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Infrared triggered dwell and active cooling thermal control effects on microstructural uniformity in DED 红外触发驻留和主动冷却热控制对DED微结构均匀性的影响
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-01-14 DOI: 10.1016/j.addma.2026.105088
James C. Haley , Chris Fancher , Gyan Shankar , Kyle Saleeby , Calen Kimmel , John Potter , Wei Tang , Ke An , Dunji Yu , Alex Plotkowski
Directed Energy Deposition (DED) offers rapid large scale fabrication, but difficulty in delivering consistent microstructures and properties hinders the use of DED fabricated components in safety or performance critical applications. Variability stems from the complex thermal cycles generated by the toolpath used to print the required geometry. Several practical methods have become established in DED to regulate overheating, such as active cooling of the baseplate structure or the use of an infrared camera to inject interlayer pauses to ensure the top layer of the component cools to a set temperature, which have been shown to affect microstructure. However, no critical assessment has been performed as to how effective these controls are in promoting microstructural uniformity in the context of complex layer timing commonly generated by non-prismatic geometries. Here we show how controls influence the thermal field, phase transformations, and dynamic annealing of a low-temperature transformation steel using infrared imaging and operando neutron diffraction. Counterintuitively, common thermal homogenization process controls can reduce microstructural uniformity because these approaches stabilize peak temperature while overlooking temperatures near the solid-state phase transformation fronts. Instead, the cyclic reheating induces spatially-variant dynamically annealed regions which can be modulated via control parameters. We show that these controls have spatially linked effects centimeters away from the active weld, which implies that microstructure control must co-optimize thermal input across many subsequent layers. Our results demonstrate the pressing need for higher order controls that integrate predictive elements of simulation data to stabilize printed properties for future qualification of DED components.
定向能沉积(DED)提供了快速的大规模制造,但在提供一致的微结构和性能方面的困难阻碍了DED制造组件在安全或性能关键应用中的使用。可变性源于用于打印所需几何形状的工具路径产生的复杂热循环。在DED中已经建立了几种实用的方法来调节过热,例如对基板结构进行主动冷却或使用红外摄像机注入层间暂停,以确保组件的顶层冷却到设定的温度,这些方法已被证明会影响微观结构。然而,对于这些控制在促进微观结构均匀性方面的效果如何,目前还没有进行严格的评估,这些控制通常是由非棱镜几何形状产生的复杂层同步。在这里,我们展示了控制如何影响热场,相变和低温相变钢的动态退火,使用红外成像和operando中子衍射。与直觉相反,普通的热均质过程控制可以降低微观组织的均匀性,因为这些方法稳定了峰值温度,而忽略了固态相变前沿附近的温度。相反,循环再加热会产生空间变化的动态退火区域,这些区域可以通过控制参数进行调制。研究表明,这些控制在距离活动焊缝几厘米处具有空间关联效应,这意味着微观结构控制必须在许多后续层中共同优化热输入。我们的研究结果表明,迫切需要高阶控制,集成仿真数据的预测元素,以稳定印刷性能,为未来的DED组件鉴定。
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引用次数: 0
Prediction and homogenization of optical tomography images and microstructure during powder bed fusion of metals using a laser beam by means of a style-based generative adversarial network 基于风格生成对抗网络的激光粉末床金属熔合过程中光学层析成像和微观结构的预测和均匀化
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-01-13 DOI: 10.1016/j.addma.2026.105077
Hannes Panzer , David L. Wenzler , Dominik Rauner , Josef Spachtholz , Stefan Dopfer , Stefan Hermann , Christian Yankacar , Fabian Hackl , Michael F. Zaeh
Additive manufacturing enables the production of complex geometries with a high material efficiency, making it a key technology in modern manufacturing. However, in powder bed fusion of metals using a laser beam (PBF-LB/M), an inhomogeneous thermal energy input can lead to residual stresses and microstructural irregularities, resulting in inconsistent mechanical properties. Addressing these issues in advance requires an efficient predictive modeling and localized process parameter adaptations. While sole numerical simulations offer insights into the thermal field, their computational cost limits a scalability, making methods based on artificial intelligence (AI) a promising alternative. In this study, an AI-driven approach to predict and homogenize the thermal behavior and, therefore, the microstructure in PBF-LB/M was designed. The approach is based on a style-based generative adversarial network (sbGAN) considering process