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Effect of biochar on nitrogen retention in soil under corn plant inoculated with arbuscular mycorrhizal fungi 生物炭对接种丛枝菌根真菌玉米土壤氮保持的影响
Pub Date : 2019-07-01 DOI: 10.22104/AET.2020.3874.1191
A. Abbaspour, H. Asghari
Maintaining the levels of nitrogen in agricultural fields to ensure crop yield performance is challenging due to the complex dynamics of nitrogen transformation in soil. Nitrogen is mainly taken up by plant roots in the form of nitrate, but it is considered as an environmental pollutant that threatens human and animal health. Therefore, it is necessary to use adsorbent compounds to retain nitrate in the soil. The effectiveness of two types of biochar produced from rice husk (Br) and populous wood (Bp) and two arbuscular mycorrhizal fungi, namely Funneliformis intraradices (Mi) and Funneliformis versiforme (Mv), on nitrate leaching in soil was evaluated. The soil columns planted with corn were filled with an artificial sandy clay loam soil fertigated with urea fertilizer under glasshouse conditions . After nine weeks of growing the plants, a pulse of nitrogen (0.48 g urea per core) was added to the columns. One week after the addition of urea, the shoots of the plants were removed, and the columns immediately flushed with 500 ml of deionized water to leach the soil nitrogen from the columns. The results showed that the shoots' dry-weight increased significantly (p≤ 0.05) in almost all the treatments with the highest in the BrMi treatment when compared to the control (C). The nitrate concentration in the leachate decreased 79% (from 23.2 mg/l in C treatment to 4.2 mg/l in Bp treatment), but the nitrate concentration in the soil solution increased up to 6.7-fold (Bp was the highest), which suggested a high N retention by the biochars used. It was concluded that the application of biochar and mycorrhizal fungi could reduce nitrogen loss through this artificial sandy clay loam soil and may have some implications in environment conservation.
由于土壤中氮转化的复杂动态,维持农田氮素水平以确保作物产量表现具有挑战性。氮主要以硝酸盐的形式被植物根系吸收,但它被认为是一种威胁人类和动物健康的环境污染物。因此,有必要使用吸附剂化合物来保留土壤中的硝酸盐。研究了稻壳(Br)和树木(Bp)制备的2种生物炭和2种丛枝菌根真菌(Mi)对土壤硝态氮淋溶的影响。在温室条件下,将种植玉米的土柱填入施尿素肥的人工砂质粘土壤土。植物生长9周后,向柱中加入氮脉冲(每芯0.48 g尿素)。在添加尿素一周后,除去植株的芽,并用500毫升去离子水冲洗柱子,以浸出柱子上的土壤氮。结果表明,与对照(C)相比,几乎所有处理的芽体干重均显著增加(p≤0.05),其中以BrMi处理最高,渗滤液中硝酸盐浓度下降了79%(从C处理的23.2 mg/l降至Bp处理的4.2 mg/l),但土壤溶液中硝酸盐浓度增加了6.7倍(Bp处理最高),表明生物炭具有较高的氮保留作用。综上所述,生物炭和菌根真菌的施用可以减少人工砂质粘土壤土的氮素流失,具有一定的环境保护意义。
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引用次数: 2
Toxicity of zero-valent iron nanoparticles and its fate in Zea mays 零价铁纳米颗粒在玉米中的毒性及其命运
Pub Date : 2019-07-01 DOI: 10.22104/AET.2020.4181.1208
A. Zand
Application of nanotechnology has gained remarkable interest in recent years and environmental exposure to nanomaterials is becoming inevitable. Therefore, nanotoxicity problem is gaining more attention. Zero-valent iron nano particles (nZVI) are being used widely for different purposes such as environmental remediation. Excessive amounts of nanomaterials may pose inhibitory effects on growth of plants cultivated in nZVI-affected soils which has been addressed in this research. Moreover, fate of nZVI in plants was investigated in the present study. Plant seeds were exposed to different concentrations of nZVI i.e. 0, 100, 250, 500, 800 and 1000 mg/kg. Z. mays was selected as the model plant in this study and found to be a tolerant plant species in presence of low to moderate levels of nZVI in soil. However, addition of higher doses of nZVI reduced seedling emergence and biomass establishment. Results indicated that the total Fe concentrations in Z. mays treated with nZVI increased compared to the control. Considerably higher accumulation of Fe in roots of Z. mays compared to the shoots in all treatments was found. Results indicated that the total Fe contents in Z. mays treated with nZVI were higher than those in control, with the highest Fe accumulation capacity of 24666.2 µg per pot which was obtained in soil received 500 mg/kg nZVI. Overally, toxic effects of higher doses of nZVI on plants were observed in this study. Intelligent use of nZVI for environmental purposes such as applying low to moderate levels of nZVI in soil remediation activities could remarkably prevent their adverse impacts on plant species, promote plant phytoextraction capability, and reduce nZV emission in the environment.
