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Statistical analysis of tropospheric ozone and its precursors using principal component analysis in an urban area of Surat, India 印度苏拉特市区对流层臭氧及其前体的主成分分析统计分析
Pub Date : 2021-12-01 DOI: 10.22104/AET.2021.4834.1308
N. Jariwala, Drashti V. Kapadia
The objective of this study was to investigate the sources of tropospheric ozone (O3) precursors in an urban area using principal component analysis. Chemically reactive conventional pollutants such as carbon monoxide (CO), carbon dioxide (CO2), nitric oxide (NO), and nitrogen dioxide (NO2) as well as some selected meteorological parameters such as global solar radiation (SR), air temperature (AT), relative humidity (RH), wind speed (WS), and wind direction (WD) were incorporated in this analysis. The data obtained from real-time sensor based continuous ambient air quality monitoring stations which are established at Limbayat and Varachha, situated in Surat city, India are used in this study.. O3 data were distributed according to the four seasons owing to variations in the Indian climatic conditions. The occurrence of peak O3 level in the summer afternoon at around 5 p.m. proved the well-known fact of interconnection among temperature, solar radiation, and increment in O3 concentration. Regardless of long-range transformation and stratospheric intrusion, ozone was propagated based on only a single phenomenon, i.e., chemical reaction occurring between key pollutants manifested with large variances in the first two principal components (PCs). WS and WD were found to be the least influencing parameters using Pearson’s correlation coefficient. CO and NO The potencies of CO and NO were remarkable either in the first or second PC observed at both locations with more than 45% concentration, which alluded that the main source of O3 was urban transportation and AT contributed with weightage 50% in PC ascertained key role of photolysis process in the O3 formation.
本研究的目的是利用主成分分析法研究城市地区对流层臭氧(O3)前体的来源。化学反应性的常规污染物,如一氧化碳(CO)、二氧化碳(CO2)、一氧化氮(NO)和二氧化氮(NO2),以及一些选定的气象参数,如全球太阳辐射(SR)、气温(AT)、相对湿度(RH)、风速(WS)和风向(WD),都被纳入该分析。本研究使用了印度苏拉特市Limbayat和Varachha建立的基于实时传感器的连续环境空气质量监测站的数据。由于印度气候条件的变化,臭氧数据按四季分布。O3峰值出现在夏季下午5点左右,证明了气温、太阳辐射和O3浓度增量之间存在着众所周知的相互作用。不考虑远距离转化和平流层入侵,臭氧的传播仅基于一种现象,即关键污染物之间发生的化学反应,在前两个主成分(PCs)中表现出较大的差异。Pearson相关系数分析发现WS和WD是影响最小的参数。CO和NO在浓度均大于45%的第一和第二PC中均表现出显著的浓度,说明城市交通是O3的主要来源,at在PC中占50%的比重,确定了光解过程在O3形成中的关键作用。
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引用次数: 2
The effects of different materials of green roofing on the quantity and quality of stored and drainage water by using simulated rainfall setup 采用模拟降雨装置,研究了不同材料的绿色屋面对储水量和排水量的影响
Pub Date : 2021-09-06 DOI: 10.22104/AET.2021.4662.1271
Hasti Nazemi, F. Misaghi, Ali Ghahramanzadeh
One of the methods to control the rain on the spot and reuse it is the green roof. This method uses a multi-layer system of vegetation on the roof and balcony of a building to absorb part of the rainwater; the volume and peak runoff are also reduced by evaporation, transpiration, and treatment processes. This research was conducted as a field experiment in the hydraulic laboratory of the Agriculture Faculty in the University of Zanjan, Iran. The factors of the study design included a green roof covered with shards of brick and cultivated soil (grass). The experiments were performed at rainfall intensities of 45, 55, and 65 mm/h with 5, 10, and 25 year return periods, respectively. Also, the volume of the water stored and drainage was measured in different conditions. The results of this study showed that regardless of the type of materials used in the green roof, with increasing time, the amount of water stored in the green roof decreased, and the amount of drained water increased. A comparison of the average performance of the brick and grass modifiers for green roofs showed that the volume of the stored water in the grass corrector was higher; if the shards of bricks were used, 69% of the rainfall would be stored, and 31% was drained. However, adding grass to the green roof increased the volume of stored water to 78% and reduced the volume of drainage water to 22%. Also, the presence of grass on the green roof reduced the electrical conductivity by 32% compared to the single brick.