statistics while remaining consistent with the underlying process physics. Optical tomography (OT) data along with finite element simulations were used to train, to validate, and to test the sbGAN model for Inconel 718 in terms of OT image predictions. The predicted images were then utilized to apply a laser power modification approach to reduce two types of overheating. These are characterized by a geometry-induced overheating, caused by part shapes with a reduced heat flux towards the build platform, and a vector-induced overheating, arising from short scan paths and low laser beam return times within individual layers. The effectiveness of this approach was assessed through the degree of OT signal uniformity and the microstructural homogeneity. The findings of this study proved the operational performance of the sbGAN model in predicting OT data both qualitatively and quantitatively. Overheated regions were reliably predicted, and the results agreed well with the experimental observations. For various test build jobs, the predicted mean values deviated by a maximum of 1.64% from the experimental values, while the standard deviation values differed by a maximum of 15.72%. The subsequent homogenization approach was demonstrated to be useful in reducing overheating. This approach contributed to a homogenization of the thermal signals and, by this, of the microstructure in PBF-LB/M. These findings advance AI-driven thermal modeling and process optimization, improving the final part quality and enhancing the reliability of PBF-LB/M.
增材制造能够以高材料效率生产复杂几何形状,使其成为现代制造业的关键技术。然而,在使用激光束(PBF-LB/M)进行金属粉末床熔合时,不均匀的热能输入会导致残余应力和微结构不规则,从而导致机械性能不一致。提前解决这些问题需要有效的预测建模和本地化的过程参数适应。虽然单一的数值模拟提供了对热场的深入了解,但它们的计算成本限制了可扩展性,这使得基于人工智能(AI)的方法成为一个有前途的选择。在这项研究中,设计了一种人工智能驱动的方法来预测和均匀化PBF-LB/M的热行为,从而设计了PBF-LB/M的微观结构。该方法基于基于风格的生成对抗网络(sbGAN),考虑过程统计,同时与底层过程物理保持一致。光学层析成像(OT)数据与有限元模拟一起用于训练、验证和测试用于Inconel 718的sbGAN模型的OT图像预测。然后利用预测的图像应用激光功率修改方法来减少两种类型的过热。它们的特点是几何诱导的过热,这是由面向构建平台的热流减少的零件形状引起的,以及矢量诱导的过热,这是由单个层内的短扫描路径和低激光束返回时间引起的。该方法的有效性通过OT信号的均匀度和显微结构的均匀性来评估。本研究的结果证明了sbGAN模型在定性和定量预测OT数据方面的运行性能。对过热区域进行了可靠的预测,结果与实验结果吻合较好。对于各种测试构建作业,预测平均值与实验值的最大偏差为1.64%,而标准差值与实验值的最大偏差为15.72%。随后的均质化方法被证明对减少过热是有用的。这种方法有助于热信号的均匀化,从而改善PBF-LB/M中的微观结构。这些发现推动了人工智能驱动的热建模和工艺优化,提高了最终零件质量,增强了PBF-LB/M的可靠性。
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引用次数: 0
In situ mechanical foaming in fused filament fabrication 熔融长丝制造中的原位机械发泡
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-01-09 DOI: 10.1016/j.addma.2026.105076
Lars Eisele, Anselm Heuer, Wilfried V. Liebig
In the context of lightweight design and functional integration, the generation of foamed structures in additive manufacturing represents a key technological objective. Conventional foaming methods often rely on chemical blowing agents or physical foaming in downstream processes such as autoclaves, which require complex process chains and high energy input. To address these limitations, this work presents a first feasibility demonstration of a process-integrated mechanical foaming approach for material extrusion, ensuring continuous production in an in-line foaming process. A modular nozzle was developed, in which carbon dioxide is injected into the polymer melt under high pressure during extrusion. Gas enters the melt through a porous medium embedded in the nozzle, enabling controlled gas transfer while preventing melt backflow. This mechanism facilitates mechanical foaming within the nozzle itself, eliminating the need for separate process stages. Systematic material screening showed that metallic porous media with submicron pore diameters provide sufficient resistance to melt intrusion while allowing stable gas injection. Extrusion trials with polylactic acid confirmed that the resulting foam morphology depends on the gas-to-melt mass flow ratio, yielding uniform microcellular structures with porosities up to 25 % and mean pore diameters around 100 µm. The presented results demonstrate that stable foam extrusion based on mechanical foaming through in-nozzle gas injection is feasible, and they establish the foundation for further investigations aimed at process refinement towards finer microcellular structures and fully additively manufactured foamed components.
