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Partition laser assembling technique 分割激光装配技术
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-03-05 Epub Date: 2026-02-10 DOI: 10.1016/j.addma.2026.105119
Yueqiang Zhu , Lijing Zhong , Ce Zhang , Baiqiang Yang , Jianrong Qiu , Chen Zhang , Kaige Wang , Jintao Bai , Wei Zhao
The advancement of micro/nanofabrication techniques with high throughput, efficiency, and flexibility is critical for fields like integrated photonics, biosensing, and medical diagnostics. This study presents Partition Laser Assembling (PLA), a novel laser technique for fabricating complex micro/nanostructures akin to puzzle pieces. By dividing the target patterns described by scalable vector graphics into partitions, any structures in each partition can be fabricated via structured lights as variable “light stamp” through spatial light modulation. Unlike traditional direct laser writing, PLA eliminates reliance on mechanical components, avoiding step-like artifacts and ensuring smoother fabrication of complex trans-scale structures. By seamlessly assembling basic shapes, PLA achieves intricate structures like micro artworks and meta-lens with unmatched precision and resolution. Leveraging two-photon fabrication, PLA guarantees high resolution and structural integrity, positioning it as a potential transformative tool for nanoscale 3D printing. With applications spanning research and industry, PLA paves the way for advanced optical devices, micro/nano-fabrications, and next-generation manufacturing technologies.
具有高通量、高效率和灵活性的微/纳米制造技术的进步对于集成光子学、生物传感和医学诊断等领域至关重要。本研究提出了一种新型激光拼装技术,用于制造类似拼图的复杂微纳米结构。通过将可缩放矢量图形描述的目标图案划分为分区,每个分区中的任何结构都可以通过结构光作为可变的“光戳”通过空间光调制来制造。与传统的直接激光书写不同,PLA消除了对机械部件的依赖,避免了阶梯状的工件,并确保了复杂的跨尺度结构的更平滑的制造。通过无缝组装基本形状,PLA以无与伦比的精度和分辨率实现了微型艺术品和元透镜等复杂结构。利用双光子制造,PLA保证了高分辨率和结构完整性,将其定位为纳米级3D打印的潜在变革工具。随着研究和工业领域的应用,PLA为先进的光学器件,微/纳米制造和下一代制造技术铺平了道路。
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引用次数: 0
Assessment of the powder spreading parameters for non-spherical polymeric powder used in powder bed fusion process: A DEM simulation study 粉末床熔合过程中非球形聚合物粉末扩散参数的数值模拟研究
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-03-05 Epub Date: 2026-01-31 DOI: 10.1016/j.addma.2026.105099
Sina Zinatlou Ajabshir , Colin Hare , Diego Barletta , Massimo Poletto
In this study, a Discrete Element Method (DEM)-based model was developed to simulate the powder spreading process in Powder Bed Fusion (PBF) using non-spherical Polyamide 6 (PA6) powder. Various spreading tools—including sharp blades, curved round blades, flat blades, a roller, and a rigid rake-style brush—were tested at three spreading speeds (3, 30 and 90 mm/s) to evaluate their impact on powder bed characteristics. Key metrics such as packing fraction (η), compressive force distribution, spreading density ratio, and surface roughness were analysed within a defined area of interest. Particle velocity distribution and the vertical-to-horizontal velocity ratio were investigated to understand particle dynamics and settling behaviour during spreading. Results revealed that curved round tools, especially the horizontal round blade and roller, delivered denser, smoother, and more uniform powder layers. In contrast, sharp and flat blades caused poor compaction and elevated roughness, especially at higher speeds. The brush and 135° blade showed moderate but consistent performance. These findings emphasize the importance of tool geometry–speed interaction and provide insight for optimizing spreading strategies in PBF processes.
