首页 > 最新文献

Acta Scientiarum-technology最新文献

英文 中文
Numerical Integration of locally Peaked Bivariate Functions 局部峰值二元函数的数值积分
4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-10-02 DOI: 10.4025/actascitechnol.v45i1.63310
Abdelhamid Taieb Zaidi
The aim of this paper is to compare the relative accuracies between deterministic and stochastic methods for solving bounded integrals numerically to observe which methods tend to function well and converge to a small amount of error based on computational resources. For the deterministic method, the Gauss-Legendre quadrature method has been selected and for the stochastic method, the Monte Carlo integration has been selected. For each case, the number of variables will be adjusted to observe the effect on error. For the Gauss-Legendre quadrature method the permutations increased with the inaccuracy of 9% when the number of nodes increased to 3 but was reduced by 90% and later on the error depicted a drop as the number of nodes raised further. For the stochastic method, that was chosen from large sample size, the inaccuracy was found to be inversely proportional to the sample size. This concluded that the monte-carlo approach was not affected by the impact of dimensionality moreover, deterministic method also seemed to overcome the dimensionality constraint.
本文的目的是比较确定方法和随机方法在数值上求解有界积分的相对精度,以观察哪种方法在计算资源有限的情况下更能有效地收敛到较小的误差。对于确定性方法,选择高斯-勒让德正交法;对于随机方法,选择蒙特卡罗积分法。对于每种情况,将调整变量的数量,以观察对误差的影响。对于Gauss-Legendre正交法,当节点数增加到3时,排列的不准确性增加了9%,但减少了90%,后来随着节点数的进一步增加,误差下降。对于选择大样本量的随机方法,发现不准确性与样本量成反比。这表明蒙特卡罗方法不受维数的影响,确定性方法似乎也克服了维数的限制。
{"title":"Numerical Integration of locally Peaked Bivariate Functions","authors":"Abdelhamid Taieb Zaidi","doi":"10.4025/actascitechnol.v45i1.63310","DOIUrl":"https://doi.org/10.4025/actascitechnol.v45i1.63310","url":null,"abstract":"The aim of this paper is to compare the relative accuracies between deterministic and stochastic methods for solving bounded integrals numerically to observe which methods tend to function well and converge to a small amount of error based on computational resources. For the deterministic method, the Gauss-Legendre quadrature method has been selected and for the stochastic method, the Monte Carlo integration has been selected. For each case, the number of variables will be adjusted to observe the effect on error. For the Gauss-Legendre quadrature method the permutations increased with the inaccuracy of 9% when the number of nodes increased to 3 but was reduced by 90% and later on the error depicted a drop as the number of nodes raised further. For the stochastic method, that was chosen from large sample size, the inaccuracy was found to be inversely proportional to the sample size. This concluded that the monte-carlo approach was not affected by the impact of dimensionality moreover, deterministic method also seemed to overcome the dimensionality constraint.","PeriodicalId":7140,"journal":{"name":"Acta Scientiarum-technology","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135902371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of a bulk cargo fruit sampler 散装水果取样机的研制
4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-09-27 DOI: 10.4025/actascitechnol.v45i1.61804
Tulio de Almeida Machado, Haroldo Carlos Fernandes, Fábio Lúcio Santos, Clarice Aparecida Megguer, Nara Silveira Velloso
The design of an agricultural machine or equipment can be considered of great complexity, due to the interactions between the operator, the machine, the product and the environment. There is a lack of available technologies for collecting fruit in bulk cargo at any time from transport to industries. A limiting factor is the loading of fruits that are at the base of the cargo. This study was carried out to develop a detailed design of a bulk cargo fruit sampler that can collect fruits in any position of the x, y and z axes. A methodology was applied and adapted to execute the design. This methodology was divided into the following stages: design planning, informational design, conceptual design, preliminary design and detailed design. The variant considered the most appropriate was selected for the preliminary design and detailed design. The concepts were divided into chassis or support, sample collector and support for sample removal. The removal of fruits was carried out to maintain as much of their interaction with the environment outside the collector as possible. With the conclusion of the detailed design, it was possible to file, at the National Institute of Industrial Property, the patent for the collector of fruit samples in bulk cargo. Results obtained from fruits in the collector were used in doctoral theses.
