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Electromechanical Fatigue Properties of Dielectric Elastomer Capacitive Sensors Based on Plantarflexion of the Human Ankle Joint 基于人踝关节跖屈的介质弹性电容传感器的机电疲劳特性
Pub Date : 2023-01-11 DOI: 10.1149/2754-2726/acb21e
A. Persons, Carver Middleton, Erin Parker, J. Ball, R. Burch V., David Macias, C. L. Simpson, S. Elder
Wearable stretch sensors have potential applications across many fields including medicine and sports, but the accuracy of the data produced by the sensors over repeated uses is largely unknown due to a paucity of high-cycle fatigue (HCF) studies on both the materials comprising the sensors and the signal produced by the sensors. To overcome these limitations, using human physiologically-based parameters, stretch sensors were subjected to quasi-static testing and HCF with simultaneous capture of the signal. The strain produced by the sensor was then compared to the strain produced by testing instrument, and the results suggest that the output from the stretch sensors is strongly correlated with output from the testing instrument under quasi-static conditions; however, this correlation deteriorates under fatigue conditions. Such deterioration may be the result of several factors, including a mismatch between the material response to fatiguing and the signal response to fatiguing. From a materials perspective, the shape of the stress-life curve for the polymers comprising the sensors conforms to the Rabinowitz-Beardmore model of polymer fatigue. Based on these results, consideration of the material properties of a stretch sensor are necessary to determine how accurate the output from the sensor will be for a given application.
可穿戴拉伸传感器在包括医学和体育在内的许多领域都有潜在的应用,但由于缺乏对构成传感器的材料和传感器产生的信号的高周疲劳(HCF)研究,传感器在重复使用中产生的数据的准确性在很大程度上是未知的。为了克服这些限制,使用基于人类生理学的参数,对拉伸传感器进行准静态测试和HCF,同时捕获信号。然后将传感器产生的应变与测试仪器产生的应变进行比较,结果表明,在准静态条件下,拉伸传感器的输出与测试仪器的输出密切相关;然而,这种相关性在疲劳条件下恶化。这种劣化可能是几个因素的结果,包括对疲劳的材料响应和对疲劳的信号响应之间的不匹配。从材料的角度来看,包括传感器的聚合物的应力-寿命曲线的形状符合聚合物疲劳的Rabinowitz-Beardmore模型。基于这些结果,有必要考虑拉伸传感器的材料特性,以确定传感器的输出对于给定应用的准确性。
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引用次数: 0
Flexible Graphite-Based Humidity Sensor Using Green Technology 采用绿色技术的柔性石墨基湿度传感器
Pub Date : 2022-12-22 DOI: 10.1149/2754-2726/acadee
A. Mansoori, S. Bansal, Munish Vashishath, Shamim Ahmad
The low-cost graphite based pattern on cellulose paper was investigated in the present work. The graphite pattern used was fabricated by using normal inkjet printer on paper substrate that acted as working substrate as well as sensing material for humidity measurements. The quantitative electrical characterizations were measured by using different saturated salt-solutions producing relative humidity (RH) of 15%–92% at room conditions of 27 °C and 40%RH. The developed humidity sensor shows the sensitivity of 0.57 MΩ/%RH in the whole range of 15%–92%RH with a linearity co-efficient of R2 = 0.968, response (τ res) and recovery (τ rec) time of 294 s and 306 s respectively. The hydrophilic nature of the paper substrate is helpful for sensing, though the fabricated sensor is not so viable in terms of sensitivity, repeatability, and reuse but the method was simple, low-cost, bio-degradable, and use & throw which can be used for flexible and green electronics.