在轻量化设计和功能集成的背景下,增材制造中泡沫结构的产生是一个关键的技术目标。传统的发泡方法通常依赖于化学发泡剂或下游工艺中的物理发泡,如高压灭菌器,这需要复杂的工艺链和高能量输入。为了解决这些限制,这项工作提出了一个过程集成的机械发泡方法的可行性演示材料挤压,确保连续生产在一个在线发泡过程。开发了一种模块化喷嘴,在高压下将二氧化碳注入聚合物熔体中。气体通过嵌入在喷嘴中的多孔介质进入熔体,从而实现可控的气体传递,同时防止熔体回流。这种机制有利于喷嘴本身的机械发泡,消除了单独工艺阶段的需要。系统的材料筛选表明,具有亚微米孔径的金属多孔介质具有足够的抗熔体侵入能力,同时可以稳定地注入气体。用聚乳酸进行的挤出试验证实,所得到的泡沫形态取决于气液质量流比,产生均匀的微孔结构,孔隙率高达25%,平均孔径约为100微米。结果表明,基于喷嘴内注气机械发泡的稳定泡沫挤出是可行的,并为进一步研究更精细的微孔结构和完全增材制造的泡沫部件奠定了基础。
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引用次数: 0
Experimental validation of the Ensemble Kalman Filter as a Laser Powder Bed Fusion digital twin 集成卡尔曼滤波器作为激光粉末床融合数字孪生体的实验验证
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-01-08 DOI: 10.1016/j.addma.2025.105054
Nathaniel Wood , Edwin Schwalbach , Sean Donegan , Andrew Gillman , David J. Hoelzle
This paper reports on the application of the Ensemble Kalman Filter (EnKF) as an Instantiated Digital Twin to estimate the temperature field inside a part being manufactured by laser powder bed fusion (L-PBF) for the purposes of in-process quality control and validation. The EnKF assimilates a physics-based model with experimental data for a feedback correction that compensates for model uncertainty. The paper describes the EnKF architecture and model development and demonstrates the effectiveness of EnKF under three subsets of PBF process physics: low temperature lasing which only induces heat conduction, nominal temperature lasing that introduces meltpool convection and radiation, and the full L-PBF processes thus introducing all modes of heat transfer for L-PBF. In comparison to the physics-based model without EnKF feedback, the EnKF demonstrates a reduction in temperature estimation error at the top surface of at least 94% for all tests. At higher temperature processing, and thus increased EnKF model uncertainty, the EnKF exhibits spurious non-physical temperature estimates at isolated spatial locations, which must be filtered out and systematic methods to eliminate this issue are reserved for future work.