由于操作人员、机器、产品和环境之间的相互作用,农业机械或设备的设计可以被认为是非常复杂的。从运输到工业,在任何时候都缺乏收集散装货物水果的可用技术。一个限制因素是货物底部的水果装载。本研究是为了开发一种散装货物水果采样器的详细设计,该采样器可以在x, y和z轴的任何位置收集水果。应用并调整了一种方法来执行设计。该方法分为设计规划、信息设计、概念设计、初步设计和详细设计四个阶段。选择了认为最合适的变型进行初步设计和详细设计。这些概念分为底盘或支架、样品收集器和样品移除支架。水果的移除是为了尽可能保持它们与收集器外环境的相互作用。随着详细设计的完成,有可能在国家工业产权局申请散装货物中水果样品收集器的专利。收集的果实结果被用于博士论文。
{"title":"Development of a bulk cargo fruit sampler","authors":"Tulio de Almeida Machado, Haroldo Carlos Fernandes, Fábio Lúcio Santos, Clarice Aparecida Megguer, Nara Silveira Velloso","doi":"10.4025/actascitechnol.v45i1.61804","DOIUrl":"https://doi.org/10.4025/actascitechnol.v45i1.61804","url":null,"abstract":"The design of an agricultural machine or equipment can be considered of great complexity, due to the interactions between the operator, the machine, the product and the environment. There is a lack of available technologies for collecting fruit in bulk cargo at any time from transport to industries. A limiting factor is the loading of fruits that are at the base of the cargo. This study was carried out to develop a detailed design of a bulk cargo fruit sampler that can collect fruits in any position of the x, y and z axes. A methodology was applied and adapted to execute the design. This methodology was divided into the following stages: design planning, informational design, conceptual design, preliminary design and detailed design. The variant considered the most appropriate was selected for the preliminary design and detailed design. The concepts were divided into chassis or support, sample collector and support for sample removal. The removal of fruits was carried out to maintain as much of their interaction with the environment outside the collector as possible. With the conclusion of the detailed design, it was possible to file, at the National Institute of Industrial Property, the patent for the collector of fruit samples in bulk cargo. Results obtained from fruits in the collector were used in doctoral theses.","PeriodicalId":7140,"journal":{"name":"Acta Scientiarum-technology","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134903155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the use of hemp fibers in recycling spinning 大麻纤维在再生纺纱中的应用研究
4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-09-27 DOI: 10.4025/actascitechnol.v45i1.63566
Eren Oner, Seher Kaya
In recycle yarn spinning, the original fibers are added to the blend as a carrier because of the recycled fibers obtained by opening from fabric scraps are very short and coarse. In the textile recycling industry, mostly petroleum-based synthetic fibers are used as carrier fibers. In an environmentally important activity such as recycling spinning, it is necessary to reduce the use of synthetics used as carrier fibers. When considered from this point of view, hemp fibers come to the fore with their important performance and environmental features. Based on this fact, in this study, in addition to the standard production conditions in the recycling yarn production facility, hemp fibers in different proportions were added to the blends to reduce the ratio of polyester as carrier fiber and the effects of this situation on yarn quality were examined. According to the results, it was observed that adding hemp fiber to the recycle yarn blend increased yarn tenacity, yarn unevenness and yarn hairiness while decreased yarn elongation properties.
