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Comparison of different calibration techniques of laser induced breakdown spectroscopy in bakery products: on NaCl measurement 烘焙产品中激光诱导击穿光谱不同校准技术的比较——以NaCl测量为例
IF 1.9 4区 物理与天体物理 Q3 OPTICS Pub Date : 2021-09-01 DOI: 10.1186/s41476-021-00164-9
Gonca Bilge, Kemal Efe Eseller, Halil Berberoglu, Banu Sezer, Ugur Tamer, Ismail Hakki Boyaci

Laser induced breakdown spectroscopy (LIBS) is a rapid optical spectroscopy technique for elemental determination, which has been used for quantitative analysis in many fields. However, the calibration involving atomic emission intensity and sample concentration, is still a challenge due to physical-chemical matrix effect of samples and fluctuations of experimental parameters. To overcome these problems, various chemometric data analysis techniques have been combined with LIBS technique. In this study, LIBS was used to show its potential as a routine analysis for Na measurements in bakery products. A series of standard bread samples containing various concentrations of NaCl (0.025%–3.5%) was prepared to compare different calibration techniques. Standard calibration curve (SCC), artificial neural network (ANN) and partial least square (PLS) techniques were used as calibration strategies. Among them, PLS was found to be more efficient for predicting the Na concentrations in bakery products with an increase in coefficient of determination value from 0.961 to 0.999 for standard bread samples and from 0.788 to 0.943 for commercial products.

激光诱导击穿光谱(LIBS)是一种快速测定元素的光谱学技术,已被广泛应用于许多领域的定量分析。然而,由于样品的物理-化学基质效应和实验参数的波动,原子发射强度和样品浓度的校准仍然是一个挑战。为了克服这些问题,各种化学计量数据分析技术已经与LIBS技术相结合。在这项研究中,LIBS被用来展示其作为烘焙产品中钠测量的常规分析的潜力。制备了一系列含不同浓度NaCl(0.025% ~ 3.5%)的标准面包样品,比较了不同的校准技术。采用标准校准曲线(SCC)、人工神经网络(ANN)和偏最小二乘(PLS)技术作为校准策略。其中,PLS预测烘焙产品中Na浓度的效率更高,标准面包样品的测定系数从0.961增加到0.999,商业产品的测定系数从0.788增加到0.943。
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引用次数: 0
Terahertz absorption characteristics of guar gum determined via microfluidic technology 微流体技术测定瓜尔胶的太赫兹吸收特性
IF 1.9 4区 物理与天体物理 Q3 OPTICS Pub Date : 2021-08-11 DOI: 10.1186/s41476-021-00162-x
Feng-Xuan Zhang, Guo-Yang Wang, Hai-Yun Huang, Meng-Han Chen, Si-Jia Zhang, Bo Su, Cun-Lin Zhang

The vibrational energy levels of many biomolecules correspond to the terahertz band; thus, terahertz technology can be used to identify these substances. Moreover, as the biological activity of most biomolecules can be observed only in aqueous solution, the characteristics of such biomolecules must be studied in aqueous solution. In this study, a simple microfluidic chip, a temperature control device and a strong electric field device were designed to study the terahertz absorption characteristics of guar gum for different temperatures, concentrations and electric field exposure durations, thus enabling the use of terahertz technology to analyse the characteristics of guar gum.

许多生物分子的振动能级与太赫兹波段相对应;因此,太赫兹技术可用于识别这些物质。此外,由于大多数生物大分子的生物活性只能在水溶液中观察到,因此必须在水溶液中研究这些生物大分子的特性。本研究设计了一个简单的微流控芯片、一个温度控制装置和一个强电场装置,以研究瓜尔胶在不同温度、浓度和电场照射时间下的太赫兹吸收特性,从而实现利用太赫兹技术分析瓜尔胶的特性。
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引用次数: 0
Graphene saturable absorbers applications in fiber lasers 石墨烯可饱和吸收剂在光纤激光器中的应用
IF 1.9 4区 物理与天体物理 Q3 OPTICS Pub Date : 2021-08-03 DOI: 10.1186/s41476-021-00163-w
Xi Peng, Yixin Yan