本文报道了集成卡尔曼滤波器(EnKF)作为实例化数字孪生的应用,用于估计激光粉末床熔合(L-PBF)制造零件内部的温度场,以实现过程中的质量控制和验证。EnKF将基于物理的模型与实验数据相结合,用于补偿模型不确定性的反馈校正。本文介绍了EnKF的结构和模型的发展,并论证了EnKF在三个PBF过程物理子集下的有效性:仅诱导热传导的低温激光,引入熔池对流和辐射的名义温度激光,以及引入L-PBF所有传热模式的全L-PBF过程。与没有EnKF反馈的基于物理的模型相比,在所有测试中,EnKF在顶部表面的温度估计误差至少降低了94%。在更高的温度处理下,从而增加了EnKF模型的不确定性,EnKF在孤立的空间位置显示出虚假的非物理温度估计,必须将其过滤掉,并为未来的工作保留消除这一问题的系统方法。
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引用次数: 0
Robotic rebar insertion and grouting for reinforcement of 3D printed concrete: Technique development and bond behavior characterization 3D打印混凝土的机器人钢筋插入和注浆:技术发展和粘结行为表征
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-01-08 DOI: 10.1016/j.addma.2026.105078
Xiangyu Wang , Sizhe Wang , Beifang Deng , Zhenbang Liu , Mingyang Li , Kah Jun Yam , Quoc Nghia Vuong , Teck Neng Wong , Bak Koon Teoh , Ming Jen Tan
This study explores vertical insertion of steel rebars into 3D printed concrete (3DPC) using a robotic arm, enabling reinforcement during the printing process. A robotic system comprising a mobile base, a 6-axis robotic arm, a force/torque sensor, and a gripper was employed, alongside a dedicated algorithm for self-calibrating surface detection and force-controlled insertion. To enhance bond performance, grouting with epoxy or high-flowability cementitious materials was investigated. A total of 19 specimens were fabricated for the pull-out test, while 3 specimens were reserved for visual inspections. Pull-out tests identified four failure modes: concrete splitting, rebar pull-out with or without splitting, and rebar fracture. Steel cable confinement prevented splitting failure and increased bond strengths. Grouting improved bond strength up to 24–42 %, whereas 0.5 vol% PVA fibers in the printed matrix reduced bond performance by 11.55 %. Confined specimens with 100 mm bond lengths and grouting exhibited rebar fracture without concrete damage, indicating sufficient bond capacity for structural applications. Visual inspections of specimens indicated that non-grouted specimens exhibited minor voids in the upper region, while grouting effectively filled voids along the insertion path. Existing bond–slip models were evaluated for robotically inserted rebars, showing reasonable predictions for splitting failure but limited accuracy for pull-out failure. An analytical model was developed based on thick-walled cylinder and fictitious crack models. Overall, robotic rebar insertion (combined with grouting) achieved an acceptable bond performance by observing rebar fracture during the pull-out test, demonstrating the feasibility and potential of this automated reinforcement strategy in 3DPC.
本研究探索了使用机械臂将钢筋垂直插入3D打印混凝土(3DPC)中,从而在打印过程中进行加固。该机器人系统包括一个移动基座、一个6轴机械臂、一个力/扭矩传感器和一个夹持器,以及一个用于自校准表面检测和力控制插入的专用算法。为了提高粘结性能,研究了用环氧树脂或高流动性胶凝材料灌浆的方法。共制作19个试件用于拔出试验,保留3个试件用于目测。拉出试验确定了四种破坏模式:混凝土劈裂、钢筋有劈裂或无劈裂的拉出以及钢筋断裂。钢索约束防止了劈裂破坏,提高了粘结强度。注浆可使粘结强度提高24 - 42% %,而印刷基体中含有0.5 vol%的PVA纤维可使粘结性能降低11.55 %。约束试件粘结长度为100 mm,注浆后出现钢筋断裂,无混凝土损伤,具有足够的粘结能力用于结构应用。肉眼观察发现,未灌浆的试件上部出现较小的孔洞,灌浆可有效填充沿注浆路径的孔洞。现有的粘结滑移模型对机器人插入钢筋进行了评估,显示出对劈裂破坏的合理预测,但对拔出破坏的准确性有限。建立了基于厚壁圆柱体和虚拟裂纹模型的解析模型。总体而言,通过在抽拔试验中观察钢筋断裂情况,机器人钢筋插入(结合注浆)获得了可接受的粘结性能,证明了这种自动化加固策略在3DPC中的可行性和潜力。
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引用次数: 0
A flexible capacitive pressure sensor with a monolithically 3D-Printed arch-structured dielectric layer 一种具有单片3d打印拱形结构介电层的柔性电容压力传感器
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-01-07 DOI: 10.1016/j.addma.2026.105080
Hyeok Bin Lee , Soo Wan Kim , Hyeon Yun Jeong , Young Jin Yang , Sung Hyun Park , Chul Ung Kang , Hyeon Beom Kim