在现场控制雨水并重新利用雨水的方法之一是绿色屋顶。这种方法利用建筑屋顶和阳台上的多层植被系统来吸收部分雨水;体积和峰值径流也通过蒸发、蒸腾和处理过程减少。这项研究是在伊朗赞詹大学农学院水力学实验室进行的实地试验。研究设计的因素包括覆盖着砖块碎片和耕地土壤(草)的绿色屋顶。试验分别在降雨强度为45、55和65 mm/h、5年、10年和25年的条件下进行。测定了不同条件下的储水量和排水量。本研究结果表明,无论绿色屋顶使用何种材料,随着时间的增加,绿色屋顶的储水量减少,排水量增加。对比了砖和草改性剂的平均性能,发现草改性剂的蓄水量更高;如果使用砖块碎片,69%的降雨将被储存,31%被排干。然而,在绿色屋顶上添加草使储水量增加到78%,排水水量减少到22%。此外,与单一砖块相比,绿色屋顶上的草减少了32%的导电性。
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引用次数: 1
The CO2 removal of flue gas using hollow fiber membrane contactor: a comprehensive modeling and new perspectives 利用中空纤维膜接触器去除烟气中的CO2:一个全面的建模和新的观点
Pub Date : 2021-09-05 DOI: 10.22104/AET.2021.5060.1371
Masoud Noordokht, S. Abdoli
In this study, a novel hollow fiber membrane contactor (HFMC) under a non-wet condition was numerically explored by CFD techniques based on the finite element method to capture CO2 from the CH4/CO2 gas mixture. A new design, such as a shell and tube heat exchanger with baffles, was proposed. The MEA, DEA, and TEA, as different amines solutions, were selected as the liquid solvents. A CO2-containing gas mixture and amine solution were passed in the shell side and the tube side of the membrane contactor, respectively. The simulation findings indicated a good agreement with the reported experimental data demonstrating that such a model would evaluate the effects of different parameters during the HFMC system. Specifically, the results showed that the baffles' presence improved the separation efficiency due to the increased residence time on the shell side. The results also indicated that the MEA solution had the highest CO2 absorption. In the new design (shell and tube heat exchanger with baffles), the rising solvent inlet velocity, decreasing gas velocity, and counter-current flow pattern positively affected separation efficiency.
本文采用基于有限元法的CFD技术,对一种新型中空纤维膜接触器(HFMC)在非湿条件下从CH4/CO2混合气体中捕集CO2进行了数值研究。提出了一种新的设计方案,即带挡板的管壳式换热器。选择MEA、DEA和TEA作为不同胺溶液作为液体溶剂。在膜接触器的壳侧和管侧分别通过含co2的混合气和胺溶液。仿真结果与实验数据吻合较好,表明该模型能较好地评价不同参数对HFMC系统的影响。结果表明,挡板的存在提高了分离效率,因为挡板在壳侧停留的时间增加了。结果还表明,MEA溶液具有最高的CO2吸收率。在新设计(带挡板的管壳式换热器)中,溶剂进口速度上升、气体速度下降和逆流流型对分离效率有积极影响。
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引用次数: 2
Social Cost of CO2 emissions in Tehran Waste Management Scenarios and select the scenario based on least impact on Global Warming by using Life Cycle Assessment 德黑兰废物管理情景CO2排放的社会成本,并利用生命周期评估选择对全球变暖影响最小的情景
Pub Date : 2021-08-30 DOI: 10.22104/AET.2021.4338.1222
Fahimeh Rahimi, F. Atabi, J. Nouri, G. Omrani
Climate change includes global warming driven by human-induced emissions of greenhouse gases and the resulting large-scale shifts in weather patterns. Tehran, Iran, has a population of 13 million (2017) and produces about 13,000 tons of municipal solid waste per day and 4.7 million tons annually. This study used the life cycle assessment (LCA) method to calculate all the emissions in different scenarios for Tehran's waste management. The IWM model was used for Phase II of the LCA. The results of the proposed scenarios showed that the highest emission was from greenhouse gases (GHG), which were9.6, 3.2, and 2.7 million tons in the first, second, and third scenarios, respectively. The IPCC reports and the results from the life cycle inventories were used to calculate the social cost analysis for the scenarios based on the CO2 equivalents. The third scenario caused a 71.8% and 17.2% reduction in terms of social costs compared to the first and second scenarios, respectively. Thus, according to the importance of greenhouse gases in global warming, employing a third scenario in the waste management system could effectively reduce greenhouse gases in Tehran.
