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Cure-state dependent viscoelastic Poisson’s ratio of LY5052 epoxy resin LY5052环氧树脂固化态粘弹性泊松比
Q3 ENGINEERING, MANUFACTURING Pub Date : 2017-07-03 DOI: 10.1080/20550340.2017.1348002
S. Saseendran, M. Wysocki, J. Varna
Abstract It is shown, using thermodynamically consistent linear viscoelastic material model that accounts for properties dependence on test temperature and cure state parameters, that for rheologically simple materials the cure and temperature related reduced times and shift factors are the same for all viscoelastic compliances, relaxation modulus, and Poisson’s ratio as well as for the storage and loss modulus. A necessary condition for that is that the cure and temperature parameters are affecting the reduced time only. This means that the Poisson’s ratio of polymeric materials, which for simplicity is often assumed constant, in fact exhibits a small dependence on time which is affected by temperature and state of cure. In this work, the evolution of the viscoelastic Poisson’s ratio of the commercial LY5052 epoxy resin is studied in relaxation test subjecting the specimen to constant axial strain. Specimens at several cure states are studied and Poisson’s ratio, defined as the lateral and axial strain ratio, is shown to evolve from 0.32 to 0.44 over time. Moreover, the data confirm that the cure state-dependent reduced time controlling the Poisson’s ratio development leads to the same shift functions as those identified in DMTA tests for storage modulus. The latter measurements also confirmed that the total shift can be considered as a sum of two shifts in the frequency domain, which means that function for reduced time calculation can be written as a product of two functions: one dependent on the test temperature and another one dependent on the cure state.
摘要:利用考虑性能依赖于测试温度和固化状态参数的热力学一致线性粘弹性材料模型,表明对于流变简单的材料,固化和温度相关的减少时间和移位因子对于所有粘弹性柔度、松弛模量、泊松比以及存储模量和损耗模量都是相同的。这样做的一个必要条件是固化和温度参数只影响缩短时间。这意味着聚合物材料的泊松比(为简单起见,通常假定为常数)实际上与受温度和固化状态影响的时间关系不大。本文研究了商用LY5052环氧树脂在恒定轴向应变下的松弛试验中粘弹性泊松比的演变规律。研究了几种固化状态下的试样,泊松比(定义为侧向应变比和轴向应变比)随着时间的推移从0.32演变到0.44。此外,数据证实,固化状态相关的减少时间控制泊松比的发展导致相同的位移函数在DMTA测试中确定的存储模量。后一种测量还证实,总位移可以被认为是两个频域位移的总和,这意味着用于减少时间计算的函数可以写成两个函数的乘积:一个依赖于测试温度,另一个依赖于固化状态。
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引用次数: 21
Factors affecting the properties of composites made by 4D printing (moldless composites manufacturing) 影响4D打印复合材料性能的因素(无模复合材料制造)
Q3 ENGINEERING, MANUFACTURING Pub Date : 2017-07-03 DOI: 10.1080/20550340.2017.1355519
S. Hoa
Abstract 3D printing is the process where layers of materials are deposited to make structures of complex geometries. 4D printing is a process that combines 3D printing with the application of some activating agent in order to change the shape of the manufactured part after the process, e.g. the flat structure will change its shape to take up the desired complicated shape such as “curved” or “S” shaped. As such the 3D printing process does not have to spend time to print the intricate parts, and the process can be faster. The requirement for 4D printing is that materials with special characteristics that are responsive to an activating agent need to be used. 4D printing of composites utilizes the same concept of 4D printing, except that the materials used are long fiber composite materials. 4D printing of composites utilizes the shrinkage of the matrix resin, and the difference in coefficients of thermal contraction of layers with different fiber orientations to activate the change in shape upon curing and cooling. This behavior can be used to make parts with curved geometries without the need for a complex mold. As such manufacturing of pieces of curved shapes can be fast and economical. However, the degree of shape changing depends on the material properties, the fiber orientation, the lay up sequence and the manufacturing process. This paper presents the results obtained from a study on the effects of these aspects on the shape of the curved parts.