本文研究了低成本的石墨基纤维素纸图案。所使用的石墨图案是通过使用普通喷墨打印机在作为工作基板以及用于湿度测量的传感材料的纸基板上制造的。通过使用在27°C和40%RH的室温条件下产生15%-92%相对湿度(RH)的不同饱和盐溶液来测量定量电学特性。所开发的湿度传感器在15%-92%RH的整个范围内显示出0.57MΩ/%RH的灵敏度,线性系数R2=0.968,响应(τres)和恢复(τrec)时间分别为294s和306s。纸基板的亲水性有助于传感,尽管所制造的传感器在灵敏度、重复性和重复使用方面不太可行,但该方法简单、低成本、可生物降解,可用于柔性和绿色电子产品。
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引用次数: 2
Perspective—6G and IoT for Intelligent Healthcare: Challenges and Future Research Directions 透视——智能医疗的6G与物联网:挑战与未来研究方向
Pub Date : 2022-12-15 DOI: 10.1149/2754-2726/acabd4
Abdul Ahad, Mohammad Tahir
Due to the rise of connected devices, a decentralised, patient-centred paradigm is being adopted in healthcare as an alternative to the traditional hospital and specialist-focused approach. As the healthcare sector expands, more applications will be connected to the network, producing data of various shapes and sizes that will allow for customised and remote healthcare services. Future intelligent healthcare will include a combination of 6G and the Internet of Things (IoT) that will address current limitations related to cellular coverage, network performance and security issues. This paper discusses and sheds light on prospects, associated challenges and future directions.
由于连接设备的兴起,在医疗保健中采用了一种分散的、以患者为中心的模式,作为传统医院和以专家为中心的方法的替代方案。随着医疗保健行业的扩展,更多的应用程序将连接到网络,产生各种形状和大小的数据,从而允许定制和远程医疗保健服务。未来的智能医疗将包括6G和物联网(IoT)的结合,这将解决当前与蜂窝覆盖、网络性能和安全问题相关的限制。本文讨论并阐明了前景、相关挑战和未来方向。
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引用次数: 6
Molecular Anchoring with 4-Mercaptobenzoic Acid and 4-Aminothiophenol for Using Active Nanorods in the Detection of Dopamine 4-巯基苯甲酸和4-氨基噻吩分子锚定在活性纳米棒检测多巴胺中的应用
Pub Date : 2022-12-15 DOI: 10.1149/2754-2726/acabd3
S. Ramírez, F. Díaz, Carlos P. Silva, J. Pavez, J. F. Silva
The incorporation and effective anchorage of gold nanorods in a gold (111) substrate is applied to electrochemical systems to detect dopamine. Gold nanorods (AuNRs) were synthesized in dispersion. They were then incorporated in a metal substrate mediated by self-assembled monolayers (SAMs) which act as structural anchors. Two molecular anchors, 4-mercaptobenzoic acid (4-MBA) and 4 aminothiophenol (4-ATP) are compared by means of the charge density (Q) in desorption of the SAMs, where 4-MBA presented a greater coverage on the metal surface. Both SAMs allowed the effective confinement and communication of the nanostructure to a greater or lesser extent. Characterizations were made to confirm the constructed system. First, the nanostructures synthesized in dispersion were characterized by UV-visible spectroscopy, Transmission electron microscopy and atomic force microscopy. Second, an electrochemical characterization of the working electrodes include impedance was made. The results focus on the impact of the molecular anchor on the activity of the electrochemical sensor, it was determined. Reducing the charge transfer resistance (by at least 90% with appropriate SAMs) of molecularly anchored gold nanorods increases the sensitivity of the electrochemical sensor (at least 20%), the detection of dopamine was studied by square wave voltammetry through a calibration curve, where better sensitivity and detection limit was obtained with the Au/4-MBA/AuNRs system compared to Au/4-ATP/AuNRs.