Two-dimensional materials are widely used in a variety of fields, such as medical treatment, industrial preparation, machining, etc. In this review, we have made a detailed description of the development of fiber lasers as well as the evolution of two-dimensional materials, especially graphene. In addition, we describe the optical properties of graphene and its preparations, for instance, chemical exfoliatio, liquid phase exfoliation, electrochemical technique, chemical vapor deposition, supercritical fluid exfoliation, and thermal exfoliation. Meanwhile, we also summarized several types of graphene saturable absorbers like all fiber, D-shaped, and optical deposition. Furthermore, we summarize the optical applications of fiber lasers based on graphene. Finally, we also take a look at the future perspectives of graphene and discuss the future applications of graphene in the field of optics. It is note worth that future fiber lasers will use more heterostructures or gas-solid mixtures to prepare saturable absorbers.

二维材料广泛应用于医疗、工业制备、机械加工等各个领域。在这篇综述中,我们详细描述了光纤激光器的发展以及二维材料的演变,特别是石墨烯。此外,我们还描述了石墨烯的光学性质及其制备方法,例如化学剥落、液相剥落、电化学技术、化学气相沉积、超临界流体剥落和热剥落。同时,总结了石墨烯可饱和吸收材料的几种类型,如全纤维型、d型和光学沉积型。最后,总结了基于石墨烯的光纤激光器的光学应用。最后,我们还展望了石墨烯的未来前景,并讨论了石墨烯在光学领域的未来应用。值得注意的是,未来的光纤激光器将更多地使用异质结构或气固混合物来制备可饱和吸收体。
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引用次数: 0
Integrable solution for light shaping based on a Fourier-pair mapping 基于傅里叶对映射的光整形的可积解
IF 1.9 4区 物理与天体物理 Q3 OPTICS Pub Date : 2021-07-26 DOI: 10.1186/s41476-021-00161-y
Liangxin Yang, Irfan Badar, Christian Hellmann, Frank Wyrowski

In far-field light shaping, one of the design methods is based on a one-to-one map between the irradiance of the source and target. However, an integrability issue may occur in this kind of algorithms, either in the ray mapping method for designing a freeform surface or in those geometric-optics-based methods for achieving a required output phase. We introduce another mapping-type algorithm to tackle the integrability problem, which instead of establishing a mapping between both the source and target irradiance in the space domain, the mapping is assumed on electric fields of a Fourier pair between the space domain and the spatial-frequency domain. By solving the mapping from the Fourier pair, the gradient of the output phase is achieved, that the gradient is equivalent to the obtained mapping function. Moreover, the existence and the characterization of the mapping guarantees the integrability of the gradient so that a smooth output phase can be directly integrated. Based on the obtained smooth output phase, a freeform surface can then be designed for the light-shaping task. Numerical examples are demonstrated for the comparison of the approaches with different mapping assumptions.