气候变化包括由人为温室气体排放导致的全球变暖,以及由此导致的天气模式的大规模变化。伊朗德黑兰拥有1300万人口(2017年),每天产生约1.3万吨城市固体废物,每年产生470万吨。本研究采用生命周期评估(LCA)方法计算了德黑兰废物管理不同情景下的所有排放量。IWM模型用于LCA的第二阶段。结果表明,温室气体(GHG)排放量最高,在第一、第二和第三种情景下分别为960万吨、320万吨和270万吨。利用IPCC的报告和生命周期清单的结果,计算了基于二氧化碳当量的情景的社会成本分析。与第一种和第二种情景相比,第三种情景的社会成本分别降低了71.8%和17.2%。因此,根据温室气体在全球变暖中的重要性,在废物管理系统中采用第三种方案可以有效地减少德黑兰的温室气体。
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引用次数: 0
Surface Ignition Using Ethanol on Mo and Al2O3-TiO2 Coated in CI Engine for Environmental Benefits 用乙醇在CI发动机上涂覆Mo和Al2O3-TiO2表面点火以提高环境效益
Pub Date : 2021-08-28 DOI: 10.22104/AET.2021.4591.1261
Balu Pandian
Today, because of expansion in oil costs, restricted petroleum product assets, ecological thought and an unnatural weather change, the ethanol fills have been centered around elective powers. The use of ethanol is more effective in compression ignition (CI) engines because it is about 30 percent more effective than in spark-ignition (SI) engines due to increased combustion efficiency. The use of ethanol in low heat rejection (LHR) engines helps raise the temperature of the combustion chamber, creating a heat barrier around it. The effect of coating the cylinder head, pistons, and valves of a diesel engine with the molybdenum (Mo) and Al2O3+TiO2 is investigated in this work. As a result, the coated pieces of the combustion chamber were accommodated by a heated boundary. The coated and uncoated engines were evaluated under similar engine operating conditions. The CO, HC, and smoke emissions were reduced, but NOx emissions slightly increased for the Al2O3+TiO2 coated engine. As a result, it has the most beneficial environmental effects.
