg&lt;sup&gt;2+&lt;/sup&gt;-rich diagenetic fluid, which allows for the dolomitization of limestone within or around the sag. As a result, the new assemblages of self-generation and self-accumulation, and lower/","PeriodicalId":67426,"journal":{"name":"Petroleum Exploration and Development","volume":"51 2","pages":"Pages 351-363"},"PeriodicalIF":0.0,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1876380424600285/pdf?md5=00cecc328fe9e197b2dffc7aa52d9f71&pid=1-s2.0-S1876380424600285-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140557501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Formation damage mechanism and control strategy of the compound function of drilling fluid and fracturing fluid in shale reservoirs 页岩储层中钻井液与压裂液复合功能的地层破坏机理及控制策略
Q1 ENERGY & FUELS Pub Date : 2024-04-01 DOI: 10.1016/S1876-3804(24)60034-0
Jinsheng SUN , Chengyuan XU , Yili KANG , Haoran JING , Jie ZHANG , Bin YANG , Lijun YOU , Hanshi ZHANG , Yifu LONG

For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid, the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture extension due to shale minerals erosion by oil-based drilling fluid. With the evaluation for the damage of natural and hydraulic fractures caused by mechanical properties weakening of shale fracture surface, fracture closure and rock powder blocking, the formation damage pattern is proposed with consideration of the compound effect of drilling fluid and fracturing fluid. The formation damage mechanism during drilling and completion process in shale reservoir is revealed, and the protection measures are raised. The drilling fluid can deeply invade into the shale formation through natural and induced fractures, erode shale minerals and weaken the mechanical properties of shale during the drilling process. In the process of hydraulic fracturing, the compound effect of drilling fluid and fracturing fluid further weakens the mechanical properties of shale, results in fracture closure and rock powder shedding, and thus induces stress-sensitive damage and solid blocking damage of natural/hydraulic fractures. The damage can yield significant conductivity decrease of fractures, and restrict the high and stable production of shale oil and gas wells. The measures of anti-collapse and anti-blocking to accelerate the drilling of reservoir section, forming chemical membrane to prevent the weakening of the mechanical properties of shale fracture surface, strengthening the plugging of shale fracture and reducing the invasion range of drilling fluid, optimizing fracturing fluid system to protect fracture conductivity are put forward for reservoir protection.

针对钻井液和压裂液复合作用引起的地层破坏分析,考虑油基钻井液对页岩矿物侵蚀引起的裂缝扩展,建立了钻井液动态侵入深度预测方法。通过对页岩裂缝表面力学性能减弱、裂缝闭合和岩粉堵塞引起的天然裂缝和水力裂缝破坏的评价,提出了考虑钻井液和压裂液复合作用的地层破坏模式。揭示了页岩储层钻完井过程中的地层破坏机理,并提出了保护措施。钻井过程中,钻井液可通过天然裂缝和诱导裂缝深入页岩层,侵蚀页岩矿物,削弱页岩力学性能。在水力压裂过程中,钻井液和压裂液的复合作用会进一步削弱页岩的力学性能,导致裂缝闭合和岩粉脱落,从而诱发天然/水力裂缝的应力敏感性破坏和固体堵塞破坏。这种破坏会导致裂缝的导电性明显降低,制约页岩油气井的高产稳产。为保护储层,提出了防塌防堵加快储层段钻进、形成化学膜防止页岩裂缝表面力学性能减弱、加强页岩裂缝封堵减小钻井液侵入范围、优化压裂液体系保护裂缝导电性等措施。
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引用次数: 0
Extreme massive hydraulic fracturing in deep coalbed methane horizontal wells: A case study of the Linxing Block, eastern Ordos Basin, NW China 深层煤层气水平井中的极端大规模水力压裂:中国西北部鄂尔多斯盆地东部林兴区块案例研究
Q1 ENERGY & FUELS Pub Date : 2024-04-01 DOI: 10.1016/S1876-3804(24)60035-2
Fan YANG , Bin LI , Kunjian WANG , Heng WEN , Ruiyue YANG , Zhongwei HUANG