The fabrication of flexible pressure sensors with micro-structured dielectric layers typically involves complex, costly, and time-consuming processes such as photolithography and molding, which also limit the design of complex three-dimensional geometries. This study presents an l approach to fabricating flexible capacitive pressure sensors by directly manufacturing an arch structure dielectric layer using photocurable 3D printing. By employing a commercial photopolymer (Agilus30), we monolithically fabricated a dielectric layer with an architecture inspired by structural arches. The resulting sensor exhibits excellent responsiveness and stability due to the optimized structure and the inherent durability of the material. As a result of the performance comparison with the non-structured (bulk) sensor fabricated from the same material, arch structure sensor demonstrates a sensitivity approximately 30 times higher than the bulk-structured counterpart, particularly in the low-pressure regime (≤ 100 kPa). The fabricated pressure sensor features high sensitivity (0.116 kPa⁻¹), a low limit of detection (20 Pa), a response time of approximately 300 ms, and excellent stability over 3500 cycles. These characteristics demonstrate potential for applications in wearable devices, and health monitoring systems, presenting a new pathway for optimizing sensor performance through direct additive manufacturing of complex dielectric architectures, thereby decoupling performance enhancement from novel material synthesis.
具有微结构介电层的柔性压力传感器的制造通常涉及复杂、昂贵和耗时的工艺,如光刻和成型,这也限制了复杂三维几何形状的设计。本研究提出了一种利用光固化3D打印技术直接制造拱形结构介质层的柔性电容压力传感器的方法。通过采用商业光聚合物(Agilus30),我们单片制造了一个电介质层,其结构灵感来自于结构拱门。由于优化的结构和材料固有的耐久性,所得到的传感器表现出优异的响应性和稳定性。通过与由相同材料制成的非结构化(散装)传感器的性能比较,拱形结构传感器的灵敏度比散装结构传感器高约30倍,特别是在低压状态下(≤100 kPa)。制作的压力传感器具有高灵敏度(0.116 kPa⁻¹),低检测限(20 Pa),响应时间约为300 ms,并且在3500次循环中具有出色的稳定性。这些特性展示了在可穿戴设备和健康监测系统中的应用潜力,为通过直接增材制造复杂介电结构优化传感器性能提供了一条新途径,从而将性能增强与新材料合成分离。
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引用次数: 0
Synergistic effects of etching and electropolishing on additively manufactured Ti-6Al-4V scaffolds for biomedical implants 蚀刻和电抛光增材制备Ti-6Al-4V生物医学植入物支架的协同效应
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-01-06 DOI: 10.1016/j.addma.2026.105083
Ruben del Olmo , Reynier I. Revilla , Floriane Debuisson , Kitty Baert , Brecht Van Hooreweder , Anne des Rieux , Iris De Graeve , Ana Santos-Coquillat
Additive manufacturing (AM) of Ti alloys, particularly for complex-shaped prosthetics in biomedicine, offers a promising solution for improving biomaterial applications in the human body. However, as-printed titanium alloys often present defects, such as partially molten particles and surface heterogeneities, which can hinder implant integration and cell-material interactions. This study investigates, for the first time, the impact of two surface treatments combined - chemical etching and electropolishing - on a scaffold-shaped Ti-6Al-4V alloy fabricated via laser powder bed fusion. While neither treatment achieved an optimal finish, their combination (etching + electropolishing) significantly reduced surface roughness and promoted a thicker, more homogeneous TiO₂ layer, resulting in a surface free of unmelted particles and a smooth finish. The materials were biocompatible with stem cells from the apical papilla (SCAP) in direct contact assays. While all scaffolds supported cell viability, the surface-modified candidate allowed a monolayer formation after 15 days in contact with the cells. Also, when seeded onto the material, an enhanced tissue-like matrix development was found after 28 days. An increased expression of CD90 and a conserved expression of CD73 and CD105 (positive stem cell markers) were observed after 28 days of culture, whereas osteogenic differentiation markers (Collagen I, alkaline phosphatase, and Runx2) were also increased, presenting a mixed population within the 3D structure. Additionally, no signs of oxidative stress were observed after 24 h with macrophages. These results demonstrate that combining etching and electropolishing for AM Ti alloys is a promising strategy for enhancing the biomedical performance of 3D-printed Ti alloys.