本文采用离散元法(DEM)建立了非球形聚酰胺6 (PA6)粉末床熔敷(PBF)粉末扩散过程的数值模拟模型。在三种扩散速度(3,30和90 mm/s)下测试了各种扩散工具(包括锋利刀片、弯曲圆刀片、平刀片、滚轮和刚性耙式刷),以评估它们对粉末床特性的影响。关键指标,如填料分数(η)、压缩力分布、扩散密度比和表面粗糙度在一个确定的兴趣区域内进行了分析。研究了颗粒的速度分布和垂直与水平速度比,以了解颗粒在扩散过程中的动力学和沉降行为。结果表明,弯曲的圆形工具,尤其是水平圆形刀片和滚轮,产生的粉末层更致密、更光滑、更均匀。相比之下,锋利和平坦的叶片会导致压实不良和粗糙度升高,特别是在高速行驶时。毛刷和135°叶片表现出中等但一致的性能。这些发现强调了刀具几何速度相互作用的重要性,并为优化PBF过程中的扩散策略提供了见解。
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引用次数: 0
Continuous parametric scanning with thermal modeling to minimize stitch zone defects in laser beam powder bed fusion validated by multi-scale X-ray CT 多尺度x射线CT验证了热建模的连续参数扫描在激光粉末床融合中的应用
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-03-05 Epub Date: 2026-02-12 DOI: 10.1016/j.addma.2026.105120
Omer Safa Cavus, Sina Khalilvandi Behrouzyar, Hamidreza Javidrad, Bahattin Koc
Stitch regions pose a fundamental challenge in both single and multi-laser systems due to overlapping scan areas where defects can form. This study introduces a continuous parametric scanning strategy designed to reduce porosity formation in stitch regions, which are frequently observed in these processes. The strategy was developed using a parametric modeling framework, which enables flexible and spatially adaptive scan-path generation while also producing the thermal-analysis inputs and build-machine files required for fabrication. By bridging the gap between design, simulation, and manufacturing, the framework supports a streamlined, end-to-end workflow tailored for metal additive manufacturing. The investigation was carried out in two phases, utilizing both transient thermal analysis and X-ray computed tomography (CT) to capture porosity across multiple scales. First, to assess the effectiveness of the proposed strategy, thermal simulations were conducted and the resulting cooling-rate distributions were analyzed. Second, these findings were validated through X-ray CT. Higher cooling-rate uniformity effectively reduced porosity formation in stitch regions. Each scanning strategy resulted in distinct mechanisms of pore formation that varied in pore size, shape, spatial distribution, and location. Compared with traditional strategies, the proposed continuous approach increased the thermal uniformity, reduced the average pore size by 25%, increased pore sphericity, and decreased the standard deviation of pore sizes.
缝线区域是单激光和多激光系统的一个基本挑战,因为重叠的扫描区域可以形成缺陷。本研究介绍了一种连续参数扫描策略,旨在减少在这些过程中经常观察到的针脚区域的孔隙形成。该策略是使用参数化建模框架开发的,该框架可以实现灵活和空间自适应的扫描路径生成,同时还可以生成制造所需的热分析输入和构建机器文件。通过弥合设计、仿真和制造之间的差距,该框架支持为金属增材制造量身定制的简化的端到端工作流程。研究分两个阶段进行,利用瞬态热分析和x射线计算机断层扫描(CT)来捕获多个尺度的孔隙度。首先,为了评估所提出策略的有效性,进行了热模拟,并分析了由此产生的冷却速率分布。其次,通过x线CT验证这些发现。更高的冷却速率均匀性有效地减少了针脚区域孔隙的形成。每种扫描策略导致不同的孔隙形成机制,这些机制在孔隙大小、形状、空间分布和位置上都有所不同。与传统方法相比,该方法提高了热均匀性,平均孔径减小了25%,孔隙球度增大,孔径标准差减小。
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引用次数: 0
Weldable, recyclable, and 3D-printable imine-based covalent adaptable networks for large-scale assembly at ambient temperature 可焊接,可回收和3d打印的亚胺基共价自适应网络,用于环境温度下的大规模组装
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-03-05 Epub Date: 2026-02-18 DOI: 10.1016/j.addma.2026.105128
Yun Liu , Mingyue Fan , Jiawei Cao , Peng Luo , Jianpeng Liu , Yu Shi , Wei Li , Liping Ren , Yadong Wu , Zaixing Jiang
Digital light processing (DLP) 3D printing technology has contributed significantly to high-resolution crosslinked polymer fabrication. However, its widespread application is limited by an inherent trade-off between printing resolution and workpiece size. To construct the large and intricate architectures, printing followed by modular assembly under external stimuli can make it possible via the imparted dynamic characteristics of designed dynamic crosslinked networks. This study presents a class of DLP-printable imine-based covalent adaptable networks with robust weldability, enabling scalable assembly at ambient temperature using only trace amounts of an aqueous amine solution. The fabricated imine resins were compatible with DLP printing to manufacture high-resolution polymeric modules. Subsequent interfacial interactions between modules at room temperature, activated by drops of primary amine aqueous solution, yield high welding efficiencies ranging from 87.66 % to 99.62 %. Moreover, the imine networks demonstrate sustainability, retaining weldability even after undergoing three recycling cycles. By enabling the scalable assembly of multi-material and multifunctional devices, the proposed strategy overcomes the current size limitations of DLP printing and provides a promising framework for green fabrication of advanced components.