Deep coal seams show low permeability, low elastic modulus, high Poisson’s ratio, strong plasticity, high fracture initiation pressure, difficulty in fracture extension, and difficulty in proppants addition. We proposed the concept of large-scale stimulation by fracture network, balanced propagation and effective support of fracture network in fracturing design and developed the extreme massive hydraulic fracturing technique for deep coalbed methane (CBM) horizontal wells. This technique involves massive injection with high pumping rate + high-intensity proppant injection + perforation with equal apertures and limited flow + temporary plugging and diverting fractures + slick water with integrated variable viscosity + graded proppants with multiple sizes. The technique was applied in the pioneering test of a multi-stage fracturing horizontal well in deep CBM of Linxing Block, eastern margin of the Ordos Basin. The injection flow rate is 18 m3/min, proppant intensity is 2.1 m3/m, and fracturing fluid intensity is 16.5 m3/m. After fracturing, a complex fracture network was formed, with an average fracture length of 205 m. The stimulated reservoir volume was 1 987×104 m3, and the peak gas production rate reached 6.0×104 m3/d, which achieved efficient development of deep CBM.

深部煤层具有渗透率低、弹性模量低、泊松比高、塑性强、压裂起始压力高、压裂扩展困难、支撑剂添加困难等特点。在压裂设计中,我们提出了压裂网络大规模增产、压裂网络均衡传播和有效支撑的概念,并开发了深层煤层气(CBM)水平井极大规模水力压裂技术。该技术包括高抽速大规模注浆+高强度支撑剂注入+等孔限流射孔+临时堵塞和分流裂缝+综合粘度可变的滑水+多种规格的分级支撑剂。该技术在鄂尔多斯盆地东缘林兴区块深层煤层气多级压裂水平井中进行了开创性试验。注入流量为 18 m3/min,支撑剂强度为 2.1 m3/m,压裂液强度为 16.5 m3/m。压裂后形成了复杂的裂缝网络,平均裂缝长度为 205 m,激发储层体积为 1 987×104 m3,产气峰值达到 6.0×104 m3/d,实现了深层煤层气的高效开发。
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引用次数: 0
Geological characteristics and exploration breakthroughs of coal rock gas in Carboniferous Benxi Formation, Ordos Basin, NW China 中国西北部鄂尔多斯盆地石炭系本溪地层煤岩气地质特征及勘探突破
Q1 ENERGY & FUELS Pub Date : 2024-04-01 DOI: 10.1016/S1876-3804(24)60022-4
Zhe ZHAO , Wanglin XU , Zhenyu ZHAO , Shiwei YI , Wei YANG , Yueqiao ZHANG , Yuanshi SUN , Weibo ZHAO , Yunhe SHI , Chunlin ZHANG , Jianrong GAO
<div><p>To explore the geological characteristics and exploration potential of the Carboniferous Benxi Formation coal rock gas in the Ordos Basin, this paper presents a systematic research on the coal rock distribution, coal rock reservoirs, coal rock quality, and coal rock gas features, resources and enrichment. Coal rock gas is a high-quality resource distinct from coalbed methane, and it has unique features in terms of burial depth, gas source, reservoir, gas content, and carbon isotopic composition. The Benxi Formation coal rocks cover an area of 16×10<sup>4</sup> km², with thicknesses ranging from 2 m to 25 m, primarily consisting of bright and semi-bright coals with primitive structures and low volatile and ash contents, indicating a good coal quality. The medium-to-high rank coal rocks have the total organic carbon (TOC) content ranging from 33.49% to 86.11%, averaging 75.16%. They have a high degree of thermal evolution (<em>R</em><sub>o</sub> of 1.2%–2.8%), and a high gas-generating capacity. They also have high stable carbon isotopic values (<em>δ</em><sup>13</sup>C<sub>1</sub> of –37.6‰ to –16‰; <em>δ</em><sup>13</sup>C<sub>2</sub> of –21.7‰ to –14.3‰). Deep coal rocks develop matrix pores such as gas bubble pores, organic pores, and inorganic mineral pores, which, together with cleats and fractures, form good reservoir spaces. The coal rock reservoirs exhibit the porosity of 0.54%–10.67% (averaging 5.42%) and the permeability of (0.001–14.600)×10<sup>−3</sup> μm<sup>2</sup> (averaging 2.32×10<sup>−3</sup> μm<sup>2</sup>). Vertically, there are five types of coal rock gas accumulation and dissipation combinations, among which the coal rock-mudstone gas accumulation combination and the coal rock-limestone gas accumulation combination are the most important, with good sealing conditions and high peak values of total hydrocarbon in gas logging. A model of coal rock gas accumulation has been constructed, which includes widespread distribution of medium-to-high rank coal rocks continually generating gas, matrix pores and cleats/fractures in coal rocks acting as large-scale reservoir spaces, tight cap rocks providing sealing, source-reservoir integration, and five types of efficient enrichment patterns (lateral pinchout complex, lenses, low-amplitude structures, nose-like structures, and lithologically self-sealing). According to the geological characteristics of coal rock gas, the Benxi Formation is divided into 8 plays, and the estimated coal rock gas resources with a buried depth of more than 2 000 m are more than 12.33×10<sup>12</sup> m<sup>3</sup>. The above understandings guide the deployment of risk exploration. Two wells drilled accordingly obtained an industrial gas flow, driving the further deployment of exploratory and appraisal wells. Substantial breakthroughs have been achieved, with the possible reserves over a trillion cubic meters and the proved reserves over a hundred billion cubic meters, which is of great significance for