钛合金的增材制造(AM),特别是用于生物医学中复杂形状的假肢,为改善生物材料在人体中的应用提供了一个有前途的解决方案。然而,打印后的钛合金通常存在缺陷,如部分熔融颗粒和表面非均质性,这可能会阻碍植入物的整合和细胞-材料的相互作用。本研究首次研究了化学蚀刻和电抛光两种表面处理相结合对激光粉末床熔合制备的支架状Ti-6Al-4V合金的影响。虽然两种处理都没有达到最佳的光洁度,但它们的组合(蚀刻+电抛光)显着降低了表面粗糙度,并促进了更厚,更均匀的TiO 2层,从而使表面没有未熔化的颗粒和光滑的光洁度。在直接接触试验中,材料与来自根尖乳头(SCAP)的干细胞具有生物相容性。虽然所有支架都支持细胞活力,但表面修饰的候选支架在与细胞接触15天后可以形成单层。此外,当将其播种到材料上时,28天后发现了增强的组织样基质发育。培养28天后,观察到CD90的表达增加,CD73和CD105(阳性干细胞标记物)的表达保守,而成骨分化标记物(Collagen I、碱性磷酸酶和Runx2)也增加,在3D结构中呈现混合群体。此外,巨噬细胞24 h后未观察到氧化应激的迹象。这些结果表明,将蚀刻和电抛光相结合的AM钛合金是提高3d打印钛合金生物医学性能的一种很有前途的策略。
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引用次数: 0
Hybrid manufacturing of absorbable Hydroxyapatite-Wollastonite/Mg3Zn interpenetrating phase composites for bone substitutes 可吸收羟基磷灰石-硅灰石/Mg3Zn互穿相复合材料骨替代物的复合制备
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-01-06 DOI: 10.1016/j.addma.2026.105082
Joana Zúquete , Simão Santos , Manuel F.R.P. Alves , Isabel Duarte , Krzysztof Naplocha , Susana M. Olhero , Georgina Miranda
Hydroxyapatite-Wollastonite/Magnesium alloy (HAp-Wol/Mg3Zn) Interpenetrating Phase Composites (IPCs) were developed by combining two different fabrication technologies, giving rise to a hybrid route for manufacturing innovative biomedical composites. A triply periodic minimal surface (TPMS) geometry was modeled, exploring two different volume fractions to control ceramic/metal ratio and interconnectivity. HAp-Wol structures were manufactured using additive manufacturing vat photopolymerization, specifically Digital Light Processing technology. The thermal debinding and sintering process of the printed HAp-Wol ceramic were optimized to allow a subsequent infiltration of the TPMS structures with a Mg3Zn alloy via investment casting, materializing the designed interpenetrating phase composites (IPCs). This approach enabled an effective infiltration of the alloy without the presence of major defects. The compressive strength of the HAp-Wol/Mg3Zn IPCs was significantly higher than that of the ceramic counterparts, increasing from 6.5 MPa to 162.5 MPa for the IPCs having the lowest ceramic ratio. The ceramic phase evidenced the formation of an apatite-like layer at their surface upon in vitro dissolution tests, evidencing bioactivity, being the calcium-rich silicate phase strongly responsible for this behavior. IPCs revealed a higher dissolution rate than the ceramic counterpart. This study demonstrates the feasibility of this hybrid manufacturing route to fabricate HAp-Wol/Mg3Zn IPCs that can be tailored by design to meet the requirements of bone substitutes, namely the mechanical performance and absorption rate.