3D打印是将材料层沉积以制造复杂几何结构的过程。4D打印是将3D打印与某些活化剂的应用相结合,以改变加工后制造零件的形状的过程,例如平面结构会改变其形状,呈现出所需的复杂形状,如“弯曲”或“S”形。因此,3D打印过程不必花费时间来打印复杂的部件,并且过程可以更快。4D打印的要求是需要使用对活化剂有反应的具有特殊特性的材料。复合材料的4D打印利用了与4D打印相同的概念,只是使用的材料是长纤维复合材料。复合材料的4D打印利用基体树脂的收缩和不同纤维取向层的热收缩系数的差异来激活固化和冷却时形状的变化。这种行为可以用来制造具有弯曲几何形状的零件,而不需要复杂的模具。因此,曲面件的制造既快速又经济。然而,形状变化的程度取决于材料性能、纤维取向、铺层顺序和制造工艺。本文介绍了这些因素对曲面零件形状影响的研究结果。
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引用次数: 20
Characterizing short-fiber-reinforced composites produced using additive manufacturing 表征使用增材制造生产的短纤维增强复合材料
Q3 ENGINEERING, MANUFACTURING Pub Date : 2017-06-26 DOI: 10.1080/20550340.2017.1341125
M. Ivey, Garrett W. Melenka, J. Carey, C. Ayranci
Abstract Material extrusion additive manufacturing (MEAM), a sub-branch of three-dimensional (3D) printing is growing in popularity. Test specimens were 3D-printed using commercial polylactic acid (PLA) filament, and PLA filament reinforced with short-carbon fibers (PLA/CF). As-printed specimens and specimens that were annealed at three different temperatures, then subjected to tensile testing. The internal microstructures of the samples were also examined. The effects of the short-carbon fiber fillers on the mechanical properties of 3D-printed PLA were investigated, and the effects of the annealing process on polymer crystallinity and mechanical properties. The annealing process was shown to increase the crystallinity of both sample groups, though no statistically significant effect of annealing on mechanical properties was observed. The tensile properties of the PLA and PLA/CF filaments showed that the addition of carbon fibers to the PLA filament led to a significant increase in elastic modulus of the MEAM samples.
摘要材料挤压增材制造(MEAM)是三维(3D)打印的一个分支,越来越受欢迎。测试样品使用商用聚乳酸(PLA)长丝和短碳纤维(PLA/CF)增强的PLA长丝进行3d打印。打印样品和在三种不同温度下退火的样品,然后进行拉伸测试。并对样品的内部组织进行了分析。研究了短碳纤维填料对3d打印PLA力学性能的影响,以及退火工艺对聚合物结晶度和力学性能的影响。退火过程提高了两组样品的结晶度,但未观察到退火对机械性能的统计学显著影响。PLA和PLA/CF长丝的拉伸性能表明,在PLA长丝中加入碳纤维可以显著提高MEAM样品的弹性模量。
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引用次数: 98
Study and characterization of LDPE/Polyolefin elastomer and LDPE/EPDM blend: effect of chlorinated water on blend performance LDPE/聚烯烃弹性体及LDPE/EPDM共混物的研究与表征:氯化水对共混物性能的影响
Q3 ENGINEERING, MANUFACTURING Pub Date : 2017-04-03 DOI: 10.1080/20550340.2017.1319114
N. Samarth, P. Mahanwar
Abstract The free chlorine present in water which is used as a disinfectant is reported to reduce the life of the polymeric material. The objective of this work is to study the influence of chlorine concentration on low-density polyethylene (LDPE) and blends of LDPE with ethylene butene copolymer (EBC) and ethylene propylene diene terpolymer (EPDM). The LDPE blend with EBC and EPDM were tested with water containing 50, 500, and 5000 ppm chlorine under static condition for 500 h at 25 and 80 °C. It has been seen that at 5000 ppm chlorine concentration, the mechanical properties of LDPE, LDPE/EBC blend, and LDPE/EPDM blend changed drastically and a significant reduction in the elongation at break was found for LDPE, LDPE/EBC, and LDPE/EPDM blend. LDPE/EPDM shows stable modulus value for 5000 ppm as 80 °C. Chemical changes in the aged sample were studied by Fourier transform infrared spectroscopy (FTIR) where an increase in the O–H and C=O peaks were observed. The thermal characteristics of LDPE, LDPE/EBC blend, and LDPE/EPDM blends were investigated using DSC and TGA which shows that the melting temperature and crystalline melt temperature remains unchanged while percent crystallinity increases slightly. Scanning electron microscope showed that there was the formation of microcracks and cavities on the fracture surface of LDPE, LDPE/EBC blend, and LDPE/EPDM blend after exposure to a higher concentration of chlorine indicative of degradation. Furthermore, the Chlorine resistance of LDPE/EPDM blend at 5000 ppm chlorine concentration is much higher than that of pristine LDPE.