在远场光整形中,其中一种设计方法是基于源和目标辐照度之间的一对一映射。然而,在这种算法中可能会出现可积性问题,无论是在设计自由曲面的光线映射方法中,还是在实现所需输出相位的基于几何光学的方法中。我们引入另一种映射型算法来解决可积性问题,该算法不是在空间域中建立源和目标辐照度之间的映射,而是在空间域和空间频域之间的傅里叶对电场上假设映射。通过求解傅里叶对的映射,得到了输出相位的梯度,该梯度等价于得到的映射函数。此外,映射的存在性和刻划性保证了梯度的可积性,从而可以直接积分光滑的输出相位。基于获得的光滑输出相位,可以设计用于光整形任务的自由曲面。通过数值算例对不同映射假设下的方法进行了比较。
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引用次数: 0
Precise spectrophotometric method for semitransparent metallic thin-film index determination using interference enhancement 干涉增强精密分光光度法测定半透明金属薄膜折射率
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2021-07-23 DOI: 10.21203/RS.3.RS-660206/V1
R. Shurvinton, F. Lemarchand, A. Moreau, J. Lumeau
A precise spectrophotometric method to determine the refractive index of a semitransparent metallic thin film is presented. This method relies on interference enhancement of the measured spectra, employing an opaque substrate with a dielectric spacer layer beneath the absorbing layer of interest to create interference fringes.The resulting spectral oscillations of the stack are highly sensitive to the properties of the top absorbing layer, allowing precise determination of the refractive index via fitting. The performance of this method is verified using simulations in comparison to the typical method of depositing the absorbing thin film directly onto a transparent substrate. An experimental demonstration is made for titanium thin films over the visible range (370-835 nm). The refractive index of these films is extracted from experimental data using a combination of the Modified Drude and Forouhi-Bloomer models. This method showed high repeatability and precision, and is verified for Ti films between 6-70 nm thickness.
提出了一种精确测定半透明金属薄膜折射率的分光光度法。这种方法依赖于测量光谱的干涉增强,采用不透明的衬底,在感兴趣的吸收层下面有一个介电间隔层来产生干涉条纹。由此产生的光谱振荡对顶部吸收层的特性高度敏感,允许通过拟合精确确定折射率。通过仿真,与直接在透明衬底上沉积吸收薄膜的典型方法进行了比较,验证了该方法的性能。在可见光范围(370 ~ 835 nm)对钛薄膜进行了实验论证。利用改进的Drude模型和Forouhi-Bloomer模型的组合,从实验数据中提取了这些薄膜的折射率。该方法具有较高的重复性和精密度,适用于厚度为6 ~ 70 nm的Ti薄膜。
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引用次数: 2
Binary defocusing technique based on complementary decoding with unconstrained dual projectors 基于无约束双投影互补解码的二值离焦技术
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2021-07-10 DOI: 10.1186/s41476-021-00159-6
Xuexing Li, Wenhui Zhang

Binary defocusing technique can effectively break the limitation of hardware speed, which has been widely used in the real-time three-dimensional (3D) reconstruction. In addition, fusion technique can reduce captured images count for a 3D scene, which helps to improve real-time performance. Unfortunately, it is difficult for binary defocusing technique and fusion technique working simultaneously. To this end, our research established a novel system framework consisting of dual projectors and a camera, where the position and posture of the dual projectors are not strictly required. And, the dual projectors can adjust defocusing level independently. Based on this, this paper proposed a complementary decoding method with unconstrained dual projectors. The core idea is that low-resolution information is employed for high-resolution phase unwrapping. For this purpose, we developed the low-resolution depth extraction strategy based on periodic space-time coding patterns and the method from the low-resolution order to high-resolution order of fringe. Finally, experimental results demonstrated the performance of our proposed method, and the proposed method only requires three images for a 3D scene, as well as has strong robustness, expansibility, and implementation.

二值离焦技术有效地突破了硬件速度的限制,在实时三维重建中得到了广泛的应用。此外,融合技术可以减少三维场景的捕获图像数量,有助于提高实时性。遗憾的是,二元离焦技术和融合技术难以同时工作。为此,我们的研究建立了一个新的系统框架,由双投影仪和一个摄像机组成,其中双投影仪的位置和姿势没有严格要求。双投影仪可独立调节离焦水平。在此基础上,提出了一种无约束双投影互补解码方法。其核心思想是将低分辨率信息用于高分辨率相位展开。为此,我们开发了基于周期空时编码模式的低分辨率深度提取策略和条纹从低分辨率阶到高分辨率阶的方法。最后,实验结果验证了该方法的有效性,该方法对三维场景只需要三张图像,具有较强的鲁棒性、可扩展性和可实现性。
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引用次数: 1
Assessment about Luneberg integrals and application to digital in-line holography Luneberg积分的评价及其在数字全息术中的应用
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2021-06-30 DOI: 10.1186/s41476-021-00154-x
S. Coëtmellec, D. Lebrun, M. Brunel, A. J. E. M. Janssen

In this publication, the Luneberg integrals are revisited and the conditions of the using of such integrals have been recalled. Additivity law of Luneberg’s integrals and the link with the Frenel kernel for the propagation are discussed. By means of the definition of the Luneberg’s integrals, the propagation of a vectorial electromagnetic field (Hertz potentials) is developed and a new approach of the computation have been proposed based on Zernike polynomials. With this new approach simulations of holograms is illustrated in the case of the digital in-line holography with an opaque disk.