羟基磷灰石-硅灰石/镁合金(HAp-Wol/Mg3Zn)互穿相复合材料(IPCs)是将两种不同的制造技术结合在一起开发出来的,为制造创新型生物医学复合材料提供了一种混合路线。三周期最小表面(TPMS)几何模型,探索了两种不同的体积分数来控制陶瓷/金属比和互连性。HAp-Wol结构是使用增材制造还原光聚合,特别是数字光处理技术制造的。优化了打印HAp-Wol陶瓷的热脱粘和烧结工艺,允许随后通过熔模铸造将Mg3Zn合金渗透到TPMS结构中,从而实现所设计的互渗相复合材料(IPCs)。这种方法能够有效地渗透合金而不存在主要缺陷。HAp-Wol/Mg3Zn复合材料的抗压强度显著高于陶瓷复合材料,陶瓷比最低的复合材料抗压强度从6.5 MPa增加到162.5 MPa。在体外溶解测试中,陶瓷相证明在其表面形成了磷灰石样层,证明了生物活性,是富钙硅酸盐相强烈负责这种行为。IPCs的溶解速率高于陶瓷。本研究证明了这种混合制造路线制造HAp-Wol/Mg3Zn IPCs的可行性,这种IPCs可以根据骨替代品的机械性能和吸收率进行定制。
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引用次数: 0
Dynamic projection lithography for high-efficiency volumetric fabrication of thin-walled ceramics 高效薄壁陶瓷体积制造的动态投影光刻技术
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-01-06 DOI: 10.1016/j.addma.2026.105081
Xunrui Wang , Wenhua Tong , Yanru Shen , Sukun Tian , Suwei Dai , Hu Chen , Weiwei Li , Jinhong Li , Xiang Wang , Yuchun Sun
This work reports a volumetric stereolithography strategy, termed Dynamic Projection Lithography (DPL), for the rapid fabrication of thin-walled, freeform ceramic shell structures. By spatiotemporally programming a photon flux gradient and exploiting the synergistic photopolymerization of high-solid-loading ceramic slurries, DPL enables monolithic, support-free curing of thin-walled green bodies within an ultra-short single exposure cycle of 10 ± 0.5 s. In contrast to conventional layer-by-layer stereolithography, DPL integrates continuous three-dimensional energy-field modulation with curing kinetics, thereby eliminating interlayer interfaces and the associated defect sensitivity. Using complex-curvature zirconia dental veneers as a model, DPL achieves a volumetric fabrication rate of 129.57 mm3/h, representing an improvement of approximately two orders of magnitude over conventional layer-wise processes (∼ 2.58 mm3/h) and shortening the total manufacturing cycle from several hours to about 3.5 min. After sintering, the ceramic shells exhibit uniform, isotropic microstructures without discernible interlayer defects and show markedly enhanced mechanical performance. The combination of dynamic pulsed exposure and inverse geometric mapping ensures accurate reproduction of curved surfaces. These results demonstrate that DPL offers a highly efficient route for volumetric ceramic printing of ultra-thin freeform structures, with strong potential for biomedical and other high-value customized applications.