数字光处理(DLP) 3D打印技术为高分辨率交联聚合物制造做出了重大贡献。然而,它的广泛应用受到印刷分辨率和工件尺寸之间固有权衡的限制。为了构建大型复杂的结构,在外界刺激下进行打印和模块化组装,可以通过赋予设计的动态交联网络的动态特性来实现。本研究提出了一类可dlp打印的基于亚胺的共价自适应网络,具有强大的可焊性,仅使用微量的水胺溶液就可以在环境温度下进行可扩展组装。制备的亚胺树脂与DLP打印兼容,可用于制造高分辨率聚合物模块。随后,在室温下,由伯胺水溶液激活的模块之间的界面相互作用产生了很高的焊接效率,范围从87.66 %到99.62 %。此外,亚胺网络具有可持续性,即使经过三次回收循环也能保持可焊性。通过实现多材料和多功能器件的可扩展组装,该策略克服了目前DLP印刷的尺寸限制,并为先进组件的绿色制造提供了一个有前途的框架。
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引用次数: 0
Geometric deviations and their effects in thin-plate lattice structures fabricated via LPBF LPBF制备薄板晶格结构的几何偏差及其影响
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-03-05 Epub Date: 2026-02-10 DOI: 10.1016/j.addma.2026.105117
Joseph Berthel, Jack Beuth, Rahul Panat
The fabrication of lattice structures through laser powder bed fusion (LPBF) has the potential to create architected materials with exceptional mechanical properties at low densities, with plate-lattice structures demonstrating the highest stiffness and strength to weight ratios. However, geometric deviations and defects introduced by the LPBF process result in plate-lattice geometries deviating from their intended ideal design, potentially compromising mechanical properties and increasing density without a proportional increase in strength. The intersecting and inclined thin-plate features that enable the high performance of plate-lattices are especially prone to compromising deviations, since plate-lattice features are fabricated at scales approaching the resolution limits of LPBF. This study presents a comprehensive analysis of geometric deviations and defects in AlSi10Mg LPBF plate-lattice structures, focusing on understanding the influence of both processing conditions and geometric features on deviation formation, and determining their detrimental effect on compression mechanics. Micro-CT scanning is used to examine the as-fabricated morphology of plate-lattice unit cells and identify trends in defect severity among different lattice topologies and volume fractions. Finite element analysis (FEA) of the ideal and as-fabricated unit cell geometry under compressive strain is performed to evaluate differences in strain energy density distribution and resultant lattice stiffness. FEA results show that deviations contribute to a 4.4–28.0 % increase in minimally load-bearing lattice mass, reducing the specific stiffness of the lattice by 11.8–31.7 % compared to ideal geometries. Minimally load-bearing mass arises from protruding surface variations and dross formations around powder drainage holes and overhanging features, while underprinting at critical plate intersections introduces stress concentrations. This work provides insight into how plate-lattice design and LPBF fabrication strategy impact as-fabricated lattice geometry and resulting mechanical performance.