在这篇文章中,我们重新审视了吕内贝格积分,并回顾了使用吕内贝格积分的条件。讨论了Luneberg积分的可加性规律及其与传播的Frenel核的联系。通过吕尼贝格积分的定义,推导了矢量电磁场(赫兹势)的传播,提出了一种基于泽尼克多项式的计算方法。利用这种新方法,以不透明磁盘的数字直线全息为例,说明了全息图的模拟。
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引用次数: 1
Design of a phosphor-converted LED based lighting system considering both the lighting and color uniformity 基于磷光转换LED的照明系统设计,兼顾照明和色彩均匀性
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2021-06-30 DOI: 10.1186/s41476-021-00158-7
Jinren Yan

In this work, a scheme of combining an aspheric reflector and a primary packaging freeform lens in phosphor-converted lighting-emitting diode (pc-LED) based lighting system design was developed. In contrast to most of previous works in which the color and illumination uniformity of the pc-LED lighting systems were improved one by one, the developed scheme can improve both indicators simultaneously. To demonstrate the feasibility of the developed design scheme, an initially designed pc-LED optical model, with an average correlated color temperature (CCT) of about 5000?K, was constructed as the light source of the illumination system. The key ingredient to the color uniformity of the illumination system was investigated at first, and then several instances with the cut-off angle ranging from 40 to 60 degrees were further discussed. Detailed analysis shows: for each case, the CCT variation decreases from over 4000?K to smaller than 300?K and the illumination uniformity increases from a very low level to better than 80% on the target region.

本文提出了一种结合非球面反射镜和主封装自由曲面透镜的磷光转换发光二极管(pc-LED)照明系统设计方案。与以往的大部分工作不同,pc-LED照明系统的颜色和照度均匀性都是逐一提高的,本方案可以同时提高这两个指标。为了证明所开发的设计方案的可行性,初步设计了pc-LED光学模型,其平均相关色温(CCT)约为5000?K,作为照明系统的光源。首先研究了影响照明系统色彩均匀性的关键因素,然后讨论了截止角在40 ~ 60度范围内的几种情况。详细分析表明:每种情况下,CCT变化从4000?K小于300?K,目标区域的照度均匀度从极低水平提高到80%以上。
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引用次数: 0
Metamaterials subwavelength terahertz resonant cavities 超材料亚波长太赫兹谐振腔
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2021-06-16 DOI: 10.1186/s41476-021-00157-8
M. Al-Rubaiee, A. H. Al-Janabi, S. C. Fleming, A. Argyros

One of the unique properties of metamaterials is the ability to manipulate electromagnetic waves at subwavelength scales, made possible by their structure on these scales. Here, rather than consider effective bulk properties, we consider the properties of microscopic features based on considering resonant unit cells. We used wire array metamaterials to form localized resonant cavities by changing the resonance frequency of one or more unit cells, surrounded by unchanged unit cells that do not support resonance for the propagating mode (i.e. forming a band gap). We validate our approach experimentally with electromagnetic waves in the terahertz range, demonstrating and characterizing subwavelength resonant cavities in this range. These resonant cavities can pave the way for ultra-compact subwavelength waveguides and other optical components.

超材料的独特特性之一是能够在亚波长尺度上操纵电磁波,这是由于它们在这些尺度上的结构而成为可能。在这里,我们不是考虑有效的体积性质,而是考虑基于谐振单元胞的微观特征的性质。我们使用线阵列超材料通过改变一个或多个单元胞的共振频率来形成局部谐振腔,周围是不变的单元胞,这些单元胞不支持传播模式的共振(即形成带隙)。我们用太赫兹范围内的电磁波实验验证了我们的方法,展示和表征了该范围内的亚波长谐振腔。这些谐振腔可以为超紧凑亚波长波导和其他光学元件铺平道路。
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引用次数: 0
Stimulated Raman scattering simulation for imaging optimization 成像优化的受激拉曼散射模拟
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2021-06-16 DOI: 10.1186/s41476-021-00155-w
Liron Zada, Bart Fokker, Heather A. Leslie, A. Dick Vethaak, Johannes F. de Boer, Freek Ariese