在再循环纺纱中,由于从织物废料中开孔得到的再循环纤维很短、很粗,所以将原纤维作为载体添加到混纺中。在纺织品回收工业中,石油基合成纤维多被用作载体纤维。在诸如循环纺纱等具有重要环境意义的活动中,有必要减少作为载体纤维的合成纤维的使用。从这个角度考虑,大麻纤维以其重要的性能和环保特性脱颖而出。基于此,本研究在再生纱生产设备的标准生产条件下,在共混物中加入不同比例的大麻纤维,降低涤纶作为载体纤维的比例,考察这种情况对成纱质量的影响。结果表明,在再生纱混纺中加入大麻纤维提高了纱线的强力、纱线不匀度和毛羽度,降低了纱线的伸长率。
{"title":"Investigation of the use of hemp fibers in recycling spinning","authors":"Eren Oner, Seher Kaya","doi":"10.4025/actascitechnol.v45i1.63566","DOIUrl":"https://doi.org/10.4025/actascitechnol.v45i1.63566","url":null,"abstract":"In recycle yarn spinning, the original fibers are added to the blend as a carrier because of the recycled fibers obtained by opening from fabric scraps are very short and coarse. In the textile recycling industry, mostly petroleum-based synthetic fibers are used as carrier fibers. In an environmentally important activity such as recycling spinning, it is necessary to reduce the use of synthetics used as carrier fibers. When considered from this point of view, hemp fibers come to the fore with their important performance and environmental features. Based on this fact, in this study, in addition to the standard production conditions in the recycling yarn production facility, hemp fibers in different proportions were added to the blends to reduce the ratio of polyester as carrier fiber and the effects of this situation on yarn quality were examined. According to the results, it was observed that adding hemp fiber to the recycle yarn blend increased yarn tenacity, yarn unevenness and yarn hairiness while decreased yarn elongation properties.","PeriodicalId":7140,"journal":{"name":"Acta Scientiarum-technology","volume":"41 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134903156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rheological behavior of dehydrated cranberry suspensions: Analysis of the influence of temperature and solid concentration on Casson’s model parameters 脱水蔓越莓悬浮液的流变行为:温度和固体浓度对卡森模型参数的影响分析
4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-09-27 DOI: 10.4025/actascitechnol.v45i1.63807
Ígor Henrique de Mello Rodrigues Ciolin, Daiane Cristina Lenhard, Carolina Castilho Garcia
Dehydrated cranberries (Vaccinium macrocarpon) are dried fruits known for their high antioxidant potential. Changes in their mechanical and rheological properties occur when cranberries are exposed to certain conditions, such as drying or immersion in a liquid medium (rehydration). To evaluate the rheological behavior of solid suspensions made from dehydrated cranberries, the effects of different temperatures and concentrations of dissolved solids were evaluated using a factorial experimental design (22) with three replications at the center point. Five models were used to investigate the suspensions' flow behavior: Ostwald de Waelle, Newton, Herschel-Bulkley, Casson, and Bingham. The rheometry of the suspensions showed that the fluids presented non-Newtonian behavior, with a satisfactory fit for the Casson model (R² > 0.94) in all evaluated temperature and concentration ranges. Furthermore, the effects of temperature and solid concentration of cranberry suspensions on the rheological parameters of the fitted model, Casson's initial shear stress (K0c), and Casson's plastic viscosity (Kc) were evaluated. From the response and the contour surfaces, it was found that increasing the concentration of the suspension above 20% resulted in higher initial shear stress, which was influenced by temperature, whose increase resulted in a significant reduction in the shear stress at a concentration of 30%. The plastic viscosity (Kc) was highly influenced by the solid’s concentration, and higher temperatures caused a decrease in the value of this parameter. So, the highest value of plastic viscosity was found for concentrations above 20% and at lower temperatures. Therefore, considering the results and for practical purposes, it can be concluded that the flow of the suspensions is facilitated if rehydration is conducted at high temperatures.
