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2020 IEEE 3rd International Conference on Dielectrics (ICD)最新文献

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Effect of Insulating Oil on Space Charge Characteristics of Oil-impregnated Paper Under DC Voltage 直流电压下绝缘油对油浸纸空间电荷特性的影响
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341880
Ganlin Mao, Shengtao Li, Shijun Li, Zhao Ge, Liuqing Yang, Liuhao Jiang
At present, the oil-paper insulation structure is mainly composed of traditional mineral oil and cellulose insulation paper. The hots pot of future research is to select better insulation oil to improve the overall insulation life of the system. Compared with traditional mineral insulation oil, gas to liquid(GTL) oil made from base oil refined by natural gas liquefaction technology by Fischer-Tropsch(FT) method are characterized by high oxidative stability and low sulfur content. In this paper, the space charge accumulation, distribution and attenuation characteristics of oil-impregnated paper composed of GTL oil and traditional mineral oil were studied. The space trap energy level and trap density distribution of two oil-impregnated papers were obtained according to isothermal decay current(IDC) method. The experimental results show that in the voltage-on stage, traditional mineral oil-impregnated paper is more prone to charge injection and the injection speed is faster. In the voltage-off stage, the traditional mineral oil-impregnated paper attenuates the charge faster, and the GTL oil-impregnated paper has more residual charge. Moreover, the trap level of GTL oil-impregnated paper is deeper than that of traditional mineral oil-impregnated paper.
目前,油纸绝缘结构主要由传统矿物油和纤维素绝缘纸组成。如何选择更好的绝缘油来提高系统的整体绝缘寿命是今后研究的热点。与传统的矿物绝热油相比,以基础油为原料,采用费托液化(FT)法制备的气转液(GTL)油具有氧化稳定性高、硫含量低等特点。本文研究了GTL油和传统矿物油组成的浸渍纸的空间电荷积累、分布和衰减特性。采用等温衰减电流(IDC)法测定了两种油浸纸的空间陷阱能级和陷阱密度分布。实验结果表明,在通电阶段,传统矿物油浸渍纸更容易发生电荷注入,注入速度更快。在电压下降阶段,传统矿物油浸渍纸的电荷衰减更快,而GTL浸渍纸的剩余电荷更多。此外,GTL油浸纸的捕集层比传统矿物油浸纸深。
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引用次数: 0
Silica Functionalization: How Does it Affect Space Charge Accumulation in Nanodielectrics Under DC? 二氧化硅功能化:如何影响直流条件下纳米介电体的空间电荷积累?
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341818
Amirhossein Mahtabani, I. Rytöluoto, R. Anyszka, Eetta Saarimäki, Xiaozhen He, K. Lahti, M. Paajanen, W. Dierkes, A. Blume
Functionalization of silica nanoparticles with polar aminosilane and its effect on space charge accumulation under high voltage direct current (DC) was studied in polypropylene (PP)/ Ethylene-Octene Copolymer (EOC) /silica nanodielectrics. The modification reaction conditions were varied in order to alter the deposited layer grafting density and morphology, and hence, the filler-polymer interfacial properties. The effect of this alteration was then studied on the space charge accumulation under a high DC field as one of the most important properties to tune for HVDC cable insulation systems. The chemical modification of the silica surface was first confirmed via Thermogravimetric Analysis (TGA) and Fourier Transform IR Spectroscopy (FTIR). Differential Scanning Calorimetry (DSC) was performed on the nanocomposites to study the effect of the nano-engineered interfacial areas on nucleation and crystal formation. The effect of the amine functional groups on the charge carrier trapping and transport in this insulation system was studied via Thermally Stimulated Depolarization Current (TSDC) method.It was argued that the amine functionality on the silica surface can induce deep trap states at the filler-polymer interfaces, and hinder further injection of the space charge. Under certain modification conditions, the aminosilane can form “island-like” structures on the silica surface. These islands can both facilitate nucleation, inducing transcrystallization at the filler-polymer interface, and further contribute to the induction of deep traps which result in reduction of space charge accumulation in the nanodielectric.
