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Influence of nanofillers and masterbatch on properties of siloxane materials 纳米填料和母粒对硅氧烷材料性能的影响
Pub Date : 2022-01-01 DOI: 10.5937/savteh2202005r
I. Ristić, Darko Manjenčić, M. Kostić, N. Vukić, S. Cakić, T. Radusin, V. Teofilović
Nanocomposites based on siloxane and silicon(IV)oxide nanoparticles (with a hydrophilic and hydrophobic surface) were synthesized to design the desired final properties of the composite material. Masterbatch, a mixture of siloxane containing vinyl functional groups and reinforcing fillers, was added to improve the mechanical properties and topology of siloxane networks. Silicon(IV)oxide was added in amounts of 1, 5, 10, and 20 wt% and masterbatch in amounts of 5 and 10 wt% to examine the effect of the amounts of fillers and masterbatch in the synthesized samples. Fourier transform infrared spectroscopy was used to analyze the chemical structure of the obtained materials. Transmission electron microscopy (TEM) was used to examine the dispersion of filler particles in siloxane nanocomposites. To examine the thermal stability and phase transition temperature of siloxane materials, thermogravimetric analyzes (TGA) and differential scanning calorimetry (DSC) were performed. The addition of masterbatch did not lead to a significant difference in melting temperature, but stoichiometry was disturbed, which decreased the thermal stability compared to samples without masterbatch. The addition of masterbatch to nanocomposites with hydrophilic fillers increases both elongations at break and tensile strength. According to the results, the combination of masterbatch and nanofillers affects the properties of siloxane materials, which could enable obtaining materials with the desired properties.
制备了基于硅氧烷和氧化硅纳米颗粒(具有亲疏水表面)的纳米复合材料,以设计所需的复合材料的最终性能。母粒是含有乙烯基官能团的硅氧烷和增强填料的混合物,加入母粒可以改善硅氧烷网络的力学性能和拓扑结构。硅(IV)氧化物添加量为1、5、10和20 wt%,母粒添加量为5和10 wt%,以检查合成样品中填料和母粒数量的影响。利用傅里叶变换红外光谱对所得材料的化学结构进行了分析。采用透射电子显微镜(TEM)研究了填料颗粒在硅氧烷纳米复合材料中的分散情况。采用热重分析(TGA)和差示扫描量热法(DSC)研究了硅氧烷材料的热稳定性和相变温度。色母粒的加入对样品的熔融温度没有显著影响,但其化学计量受到干扰,与未添加色母粒的样品相比,热稳定性下降。在含有亲水性填料的纳米复合材料中加入母粒可以提高断裂伸长率和抗拉强度。结果表明,母粒与纳米填料的组合可以影响硅氧烷材料的性能,从而获得具有理想性能的材料。
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引用次数: 0
Linear compact localized modes in flux-dressed two-dimensional plus lattice 带通量二维正晶格中的线性紧致局域模
Pub Date : 2022-01-01 DOI: 10.5937/savteh2202036m
A. Mančić, M. Stojanović, M. Stepić
It was studied a photonic linear two-dimensional plus lattice dressed by the artificial flux and explored the influence of the artificial gauge field on the energy band spectrum. The Aharonov-Bohm effect has caused the appearance of flat zones and for certain values of the flux, the lattice spectrum has been described by two momentum independent, fully degenerated flatbands and three dispersive bands. Three different types of fundamental non-orthogonal compactons have been obtained. The findings presented in this study could be tested in practice and they may be used for probing different artificial flatband systems, e. g. ultracold atoms in optical lattices, polariton condensates etc.