脱水蔓越莓(Vaccinium macrocarpon)是一种干果,以其高抗氧化潜力而闻名。当蔓越莓暴露在某些条件下,如干燥或浸泡在液体介质中(再水化),其机械和流变特性就会发生变化。为了评估由脱水蔓越莓制成的固体悬浮液的流变行为,我们使用一个在中心点有三个重复的析因实验设计(22)来评估不同温度和溶解固体浓度的影响。五个模型被用来研究悬浮液的流动行为:Ostwald de Waelle, Newton, Herschel-Bulkley, Casson和Bingham。悬浮液的流变学表明,流体表现出非牛顿的行为,与Casson模型(R²>0.94)在所有评估的温度和浓度范围。进一步考察了温度和固相浓度对拟合模型流变参数、卡森初始剪切应力(K0c)和卡森塑性粘度(Kc)的影响。从响应和等高线表面可以看出,当悬浮液浓度增加到20%以上时,初始剪应力增大,且受温度的影响,当浓度达到30%时,温度升高导致剪应力显著减小。塑性粘度(Kc)受固体浓度的影响较大,温度越高,该参数值越小。因此,在浓度超过20%和温度较低的情况下,塑料粘度的最大值被发现。因此,考虑到结果和实际目的,可以得出结论,在高温下进行复水化有利于悬浮液的流动。
{"title":"Rheological behavior of dehydrated cranberry suspensions: Analysis of the influence of temperature and solid concentration on Casson’s model parameters","authors":"Ígor Henrique de Mello Rodrigues Ciolin, Daiane Cristina Lenhard, Carolina Castilho Garcia","doi":"10.4025/actascitechnol.v45i1.63807","DOIUrl":"https://doi.org/10.4025/actascitechnol.v45i1.63807","url":null,"abstract":"Dehydrated cranberries (Vaccinium macrocarpon) are dried fruits known for their high antioxidant potential. Changes in their mechanical and rheological properties occur when cranberries are exposed to certain conditions, such as drying or immersion in a liquid medium (rehydration). To evaluate the rheological behavior of solid suspensions made from dehydrated cranberries, the effects of different temperatures and concentrations of dissolved solids were evaluated using a factorial experimental design (22) with three replications at the center point. Five models were used to investigate the suspensions' flow behavior: Ostwald de Waelle, Newton, Herschel-Bulkley, Casson, and Bingham. The rheometry of the suspensions showed that the fluids presented non-Newtonian behavior, with a satisfactory fit for the Casson model (R² > 0.94) in all evaluated temperature and concentration ranges. Furthermore, the effects of temperature and solid concentration of cranberry suspensions on the rheological parameters of the fitted model, Casson's initial shear stress (K0c), and Casson's plastic viscosity (Kc) were evaluated. From the response and the contour surfaces, it was found that increasing the concentration of the suspension above 20% resulted in higher initial shear stress, which was influenced by temperature, whose increase resulted in a significant reduction in the shear stress at a concentration of 30%. The plastic viscosity (Kc) was highly influenced by the solid’s concentration, and higher temperatures caused a decrease in the value of this parameter. So, the highest value of plastic viscosity was found for concentrations above 20% and at lower temperatures. Therefore, considering the results and for practical purposes, it can be concluded that the flow of the suspensions is facilitated if rehydration is conducted at high temperatures.","PeriodicalId":7140,"journal":{"name":"Acta Scientiarum-technology","volume":"43 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134903152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Some relations between the sets of f-statistically convergent difference sequences f统计收敛差分序列集合之间的一些关系
4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-09-27 DOI: 10.4025/actascitechnol.v45i1.59806
Sarkawt Asaad, Rifat Çolak, Yavuz Altın
In this study we establish the relations between the sets of difference sequences which are statistically convergent in connection with modulus functions.
本文用模函数建立了统计收敛的差分序列集合之间的关系。
{"title":"Some relations between the sets of f-statistically convergent difference sequences","authors":"Sarkawt Asaad, Rifat Çolak, Yavuz Altın","doi":"10.4025/actascitechnol.v45i1.59806","DOIUrl":"https://doi.org/10.4025/actascitechnol.v45i1.59806","url":null,"abstract":"In this study we establish the relations between the sets of difference sequences which are statistically convergent in connection with modulus functions.","PeriodicalId":7140,"journal":{"name":"Acta Scientiarum-technology","volume":"108 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134903153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Standardization of processing parameters and color of gels aiming to replace citric pectin by mesocarp flour or pectin of passion fruit 以中果皮粉或百香果果胶代替柠檬酸果胶为目标的凝胶的工艺参数和颜色标准化
4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-09-27 DOI: 10.4025/actascitechnol.v45i1.64193
Juliana Resende Gonçalves Silva, Jhone Gleison de Oliveira, Ricardo Augusto Mendonça Vieira, Eder Dutra de Resende
The processing of passion fruit generates a huge quantity of wastes, reaching 50% in mass of rind. The main use of the rinds is to produce rind flour or to be source of pectin as a gelling agent. This work develops a standard procedure to evaluate jelly products subjected to the same temperature histories and content of soluble solids along the processing time of the gel-based product, using different concentrations of mesocarp flour and pectin. The gels were evaluated by color patterns aiming to verify the applicability of mesocarp flour as substitute of commercial pectin in jelly of fruits. The quantitative analysis of the data for temperature histories and content of soluble solids enabled to confirm the standardization of the parameters used in the production of the gels, which is important to warrant the same processing conditions during the elaboration of the different types of gels. The gels made with passion fruit’s mesocarp flour have less translucent shades and a more yellowish color than the gels produced with commercial citric pectin, however, these small differences may not interfere in the final color of fruit jelly.