为探索鄂尔多斯盆地石炭系本溪地层煤岩气的地质特征和勘探潜力,本文对鄂尔多斯盆地煤岩分布、煤岩储层、煤岩质量以及煤岩气特征、资源量和富集程度进行了系统研究。煤岩气是一种有别于煤层气的优质资源,在埋藏深度、气源、储层、含气量、碳同位素组成等方面具有独特的特征。本溪地层煤岩面积 16×104 平方公里,厚度 2 米至 25 米不等,主要由明亮和半明亮煤组成,结构原始,挥发分和灰分含量低,煤质较好。中高级煤岩的总有机碳(TOC)含量在 33.49% 至 86.11% 之间,平均为 75.16%。它们具有较高的热演化程度(Ro 为 1.2%-2.8%)和较高的瓦斯生成能力。它们还具有较高的稳定碳同位素值(δ13C1 为-37.6‰至-16‰;δ13C2 为-21.7‰至-14.3‰)。深部煤岩发育有基质孔隙,如气泡孔隙、有机孔隙和无机矿物孔隙,这些孔隙与裂隙和断裂共同构成良好的储层空间。煤岩储层的孔隙度为 0.54%-10.67%(平均为 5.42%),渗透率为 (0.001-14.600)×10-3 μm2(平均为 2.32×10-3 μm2)。纵向上有五种煤岩瓦斯积聚消散组合,其中以煤岩-泥岩瓦斯积聚组合和煤岩-石灰岩瓦斯积聚组合最为重要,封孔条件好,瓦斯测井总烃峰值高。构建了煤岩瓦斯积聚模型,包括广泛分布的持续产气的中高等级煤岩、作为大型储层空间的基质孔隙和煤岩裂隙/断裂、提供密封性的致密盖岩、源储一体化以及五种高效富集模式(侧向挤压复合、透镜状、低振幅构造、鼻状构造和岩性自密封)。根据煤岩气的地质特征,将本溪地层划分为 8 个演替,估算埋深大于 2 000 米的煤岩气资源量大于 12.33×1012 立方米。在上述认识的指导下,部署了风险勘探工作。据此钻探的两口井获得了工业气流,推动了探井和评价井的进一步部署。取得了可能储量过万亿立方米、探明储量过千亿立方米的实质性突破,对我国天然气增储和高效开发具有重要意义。
{"title":"Geological characteristics and exploration breakthroughs of coal rock gas in Carboniferous Benxi Formation, Ordos Basin, NW China","authors":"Zhe ZHAO ,&nbsp;Wanglin XU ,&nbsp;Zhenyu ZHAO ,&nbsp;Shiwei YI ,&nbsp;Wei YANG ,&nbsp;Yueqiao ZHANG ,&nbsp;Yuanshi SUN ,&nbsp;Weibo ZHAO ,&nbsp;Yunhe SHI ,&nbsp;Chunlin ZHANG ,&nbsp;Jianrong GAO","doi":"10.1016/S1876-3804(24)60022-4","DOIUrl":"https://doi.org/10.1016/S1876-3804(24)60022-4","url":null,"abstract":"&lt;div&gt;&lt;p&gt;To explore the geological characteristics and exploration potential of the Carboniferous Benxi Formation coal rock gas in the Ordos Basin, this paper presents a systematic research on the coal rock distribution, coal rock reservoirs, coal rock quality, and coal rock gas features, resources and enrichment. Coal rock gas is a high-quality resource distinct from coalbed methane, and it has unique features in terms of burial depth, gas source, reservoir, gas content, and carbon isotopic composition. The Benxi Formation coal rocks cover an area of 16×10&lt;sup&gt;4&lt;/sup&gt; km², with thicknesses ranging from 2 m to 25 m, primarily consisting of bright and semi-bright coals with primitive structures and low volatile and ash contents, indicating a good coal quality. The medium-to-high rank coal rocks have the total organic carbon (TOC) content ranging from 33.49% to 86.11%, averaging 75.16%. They have a high degree of thermal evolution (&lt;em&gt;R&lt;/em&gt;&lt;sub&gt;o&lt;/sub&gt; of 1.2%–2.8%), and a high gas-generating capacity. They also have high stable carbon isotopic values (&lt;em&gt;δ&lt;/em&gt;&lt;sup&gt;13&lt;/sup&gt;C&lt;sub&gt;1&lt;/sub&gt; of –37.6‰ to –16‰; &lt;em&gt;δ&lt;/em&gt;&lt;sup&gt;13&lt;/sup&gt;C&lt;sub&gt;2&lt;/sub&gt; of –21.7‰ to –14.3‰). Deep coal rocks develop matrix pores such as gas bubble pores, organic pores, and inorganic mineral pores, which, together with cleats and fractures, form good reservoir spaces. The coal rock reservoirs exhibit the porosity of 0.54%–10.67% (averaging 5.42%) and the permeability of (0.001–14.600)×10&lt;sup&gt;−3&lt;/sup&gt; μm&lt;sup&gt;2&lt;/sup&gt; (averaging 2.32×10&lt;sup&gt;−3&lt;/sup&gt; μm&lt;sup&gt;2&lt;/sup&gt;). Vertically, there are five types of coal rock gas accumulation and dissipation combinations, among which the coal rock-mudstone gas accumulation combination and the coal rock-limestone gas accumulation combination are the most important, with good sealing conditions and high peak values of total hydrocarbon in gas logging. A model of coal rock gas accumulation has been constructed, which includes widespread distribution of medium-to-high rank coal rocks continually generating gas, matrix pores and cleats/fractures in coal rocks acting as large-scale reservoir spaces, tight cap rocks providing sealing, source-reservoir integration, and five types of efficient enrichment patterns (lateral pinchout complex, lenses, low-amplitude structures, nose-like structures, and lithologically self-sealing). According to the geological characteristics of coal rock gas, the Benxi Formation is divided into 8 plays, and the estimated coal rock gas resources with a buried depth of more than 2 000 m are more than 12.33×10&lt;sup&gt;12&lt;/sup&gt; m&lt;sup&gt;3&lt;/sup&gt;. The above understandings guide the deployment of risk exploration. Two wells drilled accordingly obtained an industrial gas flow, driving the further deployment of exploratory and appraisal wells. Substantial breakthroughs have been achieved, with the possible reserves over a trillion cubic meters and the proved reserves over a hundred billion cubic meters, which is of great significance for ","PeriodicalId":67426,"journal":{"name":"Petroleum Exploration and Development","volume":"51 2","pages":"Pages 262-278"},"PeriodicalIF":0.0,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1876380424600224/pdf?md5=960223c0f39abac836cc4b34031678bf&pid=1-s2.0-S1876380424600224-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140557671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experiment of dynamic seepage of tight/shale oil under matrix fracture coupling 基质断裂耦合下致密油/页岩油的动态渗流实验
Q1 ENERGY & FUELS Pub Date : 2024-04-01 DOI: 10.1016/S1876-3804(24)60032-7
Meng DU , Zhengming YANG , Weifeng LYU , Zhongcheng LI , Guofeng WANG , Xinliang CHEN , Xiang QI , Lanlan YAO , Yuhao ZHANG , Ninghong JIA , Haibo LI , Yilin CHANG , Xu HUO