近年来,纳米技术的应用引起了人们的极大兴趣,纳米材料的环境暴露已成为不可避免的问题。因此,纳米毒性问题越来越受到人们的重视。零价铁纳米颗粒在环境修复等领域得到了广泛的应用。过量的纳米材料可能会对nzvi影响土壤中栽培的植物生长产生抑制作用,本研究已经解决了这一问题。此外,本研究还探讨了nZVI在植物体内的归宿。将植物种子暴露于不同浓度的nZVI中,即0、100、250、500、800和1000 mg/kg。本研究选择Z. mays作为模式植物,发现土壤中存在低至中等水平的nZVI, Z. mays是一种耐受植物。然而,添加高剂量的nZVI降低了幼苗的出苗和生物量的建立。结果表明,与对照相比,nZVI处理后的黄颡鱼体内总铁浓度升高。结果表明,在不同处理下,根铁积累量显著高于茎铁积累量。结果表明,nZVI处理的马尾松总铁含量高于对照,500 mg/kg nZVI处理的马尾松铁积累量最高,达到24666.2µg /盆;总体而言,在本研究中观察到高剂量nZVI对植物的毒性作用。将nZVI智能应用于环境目的,如在土壤修复活动中应用低至中等水平的nZVI,可以显著防止其对植物物种的不利影响,提高植物的植物提取能力,减少环境中nZV的排放。
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引用次数: 0
Removal of Ni (II) from aqueous solution using modified MCM-41 nano-adsorbents 改性MCM-41纳米吸附剂对水溶液中Ni (II)的去除
Pub Date : 2019-07-01 DOI: 10.22104/AET.2020.4178.1207
Behrouz Raei, Afsaneh Barekat, Habibollah Shariyatinia
In this study, a synthetic and modified PPAP-MPTMS-MCM-41 nano-adsorbent was used to remove nickel (II) during a batch process. Studying the parameters that were effective on adsorption revealed that the PPAP-MPTMS-MCM-41 adsorbent was the most effective in the adsorption of nickel (II) from a standard solution (Conc. = 5 mg/L, volume = 100 mL) under the following conditions: pH=8, contact time = 20 min, 6 wt.% of poly para-aminophenol (PPAP) ligand, adsorbent mass = 0.3 g, 1 molar hydrochloric acid (to remove nickel from the adsorbent), and NaCl salt with a concentration of less than 100 g/L. The results showed that the Langmuir isotherm had a higher linear and non-linear fitting with the experimental data. Investigating the kinetic models and mass transfer of this adsorption process showed that the experimental data were in good agreement with the pseudo-second-order kinetic model and the intra-particle mass transfer model. According to thermodynamic studies, this adsorption process is endothermic; its Gibbs free energy value is positive such that with an increase in temperature, it goes to lower values, and thus the process progresses spontaneously.