通过激光粉末床融合(LPBF)制造晶格结构有可能在低密度下创造出具有卓越机械性能的建筑材料,其中板-晶格结构具有最高的刚度和强度重量比。然而,由LPBF工艺引入的几何偏差和缺陷导致板-晶格几何形状偏离其预期的理想设计,潜在地损害机械性能和增加密度,而没有成比例地增加强度。交叉和倾斜薄板特征使板晶格具有高性能,但由于板晶格特征是在接近LPBF分辨率极限的尺度上制造的,因此特别容易出现妥协偏差。本研究全面分析了AlSi10Mg LPBF板-晶格结构的几何偏差和缺陷,重点了解了加工条件和几何特征对偏差形成的影响,并确定了它们对压缩力学的不利影响。显微ct扫描用于检查板晶格单元细胞的制造形态,并确定不同晶格拓扑结构和体积分数之间缺陷严重程度的趋势。在压缩应变作用下,对理想和制造的单元格几何形状进行了有限元分析,以评估应变能密度分布和由此产生的晶格刚度的差异。有限元分析结果表明,与理想几何形状相比,偏差使最小承载晶格质量增加4.4-28.0 %,使晶格的比刚度降低11.8-31.7 %。最小的承载质量来自于突出的表面变化和粉末排水孔和悬垂特征周围的浮渣形成,而在关键板块交叉处的底印会引入应力集中。这项工作提供了关于板晶格设计和LPBF制造策略如何影响制造晶格几何形状和由此产生的机械性能的见解。
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引用次数: 0
Toward real-time chemical mapping during laser powder bed fusion: Robust in-situ spectroscopy and 3D reconstruction 激光粉末床融合过程中的实时化学制图:鲁棒原位光谱和三维重建
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-03-05 Epub Date: 2026-02-06 DOI: 10.1016/j.addma.2026.105112
Philipp Gabriel , Florian Eibl , Stephan Barcikowski , Anna Rosa Ziefuss
Laser powder bed fusion of metals (PBF-LB/M) is an established additive manufacturing (AM) technique enabling material-efficient production of complex metal components. However, current PBF-LB/M systems cannot monitor or control local chemical composition during fabrication, relying instead on ex-situ analyses after printing to assess material quality, which is incompatible with real-time quality assurance in industrial production. This study applies optical emission spectroscopy (OES) to monitor the chemical composition of parts during fabrication, with a focus on identifying and quantifying key influence factors such as laser energy input, alloy composition, integration time, and analysis position exemplified for magnet (Nd-Fe-B) and Scalmalloy (Al-Mg-Sc) printing. By comparing spectra from powder and bulk samples and evaluating characteristic peak intensity ratios, global spectral effects are effectively minimized. The machine-integrated, optically off-axis OES enabled reproducible measurements with composition sensitivity in the sub-at% range. Thereby, a novel concept for the 2D/3D reconstruction of chemical composition during PBF-LB/M is demonstrated. This approach aligns spatial and temporal OES data with the laser scan path through synchronizing the spectrometer acquisition interval with the machine clock, generating spatially resolved composition maps. Proof of concept is presented through layer-wise 2D mapping, with OES-derived data validated by ex-situ EDX analysis, with layers digitally stacked into a 3D reconstruction. This method lays the groundwork for robust in-situ chemical mapping during PBF-LB/M and supports the advancement of digital twins by a material vector. By enabling real-time monitoring and process control, it will open new pathways for quality assurance and adaptive manufacturing strategies in industrial settings.
激光粉末床金属熔合(PBF-LB/M)是一种成熟的增材制造(AM)技术,可以高效地生产复杂的金属部件。然而,目前的PBF-LB/M系统无法在制造过程中监测或控制当地的化学成分,而是依赖于打印后的非原位分析来评估材料质量,这与工业生产中的实时质量保证不相容。本研究应用光学发射光谱(OES)监测零件在制造过程中的化学成分,重点识别和量化关键影响因素,如激光能量输入、合金成分、积分时间和分析位置,以磁铁(Nd-Fe-B)和Scalmalloy (Al-Mg-Sc)打印为例。通过比较粉末样品和散装样品的光谱并评估特征峰强度比,可以有效地最小化全局光谱效应。机器集成,光学离轴OES实现了可重复测量,成分灵敏度在亚at%范围内。因此,提出了PBF-LB/M过程中化学成分二维/三维重建的新概念。该方法通过同步光谱仪采集间隔和机器时钟,将空间和时间OES数据与激光扫描路径对齐,生成空间分辨成分图。通过分层2D映射来验证概念,通过非原位EDX分析验证oes衍生数据,并将层数字堆叠成3D重建。该方法为PBF-LB/M过程中可靠的原位化学映射奠定了基础,并支持通过材料向量推进数字孪生。通过实现实时监控和过程控制,它将为工业环境中的质量保证和自适应制造战略开辟新的途径。
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引用次数: 0
Layer-to-layer closed-loop switched heating and cooling control of the laser powder bed fusion process 层间闭环开关加热和冷却控制的激光粉末床熔合过程
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-03-05 Epub Date: 2026-02-14 DOI: 10.1016/j.addma.2026.105124
Barış Kavas , Efe C. Balta , Lars Witte , Michael R. Tucker , John Lygeros , Markus Bambach
This study investigates the stabilization of interlayer temperature in the laser powder bed fusion process through a novel switched layer-to-layer closed-loop feedback controller. The controller architecture aims to measure the interlayer temperature by a laterally positioned thermal camera and maintain a preset reference temperature by switching between the heating mode through dynamic laser power adjustment and the cooling mode by assigning interlayer dwell time to allow cooling between layers. The switching controller employs a feedback optimization control algorithm for the heating mode to adjust the laser power, and a triggering algorithm that increases the interlayer dwell time until the interlayer temperature reaches the reference value. Additionally, the study compares the