A physical simulation method with a combination of dynamic displacement and imbibition was established by integrating nuclear magnetic resonance (NMR) and CT scanning. The microscopic production mechanism of tight/shale oil in pore throat by dynamic imbibition and the influencing factors on the development effect of dynamic imbibition were analyzed. The dynamic seepage process of fracking–soaking–backflow–production integration was simulated, which reveals the dynamic production characteristics at different development stages and their contribution to enhancing oil recovery (EOR). The seepage of tight/shale reservoirs can be divided into three stages: strong displacement and weak imbibition as oil produced rapidly by displacement from macropores and fractures, weak displacement and strong imbibition as oil produced slowly by reverse imbibition from small pores, and weak displacement and weak imbibition at dynamic equilibrium. The greater displacement pressure results in the higher displacement recovery and the lower imbibition recovery. However, if the displacement pressure is too high, the injected water is easy to break through the front and reduce the recovery degree. The higher the permeability, the greater the imbibition and displacement recovery, the shorter the time of imbibition balance, and the higher the final recovery. The fractures can effectively increase the imbibition contact area between matrix and water, reduce the oil-water seepage resistance, promote the oil-water displacement between matrix and fracture, and improve the oil displacement rate and recovery of the matrix. The soaking after fracturing is beneficial to the imbibition replacement and energy storage of the fluid; also, the effective use of the carrying of the backflow fluid and the displacement in the mining stage is the key to enhancing oil recovery.