在聚丙烯(PP)/乙烯-辛烯共聚物(EOC) /二氧化硅纳米电介质中研究了极性氨基硅烷对二氧化硅纳米粒子的功能化及其对高压直流电(DC)下空间电荷积累的影响。通过改变改性反应条件,改变了沉积层的接枝密度和形貌,从而改变了填料-聚合物的界面性能。然后研究了这种变化对高直流场下空间电荷积累的影响,这是高压直流电缆绝缘系统最重要的调谐特性之一。首先通过热重分析(TGA)和傅里叶变换红外光谱(FTIR)证实了二氧化硅表面的化学修饰。采用差示扫描量热法(DSC)研究了纳米工程界面面积对纳米复合材料成核和晶体形成的影响。采用热激去极化电流(TSDC)方法研究了胺类官能团对该绝缘体系中载流子捕获和输运的影响。结果表明,二氧化硅表面的胺官能团会在填料-聚合物界面处诱发深阱态,阻碍空间电荷的进一步注入。在一定的修饰条件下,氨基硅烷可以在二氧化硅表面形成“岛状”结构。这些岛既可以促进成核,在填料-聚合物界面诱导转晶,又有助于诱导深阱,从而减少纳米介电介质中的空间电荷积累。
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引用次数: 0
Interface charge effect measurement in 2-μm-thick polypropylene sample under voltage with thermal method 用热法测量2 μm厚聚丙烯试样在电压作用下的界面电荷效应
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9342009
Céline Corbrion, S. Holé
A 2-$mu$m-thick polypropylene sample has been subjected to 10 kV/mm for 4 weeks. Thanks to surface temperature measurement along with heat pulse measurement, it is possible to detect the position at which the electric field varies inside the sample even without inverse convolution calculation.
一个2-$ $ μ $m厚的聚丙烯样品经受10 kV/mm 4周。由于表面温度测量与热脉冲测量相结合,即使不进行反卷积计算,也可以检测到样品内部电场变化的位置。
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引用次数: 0
Feasibility of Mini-Scale Injection Molding for Resource-Efficient Screening of PP-Based Cable Insulation Nanocomposites 微尺度注射成型筛选pp基电缆绝缘纳米复合材料的可行性
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341820
I. Rytöluoto, Eetta Saarimäki, J. Pelto, M. Paajanen, Xiaozhen He, R. Anyszka, Amirhossein Mahtabani, W. Dierkes, P. Seri, H. Naderiallaf, K. Lahti, Minna Niittymäki
This study presents a critical evaluation of the effect of two different sample manufacturing techniques on the morphological and dielectric properties of polypropylene (PP)-based nanocomposites, namely mini-scale injection molding (IM) vs. pilot-scale cast film extrusion. Polarized light microscopy revealed that the IM specimen morphology exhibited a layered “skin-core” type morphology, largely differing from the spherulitic morphology of the corresponding extruded cast films. Higher degree of crystallinity in the IM specimens was evidenced by calorimetric and X-ray diffraction methods. The processing-dependent morphological differences were found to affect the isothermal charging current (ICC) and thermally stimulated depolarization current (TSDC) characteristics due to differences in charge mobility and trapping, thus making direct comparison of IM and cast film specimens non-straightforward. Nevertheless, mini-scale injection molding can be seen as a resource-efficient sample manufacturing method for facilitating early-stage screening of the best-performing material candidates, given that the morphological features are carefully taken into account.
本研究提出了两种不同的样品制造技术对聚丙烯(PP)基纳米复合材料的形态和介电性能的影响的关键评估,即小规模注射成型(IM)和中试规模铸膜挤出。偏振光显微镜显示,IM样品的形态表现为层状的“皮核”型形态,与相应的挤压铸造膜的球晶形态有很大不同。量热法和x射线衍射法证明了IM样品的结晶度较高。研究发现,由于电荷迁移率和俘获的差异,加工相关的形态差异会影响等温充电电流(ICC)和热激退极化电流(TSDC)特性,从而使IM和铸膜样品的直接比较变得不容易。然而,考虑到形态特征被仔细考虑,小型注射成型可以被视为一种资源高效的样品制造方法,可以促进早期筛选性能最佳的候选材料。
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引用次数: 1
Monitored Migration of Additives from Thermally Upgraded Paper into Various Insulation Liquids 热升级纸中添加剂向各种绝缘液体迁移的监测
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341830
M. Meissner, E. Matić, S. Schober, Martin Darmann, M. Mittelbach
To determine the long-term persistence of stabilizing additives in thermally upgraded Kraft paper insulation material under operation conditions, the nitrogen migration from the solid material into the encircling insulation material was monitored as part of a large-scale ageing study. Therefore, thermally upgraded as well as normal Kraft paper, combined with pressboard, copper and sheet metal in representative amounts and ratios, was immersed in different types of insulation liquids (mineral oil, G-t-L oil, synthetic as well as natural ester). A continuous 56-day ageing experiment under oxygen-free conditions at elevated temperatures (130 and 150°C) was conducted, with a continuous sampling interval of 2 weeks. The nitrogen concentration of the embedding insulation liquids stayed constant for every insulation liquid aged with natural Kraft paper material, whereas a clear increase of nitrogen levels could be observed over time as soon as thermally upgraded Kraft paper was immersed into the insulation liquids. For prolonged ageing periods at 150°C the measured nitrogen levels in the insulation liquid could rise by as much as 120 ppm, corresponding to nearly 0.3% of dry insulation paper mass, indicating a significant loss of nitrogen-rich stabilizing agents into the corresponding insulation liquid just within weeks of ageing.