performance of the proposed controller in both supported and unsupported overhanging parts to evaluate the effect of support structures on the controller performance as well as the thermal behavior of overhanging parts. Key results demonstrate the controller’s effectiveness in stabilizing interlayer temperature across varying cross-sectional areas while remaining within the material’s stable processing zone. In the heating mode, the controller efficiently tracks the reference temperature, even in geometries with significant cross-section variation. During cooling, the controller adjusts dwell times to enhance thermal control in overhanging sections. The controller’s robustness is further validated by its performance with unsupported parts, where the overheating effect is more pronounced, and in supported parts, where thermal conduction to the build plate is enhanced. The study also identifies trade-offs among process efficiency, energy consumption, and build time. Supported parts exhibit reduced overheating but consume more energy and material, while unsupported parts stabilize interlayer temperature faster but with longer build times due to increased dwell time assignments. This tradeoff is more than compensated by a reduction in post-processing effort. The research highlights notable improvements in interlayer temperature control for geometries prone to excessive thermal stresses. Moreover, the introduction of interlayer dwell time offers a practical solution to maintaining thermal stability in complex geometries.
本文通过一种新颖的层间切换闭环反馈控制器,研究了激光粉末床熔合过程中层间温度的稳定。控制器架构旨在通过侧向放置的热像仪测量层间温度,并通过动态激光功率调节加热模式和分配层间停留时间以允许层间冷却的冷却模式之间切换,保持预设的参考温度。开关控制器采用加热模式的反馈优化控制算法来调节激光功率,并采用触发算法来增加层间停留时间,直到层间温度达到参考值。此外,该研究还比较了所提出的控制器在有支撑和无支撑的悬垂部件中的性能,以评估支撑结构对控制器性能的影响以及悬垂部件的热行为。关键结果表明,控制器在稳定层间温度在不同的横截面积,同时保持在材料的稳定加工区内的有效性。在加热模式下,控制器有效地跟踪参考温度,即使在几何形状具有显著的截面变化。在冷却期间,控制器调整停留时间,以加强悬垂部分的热控制。控制器的稳健性进一步验证了其在无支撑部件上的性能,其中过热效应更为明显,而在有支撑部件上,对构建板的热传导增强。该研究还确定了过程效率、能源消耗和构建时间之间的权衡。有支撑的部件表现出较少的过热,但消耗更多的能量和材料,而无支撑的部件稳定层间温度更快,但由于驻留时间分配增加,构建时间更长。这种权衡被后处理工作量的减少所弥补。该研究强调了易于产生过度热应力的几何结构在层间温度控制方面的显著改进。此外,层间停留时间的引入为保持复杂几何形状的热稳定性提供了一种实用的解决方案。
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引用次数: 0
Bioinspired multilayer barriers of 3D-printed lunar regolith simulant-based geopolymers for mechanical and thermal protection 生物启发多层屏障的3d打印月球风化模拟基于地聚合物的机械和热保护
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-03-05 Epub Date: 2026-02-14 DOI: 10.1016/j.addma.2026.105123
Siqi Ma , Feng Zhang , Shuai Fu , Benzhi Min , Xiaodi Feng , Shengwen Wang , Guoliang Chen , Peigang He , Dechang Jia , Honghao Yue , Yifan Lu , Yu Zhou
To address the combined demands of impact resistance, thermal protection, and structural support in lunar surface shielding, we developed a multifunctional biomimetic multilayer barrier using a lunar-regolith-simulant-based geopolymer via Direct Ink Writing (DIW). The barrier comprises three bio-inspired tiers: a Bouligand helicoidal layer providing superior impact resistance, a dendritic fractal network integrating thermal insulation with load-bearing capacity, and a honeycomb-like sandwich panel mitigating vibration. Mortise-and-tenon interlocks integrate these tiers into a mechanically robust whole. Mechanical and thermal performance were evaluated through static loading, impact, and insulation experiments, supported by finite element simulations. The Bouligand layer, optimized at a 90° stacking angle, dissipated impact energy through sequential failure, enhancing toughness and resistance to dynamic loading. The dendritic layer, tuned to a 60° branching angle, achieved optimal stability and deformation adaptability, yielding the highest energy absorption and over 60 % thermal insulation effectiveness. The honeycomb base layer outperformed auxetic and chiral counterparts in compressive strength and robustness, while maintaining efficient vibration isolation. Collectively, the integrated architecture demonstrated complementary mechanical and thermal performance, providing multifunctional protection beyond that achievable by conventional single-function layered materials. Under external thermal loads of up to 127°C, the internal temperature remained stabilized near 30°C, confirming excellent thermal shielding. This study clarifies how geometric parameters of biomimetic substructures govern composite barrier responses and establishes an engineering-feasible design paradigm for multifunctional shielding systems, providing theoretical and experimental foundations for lunar infrastructure optimization.