今天,由于石油成本的上涨、石油产品资产的限制、生态思想和非自然的天气变化,乙醇填充已经集中在选择性权力上。在压缩点火(CI)发动机中使用乙醇更有效,因为由于燃烧效率的提高,它比火花点火(SI)发动机的效率高出约30%。在低排热(LHR)发动机中使用乙醇有助于提高燃烧室的温度,在燃烧室周围形成热障。研究了钼(Mo)和Al2O3+TiO2对柴油机缸盖、活塞和气门的涂层效果。结果,燃烧室的涂层片被加热边界容纳。在相似的发动机工况下对涂覆和未涂覆发动机进行了评价。Al2O3+TiO2涂层发动机的CO、HC和烟雾排放量降低,但NOx排放量略有增加。因此,它具有最有利的环境影响。
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引用次数: 0
Vertically aligned carbon nanotube membrane: synthesis, characterization and application in salt water desalination 垂直排列碳纳米管膜的合成、表征及其在海水淡化中的应用
Pub Date : 2021-05-20 DOI: 10.22104/AET.2021.4707.1281
H. Azami, M. Omidkhah
Previous studies used molecular dynamics simulation to assess the feasibility of applying the vertically aligned carbon nanotube membranes (VA-CNT) for salt water desalination. The presented report experimentally determined the potential of salt water desalination by VA-CNT membrane. The VA-CNT membranes were synthesized through the templated-assisted pyrolysis of polybenzimidazole-Kapton inside the pores of anodized aluminium oxide (AAO) and were characterized by several techniques. The permeability, salt rejection, and biofouling tendency of VA-CNT membranes were measured in various operating conditions and the results were compared with performance of commercial reverse osmosis (RO) membrane (BW30). The VA-CNT membranes permeability was about two-fold higher than permeability of RO membrane. Furthermore, VA-CNT membranes had higher stability against biofouling phenomena and, also showed antibacterial activity so that about 70% of adsorbed cells on VA-CNT membranes were killed by CNTs tips which were vertically aligned on the membrane surface. The rejection efficiency of the VA-CNT membrane was comparable to the commercial RO membrane. Finally, chlorine stability studies showed that strong hypochlorite exposure (48000 ppm.h) did not significantly fail the flux and rejection of the VA-CNT membranes confirming their chemical stability. This study shows the high capability of the VA-CNT membrane in the water treatment process.
以往的研究通过分子动力学模拟来评估垂直排列碳纳米管膜(VA-CNT)用于海水淡化的可行性。本报告通过实验确定了VA-CNT膜在海水淡化中的潜力。采用模板辅助热解法在阳极氧化铝(AAO)孔内制备了聚苯并咪唑-卡普顿(polybenzimidazole-Kapton),并对其进行了表征。测试了不同操作条件下VA-CNT膜的渗透性、阻盐性和生物污染倾向,并与商业反渗透(RO)膜(BW30)的性能进行了比较。VA-CNT膜的渗透性比RO膜高2倍左右。此外,VA-CNT膜对生物污垢现象具有更高的稳定性,并且还具有抗菌活性,因此VA-CNT膜上约70%的吸附细胞被垂直排列在膜表面的CNTs尖端杀死。VA-CNT膜的截留效率与商用反渗透膜相当。最后,氯稳定性研究表明,强次氯酸盐暴露(48000 ppm.h)并没有显著影响VA-CNT膜的通量和排斥,证实了它们的化学稳定性。该研究表明了VA-CNT膜在水处理过程中的高性能。
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引用次数: 2
Seasonal variations of gaseous air pollutants (SO2, NO2, O3, CO) and particulates (PM2.5, PM10) in Gazipur: an industrial city in Bangladesh 孟加拉国工业城市加济普尔的气态空气污染物(SO2, NO2, O3, CO)和颗粒物(PM2.5, PM10)的季节变化
Pub Date : 2020-10-01 DOI: 10.22104/AET.2021.4890.1320
Tarmina Akhtar Mukta, Mir Md. Mozammal Hoque, Md. Eusuf Sarker, N. Hossain, Gautom Kumar Biswas