金纳米棒在金(111)底物中的结合和有效锚固被应用于电化学系统以检测多巴胺。采用分散法制备了金纳米棒。然后将它们掺入由自组装单层(sam)介导的金属基板中,作为结构锚点。通过对两种分子锚点4-巯基苯甲酸(4- mba)和4-氨基噻吩(4- atp)在SAMs脱附过程中的电荷密度(Q)进行比较,其中4- mba在金属表面的覆盖范围更大。两种SAMs都或多或少地实现了纳米结构的有效约束和通信。对所构建的系统进行了表征。首先,利用紫外可见光谱、透射电子显微镜和原子力显微镜对分散合成的纳米结构进行了表征。其次,对包括阻抗在内的工作电极进行了电化学表征。研究了分子锚对电化学传感器活性的影响,确定了分子锚对电化学传感器活性的影响。降低了分子锚定金纳米棒的电荷转移电阻(在适当的SAMs下至少降低90%),增加了电化学传感器的灵敏度(至少20%)。通过校准曲线,方波伏安法研究了Au/4-MBA/AuNRs系统对多巴胺的检测,与Au/4-ATP/AuNRs相比,Au/4-MBA/AuNRs系统获得了更好的灵敏度和检测限。
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引用次数: 2
Review—Micro-Fuel Cell Principal Biosensors for Monitoring Transdermal Volatile Organic Compounds in Humans 微燃料电池主要生物传感器监测人体经皮挥发性有机化合物
Pub Date : 2022-12-07 DOI: 10.1149/2754-2726/aca95b
T. Benhaddouch, Sofia K. Pinzon, D. Landi, John Marcial, Prateek Mehta, Karen Romero, T. Rockward, S. Bhansali, D. Dong
Knowledge of transduction mechanisms in biosensing applications paves the way for ultrasensitive and dynamic detection in living systems. Real-world biosensing applications where ultra-sensitivity and dynamic detection are paramount include monitoring the anesthetic agent concentration during surgery; the slightest variation in concentration can potentially result in a life-threatening overdose or, on the other end of the spectrum, the patient’s awareness during the procedure. We review the benefits and functions of the transcutaneous biosensor device compared with other current technology and discuss the sensor’s capability to accurately measure volatile anesthetic gas concentration in blood using fuel cell technology. We review fundamental concepts of fuel-cell technology for wearable bio-sensing applications. The fuel cell sensor can also continuously monitor other volatile organic compounds making it versatile with numerous potential applications.
生物传感应用中的转导机制知识为在生命系统中进行超灵敏和动态检测铺平了道路。在现实世界中,超灵敏度和动态检测至关重要的生物传感应用包括监测手术过程中的麻醉剂浓度;浓度的微小变化可能会导致危及生命的过量,或者在另一个极端,病人在手术过程中的意识。我们回顾了经皮生物传感器设备与其他现有技术相比的优点和功能,并讨论了传感器使用燃料电池技术精确测量血液中挥发性麻醉气体浓度的能力。我们回顾了燃料电池技术在可穿戴生物传感应用中的基本概念。燃料电池传感器还可以连续监测其他挥发性有机化合物,使其具有许多潜在的应用。
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引用次数: 3
Design and Development of Paper/ZnO–SnO2 Heterostructured Ultra-Fast TENG Based LPG Sensor 基于纸张/ ZnO-SnO2异质结构超快速TENG的LPG传感器设计与研制
Pub Date : 2022-11-21 DOI: 10.1149/2754-2726/aca48b
P. Yadav, Ajeet Singh, Shakti Singh, Dheeraj Kumar
This work establishes a very simple and economical preparation of paper-based triboelectric nanogenerators for self-powered LPG sensing. Magnification in the output of TENG was achieved by ZnO/SnO2 synthesized by hydrothermal. This material has been thoroughly characterized through XRD, UV, FESEM, FTIR, and Nanozetasizer. The average crystallite size of the heterostructure was obtained as 17.59 nm. Bandgap of ZnO/SnO2 material was found as 3.49 eV. FESEM exhibits that present heterostructure material exhibits spherical nature with lots of voids on the film surface. From Nanozetasizer, the diameter of particles resides between the range 50–80 nm with an average particle size as 63.23 nm. The fabricated TENG generates a maximum output voltage of ∼75 volts which is more than the output of paper-based TENG. This TENG was used as a power source to operate a resistive LPG sensing film. The maximum response of 24 and minimum response-recovery times of 120–135 ms were observed, which makes this LPG sensing device ultra-fast.