为了解决月球表面屏蔽中抗冲击、热防护和结构支撑的综合需求,我们通过直接墨水书写(DIW)技术,利用月球表面模拟岩石层的地聚合物开发了一种多功能仿生多层屏障。屏障由三个仿生层组成:提供卓越抗冲击性的Bouligand螺旋层,将隔热与承重能力结合在一起的树枝状分形网络,以及蜂巢状的夹层板,可以减轻振动。榫卯互锁将这些层整合成一个机械坚固的整体。机械和热性能通过静态加载、冲击和绝缘实验进行评估,并辅以有限元模拟。Bouligand层以90°堆积角优化,通过顺序破坏耗散冲击能,增强了韧性和抗动载荷能力。枝晶层,调整到60°分支角,实现了最佳的稳定性和变形适应性,产生最高的能量吸收和超过60% %的保温效率。蜂窝基层在抗压强度和鲁棒性方面优于辅助基层和手性基层,同时保持有效的隔振。总的来说,集成的结构展示了互补的机械和热性能,提供了超越传统单一功能层状材料所能实现的多功能保护。在高达127°C的外部热负荷下,内部温度保持稳定在30°C附近,证实了出色的热屏蔽性。本研究阐明了仿生子结构几何参数对复合屏障响应的影响,建立了多功能屏蔽系统的工程可行设计范式,为月球基础设施优化提供了理论和实验基础。
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引用次数: 0
Self-activating resins for the straightforward electroless metallization of 3D printed parts 用于3D打印部件的直接化学金属化的自激活树脂
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-03-05 Epub Date: 2026-02-18 DOI: 10.1016/j.addma.2026.105129
Roberto Bernasconi , Pierre Rogiers , Luca Magagnin
A self-activating photocurable resin system is proposed as a cost-effective route for the direct electroless metallization of 3D printed components. The strategy relies on the incorporation of inexpensive metallic precursors, namely NiCl2 and CuSO4, into a commercial digital light processing (DLP) resin, enabling the in situ formation of catalytic sites after a single chemical reduction step. This approach removes the need for conventional multi-step surface activation and the use of noble metals such as palladium. The rheological and photopolymerization behavior of the composite resins demonstrates that all formulations remain compatible with DLP printing, with the embedded salts significantly affecting viscosity, curing depth and mechanical properties of the resulting photopolymerized materials. The printed parts are reduced in aqueous environment, resulting in partial dissolution and conversion of the precursors into metallic nuclei that can initiate electroless deposition of NiP and Cu. The obtained metallic coatings exhibit uniform morphology, compact structure and strong adhesion to the polymer substrate, as confirmed by SEM/EDS and XRD. Moreover, the metallized substrates enable the sequential electroplating of multiple metallic layers using electrolytic deposition, producing continuous and adherent multilayer architectures. The versatility of the proposed method is further expanded through multimaterial DLP printing, which allows selective metallization by combining clear and self-activating regions within a single object. Metallization occurrs exclusively in the catalytically active areas following reduction. Overall, this study introduces a simple and scalable metallization route for polymer-based additive manufacturing, reducing cost and process complexity while maintaining high coating quality. The proposed self-activating resins provide a sustainable pathway toward functional metallic architectures, electronic interconnects and decorative finishes produced directly via DLP 3D printing.