摘要据报道,水中的游离氯用作消毒剂会降低高分子材料的使用寿命。本研究的目的是研究氯浓度对低密度聚乙烯(LDPE)及其与乙烯丁烯共聚物(EBC)和乙丙二烯三元共聚物(EPDM)共混物的影响。将EBC和EPDM的LDPE共混物在含氯50、500和5000 ppm的水中,在25和80℃的静态条件下测试500 h。结果表明,在5000ppm氯浓度下,LDPE、LDPE/EBC共混物和LDPE/EPDM共混物的力学性能发生显著变化,断裂伸长率显著降低。LDPE/EPDM在80°C下,在5000 ppm条件下显示稳定模量值。傅里叶变换红外光谱(FTIR)研究了老化样品的化学变化,观察到O - h和C=O峰的增加。采用DSC和TGA对LDPE、LDPE/EBC共混物和LDPE/EPDM共混物的热特性进行了研究,结果表明,LDPE/EBC共混物的熔融温度和结晶熔体温度保持不变,结晶度略有提高。扫描电镜显示,LDPE、LDPE/EBC共混物、LDPE/EPDM共混物在较高氯浓度下,断口表面出现微裂纹和空腔,表明其降解。此外,在5000 ppm氯浓度下,LDPE/EPDM共混物的耐氯性能远高于原始LDPE。
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引用次数: 5
In-situ simultaneous measurement of strain and temperature in automated fiber placement (AFP) using optical fiber Bragg grating (FBG) sensors 利用光纤布拉格光栅(FBG)传感器对自动光纤铺放(AFP)过程中的应变和温度进行原位同时测量
Q3 ENGINEERING, MANUFACTURING Pub Date : 2017-04-03 DOI: 10.1080/20550340.2017.1317447
E. Oromiehie, B. Gangadhara Prusty, P. Compston, G. Rajan
Abstract There has been a tremendous growth of utilizing automated fiber placement (AFP) to manufacture highly precise components and large structures like fuselage panels and wing skins for high-end applications in aircrafts and next generation of spacecrafts. Consequently, in-situ identification of potential defects and strain level within the laminates is critical to ensure the quality and integrity of the final product. In this study, optical fiber Bragg grating sensors (FBGs) have been implemented as an on-line monitoring technique for simultaneous measurement of strain and temperature in AFP. In addition, it is also shown that, the embedded FBG sensors can remain within the laminate for continuous health monitoring after manufacturing process toward the identification of crack induced acoustic emissions.
在飞机和下一代航天器的高端应用中,利用自动纤维放置(AFP)制造高精度部件和大型结构,如机身面板和机翼蒙皮,已经取得了巨大的增长。因此,在层压板内的潜在缺陷和应变水平的原位识别对于确保最终产品的质量和完整性至关重要。在这项研究中,光纤布拉格光栅传感器(fbg)已经实现了一种在线监测技术,用于同时测量AFP中的应变和温度。此外,还表明,在制造过程中,嵌入式FBG传感器可以留在层压板内进行连续健康监测,以识别裂纹声发射。
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引用次数: 37
Parametric optimization of the processing of all-cellulose composite laminae 全纤维素复合材料层的工艺参数优化
Q3 ENGINEERING, MANUFACTURING Pub Date : 2017-04-03 DOI: 10.1080/20550340.2017.1324351
M. Mat Salleh, K. Magniez, S. Pang, J. Dormanns, M. Staiger
Abstract Single-polymer composites based on cellulose I and/or II (aka all-cellulose composites) are emerging as a class of high-performance bio-based composite materials with mechanical properties suited to structural applications. There are various synthesis routes for the preparation of all-cellulose composites. However, little has been reported on the optimization of the processing variables affecting the properties of all-cellulose composites. In the present work, a range of all-cellulose composites were produced as single laminae via solvent infusion processing using a precursor of cellulose II fibers that were assembled as a woven 2D textile. The effects of dissolution time, dissolution temperature, and compaction pressure during hot pressing on the properties of the laminae were then systematically examined using a Taguchi design of experiment approach in order to identify the critical control factors. The tensile properties, fiber volume fraction, and crystallinity of the laminae were determined. Statistical analysis of variance and the signal-to-noise ratio were used to rank the importance of key control factors.