结合核磁共振(NMR)和CT扫描,建立了动态位移与浸润相结合的物理模拟方法。分析了孔喉动态浸润致密油/页岩油的微观产油机理及动态浸润开发效果的影响因素。模拟了压裂-浸润-回流-增产一体化的动态渗流过程,揭示了不同开发阶段的动态增产特征及其对提高石油采收率(EOR)的贡献。致密/页岩油藏的渗流可分为三个阶段:由大孔隙和裂缝快速位移产油的强位移、弱浸润阶段;由小孔隙反向浸润缓慢产油的弱位移、强浸润阶段;以及处于动态平衡的弱位移、弱浸润阶段。位移压力越大,位移采收率越高,而浸润采收率越低。但如果位移压力过大,注入水容易突破前沿,降低回收率。渗透率越高,浸润回收率和位移回收率越高,浸润平衡时间越短,最终回收率越高。裂缝能有效增加基质与水的浸润接触面积,降低油水渗流阻力,促进基质与裂缝间的油水位移,提高基质的排油率和采收率。压裂后的浸泡有利于流体的浸润置换和储能;同时,有效利用回流液的携带和开采阶段的位移也是提高采油率的关键。
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引用次数: 0
Development, challenges and strategies of natural gas industry under carbon neutral target in China 碳中和目标下中国天然气产业的发展、挑战与战略
Q1 ENERGY & FUELS Pub Date : 2024-04-01 DOI: 10.1016/S1876-3804(24)60038-8
Caineng ZOU , Minjie LIN , Feng MA , Hanlin LIU , Zhi YANG , Guosheng ZHANG , Yichao YANG , Chunxiao GUAN , Yingbo LIANG , Ying WANG , Bo XIONG , Hao YU , Ping YU

In the mid-21st century, natural gas will enter its golden age, and the era of natural gas is arriving. This paper reviews the development stages of global natural gas industry and the enlightenment of American shale gas revolution, summarizes the development history and achievements of the natural gas industry in China, analyzes the status and challenges of natural gas in the green and low-carbon energy transition, and puts forward the natural gas industry development strategies under carbon neutral target in China. The natural gas industry in China has experienced three periods: start, growth, and leap forward. At present, China has become the fourth largest natural gas producer and third largest natural gas consumer in the world, and has made great achievements in natural gas exploration and development theory and technology, providing important support for the growth of production and reserves. China has set its goal of carbon neutrality to promote green and sustainable development, which brings opportunities and challenges for natural gas industry. Natural gas has significant low-carbon advantages, and gas-electric peak shaving boosts new energy development; the difficulty and cost of development are more prominent. For the national energy security and harmonious development between economy and ecology under the carbon neutral goal, based on the principle of “comprehensive planning, technological innovation, multi-energy complementarity, diversified integration, flexibility and efficiency, optimization and upgrading”, the construction of the production-supply- storage-marketing system has to be improved so as to boost the development of the natural gas industry. First, it is necessary to strengthen efforts in the exploration and development of natural gas, making projects and arrangement in key exploration and development areas, meanwhile, it is urgent to make breakthroughs in key science theories and technologies, so as to increase reserve and production. Second, it should promote green and innovative development of the natural gas by developing new techniques, expanding new fields and integrating with new energy. Third, there is a demand to realize transformation and upgrading of the supply and demand structure of natural gas by strengthening the layout of pipeline gas, liquefied natural gas and the construction of underground gas storage, establishing reserve system for improving abilities of emergency response and adjustment, raising the proportion of natural gas in the primary energy consumption and contributing to the transformation of energy consumption structure, realizing low-carbon resources utilization and clean energy consumption.