在本研究中,合成并改性的PPAP-MPTMS-MCM-41纳米吸附剂用于间歇法去除镍(II)。实验结果表明,PPAP-MPTMS-MCM-41吸附剂对镍(II)的吸附效果最好。= 5 mg/L,体积= 100 mL),条件为:pH=8,接触时间= 20 min, 6 wt.%的聚对氨基酚(PPAP)配体,吸附剂质量= 0.3 g, 1摩尔盐酸(用于去除吸附剂中的镍),NaCl盐浓度小于100 g/L。结果表明,Langmuir等温线与实验数据有较好的线性和非线性拟合。对吸附过程的动力学模型和传质过程的研究表明,实验数据与拟二级动力学模型和颗粒内传质模型吻合较好。根据热力学研究,这种吸附过程是吸热的;它的吉布斯自由能是正的,因此随着温度的升高,它的值会降低,因此这个过程是自发进行的。
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引用次数: 0
Environmental Impact Assessment of Solid Waste Disposal Options in Touristic Islands 旅游岛屿固体废物处置方案的环境影响评估
Pub Date : 2019-04-01 DOI: 10.22104/AET.2020.4143.1205
A. Zand, A. V. Heir
Kish Island is a popular tourist destination in Iran, and tourism plays an important role in its economy. The volume of waste produced in the island has increased given the construction of numerous industrial projects over the past decade, as well as an increase in the tourist population. This expansion signals a need to create new methods of waste disposal. Environmental Impact Assessment (EIA) is a process that can be used to evaluate the impact of waste disposal options on Kish Island. Rapid impact assessment matrix (RIAM) is a powerful tool to carry out the environmental impact assessment. The RIAM conducted in this research incorporated the mathematical sustainability model to evaluate the impacts of four municipal solid waste disposal options on the environment on Kish Island. The options included: (Option 1) Continuing the current disposal activities in Kish Island, i.e., 50% waste recycling and 50% waste landfilling; (Option 2) 30% composting, 50% waste recycling, and 20% waste landfilling; (Option 3) 30% composting, 50% waste recycling, and 20% waste incineration; and (Option 4) 50% waste recycling and 50% waste incineration. Among these options, option 4 was the priority for the establishment of final waste disposal with the highest score (0.043) in terms of sustainability, as well as having fewer adverse environmental impacts. However, the current environmental status of the Kish Island disposal site (Option 1) had the lowest score (-0.263) in terms of sustainability and was found to be the last priority with the most destructive environmental effects.
基什岛是伊朗的热门旅游目的地,旅游业在其经济中发挥着重要作用。在过去十年中,由于许多工业项目的建设以及旅游人口的增加,岛上产生的废物量有所增加。这种扩大表明需要创造新的废物处理方法。环境影响评估(EIA)是一个可用于评估基什岛废物处置方案影响的过程。快速影响评价矩阵(RIAM)是进行环境影响评价的有力工具。在本研究中进行的RIAM结合了数学可持续性模型来评估四种城市固体废物处理方案对基什岛环境的影响。方案包括:(方案1)继续目前在基什岛的处置活动,即50%的废物回收和50%的废物堆填;(方案二)30%堆肥、50%废物循环再造及20%废物堆填;(方案3)30%堆肥,50%废物回收,20%废物焚烧;及(方案4)50%废物循环再造及50%废物焚化。在这些方案中,方案4是优先建立最终废物处置的方案,可持续性得分最高(0.043),并且对环境的不良影响较小。然而,基什岛处置场地(方案1)目前的环境状况在可持续性方面得分最低(-0.263),并被认为是最具破坏性的环境影响的最后优先事项。
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引用次数: 4
Developing a multi-criteria decision support system based on fuzzy analytical hierarchical process (AHP) method for selection of appropriate high-strength wastewater treatment plant 开发了一种基于模糊层次分析法的多准则决策支持系统,用于选择合适的高强度污水处理厂
Pub Date : 2019-04-01 DOI: 10.22104/AET.2020.4100.1202
A. H. Moghaddam, J. Shayegan
The selection of an optimum treatment process for high-strength wastewater is complicated. Familiarity with wastewater treatment methods is not enough to design a plant and requires a multidisciplinary knowledge base. In this research, five alternative wastewater treatment methods for high-strength wastewater were investigated and ranked based on the analytic hierarchy process (AHP) fuzzy method: upflow anaerobic sludge blanket (UASB) + membrane bioreactor (MBR), UASB + extended aeration (EA), anaerobic baffled reactor (ABR), anaerobic lagoon (ANL) + aerated lagoon (AL), and sequencing batch reactor (SBR) + ABR. These treatment methods were ranked based on five criteria, namely energy consumption, effluent total suspended solids (TSS), effluent chemical oxygen demand (COD), cost, and level of technology. The different options of the wastewater treatment plant were rated by expert decision-makers in this field. The results show that for typical high-strength wastewater, the use of an UASB reactor followed by a MBR is the most appropriate alternative for treating the wastewater.