基于纤维素I和/或II的单聚合物复合材料(又称全纤维素复合材料)是一类高性能的生物基复合材料,具有适合结构应用的机械性能。制备全纤维素复合材料的合成路线多种多样。然而,关于影响全纤维素复合材料性能的工艺变量优化的报道很少。在目前的工作中,一系列全纤维素复合材料通过溶剂灌注处理,使用纤维素II纤维的前体,组装成编织的二维纺织品,作为单层生产。采用田口设计的实验方法,系统考察了热压过程中溶解时间、溶解温度和压实压力对薄片性能的影响,以确定关键控制因素。测定了薄片的拉伸性能、纤维体积分数和结晶度。采用方差统计分析和信噪比分析对关键控制因素的重要性进行排序。
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引用次数: 10
Heating rate effects on thermal analysis measurement of Tg in composite materials 加热速率对复合材料中Tg热分析测量的影响
Q3 ENGINEERING, MANUFACTURING Pub Date : 2017-04-03 DOI: 10.1080/20550340.2017.1315908
A. Yong, G. Sims, S. Gnaniah, S. Ogin, P. Smith
Abstract Three measurement techniques used to measure the glass transition temperature (Tg) have been subjected to a critical comparison; dynamic mechanical analysis (DMA), thermomechanical analysis, and differential scanning calorimetry. A new procedure, whereby different specimens are tested over a range of heating rates, has been used in order to eliminate the effects of thermal lag and determine a Tg independent of heating rate (Tg(0)). It has been shown that for measurements of Tg(0) for composites, the DMA thermal lag “corrected” method gave the most reliable data. The work has provided additional guidance on these techniques that could usefully be incorporated in future standards, to improve precision, comparisons, and consistency of Tg measurement.
摘要对三种测量玻璃化转变温度(Tg)的技术进行了比较;动态力学分析(DMA)、热力学分析和差示扫描量热法。为了消除热滞后的影响并确定与加热速率无关的Tg(Tg(0)),已经使用了一种新的程序,即在不同的加热速率范围内测试不同的试样。研究表明,对于复合材料Tg(0)的测量,DMA热滞后“修正”方法给出了最可靠的数据。这项工作为这些技术提供了额外的指导,可以有效地纳入未来的标准,以提高Tg测量的精度、比较和一致性。
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引用次数: 38
Corrugated composites: production-integrated quality assurance in carbon fiber reinforced thermoplastic sine wave beam production 波纹复合材料:生产一体化的质量保证在碳纤维增强热塑性正弦波梁生产
Q3 ENGINEERING, MANUFACTURING Pub Date : 2017-01-02 DOI: 10.1080/20550340.2017.1283100
Frederic J. C. Fischer, Matthias Beyrle, Arthur-Hans Thellmann, Manuel Endrass, Thomas Stefani, T. Gerngross, M. Kupke
Abstract Carbon fiber-reinforced thermoplastics offer the possibility for short lead times and dustless assembly in aerospace applications. However, their great potential for efficient processing to date is not entirely exploited. At the Center for Lightweight Production Technology (ZLP) in Augsburg smart automation of thermoplastic composite production is investigated. To assess the overall process chain a sine wave beam designed as crash-absorber serves as demonstrator. The production process from as-delivered material to final assembly is presented. In addition to non-destructive testing at the end of the value adding process chain, production-integration quality assurance, and process characterization serve to evaluate each process step. In this context, water-coupled ultrasonic testing as an established method in aerospace production is used to assess the degree of consolidation after vacuum consolidation and press-forming. Thus, quality issues and crucial process parameters can be identified and optimized to improve robustness.