提出了一种自激活光固化树脂体系,作为3D打印部件直接化学金属化的一种经济有效的途径。该策略依赖于将廉价的金属前体,即NiCl2和CuSO4结合到商业数字光处理(DLP)树脂中,从而在单一化学还原步骤后原位形成催化位点。这种方法不需要传统的多步骤表面活化和使用贵金属,如钯。复合树脂的流变学和光聚合行为表明,所有配方都与DLP打印兼容,嵌入的盐显著影响光聚合材料的粘度、固化深度和机械性能。打印部件在水环境中被还原,导致前驱体部分溶解并转化为金属核,从而引发化学沉积NiP和Cu。SEM/EDS和XRD分析表明,所制备的金属涂层形貌均匀,结构致密,与聚合物基体的附着力强。此外,金属化衬底能够使用电解沉积对多个金属层进行顺序电镀,从而产生连续和粘附的多层结构。所提出的方法的多功能性通过多材料DLP打印进一步扩展,通过在单个对象内结合清晰和自激活区域,允许选择性金属化。金属化只发生在还原后的催化活性区域。总体而言,本研究为基于聚合物的增材制造引入了一种简单且可扩展的金属化路线,在保持高涂层质量的同时降低了成本和工艺复杂性。提出的自激活树脂为功能性金属结构、电子互连和装饰饰面直接通过DLP 3D打印提供了可持续的途径。
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引用次数: 0
Prediction of process instability by WAAM in-process monitoring and CTWD drift estimation 基于WAAM过程监测和CTWD漂移估计的过程不稳定性预测
IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2026-03-05 Epub Date: 2026-02-18 DOI: 10.1016/j.addma.2026.105127
Sarra Oueslati , Mathieu Ritou , Elodie Paquet , Farouk Belkadi , Philippe Le Bot
Wire Arc Additive Manufacturing (WAAM) is a promising technology to produce large metallic components. However, drifts of the Contact Tube to Workpiece Distance (CTWD) are difficult to manage, which can induce process instability and defects like porosity. To safeguard material integrity, instability must be detected before it occurs, which is very challenging. This paper proposes an original predictive model for process instability caused by CTWD drift. In-process monitoring data were collected on a robotic cell and sixteen key features were extracted as potential monitoring criteria for CTWD drift estimation. Feature selection was then performed by several filtering methods, to identify the best indicator for CTWD drift estimation through regression model. ANOVA was used to identify which Key Process Parameters (KPP) should be considered for finetuning the linear regression model. Then, Support Vector Regression (SVR) model was developed to predict the boundary of instability T*, based on dedicated KPP identified by ANOVA. By combining the estimated CTWD drift and drift speed with the predicted boundary T*, the model predicts the Number of Remaining Layers (nRL) before process instability onset. The proposed method was evaluated on a use-case of thin wall manufacturing. Instability predictions aligned with observations, demonstrating the model capability to anticipate defects. The instability consequences on material integrity were confirmed by metallographic examination. The combination of real-time monitoring, data-driven models and eXplainable AI, provides a robust and interpretable framework to improve WAAM control, while providing manufacturing experts with new insight on the KPP for instability prediction and proactive intervention.
电弧增材制造(WAAM)是一种很有前途的大型金属部件制造技术。然而,接触管对工件距离的漂移(CTWD)难以控制,这可能导致工艺不稳定和气孔等缺陷。为了保证材料的完整性,必须在不稳定发生之前检测到它,这是非常具有挑战性的。本文提出了一种由CTWD漂移引起的过程不稳定性的原始预测模型。在机器人单元上收集过程监测数据,并提取16个关键特征作为CTWD漂移估计的潜在监测准则。然后通过多种滤波方法进行特征选择,通过回归模型确定CTWD漂移估计的最佳指标。方差分析用于确定应该考虑哪些关键过程参数(KPP)来微调线性回归模型。然后,基于方差分析识别的专用KPP,建立支持向量回归(SVR)模型来预测不稳定边界T*。通过将估计的CTWD漂移和漂移速度与预测边界T*相结合,该模型预测了过程不稳定发生前的剩余层数(nRL)。在薄壁制造用例中对该方法进行了评估。不稳定性预测与观察一致,展示了模型预测缺陷的能力。金相检验证实了不稳定性对材料完整性的影响。实时监测、数据驱动模型和可解释的人工智能相结合,为改善WAAM控制提供了一个强大且可解释的框架,同时为制造专家提供了关于KPP的新见解,用于不稳定预测和主动干预。
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Additive manufacturing
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