为了确定在运行条件下稳定添加剂在热升级牛皮纸绝缘材料中的长期持久性,作为大规模老化研究的一部分,监测了氮从固体材料向包围绝缘材料的迁移。因此,将热升级后的牛皮纸和普通牛皮纸,按一定的数量和比例与纸板、铜和金属板结合,浸入不同类型的绝缘液(矿物油、G-t-L油、合成酯和天然酯)中。在高温(130°C和150°C)无氧条件下进行连续56天的老化实验,连续采样间隔2周。每次使用天然牛皮纸材料老化的保温液中,包埋的保温液中氮浓度保持不变,而一旦将热升级后的牛皮纸浸入保温液中,随着时间的推移,氮含量明显增加。在150°C的长时间老化过程中,绝缘液中测量到的氮含量可能上升高达120ppm,相当于干燥绝缘纸质量的近0.3%,这表明在老化的几周内,富含氮的稳定剂大量流失到相应的绝缘液中。
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引用次数: 0
Preliminary Development and Application of a Stress-Strength Model for Reliability Estimation of Aged LV Cables for Nuclear Power Plants 核电厂低压电缆老化可靠性应力-强度模型的初步建立与应用
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341856
D. Fabiani, G. Mazzanti, S. V. Suraci, B. Diban
As a part of the H2020 EU Project called “TeaM Cables” - which has, among its aims, modelling reliability of Nuclear Power Plant (NPP) cables - the goal of this paper is to develop a model for the prediction of the residual reliability of Low Voltage (LV) cables for NPPs subjected to gamma radiation stress. The model estimates the probability that such cables withstand random stress overshoot in-service.
作为H2020欧盟项目“电缆团队”的一部分,本文的目标是开发一个模型,用于预测核电厂(NPP)电缆在伽马辐射应力下的低压(LV)电缆的剩余可靠性。该项目的目标之一是建立核电厂电缆可靠性模型。该模型估计了这种电缆在使用中承受随机应力超调的概率。
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引用次数: 1
Research of internal charging characteristics of Polyetherimide irradiated by energetic electrons 高能电子辐照下聚醚酰亚胺内部充电特性的研究
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341947
Penghui Shang, Jiang Wu, Xiaoquan Zheng
In the space irradiation environment, the energetic electrons can penetrate the shielding of the spacecraft and deposit in the dielectric, resulting in internal charging. The deposit charge is difficult to release due to the very low conductivity. When the electric field established by the deposit charge exceeds the threshold of the dielectric, the electrostatic discharges will occur. It is one of the important factors threatening the safe operation of spacecraft. Polyetherimide (PEI) is a high-performance thermoplastic, it maintains desirable electrical and mechanical properties up to 300°C and above. Due to the good processing behavior, it is considered to be used to manufacture the complex components of spacecraft. However, there is rare literature on the internal charging of polyetherimide. This is the primary purpose of this paper. In this paper, A threedimensional charge transport equation for internal charging in dielectric is established. Geant4 is used to calculate the charge deposition rate and energy deposition rate during the interaction of electrons and PEI. The electric field distribution in PEI under different initial energies, different beam densities and different grounding modes is calculated. Research shows that the maximum internal electric field of PEI irradiated by electrons depends on the beam current density, initial energy and the grounding types, which needs to be analyzed based on the operating environment.