这项工作报告了一种称为动态投影光刻(DPL)的体积立体光刻策略,用于快速制造薄壁,自由形状的陶瓷外壳结构。通过对光子通量梯度进行时空编程并利用高固载陶瓷浆料的协同光聚合,DPL可以在10 ± 0.5 s的超短单曝光周期内实现薄壁绿体的单片无支撑固化。与传统的逐层立体光刻相比,DPL集成了连续的三维能量场调制和固化动力学,从而消除了层间界面和相关的缺陷灵敏度。使用复杂曲率氧化锆牙科贴面作为模型,DPL实现了129.57 mm3/h的体积制造速率,比传统的分层工艺(~ 2.58 mm3/h)提高了大约两个数量级,并将总制造周期从几个小时缩短到约3.5 min。烧结后,陶瓷壳呈现均匀、各向同性的微观结构,无明显的层间缺陷,力学性能显著提高。动态脉冲曝光和逆几何映射的结合确保了曲面的精确再现。这些结果表明,DPL为超薄自由形状结构的体积陶瓷打印提供了一种高效的途径,在生物医学和其他高价值定制应用方面具有强大的潜力。
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引用次数: 0
Self-supported vapor-induced phase-separation direct ink writing of 3D cellular lattices with subroutine-enabled tool path generation 自支撑气相分离直接墨水写入三维细胞格与子程序支持的工具路径生成
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-01-05 DOI: 10.1016/j.addma.2026.105075
Benjamin J. Ryder , John-Thomas T. Robinson , Yunxia Chen , Lillian N. Badger , Marc Sole-Gras , Gang Li , Srikanth Pilla , Yong Huang
Additive manufacturing (AM) has emerged as a prevailing technology for fabricating three-dimensional (3D) cellular lattices, which offer superior performance compared to bulk materials for many applications. However, printing such cellular lattice geometries remains a critical challenge across most AM processes, often requiring an external support to maintain the printed structure during printing. The objective of this study is to demonstrate the self-supported printing capability of vapor-induced phase-separation (VIPS)-enabled direct ink writing (VIPS-DIW) for 3D cellular lattice fabrication in air, and to further illustrate the necessity of using subroutine-enabled tool path generation with customized subroutines as needed for the self-supported creation of complex 3D lattices in air from strut-based designs. Notably, in addition to a conventional subroutine for the printing of struts, three unique subroutines are proposed as atypical nozzle movement commands in printing lattice structures: printing pause, nozzle lift-off, and node priming line. The customizable, subroutine-based tool path generation approach facilitates the fabrication of a wide variety of lattice geometries using simple DIW equipment, which can make features at any orientation relative to the print bed. The subroutine-enabled VIPS-DIW process demonstrates robust versatility, enabling the successful fabrication of self-supported 3D lattices with high printing fidelity, offering new possibilities for lattice manufacturing.
增材制造(AM)已经成为制造三维(3D)细胞晶格的主流技术,在许多应用中,与大块材料相比,它提供了优越的性能。然而,在大多数增材制造过程中,打印这种细胞晶格几何形状仍然是一个关键的挑战,在打印过程中通常需要外部支撑来维持打印结构。本研究的目的是展示气相分离(VIPS)支持的直接墨水书写(VIPS- diw)在空气中3D细胞晶格制造中的自我支持打印能力,并进一步说明使用子程序支持的工具路径生成的必要性,并根据需要定制子程序,从基于支柱的设计中在空气中自我支持创建复杂的3D晶格。值得注意的是,除了用于打印支柱的常规子程序外,还提出了三个独特的子程序作为打印点阵结构中的非典型喷嘴运动命令:打印暂停、喷嘴起飞和节点启动线。可定制的、基于子程序的刀具路径生成方法有助于使用简单的DIW设备制造各种晶格几何形状,可以在相对于打印床的任何方向上制造特征。子程序支持的VIPS-DIW工艺展示了强大的多功能性,能够成功制造具有高打印保真度的自支撑3D晶格,为晶格制造提供了新的可能性。
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Additive manufacturing
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