Additive manufacturing of immiscible materials by laser-based technology offers a unique opportunity to design property-graded structures. The CuCrZr–316L system serves as a prime example of this approach, combining the benefits of the superior thermal/electrical properties of the former and the robust mechanical characteristics of the latter. However, to understand the resulting properties, insights into the microstructure transformations induced by the laser-induced extreme processing conditions are needed. Correlative characterization using transmission electron backscattered diffraction, transmission electron microscopy and nanoscale energy-dispersive X-ray spectroscopy analyses was implemented to assess the microstructural and chemical landscape across the multiple length scales of a laser-powder bed fusion (PBF-LB) processed CuCrZr–316L multi-material. Micron-scale residual stress measurements were performed by focused ion beam-digital image correlation technique to obtain spatially resolved stress gradients across the CuCrZr–316L interface. The findings were utilized to establish an intricate correlation between the structural/compositional hierarchy and the local stress states of the material; they reveal unusual phase transformation pathways that can generally act in materials solidified under extreme and metastable conditions. Multiscale phase separation into Cu- and Fe-rich regions occurred both within the melt and spinodally within the solid state. While the Cu-rich regions exhibited an FCC structure, the Fe-rich regions comprised FCC and the unexpected formation of BCC phases. A novel phase decomposition-mediated structural transformation was observed in the CuCrZr–316L interfacial zone, resulting from nanoscale compositional fluctuations and straddling the boundary of a spinodal-binodal transition. Moreover, this work reveals the correlation between local stress heterogeneities in additively manufactured (AM) multi-material microstructures and the associated local dislocation-mediated strengthening mechanisms. Such microstructural mechanisms, enabled by PBF-LB, can be utilized to generate materials with contrasting property combinations, such as a simultaneous strength-ductility enhancement.
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