在空间辐照环境下,高能电子可以穿透航天器的屏蔽,沉积在电介质中,造成内部充电。由于电导率很低,沉积电荷难以释放。当沉积电荷形成的电场超过介电介质的阈值时,就会发生静电放电。它是威胁航天器安全运行的重要因素之一。聚醚酰亚胺(PEI)是一种高性能热塑性塑料,在高达300°C及以上的温度下仍能保持理想的电气和机械性能。由于其良好的加工性能,被认为可用于制造航天器的复杂部件。然而,关于聚醚酰亚胺内充电的研究文献很少。这是本文的主要目的。本文建立了介质内部电荷的三维电荷输运方程。利用Geant4计算电子与PEI相互作用过程中的电荷沉积速率和能量沉积速率。计算了不同初始能量、不同束流密度和不同接地方式下PEI中的电场分布。研究表明,电子辐照PEI的最大内部电场取决于束流密度、初始能量和接地类型,需要根据运行环境进行分析。
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引用次数: 0
Core-shell piezoelectric nanofibers for multifunctional composite materials 多功能复合材料的核壳型压电纳米纤维
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341920
D. Fabiani, A. Zucchelli, T. Brugo, G. Selleri, F. Grolli, M. Speranza
This paper deals with the realization of core-shell piezoelectric nanofibers for the production of a multifunctional composite material. The nanofibers are integrated in a hosting material, such as epoxy resin or PDMS (silicon rubber). The aim of this work is to realize a material that is able to recognize a mechanical impact thanks to the specific disposition of the piezoelectric nanofibers.
本文研究了用于制备多功能复合材料的核壳型压电纳米纤维的实现方法。纳米纤维被集成在一种承载材料中,如环氧树脂或PDMS(硅橡胶)。这项工作的目的是实现一种能够识别机械冲击的材料,这要归功于压电纳米纤维的特定配置。
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引用次数: 1
Electrical characterization of low-density solid insulating fillers for hollow-core composite insulators 空心复合绝缘子用低密度固体绝缘填料的电学特性
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341821
Diego Machetti, E. Moal, J. Seifert, R. Puffer
Insulating materials that can fill the internal space of hollow-core composite insulators (HCIs) are gaining relevance due to the new areas of applications of these insulators. Such materials must be light and have sufficient electrical properties to preserve the integrity of the inner room of the HCIs. The electrical properties of a light polymeric foam, known as dry syntactic foam (DSF), which is based on two types of hollow microspheres (HMSs), were investigated. Special emphasis is placed on the influence of the density of the resulting material regarding the electrical properties. The results show that the dissipation factor and the relative permittivity have a proportional relationship with the density. Furthermore, two main properties, namely the number of interfaces and the pore size are found to influence the breakdown strength of the DSF.
由于空心复合绝缘子的新应用领域,填充空心复合绝缘子内部空间的绝缘材料越来越受到重视。这种材料必须很轻,并具有足够的电气性能,以保持hci内部房间的完整性。研究了以两种空心微球(hms)为基材的干式复合轻聚合物泡沫(DSF)的电学性能。特别强调的是所得到的材料的密度对电性能的影响。结果表明,耗散系数和相对介电常数与密度成正比关系。此外,发现两个主要性质,即界面数量和孔径大小影响了DSF的击穿强度。
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引用次数: 1
Charge Accumulation/Decumulation on DC-GIS Spacer under 10,000-hour DC Field Application DC- gis间隔器10000小时直流现场应用下的电荷积累/衰减
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341834
Hajime Shimakawa, A. Kumada, K. Hidaka, T. Yasuoka, Y. Hoshina, M. Shiiki
Surface charges on an insulating epoxy spacer in DC-GIS under high DC electric field lead to decrease breakdown voltage on the spacer, but charge accumulation phenomena of insulators are not clear in detail. In this paper, surface charge distributions on the epoxy model spacer were measured under DC-GIS simulated environment during the DC voltage application for 10,000 hours and the short circuit for 2400 hours. The saturation tendency of charge accumulation in which only the homo-charges develop concentrically near the electrodes was obtained. The time constant of charge accumulation below 20? agreed with the theoretical value calculated from the equivalent circuit. Surface charge characteristics with irregular charge, the ones during charge decumulation, and the relationship between charging saturation tendency and temperature were also obtained.
在直流强电场作用下,DC- gis中环氧绝缘子的表面电荷导致绝缘子击穿电压降低,但绝缘子的电荷积累现象尚不清楚。本文在DC- gis模拟环境下,测量了环氧树脂模型隔片在直流电压作用10000小时和短路2400小时时的表面电荷分布。得到了在电极附近只有同质电荷集中发展的电荷积累饱和趋势。电荷积累的时间常数小于20?与等效电路计算的理论值一致。得到了不规则电荷时的表面电荷特性、电荷减积时的表面电荷特性以及电荷饱和趋势与温度的关系。
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引用次数: 1
期刊
2020 IEEE 3rd International Conference on Dielectrics (ICD)
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