21世纪中叶,天然气将进入黄金时代,天然气时代正在到来。本文回顾了全球天然气产业的发展阶段和美国页岩气革命的启示,总结了我国天然气产业的发展历程和成就,分析了天然气在能源绿色低碳转型中的现状和挑战,提出了我国碳中和目标下的天然气产业发展战略。中国天然气产业经历了起步、成长和跨越三个时期。目前,我国已成为世界第四大天然气生产国和第三大天然气消费国,在天然气勘探开发理论和技术方面取得了巨大成就,为产量和储量的增长提供了重要支撑。中国提出 "碳中和 "目标,推动绿色可持续发展,这给天然气产业带来了机遇和挑战。天然气低碳优势明显,气电调峰助推新能源发展,发展难度和成本更加突出。为保障国家能源安全,实现碳中和目标下经济与生态的协调发展,按照 "统筹规划、技术创新、多能互补、多元融合、灵活高效、优化升级 "的原则,完善产供储销体系建设,促进天然气产业发展。一是要加大天然气勘探开发力度,在重点勘探开发领域进行立项和布局,同时亟需突破关键科学理论和技术,实现增储上产。二是要通过开发新技术、拓展新领域、与新能源融合,推动天然气绿色创新发展。三是要通过加强管道气、液化气布局和地下储气库建设,实现天然气供需结构转型升级,建立提高应急和调节能力的储备体系,提高天然气在一次能源消费中的比重,促进能源消费结构转型,实现资源利用低碳化和能源消费清洁化。
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引用次数: 0
Tracing of natural gas migration by light hydrocarbons: A case study of the Dongsheng gas field in the Ordos Basin, NW China 轻烃对天然气迁移的追踪:中国西北部鄂尔多斯盆地东胜气田案例研究
Q1 ENERGY & FUELS Pub Date : 2024-04-01 DOI: 10.1016/S1876-3804(24)60025-X
Xiaoqi WU , Chunhua NI , Liangbang MA , Fubin WANG , Huichong JIA , Ping WANG

Based on the analysis of light hydrocarbon compositions of natural gas and regional comparison in combination with the chemical components and carbon isotopic compositions of methane, the indication of geochemical characteristics of light hydrocarbons on the migration features, dissolution and escape of natural gas from the Dongsheng gas field in the Ordos Basin is revealed, and the effect of migration on specific light hydrocarbon indexes is further discussed. The study indicates that, natural gas from the Lower Shihezi Formation (P1x) in the Dongsheng gas field displays higher iso-C5−7 contents than n-C5−7 contents, and the C6−7 light hydrocarbons are composed of paraffins with extremely low aromatic contents (<0.4%), whereas the C7 light hydrocarbons are dominated by methylcyclohexane, suggesting the characteristics of coal-derived gas with the influence by secondary alterations such as dissolution. The natural gas from the Dongsheng gas field has experienced free-phase migration from south to north and different degrees of dissolution after charging, and the gas in the Shiguhao area to the north of the Borjianghaizi fault has experienced apparent diffusion loss after accumulation. Long-distance migration in free phase results in the decrease of the relative contents of the methylcyclohexane in C7 light hydrocarbons and the toluene/n-heptane ratio, as well as the increase of the n-heptane/methylcyclohexane ratio and heptane values. The dissolution causes the increase of isoheptane values of the light hydrocarbons, whereas the diffusion loss of natural gas in the Shiguhao area results in the increase of n-C5−7 contents compared to the iso-C5−7 contents.

在分析天然气轻烃组成的基础上,结合甲烷的化学成分和碳同位素组成进行区域对比,揭示了轻烃地球化学特征对鄂尔多斯盆地东胜气田天然气迁徙特征、溶解和逸出的影响,并进一步讨论了迁徙对特定轻烃指标的影响。研究表明,东胜气田下石河子地层(P1x)天然气的异C5-7含量高于正C5-7含量,C6-7轻烃由芳烃含量极低(0.4%)的石蜡组成,而C7轻烃则以甲基环己烷为主,这表明天然气具有受溶解等二次变化影响的煤源特征。东胜气田的天然气在充注后经历了由南向北的自由相迁移和不同程度的溶解,博尔江海子断层以北石鼓浩地区的天然气在积聚后经历了明显的扩散损失。游离相的长距离迁移导致 C7 轻烃中甲基环己烷的相对含量和甲苯/正庚烷比值下降,而正庚烷/甲基环己烷比值和庚烷值上升。溶解导致轻烃的异庚烷值增加,而石鼓豪地区天然气的扩散损失导致正-C5-7 含量比异-C5-7 含量增加。
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引用次数: 0
Discovery and petroleum geological significance of delta in the third member of Oligocene Lingshui Formation in southern Baodao Sag, Qiongdongnan Basin, South China Sea 南海琼东南盆地宝岛沙格南部渐新世陵水地层第三系三角洲的发现及其石油地质意义
Q1 ENERGY & FUELS Pub Date : 2024-04-01 DOI: 10.1016/S1876-3804(24)60027-3
Jianxiang PEI, Wei LUO, Shiyang GUO, Lu LIN, Keliang LI