研究了人工通量修饰的光子线性二维正晶格,探讨了人工规范场对能带谱的影响。Aharonov-Bohm效应引起了平坦带的出现,对于一定的通量值,晶格谱可以用两个动量独立的完全简并的平坦带和三个色散带来描述。得到了三种不同类型的基本非正交紧子。本研究结果可以在实践中进行验证,并可用于探测不同的人工平带体系,如光学晶格中的超冷原子、极化子凝聚体等。
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引用次数: 0
Antimicrobial activity and overall sensory acceptance of fermented goat whey beverage: Process conditions optimization using response surface approach 发酵山羊乳清饮料的抗菌活性和整体感官接受度:利用响应面法优化工艺条件
Pub Date : 2022-01-01 DOI: 10.5937/savteh2202026k
Ivana T. Karabegović, Sandra Stamenkovic-Stojanovic, M. Lazić, Natalija Đorđević, B. Danilović
Even though it contains high levels of many important nutritive compounds, whey has not been widely accepted by consumers due to its unappealing taste and texture. Whey fermentation could improve its sensory properties and result in a functional beverage with appealing characteristics and a clear potential to replace traditional functional milk-based beverages. Therefore, this work aimed to develop a goat whey-based functional beverage fermented with kefir grains and to examine the influence of fermentation temperature and inoculum size on the overall sensorial acceptability of the product and its antimicrobial activity. Response surface methodology along with the central composite design was used to estimate the individual and combined effect of temperature and inoculum size on lactic and acetic acid, ethanol, antimicrobial activity and overall sensory acceptability of the obtained beverage. The experimental data for lactic and acetic acid, antimicrobial activity and overall sensory acceptance of beverage were fitted to a quadratic model, while a linear 2FI model was proposed for the ethanol content. Temperature and inoculum size have been found to affect the quality of the obtained beverage. Multi-response optimization provided an optimum solution for the production of the most acceptable beverage with the highest antimicrobial activity. According to desirability criteria, with overall desirability of 0.79, the following fermentation conditions were proposed for the fermentation of goat whey using kefir: temperature of 27.5 ° C and inoculum size of 7.36%. Proposed values were validated confirming the minimum deviation of experimental and predicted values.
尽管乳清含有大量重要的营养化合物,但由于其味道和质地不吸引人,消费者还没有广泛接受它。乳清发酵可以改善其感官特性,从而产生具有吸引人的特性的功能饮料,并有明显的潜力取代传统的功能性乳基饮料。因此,本研究旨在开发一种以山羊乳清为基础的以开菲尔颗粒发酵的功能饮料,并研究发酵温度和接种量对产品整体感官接受度和抗菌活性的影响。采用响应面法和中心复合设计来评估温度和接种量对饮料的乳酸和乙酸、乙醇、抗菌活性和整体感官接受度的单独和联合影响。饮料的乳酸和乙酸、抗菌活性和整体感官接受度的实验数据拟合为二次模型,乙醇含量的实验数据拟合为线性2FI模型。温度和接种量的大小对所得饮料的质量有影响。多响应优化为生产具有最高抑菌活性的可接受饮料提供了最优方案。根据理想度标准,在总体理想度为0.79的条件下,提出了利用开菲尔发酵山羊乳清的发酵条件:温度27.5℃,接种量7.36%。对提出的数值进行了验证,确认了实验值与预测值的最小偏差。
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引用次数: 0
Qualitative and quantitative analysis of the pre-consumer textile waste in North Macedonia 北马其顿消费前纺织品废料的定性和定量分析
Pub Date : 2022-01-01 DOI: 10.5937/savteh2201088m
S. Maksimov, Sonja Jordeva, Silvana Zhezhova, Longurova Golomeova, D. Andronikov
Textile waste in North Macedonia participates with 4.7% in the total composition of the municipal solid waste which is completely landfilled. The purpose of this paper is investigation of the textile waste quantity and quality as a pre-condition for its further management. The results obtained show domination of the apparel cutting waste, the total amount has an average value of 2792.7 tons per year. The further analysis shows that cotton waste is the most represented with 46.4%, then waste from artificial and synthetic fibres with 41.4%. During the research period (2015-2020), 1.42 kg/capita (on average) of pure pre-consumer textile waste with retained physical and mechanical properties is generated annually.