The present study assessed the impacts of seasonal variation on the atmospheric abundance of gaseous air pollutants (SO2, NO2, O3, CO) and particulates (PM2.5 and PM10) at Gazipur city. The air pollution data was collected from the study area using a Continuous Air Monitoring Station (CAMS) (CAMS-4, Gazipur) of DoE from October 2017 to September 2018. The highest concentrations of air pollutants were found in the winter (PM2.5=208 μg/m3, PM10=300 μg/m3, NO2=45.1 ppb, CO=3.91 ppm, O3=4.17 ppb) as opposed to those of the post-monsoon (PM2.5=133μg/m3, PM10=169 μg/m3, NO2=23.52 ppb, CO=2.25 ppm, O3=7.71 ppb), pre-monsoon (PM2.5=115 μg/m3, PM10=216 μg/m3, NO2=33.5 ppb, CO=1.75 ppm, O3=4.23 ppb), and monsoon (PM2.5=37.5 μg/m3, PM10=85.6 μg/m3, NO2=13.9 ppb, CO=0.84 ppm, O3=4.23 ppb). The highest concentration of five air pollutants (PM10, PM2.5, NO2, CO, O3)indicated that the higher pollutant load in the winter was associated with large-scale polluted air transported from the brick kiln at a distance of 5-7 km at the sampling site. The wind-rose data analysis indicated that most of the air during the winter season came to the sampling site from the northern part of the Gazipur district, from the brickfield zones. In contrast, a reverse relationship between the rainfall and atmospheric pollution, temperature, and atmospheric pollution load was observed during the pre-monsoon, monsoon, post-monsoon, and winter. This finding revealed that the lowest concentration of air pollutants during monsoon was associated with the washout effect of precipitation on atmospheric pollutants. A moderate correlation (R2=0.58) between CO and O3 pollutants during the study indicated their atmospheric origin by photochemical reactions was associated with volatile organic compounds (VOCs). PM2.5 showed a positive correlation with PM10 (R2=0.84), indicating that both PM2.5 and PM10 were produced from similar pathways of fossil fuel combustion by automobiles and industrial activities. Further, the air quality index (AQI) analysis showed unhealthy atmospheric conditions throughout the year for city dwellers around the study area.
本研究评估了季节变化对加济浦尔市大气中气态污染物(SO2、NO2、O3、CO)和颗粒物(PM2.5和PM10)丰度的影响。2017年10月至2018年9月,通过美国能源部的连续空气监测站(CAMS-4, Gazipur)收集了研究区域的空气污染数据。空气污染物浓度最高的季节为冬季(PM2.5=208 μg/m3, PM10=300 μg/m3, NO2=45.1 ppb, CO=3.91 ppm, O3=4.17 ppb),而季风后(PM2.5=133μg/m3, PM10=169 μg/m3, NO2=23.52 ppb, CO=2.25 ppm, O3=7.71 ppb)、季风前(PM2.5=115 μg/m3, PM10=216 μg/m3, NO2=33.5 ppb, CO=1.75 ppm, O3=4.23 ppb)和季风期(PM2.5=37.5 μg/m3, PM10=85.6 μg/m3, NO2=13.9 ppb, CO=0.84 ppm, O3=4.23 ppb)。PM10、PM2.5、NO2、CO、O3 5种空气污染物浓度最高,表明冬季较高的污染物负荷与采样点5 ~ 7 km范围内砖窑输送的大规模污染空气有关。风玫瑰数据分析表明,冬季的大部分空气来自加济普尔地区北部的布里菲尔德区。在季风前、季风后、季风后和冬季,降雨量与大气污染、温度和大气污染负荷呈负相关。这一发现揭示了季风期间空气污染物浓度最低与降水对大气污染物的冲刷作用有关。研究期间CO和O3污染物之间存在中等相关性(R2=0.58),表明其光化学反应的大气来源与挥发性有机化合物(VOCs)有关。PM2.5与PM10呈正相关(R2=0.84),表明PM2.5和PM10的产生途径与汽车燃烧化石燃料和工业活动相似。此外,空气质量指数(AQI)分析显示,研究区域周围的城市居民全年都处于不健康的大气状态。
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引用次数: 9
Health Risks Assessment of Heavy Metal Contamination in Drinking Water Collected from Different Educational Institutions of Khulna City Corporation, Bangladesh 孟加拉国库尔纳市公司不同教育机构收集的饮用水重金属污染的健康风险评估
Pub Date : 2020-10-01 DOI: 10.22104/AET.2021.4932.1331
P. Dhar, Arifa Naznin, Mosummath Hosna Ara
Clean and safe drinking water is indispensable for maintaining the sound health of humans. The presence of toxic elements in drinking water may cause several health effects. In this study, the concentrations of heavy metals in the drinking water of different academic institutions of Khulna city corporation (KCC) were determined using an atomic absorption spectrophotometer (AAS) and the human health risks were assessed based on estimated daily intake (EDI), target hazard quotient (THQ), hazardous index (HI) and target cancer risks (TCR). The range of the investigated heavy metals was as follows: Fe (18.5−861.6 µg/L), Mn (0.020−0.564 µg/L), Zn (8.8−96.1 µg/L), Cu (5.6−52.9 µg/L), and As (<0.5−105.3 µg/L). About 52% of the drinking water samples for Mn and 12% samples for As surpassed the Bangladesh standard (BDS) value of 50.0 µg/L. On the other hand, As concentration in 88% of samples exceeded the guideline value of the World Health Organization (WHO) (10.0 µg/L). Analysis of Pearson’s correlation matrix (r) showed a positive correlation between Zn−Mn, Cu−Mn, Zn−Fe, Cu−Fe, and Fe−Mn at 0.01 level; and Zn−Cu and Fe−As at 0.05 level, indicating the same pollution source. However, the THQ values of Zn, Cu, Fe, and Mn in all the studied samples were within the threshold risk limit (THQ < 1.0), hence safe from metal toxicity. But, THQ and HI of As for both adults and children; and TCR of As for adults in most of the investigated samples exceeded the maximum risk limit (THQ < 1.0; HI < 1.0; and TCR = 10−4), which revealed As could be a potential source of carcinogenic and non-carcinogenic health risks. Therefore, regular monitoring of heavy metals should be carried out to assure good quality drinking water for the students and academic staff.
清洁安全的饮用水是维持人类健康不可或缺的。饮用水中有毒元素的存在可能会造成几种健康影响。本研究采用原子吸收分光光度计(AAS)测定了库尔纳市公司(KCC)不同学术机构饮用水中重金属的浓度,并根据估计日摄入量(EDI)、目标危害商(THQ)、危害指数(HI)和目标致癌风险(TCR)评价了人体健康风险。研究的重金属范围为:Fe(18.5 ~ 861.6µg/L)、Mn(0.020 ~ 0.564µg/L)、Zn(8.8 ~ 96.1µg/L)、Cu(5.6 ~ 52.9µg/L)和as(<0.5 ~ 105.3µg/L)。约52%的饮用水锰样品和12%的砷样品超过了孟加拉国标准(BDS)的50.0µg/L。另一方面,88%的样品中As的浓度超过了世界卫生组织(WHO)的指导值(10.0µg/L)。Pearson相关矩阵(r)分析显示,Zn - Mn、Cu - Mn、Zn - Fe、Cu - Fe和Fe - Mn之间呈0.01水平的正相关;Zn−Cu和Fe−As在0.05水平,表明污染源相同。但所有研究样本中Zn、Cu、Fe、Mn的THQ值均在阈值风险限值(THQ < 1.0)内,不存在金属毒性。但是,成人和儿童的THQ和HI;大部分调查样本成人的TCR均超过最大危险限值(THQ < 1.0;Hi < 1.0;TCR = 10−4),这表明砷可能是致癌和非致癌健康风险的潜在来源。因此,应定期监测重金属,以确保学生和教职员工的优质饮用水。
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引用次数: 4
Study of Multi-Stage Cadmium Adsorption by Riverine Sediments 河流沉积物对镉的多级吸附研究
Pub Date : 2020-10-01 DOI: 10.22104/AET.2021.4421.1238
M. Nasrabadi, M. Omid, A. Mazdeh
Most riverine sediments have the high capability to adsorb and store the heavy metal ions. In the present study, the adsorption capacity of ‎the bed sediments collected from Karaj River (Iran), have ‎been experimentally studied for the cadmium ion adsorption. Multi-stage batch adsorption experiments were carried out for a constant ‎sediment concentration of 20 g/L and different initial cadmium concentrations ‎of 0.2, 0.5, 1, 10, 20, and 50 mg/L. The cadmium solutions with known concentration were added to the bed ‎sediment with the mean diameter of 0.53 mm in five stages to characterize what is the capacity of the sediments to adsorb cadmium. The batch adsorption experiments were conducted as both kinetics and equilibrium. ‎‎The results showed that by adding cadmium ions to the sediment at each stage, the adsorption capacity is less than the previous stage, so that, for cadmium concentration of 0.2 mg/L the adsorption percent and the amount of adsorbed cadmium was reduced from 88 to 70% and 9 to 6.8 mg/kg, respectively. These changes was decreased with increasing initial Cd concentrations. This process is useful for the seasonal rivers in which a certain concentration of heavy metal pollution may occasionally flow over the bed.