这项工作建立了一种非常简单和经济的制备纸基摩擦电纳米发电机,用于自供电液化石油气传感。水热法合成ZnO/SnO2可使TENG的输出放大。通过XRD、UV、FESEM、FTIR和纳米化剂对该材料进行了表征。异质结构的平均晶粒尺寸为17.59 nm。ZnO/SnO2材料的带隙为3.49 eV。FESEM显示,所呈现的异质结构材料呈现球形性质,薄膜表面存在大量空隙。从纳米zetasizer上看,颗粒直径在50 ~ 80 nm之间,平均粒径为63.23 nm。制造的TENG产生的最大输出电压为~ 75伏,比纸质TENG的输出电压要高。该TENG被用作操作电阻式液化石油气传感膜的电源。最大响应时间为24毫秒,最小响应恢复时间为120-135毫秒,这使得该液化气传感装置具有超快的速度。
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引用次数: 5
Review—Emerging Trends in the Development of Electrochemical Devices for the On-Site Detection of Food Contaminants 综述——食品污染物现场检测电化学装置的发展趋势
Pub Date : 2022-10-25 DOI: 10.1149/2754-2726/ac9d4a
R. Umapathi, S. M. Ghoreishian, Gokana Mohana Rani, Youngjin Cho, Y. Huh
Traditional laboratory-based sensing strategies for food contaminant detection are often limited because they are time-consuming and expensive and require trained personnel, which makes them unsuitable for routine sensing. Therefore, the scientific and industrial community is showing enormous interest in the design and development of portable sensing devices for the on-site and point-of-care detection of food contaminants. Portability is one of the chief characteristic features of designing contemporary analytical devices. Portable devices have received tremendous attention, as these novel devices have advanced the field of sensing. Various sensing strategies have been utilized for on-site detection of food contaminants. Among these, portable electrochemical devices have emerged vigorously in the past few years. Scientists and industrialists have worked effortlessly to develop portable electrochemical devices for a minute amount of food contaminant detection in water bodies and food products. The current work aims to demonstrate recent research progress related to the design, development, and improvement of portable electrochemical devices for detection of food contaminants.
传统的基于实验室的食品污染物检测传感策略通常是有限的,因为它们耗时且昂贵,并且需要训练有素的人员,这使得它们不适合常规传感。因此,科学界和工业界对设计和开发用于食品污染物现场和护理点检测的便携式传感设备表现出极大的兴趣。便携性是设计现代分析设备的主要特征之一。随着这些新型设备在传感领域的发展,便携式设备受到了极大的关注。各种传感策略已被用于食品污染物的现场检测。其中,便携式电化学设备在过去几年中蓬勃发展。科学家和实业家毫不费力地开发出便携式电化学设备,用于检测水体和食品中的微量食品污染物。目前的工作旨在展示用于检测食品污染物的便携式电化学设备的设计、开发和改进方面的最新研究进展。
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引用次数: 15
Perspective—Doped ZnO Nanostructures Based on Ultraviolet Photosensors 基于紫外光传感器的透视掺杂ZnO纳米结构
Pub Date : 2022-10-19 DOI: 10.1149/2754-2726/ac9b71
S. Young, Yi-Hsing Liu
In the past decades, the variety morphologies and doping zinc oxide (ZnO) nanomaterials have attracted significant attention due to its outstanding properties for photodetectors (PDs). This perspective article provides the state of recent advancements regarding the doping of ZnO-based PDs and discusses future directions of ZnO-based optoelectronic devices. The article can provide a useful reference for those who are interested in PDs.
在过去的几十年里,氧化锌(ZnO)纳米材料由于其在光电探测器(PDs)中的优异性能而引起了人们的广泛关注。本文介绍了zno基PDs掺杂的最新进展,并讨论了zno基光电器件的未来发展方向。本文可以为那些对pd感兴趣的人提供有用的参考。
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引用次数: 3
Molecular Recognition and Quantification of MLH1, MSH2, MSH6, PMS2, and KRAS in Biological Samples 生物样品中MLH1、MSH2、MSH6、PMS2和KRAS的分子识别和定量
Pub Date : 2022-10-04 DOI: 10.1149/2754-2726/ac9740
Raluca-Ioana Ștefan-van Staden, Ruxandra-Maria Ilie-Mihai, M. Coroş, S. Pruneanu
Two stochastic sensors based on modification of nitrogen and boron dopped exfoliated graphene with a complex of protoporphyrin and cobalt, were used for molecular recognition and quantification of MLH1, MSH2, MSH6, PMS2 and KRAS biomarkers in biological samples (whole blood, urine, saliva, tumoral tissue). Limits of determination of fg ml−1 magnitude order and broad linear concentration ranges favorized their determination from very low to higher concentrations in biological samples. The student t-test showed that there is no significant difference between the results obtained by utilizing the two microsensors for screening tests, at 99% confidence level, the results obtained being lowr than the tabulated value.