北马其顿的纺织废物占完全填埋的城市固体废物总量的4.7%。本文的目的是调查纺织废料的数量和质量,为进一步管理纺织废料提供前提条件。结果表明,服装裁剪废弃物占主导地位,年均总量为2792.7吨。进一步分析表明,棉花废料占46.4%,其次是人造纤维和合成纤维废料占41.4%。在研究期间(2015-2020年),每年人均(平均)产生1.42 kg的保留物理和机械性能的纯消费前纺织废料。
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引用次数: 0
The effect of distillation methods on the yield, composition and biological activity of basil (Ocimum basilicum L.) essential oil 研究了不同蒸馏方法对罗勒挥发油收率、成分及生物活性的影响
Pub Date : 2022-01-01 DOI: 10.5937/savteh2202016d
Natalija Đorđević, Stojan Mančić, Ivana T. Karabegović, D. Cvetković, J. Stanojević, D. Savić, B. Danilović
Basil (Ocimum basilicum L.) is an aromatic plant, well known for its characteristic scent and healing properties, which has a wide application, from cooking to alternative medicine. The objective of this work was to evaluate the chemical composition, antimicrobial and antioxidant activity of basil essential oil obtained by hydrodistillation, microwave-assisted hydrodistillation and solvent-free microwave-assisted hydrodistillation. Gas chromatography analysis showed that the main components present in all three essential oils were linalool (30.3-58.2%) and epi-a-cadinol (5.6-7.3%). The distillation method mainly affected the content of terpenes, and aromatic compounds. The essential oils expressed good antimicrobial activity, most effective against Escherichia coli ATCC 25922, while the Pseudomonas aeruginosa ATCC 27853 was the most resistant strain. Good antioxidant activity was established after 120 min of incubation for all obtained essential oils with a significant difference regarding the applied distillation method. The results showed a great influence of the distillation method on the chemical composition, detected compounds, as well as antioxidant potential and antimicrobial activity of basil essential oils. The use of microwave assisted hydrodistillation has shown a significant difference in oil yield, energy consumption and environmental impact, which makes it a more suitable distillation process compared to conventional hydrodistillation.
罗勒(Ocimum basilicum L.)是一种芳香植物,以其独特的气味和治疗特性而闻名,从烹饪到替代医学都有广泛的应用。摘要研究了通过加氢蒸馏、微波辅助加氢蒸馏和无溶剂微波辅助加氢蒸馏得到的罗勒精油的化学成分、抑菌活性和抗氧化活性。气相色谱分析表明,三种精油的主要成分为芳樟醇(30.3 ~ 58.2%)和外阴-甲二醇(5.6 ~ 7.3%)。蒸馏法主要影响萜烯和芳香族化合物的含量。精油对大肠杆菌ATCC 25922和铜绿假单胞菌ATCC 27853的抑菌效果最好。所有得到的精油在120 min的孵育后都具有良好的抗氧化活性,不同的蒸馏方法有显著差异。结果表明,蒸馏方法对罗勒精油的化学成分、检测到的化合物、抗氧化活性和抑菌活性均有较大影响。微波辅助加氢蒸馏在油收率、能耗和环境影响方面均有显著差异,是一种比常规加氢蒸馏更适合的蒸馏工艺。
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引用次数: 2
Advantages of dyeing wool fibers at 60 °C after previous modification with alcohol 羊毛纤维经前期醇改性后60℃染色的优点
Pub Date : 2022-01-01 DOI: 10.5937/savteh2202062n
M. Nikodijević, S. Konstantinović, Marija Kodrić, D. Đorđević
This research work describes the advantages of dyeing wool fibers at 60 °C after pre-treatment with alcohol. Wool is a natural fiber. This fiber can be dyed with acid, metal-complex and other dyes. Acid dyes should be soluble in water and most commonly used for dyeing wool, silk and nylon. Wool fibers with 100 % chemical composition were used in this study. The wool fiber was pre-treated in alcohol (npentanol) at a temperature of 60 °C for 30 minutes. Pre-treated wool fibers were dyed with Supramin Blau acid dye. The time for dyeing samples of wool fibers was 5, 10, 20, 30, 40, 50 and 60 minutes. The process of dyeing wool fibers with acid dye at 60 °C showed a higher degree of exhaustion and adsorption capacity when wool was pre-treated with n-pentanol compared to wool that was not pre-treated with n-pentanol. A constant increase in the degree of dye exhaustion on the pretreated wool fiber was observed during the increase in initial dye concentration. A longer dyeing time for pre-treated wool results in a higher degree of dye exhaustion. Models Weber-Morris and Elovich are applicable for describing the adsorption flow because there is very little scatter around the ideal curve, so functional straight lines cover most points very well.