百香果在加工过程中产生大量废弃物,果皮质量高达50%。果皮的主要用途是生产果皮粉或作为胶凝剂的果胶来源。本研究开发了一种标准程序,使用不同浓度的中果皮面粉和果胶,在凝胶基产品的加工过程中,对受相同温度历史和可溶性固体含量影响的果冻产品进行评估。采用彩色图案法对凝胶进行评价,以验证中果皮粉作为商品果胶替代品在水果果冻中的适用性。对温度历史和可溶性固形物含量数据的定量分析能够确认凝胶生产中使用的参数的标准化,这对于保证不同类型凝胶的加工过程中相同的加工条件非常重要。用百香果中果皮面粉制成的凝胶比用商用柠檬酸果胶制成的凝胶透明度低,颜色偏黄,然而,这些微小的差异可能不会影响果冻的最终颜色。
{"title":"Standardization of processing parameters and color of gels aiming to replace citric pectin by mesocarp flour or pectin of passion fruit","authors":"Juliana Resende Gonçalves Silva, Jhone Gleison de Oliveira, Ricardo Augusto Mendonça Vieira, Eder Dutra de Resende","doi":"10.4025/actascitechnol.v45i1.64193","DOIUrl":"https://doi.org/10.4025/actascitechnol.v45i1.64193","url":null,"abstract":"The processing of passion fruit generates a huge quantity of wastes, reaching 50% in mass of rind. The main use of the rinds is to produce rind flour or to be source of pectin as a gelling agent. This work develops a standard procedure to evaluate jelly products subjected to the same temperature histories and content of soluble solids along the processing time of the gel-based product, using different concentrations of mesocarp flour and pectin. The gels were evaluated by color patterns aiming to verify the applicability of mesocarp flour as substitute of commercial pectin in jelly of fruits. The quantitative analysis of the data for temperature histories and content of soluble solids enabled to confirm the standardization of the parameters used in the production of the gels, which is important to warrant the same processing conditions during the elaboration of the different types of gels. The gels made with passion fruit’s mesocarp flour have less translucent shades and a more yellowish color than the gels produced with commercial citric pectin, however, these small differences may not interfere in the final color of fruit jelly.","PeriodicalId":7140,"journal":{"name":"Acta Scientiarum-technology","volume":"56 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134903151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
DNA Release from Polyaziridine Polyplexes Aided by Biomacromolecules: Effect of pH 生物大分子辅助聚氮吡啶复合物的DNA释放:pH的影响
4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-09-27 DOI: 10.4025/actascitechnol.v45i1.60454
Iram Bibi, Syed Waqar Hussain Shah
The pH dependence of heparin and dextran sulfate aided release of DNA from its polyplexes with polyaziridine (PA) has been investigated using Quartz crystal microbalance with dissipation monitoring (QCM-D). The acoustic behavior of ternary systems indicated that the DNA decondensation was favored at physiological pH. When pH < 7.4, PA was significantly positively charged and ternary complexation occurred. When pH exceeded 7.4, very small proportion of DNA was released upon heparin addition due to marked reduction in cationic nature of PA. An increase in thickness at the interface due to adsorbed material at pH 9.0 showed the retention of heparin on the surface despite of negligible release of DNA. In terms of PA binding, heparin proved to be a better competitor than dextran sulfate.