Based on the 3D seismic data and the analysis and test data of lithology, electricity, thin sections and chronology obtained from drilling of the Qiongdongnan Basin, the characteristics and the quantitative analysis of the source-sink system are studied of the third member of the Upper Oligocene Lingshui Formation (Ling 3 Member) in the southern fault step zone of the Baodao Sag. First, the YL10 denudation area of the Ling 3 Member mainly developed two fluvial systems in the east and west, resulting in the formation of two dominant sand transport channels and two delta lobes in southern Baodao Sag, which are generally large in the west and small in the east. The evolution of the delta has experienced four stages: initiation, prosperity, intermittence and rejuvenation. Second, the source-sink coupled quantitative calculation is performed depending on the parameters of the delta sand bodies, including development phases, distribution area, flattening thickness, area of different parent rocks, and sand-forming coefficient, showing that the study area has the material basis for the formation of large-scale reservoir. Third, the drilling reveals that the delta of the Ling 3 Member is dominated by fine sandstone, with total sandstone thickness of 109–138 m, maximum single-layer sandstone thickness of 15.5–30.0 m, and sand-to-strata ratio of 43.7%–73.0%, but the physical properties are different among the fault steps. Fourth, the large delta development model of the small source area in the step fault zone with multi-stage uplift is established. It suggests that the episodic uplift provides sufficient sediments, the fluvial system and watershed area control the scale of the sand body, the multi-step active fault steps dominate the sand body transport channel, and local fault troughs decide the lateral propulsion direction of the sand body. The delta of the Ling 3 Member is coupled with fault blocks to form diverse traps, which are critical exploration targets in southern Baodao Sag.

根据三维地震资料和琼东南盆地钻探获得的岩性、电性、薄断面、年代学等分析测试资料,研究了宝岛相南断裂阶梯带上更新统陵水地层第三系(陵三系)的源-汇系统特征及定量分析。首先,灵三系YL10剥蚀区主要发育东西两个河道系统,在宝岛嵯峨南部形成了两个主要输沙河道和两个三角洲裂片,总体上西大东小;其次,灵三系YL10剥蚀区主要发育东西两个河道系统,在宝岛嵯峨南部形成了两个主要输沙河道和两个三角洲裂片。三角洲的演化经历了起始、繁荣、间歇和复兴四个阶段。其次,根据三角洲砂体的发育阶段、分布面积、平整厚度、不同母岩面积、成砂系数等参数,进行了源-汇耦合定量计算,表明研究区具有形成大型储层的物质基础。第三,钻探揭示岭3系三角洲以细砂岩为主,砂岩总厚度109-138米,最大单层砂岩厚度15.5-30.0米,砂层比43.7%-73.0%,但各断层台阶物性不同。第四,建立了阶式断裂带小源区多级隆起的大三角洲发育模型。认为偶发性隆起提供了充足的沉积物,河流水系和流域面积控制了砂体规模,多级活动断层台阶主导了砂体运移通道,局部断层槽决定了砂体的横向推进方向。岭3组的三角洲与断层块体耦合形成多样的陷落,是宝岛沙格南部重要的勘探目标。
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引用次数: 0
Microscopic experiment on efficient construction of underground gas storages converted from water-invaded gas reservoirs 水侵气藏转化为地下储气库的高效建造微观实验
Q1 ENERGY & FUELS Pub Date : 2024-02-01 DOI: 10.1016/S1876-3804(24)60017-0
Tongwen JIANG , Huan QI , Zhengmao WANG , Yiqiang LI , Jinfang WANG , Zheyu LIU , Jinxin CAO