本研究介绍了羊毛纤维经酒精预处理后,在60℃下染色的优点。羊毛是一种天然纤维。这种纤维可以用酸、金属络合物和其他染料染色。酸性染料应可溶于水,最常用于染色羊毛、丝绸和尼龙。本研究采用100%化学成分的羊毛纤维。将羊毛纤维在60℃的乙醇(戊醇)中预处理30分钟。用超蛋白蓝酸性染料对预处理羊毛纤维进行染色。羊毛纤维样品染色时间分别为5、10、20、30、40、50、60分钟。在60℃酸性染料染色羊毛纤维的过程中,经正戊醇预处理的羊毛比未经正戊醇预处理的羊毛具有更高的耗竭程度和吸附能力。在初始染料浓度的增加过程中,观察到预处理羊毛纤维的染料耗尽程度不断增加。预处理羊毛染色时间越长,染料耗损程度越高。Weber-Morris和Elovich模型适用于描述吸附流动,因为理想曲线周围的散射很小,所以功能直线很好地覆盖了大多数点。
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引用次数: 0
UHPLC-DAD-ESI-MS analysis of the 'Centaurium erythraea' infusion 半人马草注射液的hplc - dad - esi - ms分析
Pub Date : 2022-01-01 DOI: 10.5937/savteh2201013n
V. Nikolić, J. Zvezdanović, S. Konstantinović
Chemical composition was estimated in a tea sample, i.e. infusion prepared from dried aerial herb of Centaurium erythraea. The plant was harvested in the Stara Planina mountain (Serbia, 42°43'00"N; 24°55'04"E) during the flowering stage. The flowering tops of the plant were dried to the moisture content of 7.89 (w/w) in a dark place. Qualitative analysis was done by Ultrahigh performance liquid chromatography-diode array detector-electrospray mass spectrometry (UH-PLC-DAD-ESI-MS/MS) method. The aim of this study was to detect and identify phytochemicals in the infusion prepared in a traditional way and present it as a good source of biologically active substances and bio-antioxidants. The analysis of C. erythraea infusion primarily indicated the presence of secoiridoid glycosides (sweroside, gentiopicroside, secologanoside, swertiamarin), xanthones and flavo-noids, which promises good quality of tea from Eastern Serbia.
化学成分估计在茶样品,即冲剂配制从干燥的半人马座赤草。该植物在Stara Planina山(塞尔维亚,42°43'00"N;24°55'04"E),在花期。将植株花顶置于阴暗处干燥至水分含量7.89 (w/w)。采用超高效液相色谱-二极管阵列检测器-电喷雾质谱(UH-PLC-DAD-ESI-MS/MS)方法进行定性分析。本研究的目的是检测和鉴定传统方法制备的冲剂中的植物化学物质,并将其作为生物活性物质和生物抗氧化剂的良好来源。通过对赤藓茶泡茶的分析,发现其主要成分为银环醚萜苷类(獐牙菜苷、龙胆苦苷、龙胆皂苷、獐牙菜苦苷)、山酮类和类黄酮,具有优良的东塞尔维亚茶叶品质。
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引用次数: 0
A short review of titania-graphene oxide based composites as a photocatalysts 二氧化钛-氧化石墨烯基复合材料光催化剂的研究进展
Pub Date : 2021-01-01 DOI: 10.5937/savteh2102051s
Katarina Stepic, Radomir Ljupković, Jovana D. Ickovski, A. Zarubica
New and effective methods of water purification are necessary to minimize pollution. Many methods have been used in wastewater treatment, but sorption is considered as an easy and economic process. The efficiency of any sorption process mainly depends on the physicochemical properties of the used adsorbent. Since photocatalysts can initiate reactions of decomposition organic contaminants under ultraviolet or sunlight irradiation without using chemicals or producing chemical wastes, photocatalytic reactions are considered a sustainable way to remove a variety of environmental pollutants. Ultraviolet water purification became the most effective method of water disinfection and purification. Heterogeneous semiconductor photocatalysts have recently emerged as an efficient material for purifying water. The crystal structure is crucial for photocatalytic activity and efficiency of semiconductors, thus optimal parameters must be provided during the preparation of photocatalysts. To overcome problems with semiconductors usage, the use of co-catalysts and photocatalyst carriers is one of the solutions. Recently, much emphasis has been placed on using graphene oxide (GO) supported semiconductor photocatalysts. In this paper, a short review of composites of titanium dioxide and graphene oxide-based materials is given.