利用石英晶体微天平耗散监测(QCM-D)研究了肝素和硫酸葡聚糖对DNA与聚氮吡啶(PA)多聚物释放的pH依赖性。三元体系的声学行为表明,在生理pH下有利于DNA的去浓缩。7.4, PA带明显正电荷,出现三元络合。当pH超过7.4时,由于PA的阳离子性明显降低,加入肝素释放的DNA比例很小。在pH为9.0时,由于吸附材料的作用,界面厚度增加,表明尽管DNA的释放可以忽略不计,但肝素仍保留在表面。在PA结合方面,肝素被证明是比葡聚糖硫酸盐更好的竞争对手。
{"title":"DNA Release from Polyaziridine Polyplexes Aided by Biomacromolecules: Effect of pH","authors":"Iram Bibi, Syed Waqar Hussain Shah","doi":"10.4025/actascitechnol.v45i1.60454","DOIUrl":"https://doi.org/10.4025/actascitechnol.v45i1.60454","url":null,"abstract":"The pH dependence of heparin and dextran sulfate aided release of DNA from its polyplexes with polyaziridine (PA) has been investigated using Quartz crystal microbalance with dissipation monitoring (QCM-D). The acoustic behavior of ternary systems indicated that the DNA decondensation was favored at physiological pH. When pH < 7.4, PA was significantly positively charged and ternary complexation occurred. When pH exceeded 7.4, very small proportion of DNA was released upon heparin addition due to marked reduction in cationic nature of PA. An increase in thickness at the interface due to adsorbed material at pH 9.0 showed the retention of heparin on the surface despite of negligible release of DNA. In terms of PA binding, heparin proved to be a better competitor than dextran sulfate.","PeriodicalId":7140,"journal":{"name":"Acta Scientiarum-technology","volume":"26 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134902105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterization of a new ruthenium (II) terpyridyl diphosphine complex 新型三吡啶二膦钌配合物的合成与表征
4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-09-27 DOI: 10.4025/actascitechnol.v45i1.62458
Claudemir Batalini, Wagner Ferraresi De Giovani
Ruthenium complexes have been prepared for several applications, mostly for electrocatalysis, catalytic hydrogenation, energy conversion, photolysis, medicinal chemistry, among other fields. Bipyridine and terpyridine ligands are commonly found in the metal coordination sphere, including ruthenium, largely due to the high stability exhibited by the resulting complex and the possibility of greater stereochemical control during synthesis. The combination of substituted terpyridine ligands with diphosphine ligands to the metal ruthenium occurs to a lesser extent and its catalytic potential has been examined in several studies. This paper describes the synthesis of a new ruthenium (II) aqua complex containing aryl diphosphine and substituted terpyridine ligands: [Ru(L)(totpy)(OH2)](ClO4)2 (L=Ph2PCH2CH2PPh2); (totpy=4´-(4-tolyl)-2,2´:6´,2´´-terpyridine). The synthesis route was conducted in three steps; the final and the intermediate products have shown good reaction yields; the results of the characterization of the aqua complex by cyclic voltammetry, UV-visible spectroscopy and elemental analysis are consistent with the proposed chemical structure.
钌配合物在电催化、催化加氢、能量转化、光解、药物化学等领域有广泛的应用。联吡啶和三吡啶配体通常存在于金属配位球中,包括钌,这主要是由于所得到的配合物表现出的高稳定性和在合成过程中更大的立体化学控制的可能性。取代三联吡啶配体与二膦配体与金属钌的结合较少发生,其催化潜力已在几项研究中进行了研究。本文合成了一种新的含芳基二膦和取代三联吡啶配体的钌(II)水络合物:[Ru(L)(topy)(OH2)](ClO4)2 (L=Ph2PCH2CH2PPh2);(totpy = 4´——(4-tolyl) 2、2´:6´,2´´-terpyridine)。合成路线分为三个步骤;最终产物和中间产物均表现出良好的反应产率;通过循环伏安法、紫外可见光谱法和元素分析对该水合物进行了表征,结果与所提出的化学结构一致。
{"title":"Synthesis and characterization of a new ruthenium (II) terpyridyl diphosphine complex","authors":"Claudemir Batalini, Wagner Ferraresi De Giovani","doi":"10.4025/actascitechnol.v45i1.62458","DOIUrl":"https://doi.org/10.4025/actascitechnol.v45i1.62458","url":null,"abstract":"Ruthenium complexes have been prepared for several applications, mostly for electrocatalysis, catalytic hydrogenation, energy conversion, photolysis, medicinal chemistry, among other fields. Bipyridine and terpyridine ligands are commonly found in the metal coordination sphere, including ruthenium, largely due to the high stability exhibited by the resulting complex and the possibility of greater stereochemical control during synthesis. The combination of substituted terpyridine ligands with diphosphine ligands to the metal ruthenium occurs to a lesser extent and its catalytic potential has been examined in several studies. This paper describes the synthesis of a new ruthenium (II) aqua complex containing aryl diphosphine and substituted terpyridine ligands: [Ru(L)(totpy)(OH2)](ClO4)2 (L=Ph2PCH2CH2PPh2); (totpy=4´-(4-tolyl)-2,2´:6´,2´´-terpyridine). The synthesis route was conducted in three steps; the final and the intermediate products have shown good reaction yields; the results of the characterization of the aqua complex by cyclic voltammetry, UV-visible spectroscopy and elemental analysis are consistent with the proposed chemical structure.","PeriodicalId":7140,"journal":{"name":"Acta Scientiarum-technology","volume":"2 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134902102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Relationship between the rainfall index for Southern Brazil and the indexes of the Tropical Pacific and the Tropical Atlantic Oceans 巴西南部降水指数与热带太平洋和热带大西洋指数的关系