大多数河流沉积物具有较高的吸附和储存重金属离子的能力。本研究对伊朗Karaj河河床沉积物的镉离子吸附能力进行了实验研究。在恒定沉积物浓度为20 g/L和初始镉浓度为0.2、0.5、1、10、20和50 mg/L的条件下,进行了多阶段间歇吸附实验。将已知浓度的镉溶液分五个阶段加入到平均直径为0.53 mm的沉积物中,以表征沉积物对镉的吸附能力。同时进行了动力学和平衡吸附实验。结果表明:各阶段镉离子对沉积物的吸附量均小于前一阶段,当镉浓度为0.2 mg/L时,沉积物对镉的吸附率由88%降至70%,吸附量由9降至6.8 mg/kg。这些变化随着初始镉浓度的增加而减小。这个过程对季节性河流是有用的,在这些河流中,偶尔会有一定浓度的重金属污染流过河床。
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引用次数: 1
Hardness and chloride removal in dewatering system: Modeling and optimization of electrochemical reaction 脱水系统的硬度和氯离子去除:电化学反应的建模和优化
Pub Date : 2020-10-01 DOI: 10.22104/AET.2021.4535.1254
Ali Hasanzadeh-Sabloue, S. M. Moosavirad
The electrocoagulation (EC) process is a novel approach in the mining industry, especially to recycle water in the dewatering system of a mineral processing plant. In this research, the electrocoagulation process was studied to remove the hardness and chloride ions from concentrate thickener overflow water under different operating conditions: retention time (5–15 min), initial pH (4–10), current density (41.6–166.6 A/m2) and electrode type (Fe, Fe-Al, Al). Four factors with three levels with the D-optimal response surface design were applied for optimization. As a result, the optimal situation for the electrocoagulation process was characterized by a retention time of 15 min, initial pH of 9.08, the current density of 139.59 A/m2, and electrode type Fe-Al. In this situation, the maximum removal efficiency of hardness (60.11%) and chloride (98.38%) were yielded with a desirability value of 0.989. These results illustrated the effectiveness of the EC process as an influence method for the removal of hardness and chloride in terms of separation.
电絮凝工艺在矿山工业中是一种新颖的工艺方法,特别是在选矿厂脱水系统中水的回用。本研究对电絮凝工艺在保留时间(5-15 min)、初始pH(4-10)、电流密度(41.6-166.6 A/m2)、电极类型(Fe、Fe-Al、Al)等不同操作条件下去除浓缩浓缩器溢流水中的硬度和氯离子进行了研究。采用d -最优响应面设计进行四因子三水平优化。结果表明,电絮凝工艺的最佳条件为停留时间为15 min,初始pH为9.08,电流密度为139.59 a /m2,电极类型为Fe-Al。在此条件下,对硬度和氯离子的去除率分别为60.11%和98.38%,理想值为0.989。这些结果说明了EC工艺作为一种影响分离硬度和氯离子去除的方法是有效的。
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Advances in environmental science and technology
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