新的和有效的水净化方法是必要的,以尽量减少污染。废水处理的方法有很多,但吸附被认为是一种简单、经济的处理方法。任何吸附过程的效率主要取决于所用吸附剂的物理化学性质。由于光催化剂可以在紫外线或日光照射下引发分解有机污染物的反应,而不使用化学品或产生化学废物,因此光催化反应被认为是一种可持续去除多种环境污染物的方法。紫外线净水成为最有效的水消毒净化方法。非均相半导体光催化剂是近年来发展起来的一种高效的水净化材料。晶体结构对半导体的光催化活性和效率至关重要,因此在制备光催化剂时必须提供最佳的参数。为了克服半导体的使用问题,使用共催化剂和光催化剂载体是解决方案之一。近年来,使用氧化石墨烯(GO)负载的半导体光催化剂受到了广泛的关注。本文综述了二氧化钛与氧化石墨烯基复合材料的研究进展。
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引用次数: 2
Compression properties of knitted fabrics printed by sublimation transfer printing technique 升华转移印花针织物的压缩性能
Pub Date : 2021-01-01 DOI: 10.5937/savteh2101046s
S. Stojanović, J. Geršak, D. Trajković
Compression properties of textile materials are useful for determining fullness, softness, smoothness, and stiffness. In addition, compression parameters have significant influence on fabric hand value and quality of textile materials. The present paper reports a study of the sublimation printing process influence on the change in compression properties of knitted fabrics (polyester, cotton, and cotton/ polyester) intended for sportswear manufacturing. For that purpose, the KES-FB3-A Compression Tester was used for measuring compression parameters of knitted fabrics. The parameters, which contributed to the smallest reduction percentage in compression properties of polyester knitted fabrics were yarn linear density and weight. For cotton-rich knitted fabrics sublimation coating powder was used for paper modification to bond disperse dyes to cotton fibres. The analysis of the results showed that the printing process had a smaller influence on the change of compression parameters of polyesters in relation to cotton and cotton/polyester knitted fabrics. It was noted that the printing process had the effect of thickness reduction for all knitted fabrics to varying degrees. Printing process contributed to small decrease in compressibility and specific volume values for polyester knitted fabrics. The modification process contributed to the significant reduction of the compressibility for cotton (from 34.46% to 47.89%) and cotton/polyester (from 38.81% to 50.75%) knitted fabrics. In addition, reduction in specific volume values range from 41.86% to 44.19% for cotton and from 42.37% to 45.75% for cotton/ polyester knitted fabrics was notted.
纺织材料的压缩性能对确定丰满度、柔软度、平滑度和刚度是有用的。此外,压缩参数对织物的手值和纺织材料的质量有显著影响。本文报道了一项研究升华印花工艺对用于运动服装制造的针织物(涤纶、棉和棉/涤纶)压缩性能变化的影响。为此,使用KES-FB3-A压缩测试仪测量针织物的压缩参数。对涤纶针织物压缩性能降低百分比最小的参数是纱线线密度和纱线重。对富棉针织物采用升华涂布粉进行纸张改性,使分散染料与棉纤维结合。分析结果表明,印花工艺对涤纶压缩参数变化的影响要小于棉和棉/涤纶针织物。指出印花工艺对所有针织物都有不同程度的减薄作用。印花工艺对涤纶针织物的可压缩性和比体积值有较小的影响。改性工艺使棉织物的可压缩性(从34.46%降至47.89%)和棉/涤纶针织物的可压缩性(从38.81%降至50.75%)显著降低。此外,棉和棉/涤纶针织物的比体积值分别减少41.86%至44.19%和42.37%至45.75%。
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引用次数: 0
The effect of the nitrogen source type on the growth and consumption of crude glycerol by Streptomyces hygroscopicus CH-7 不同氮源类型对吸湿链霉菌CH-7生长和消耗粗甘油的影响
Pub Date : 2021-01-01 DOI: 10.5937/savteh2101041i
S. Ilić, J. Ćirić, G. Gojgić-Cvijović
In this paper we studied the effect of different amino acids (arginine, tryptophan, tyrosine, and phenylalanine) as nitrogen sources on the growth of actinomycete Streptomyces hygroscopicus CH-7 and the consumption of crude glycerol, obtained as a by-product in the biodiesel production from sunflower oil. The highest biomass concentration (9.5 g/L) was achieved using the basic medium and the medium with tryptophan (9.2 g/L), while the crude glycerol consumption was the highest in the basic medium (5.9 mg/mL) and the medium with phenylalanine (3.3 mg/mL).
本文研究了不同氨基酸(精氨酸、色氨酸、酪氨酸和苯丙氨酸)作为氮源对吸湿链霉菌CH-7生长和葵花籽油生产生物柴油副产物粗甘油消耗的影响。基础培养基和添加色氨酸的培养基(9.2 g/L)的生物量浓度最高,为9.5 g/L,而粗甘油消耗量在基础培养基(5.9 mg/mL)和添加苯丙氨酸的培养基(3.3 mg/mL)中最高。
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引用次数: 0
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Advanced Technologies
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