4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-09-27 DOI: 10.4025/actascitechnol.v45i1.58368
Beatriz Siqueira, Jonas Teixeira Nery, Ana Cláudia Carfan
The proposed study verified the possible influences of sea surface temperature (SST) anomalies in the equatorial Pacific and the tropical Atlantic on the rainfall in the southern region of Brazil. The rainfall stations used have monthly data for the period from 1977 to 2015 and are distributed throughout that region. Monthly TSM anomalies in the Niño 3.4 and Niño 1 + 2 areas, the Southern Oscillation Index and the Monthly Tropical South Atlantic Temperature Index were also used, from the database provided by the Climate Prediction Centre. The results show the association of precipitation in the South region with variations in sea surface temperature in the Tropical Pacific Ocean and, to a lesser extent, with sea surface temperatures in the Tropical South Atlantic Ocean.
本研究验证了赤道太平洋和热带大西洋海温异常对巴西南部地区降雨的可能影响。所使用的雨量站有1977年至2015年的月度数据,分布在整个地区。利用气候预报中心提供的数据库中Niño 3.4和Niño 1 + 2地区的逐月TSM距平,以及南方涛动指数和热带南大西洋逐月温度指数。结果表明,南部地区的降水与热带太平洋的海表温度变化有关,与热带南大西洋的海表温度变化的关系较小。
{"title":"Relationship between the rainfall index for Southern Brazil and the indexes of the Tropical Pacific and the Tropical Atlantic Oceans","authors":"Beatriz Siqueira, Jonas Teixeira Nery, Ana Cláudia Carfan","doi":"10.4025/actascitechnol.v45i1.58368","DOIUrl":"https://doi.org/10.4025/actascitechnol.v45i1.58368","url":null,"abstract":"The proposed study verified the possible influences of sea surface temperature (SST) anomalies in the equatorial Pacific and the tropical Atlantic on the rainfall in the southern region of Brazil. The rainfall stations used have monthly data for the period from 1977 to 2015 and are distributed throughout that region. Monthly TSM anomalies in the Niño 3.4 and Niño 1 + 2 areas, the Southern Oscillation Index and the Monthly Tropical South Atlantic Temperature Index were also used, from the database provided by the Climate Prediction Centre. The results show the association of precipitation in the South region with variations in sea surface temperature in the Tropical Pacific Ocean and, to a lesser extent, with sea surface temperatures in the Tropical South Atlantic Ocean.","PeriodicalId":7140,"journal":{"name":"Acta Scientiarum-technology","volume":"59 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134902104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rainfall intensity model with spatialization of intensity-duration-frequency curve parameters - A case study for the state of Maranhão, Brazil 具有强度-持续时间-频率曲线参数空间化的降雨强度模型——以巴西maranh<e:1>州为例
4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-09-27 DOI: 10.4025/actascitechnol.v45i1.63369
Mariana Medeiros Coelho, Nélio Moura de Figueiredo, Maria Teresinha de Medeiros Coelho, Lúcio Carlos Pinheiro Campos Filho
The characterization of intense rainfall in engineering projects is fundamental, mainly regarding the estimate of design flows necessary for designing hydraulic works. Intense rainfall events are commonly measured by Equations and curves that relate their intensity, duration, and frequency. Such relations, known as IDF, enable the hydrological characterization of a given region. This article presents a methodological design and results from both determination and spatialization of IDF curve parameters for the state of Maranhão. Historical series of maximum daily rainfalls obtained from National Water and Sanitation Agency (ANA) were used in 126 rainfall gauge stations and the Gumbel probability distribution estimated the maximum daily rainfall for 5, 10, 15, 25, 50, and 100 return periods. The Isozonal Method obtained the IDF correlations of intense rainfall events for 0,1. 1, and 24 h durations, and their performance were conducted by Nash-Sutcliffe R2 coefficient and Root Mean Square Relative Error (RMSE). “K, a, b, and c” parameters of intense rainfall equations were determined by optimization and convergence processes and their spatialization was carried out by interpolation by Inverse Distance Weighted (IDW), which enabled to determine the values of each parameter in regions without physical measurements of rainfall. Similarly, rainfall intensity was spatialized for the entire state. According to the results, the rainfall distribution in the state of Maranhão shows a variation in the indexes of precipitation, with the highest values found in areas located in central-southern, southwestern, and southeastern regions.