碳纤维增强热塑性塑料在航空航天应用中提供了缩短交货时间和无尘组装的可能性。然而,迄今为止,它们在有效处理方面的巨大潜力尚未得到充分利用。在奥格斯堡的轻量化生产技术中心(ZLP),热塑性复合材料生产的智能自动化进行了研究。为了评估整个过程链,一个设计为碰撞减震器的正弦波束作为演示。介绍了从交货到总装的生产过程。除了在增值工艺链末端的无损检测之外,生产集成质量保证和工艺表征有助于评估每个工艺步骤。在这种情况下,水耦合超声测试作为航空航天生产中的既定方法,用于评估真空固结和压制成型后的固结程度。因此,质量问题和关键工艺参数可以识别和优化,以提高鲁棒性。
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引用次数: 9
The advanced ply placement process – an innovative direct 3D placement technology for plies and tapes 先进的铺层工艺-一种创新的铺层和胶带直接3D铺层技术
Q3 ENGINEERING, MANUFACTURING Pub Date : 2017-01-02 DOI: 10.1080/20550340.2017.1291398
Marko Szcesny, F. Heieck, S. Carosella, P. Middendorf, H. Sehrschön, M. Schneiderbauer
Abstract Breaking down the cost structure of state-of-the-art CFRP part shows that a major share of the costs is caused by labor and equipment as well as process energy consumption. Therefore, the main goal of the EU funded FP7 project LOWFLIP (Low Cost Flexible Integrated Composite Process) has been the reduction of these costs by introducing new technologies into CFRP production processes. The LOWFLIP concept focuses on three main aspects:• Development of a new out-of-autoclave (OOA) prepreg system with snap cure capabilities.• Development of a direct 3D placement technology for plies and tapes.• Development of energy efficient and fast heating toolings. The main content of this paper is detailed information on a novel direct 3D prepreg layup process for automated production of large-scale fiber reinforced parts of small and medium lot sizes. The advanced ply placement process, which is able to drape and compact unidirectional prepreg tapes with currently up to 300 mm ply width directly into a double curved tooling, is being introduced. Two large-scale demonstrator parts from the transport and aerospace sector will be presented. Experiences gained during prototype manufacturing will be reflected and benchmarks of the equipment are presented.
通过对最先进的碳纤维复合材料部件的成本结构进行分析,可以发现成本的很大一部分是由人工和设备以及工艺能耗引起的。因此,欧盟资助的FP7项目LOWFLIP(低成本柔性集成复合材料工艺)的主要目标是通过将新技术引入CFRP生产过程来降低这些成本。LOWFLIP的概念主要集中在三个方面:•开发具有快速固化功能的新型非高压灭菌器(OOA)预浸料系统。•开发胶层和胶带的直接3D贴片技术。•开发节能和快速加热工具。本文的主要内容是详细介绍了一种用于中小批量大型纤维增强部件自动化生产的新型直接三维预浸料铺层工艺。目前正在引入先进的铺层工艺,该工艺能够将目前铺层宽度达300毫米的单向预浸料带直接铺成双弯曲模具。来自运输和航空航天部门的两个大型演示部件将被展示。将反映在原型制造过程中所获得的经验,并提出设备的基准。
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引用次数: 22
A three-dimensional transient model for heat transfer in thermoplastic composites during continuous resistance welding 热塑性复合材料连续电阻焊过程的三维瞬态传热模型
Q3 ENGINEERING, MANUFACTURING Pub Date : 2017-01-02 DOI: 10.1080/20550340.2017.1311094
Imad Zammar, M. Huq, I. Mantegh, A. Yousefpour, M. Ahmadi
Abstract The resistance welding technique for thermoplastic composites (TPCs) entails melting the TPC polymer at the joint interface using heat generated by resistive (Joule) heating of a conductive mesh or heating element placed between the surfaces to be welded. The continuous resistance welding (CRW) is an automated large-scale resistance welding technique that consists of a moving voltage source along the heating element creating a continuous weld along its path. This paper presents a transient model that is developed to predict the heat transfer in TPCs in all three dimensions during the CRW process. The model is finite element in nature and includes both the resistive and thermal conductivity behaviors of the material involved. The significance of this modeling approach is that it captures the movement of the electrical connection, as well as the nonuniform distribution of the current and resistive heating along the length and width of the weld seam. The modeling results are compared with experimental data obtained by thermocouples and an infrared camera, and exhibit solid conformance for predicting the trend of variations in weld temperature.
热塑性复合材料(TPC)的电阻焊接技术需要利用放置在待焊接表面之间的导电网或加热元件的电阻(焦耳)加热产生的热量在接合界面熔化TPC聚合物。连续电阻焊(CRW)是一种自动化的大规模电阻焊技术,它由沿加热元件移动的电压源组成,沿着其路径形成连续焊缝。本文提出了一个瞬态模型,该模型可以在三个维度上预测冷堆过程中tpc内的传热。该模型本质上是有限元模型,包含了所涉及材料的电阻和导热行为。这种建模方法的意义在于,它捕捉到了电气连接的运动,以及沿着焊缝长度和宽度的电流和电阻加热的不均匀分布。将模拟结果与热电偶和红外相机的实验数据进行了比较,结果与预测焊缝温度变化趋势的结果一致。
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引用次数: 5
期刊
Advanced Manufacturing: Polymer & Composites Science
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