Based on the microfluidic technology, a microscopic visualization model was used to simulate the gas injection process in the initial construction stage and the bottom water invasion/gas injection process in the cyclical injection-production stage of the underground gas storage (UGS) rebuilt from water-invaded gas reservoirs. Through analysis of the gas-liquid contact stabilization mechanism, flow and occurrence, the optimal control method for lifecycle efficient operation of UGS was explored. The results show that in the initial construction stage of UGS, the action of gravity should be fully utilized by regulating the gas injection rate, so as to ensure the macroscopically stable migration of the gas-liquid contact, and greatly improve the gas sweeping capacity, providing a large pore space for gas storage in the subsequent cyclical injection-production stage. In the cyclical injection-production stage of UGS, a constant gas storage and production rate leads to a low pore space utilization. Gradually increasing the gas storage and production rate, that is, transitioning from small volume to large volume, can continuously break the hydraulic equilibrium of the remaining fluid in the porous media, which then expands the pore space and flow channels. This is conducive to the expansion of UGS capacity and efficiency for purpose of peak shaving and supply guarantee.

基于微流控技术,采用微观可视化模型模拟了由水侵气藏重建的地下储气库(UGS)在初始建设阶段的注气过程和循环注采阶段的底水入侵/注气过程。通过对气液接触稳定机理、流动和发生的分析,探索了地下储气库全生命周期高效运行的优化控制方法。结果表明,在 UGS 建设初期,应充分利用重力作用,调节注气量,确保气液接触宏观稳定迁移,大幅提高扫气能力,为后续的循环注采阶段提供较大的储气孔隙空间;在循环注采阶段,应充分利用重力作用,调节注气量,确保气液接触宏观稳定迁移,大幅提高扫气能力,为后续的循环注采阶段提供较大的储气孔隙空间;在循环注采阶段,应充分利用重力作用,调节注气量,确保气液接触宏观稳定迁移,为后续的循环注采阶段提供较大的储气孔隙空间。在 UGS 的循环注采阶段,恒定的储气和产气速率会导致孔隙空间利用率较低。逐步提高储气和产气速度,即从小体积过渡到大体积,可以不断打破多孔介质中剩余流体的水力平衡,从而扩大孔隙空间和流道。这有利于扩大 UGS 的产能和效率,达到调峰和保供的目的。
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引用次数: 0
A transient production prediction method for tight condensate gas wells with multiphase flow 多相流致密凝析气井瞬态产量预测方法
Q1 ENERGY & FUELS Pub Date : 2024-02-01 DOI: 10.1016/S1876-3804(24)60014-5
Wenpeng BAI, Shiqing CHENG, Yang WANG, Dingning CAI, Xinyang GUO, Qiao GUO

Considering the phase behaviors in condensate gas reservoirs and the oil-gas two-phase linear flow and boundary-dominated flow in the reservoir, a method for predicting the relationship between oil saturation and pressure in the full-path of tight condensate gas well is proposed, and a model for predicting the transient production from tight condensate gas wells with multiphase flow is established. The research indicates that the relationship curve between condensate oil saturation and pressure is crucial for calculating the pseudo-pressure. In the early stage of production or in areas far from the wellbore with high reservoir pressure, the condensate oil saturation can be calculated using early-stage production dynamic data through material balance models. In the late stage of production or in areas close to the wellbore with low reservoir pressure, the condensate oil saturation can be calculated using the data of constant composition expansion test. In the middle stages of production or when reservoir pressure is at an intermediate level, the data obtained from the previous two stages can be interpolated to form a complete full-path relationship curve between oil saturation and pressure. Through simulation and field application, the new method is verified to be reliable and practical. It can be applied for prediction of middle-stage and late-stage production of tight condensate gas wells and assessment of single-well recoverable reserves.

考虑到凝析气藏的相行为以及储层中的油气两相线性流动和边界主导流动,提出了致密凝析气井全通路油饱和度与压力关系的预测方法,并建立了多相流动致密凝析气井瞬时产量预测模型。研究表明,凝析油饱和度与压力的关系曲线对于计算伪压力至关重要。在生产早期或远离井筒、储层压力较高的地区,凝析油饱和度可通过物料平衡模型,利用早期生产动态数据进行计算。在生产后期或靠近井筒、储层压力较低的地区,凝析油饱和度可通过恒定成分膨胀试验数据进行计算。在生产中期或储层压力处于中间水平时,可将前两个阶段获得的数据进行内插,形成完整的石油饱和度与压力的全路径关系曲线。通过模拟和现场应用,验证了新方法的可靠性和实用性。该方法可用于致密凝析气井的中后期产量预测和单井可采储量评估。
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引用次数: 0
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Petroleum Exploration and Development
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