工程项目中强降雨的表征是基本的,主要是关于设计水工工程所需的设计流量的估计。强降雨事件通常通过与其强度、持续时间和频率相关的方程和曲线来测量。这种关系被称为IDF,使某一地区的水文特征得以确定。本文介绍了maranh状态的IDF曲线参数的确定和空间化的方法设计和结果。利用126个雨量站的历史最大日降雨量序列,利用Gumbel概率分布估计了5、10、15、25、50和100个回归期的最大日降雨量。等纬法获得了2001年强降水事件的IDF相关。采用Nash-Sutcliffe R2系数和均方根相对误差(Root Mean Square Relative Error, RMSE)评价其处理效果。通过优化和收敛过程确定强降雨方程的“K, a, b, c”参数,并通过IDW插值对其进行空间化,从而在没有降雨物理测量的地区确定各参数的值。同样,整个州的降雨强度也被空间化了。结果表明,马兰河州的降水分布在降水指标上存在一定的差异,在中南部、西南部和东南部地区降水量最大。
{"title":"Rainfall intensity model with spatialization of intensity-duration-frequency curve parameters - A case study for the state of Maranhão, Brazil","authors":"Mariana Medeiros Coelho, Nélio Moura de Figueiredo, Maria Teresinha de Medeiros Coelho, Lúcio Carlos Pinheiro Campos Filho","doi":"10.4025/actascitechnol.v45i1.63369","DOIUrl":"https://doi.org/10.4025/actascitechnol.v45i1.63369","url":null,"abstract":"The characterization of intense rainfall in engineering projects is fundamental, mainly regarding the estimate of design flows necessary for designing hydraulic works. Intense rainfall events are commonly measured by Equations and curves that relate their intensity, duration, and frequency. Such relations, known as IDF, enable the hydrological characterization of a given region. This article presents a methodological design and results from both determination and spatialization of IDF curve parameters for the state of Maranhão. Historical series of maximum daily rainfalls obtained from National Water and Sanitation Agency (ANA) were used in 126 rainfall gauge stations and the Gumbel probability distribution estimated the maximum daily rainfall for 5, 10, 15, 25, 50, and 100 return periods. The Isozonal Method obtained the IDF correlations of intense rainfall events for 0,1. 1, and 24 h durations, and their performance were conducted by Nash-Sutcliffe R2 coefficient and Root Mean Square Relative Error (RMSE). “K, a, b, and c” parameters of intense rainfall equations were determined by optimization and convergence processes and their spatialization was carried out by interpolation by Inverse Distance Weighted (IDW), which enabled to determine the values of each parameter in regions without physical measurements of rainfall. Similarly, rainfall intensity was spatialized for the entire state. According to the results, the rainfall distribution in the state of Maranhão shows a variation in the indexes of precipitation, with the highest values found in areas located in central-southern, southwestern, and southeastern regions.","PeriodicalId":7140,"journal":{"name":"Acta Scientiarum-technology","volume":"2011 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134903159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Acta Scientiarum-technology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1