Two simulation programs of a stimulated Raman scattering microscopy (SRS) imaging system with lock-in amplifier (LIA) detection were developed. SRS is an imaging technique based on the vibrational Raman cross-section as the contrast mechanism and enables fast, label-free imaging. Most SRS implementations are based on LIA detection of a modulated signal. However, building and operating such SRS set-ups still poses a challenge when selecting the LIA parameter settings for optimized acquisition speed or image quality. Moreover, the type of sample, e.g. a sparse sample vs. a densely packed sample, the required resolution as well as the Raman cross-section and the laser powers affect the parameter choice.

A simulation program was used to find these optimal parameters. The focal spot diameters of the individual lasers (pump and Stokes) were used to estimate the effective SRS signal focal spot and the (optical) spatial resolution. By calibrating the signal and noise propagation through an SRS system for a known molecule, we estimated the signal and noise input to the LIA. We used a low pass filter model to simulate the LIA behavior in order to find the optimal parameters (i.e. filter order and time constant).

Optimization was done for either image quality (expressed as contrast to noise ratio) or acquisition time. The targeted object size was first determined as a measure for the required resolution. The simulation output consisted of the LIA parameters, pixel dwell time and contrast to noise ratio.

In a second simulation we evaluated SRS imaging based on the same principles as the optimal setting simulation, i.e. the signals were propagated through an imaging system and LIA detection. The simulated images were compared to experimental SRS images of polystyrene beads.

Finally, the same software was used to simulate multiplexed SRS imaging. In this study we modeled a six-channel frequency-encoded multiplexed SRS system demodulated with six LIA channels. We evaluated the inter-channel crosstalk as a function of chosen LIA parameters, which in multiplex SRS imaging also needs to be considered.

These programs to optimize the contrast to noise ratio, acquisition speed, resolution and crosstalk will be useful for operating stimulated Raman scattering imaging setup, as well as for designing novel setups.

开发了具有锁相放大器(LIA)检测的受激拉曼散射显微镜(SRS)成像系统仿真程序。SRS是一种基于振动拉曼截面作为对比机制的成像技术,可以实现快速、无标记的成像。大多数SRS实现是基于调制信号的LIA检测。然而,在选择LIA参数设置以优化采集速度或图像质量时,构建和操作此类SRS设置仍然面临挑战。此外,样品的类型,例如稀疏样品与密集填充样品,所需的分辨率以及拉曼截面和激光功率都会影响参数的选择。利用仿真程序求出这些最优参数。利用单个激光器(泵浦激光器和斯托克斯激光器)的焦斑直径来估计SRS信号的有效焦斑和(光学)空间分辨率。通过校准信号和噪声在已知分子的SRS系统中的传播,我们估计了输入到LIA的信号和噪声。我们使用低通滤波器模型来模拟LIA行为,以找到最优参数(即滤波器阶数和时间常数)。对图像质量(表示为噪声比对比)或采集时间进行了优化。首先确定目标对象的大小作为所需分辨率的度量。仿真输出包括LIA参数、像素驻留时间和噪比对比。在第二个模拟中,我们基于与最优设置模拟相同的原理评估SRS成像,即信号通过成像系统和LIA检测传播。将模拟图像与聚苯乙烯珠的实验SRS图像进行了比较。最后,使用相同的软件模拟多路SRS成像。在这项研究中,我们模拟了一个六通道频率编码多路SRS系统与六个LIA通道解调。我们评估了通道间串扰作为所选LIA参数的函数,这在多路SRS成像中也需要考虑。这些优化对比度噪声比、采集速度、分辨率和串扰的程序将有助于操作受激拉曼散射成像装置,以及设计新的装置。
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引用次数: 6
期刊
Journal of the European Optical Society-Rapid Publications
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