两个基于氮和硼掺杂的剥离石墨烯与原卟啉和钴复合物修饰的随机传感器用于生物样品(全血、尿液、唾液、肿瘤组织)中MLH1、MSH2、MSH6、PMS2和KRAS生物标志物的分子识别和定量。fg ml−1数量级的测定限值和宽的线性浓度范围有利于生物样品中从非常低到更高浓度的测定。学生t检验表明,在99%的置信水平下,使用两个微传感器进行筛选测试所获得的结果之间没有显著差异,所获得的值低于表中的值。
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引用次数: 6
Nickel Doped Zinc Oxide Thin Films for Visible Blind Ultraviolet Photodetection Applications 镍掺杂氧化锌薄膜在可见光盲紫外光探测中的应用
Pub Date : 2022-10-04 DOI: 10.1149/2754-2726/ac973f
Sunil Agrohiya, Dr Sajjan Dahiya, P. Goyal, Ishpal Rawal, A. Ohlan, Rajesh Poonia, A. Maan
The current research aims to investigate the effect of nickel doping on the structural and opto-electrical characteristics of zinc oxide thin films. Sol-gel spin coating technique has been utilized to deposit Zn1-xNixO (x = 0, 0.005, 0.010, and 0.015) films on glass substrates. X-ray diffraction (XRD) analysis confirms the formation of crystalline zinc oxide thin films with hexagonal wurtzite structure. Williamson-Hall analysis has been performed to study the individual contribution of lattice strain and crystallite size to the peak broadening in the XRD pattern. Scanning electron microscopy (SEM), Photoluminescence spectroscopy, and UV–visible spectroscopic techniques have been used to examine the surface morphology and optical properties of the deposited films. Transient photocurrent measurements have been performed on all the films under the exposure of ultraviolet (UV) light of wavelengths 365 and 254 nm with on/off cycle of 100 s, and various device key parameters such as sensitivity, responsivity, and quantum efficiency, etc have been determined. Sensitivities of the fabricated photodetectors (PDs) are found to be 5463%, 3809%, 3100%, and 831% for pristine ZnO, Zn0.995Ni0.005O, Zn0.99Ni0.01O, and Zn0.985Ni0.015O, respectively. The UV photodetection mechanism, which is based on the interaction between chemisorbed oxygen on the surface of ZnO and photo-generated holes, has been thoroughly discussed.
本研究旨在探讨镍掺杂对氧化锌薄膜结构和光电特性的影响。利用溶胶-凝胶自旋镀膜技术在玻璃衬底上沉积了Zn1-xNixO (x = 0,0.005, 0.010和0.015)薄膜。x射线衍射(XRD)分析证实形成了具有六方纤锌矿结构的结晶氧化锌薄膜。采用Williamson-Hall分析研究了晶格应变和晶粒尺寸对XRD谱峰展宽的影响。扫描电子显微镜(SEM)、光致发光光谱和紫外可见光谱技术已经被用来检查沉积薄膜的表面形貌和光学性质。在波长为365 nm和254 nm的紫外光照射下,以100 s的开/关周期对所有薄膜进行了瞬态光电流测量,并测定了器件的灵敏度、响应率和量子效率等关键参数。对原始ZnO、zn0.995 ni0.0050 o、zn0.99 ni0.010 o和Zn0.985Ni0.015O的检测灵敏度分别为5463%、3809%、3100%和831%。讨论了基于ZnO表面化学吸附氧与光生成空穴相互作用的紫外光探测机理。
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引用次数: 6
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