高强度废水的最佳处理工艺选择比较复杂。熟悉污水处理方法是不够的,设计一个工厂,需要多学科的知识基础。本研究采用层次分析法(AHP)对5种不同的高强度废水处理方法进行了研究,并采用模糊排序法对其进行了排序:上流式厌氧污泥毯(UASB) +膜生物反应器(MBR)、UASB +延长曝气(EA)、厌氧挡板反应器(ABR)、厌氧泻湖(ANL) +曝气泻湖(AL)、序批式反应器(SBR) + ABR。根据能耗、出水总悬浮固体(TSS)、出水化学需氧量(COD)、成本和技术水平等5个标准对这些处理方法进行了排名。该领域的专家决策者对污水处理厂的不同选择进行了评级。结果表明,对于典型的高强度废水,采用UASB + MBR处理是最合适的方案。
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引用次数: 1
Photocatalytic degradation of methylene blue from aqueous solution using Fe3O4@SiO2@CeO2 core-shell magnetic nanostructure as an effective catalyst 利用Fe3O4@SiO2@CeO2核壳磁性纳米结构光催化降解水溶液中的亚甲基蓝
Pub Date : 2019-04-01 DOI: 10.22104/AET.2020.4137.1204
Fatemeh Ziaadini, A. Mostafavi, T. Shamspur, F. Fathirad
In the present study, the core-shell magnetic nanostructure of Fe3O4@SiO2@CeO2 was synthesized to investigate its use as an effective photocatalyst for methylene blue removal. The prepared samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and a vibrating sample magnetometer (VSM). The photocatalytic activity for the Fe3O4@SiO2@CeO2 core-shell magnetic nanostructure was investigated under visible light by determining the degradation rate of methylene blue for 50 min. At the end of the photocatalytic degradation process, the magnetic catalyst was recovered by an external magnetic field. The performance of the proposed catalyst for the degradation of methylene blue was improved with the optimization of the effective parameters such as the amount of catalyst, pH, and reaction time. Under optimum conditions, the efficiency of methylene blue removal with the proposed photocatalyst remains higher than 92 % after five times of use. The second pseudo-model was selected as the kinetic model to calculate catalytic degradation. The present results show that the Fe3O4@SiO2@CeO2 can be an efficient nanocatalyst for the photodegradation of dye pollutants.
在本研究中,合成了核壳磁性纳米结构Fe3O4@SiO2@CeO2,以研究其作为去除亚甲基蓝的有效光催化剂的用途。采用x射线衍射(XRD)、透射电子显微镜(TEM)和振动样品磁强计(VSM)对制备的样品进行了表征。通过测定50 min的亚甲基蓝降解速率,研究了Fe3O4@SiO2@CeO2核壳磁性纳米结构在可见光下的光催化活性。在光催化降解过程结束时,磁性催化剂被外磁场回收。通过对催化剂用量、pH、反应时间等有效参数的优化,提高了催化剂对亚甲基蓝的降解性能。在最佳条件下,该光催化剂使用5次后对亚甲基蓝的去除率仍保持在92%以上。选择第二个伪模型作为计算催化降解的动力学模型。研究结果表明,Fe3O4@SiO2@CeO2是一种高效的光降解染料污染物的纳米催化剂。
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引用次数: 16
A comparative study of the effect of compost/woodchips mixture, natural zeolite and zeolite/activated carbon mixture as packing materials on the biofilter performance 对比研究了堆肥/木屑混合物、天然沸石和沸石/活性炭混合物作为填料对生物滤池性能的影响
Pub Date : 2019-04-01 DOI: 10.22104/AET.2020.3973.1198
Elham Narooei, Davod Mohebbi-Kalhori, A. Samimi, M. Zivdar
The removal of formaldehyde from contaminated air was investigated via three laboratory-scale biofilters packed with different materials: a mixture of compost and woodchips (І), the natural clinoptilolite zeolite particles in the original form (II), and the mixture of zeolite/activated carbon (III). The biofilters were inoculated using aerobic sludge. The average removal efficiencies of 97.5%, 90%, and 93.5% were obtained at a 100 s empty bed residence time (EBRT) and 20 mg/m3 inlet concentration of formaldehyde for the biofilter of configurations І, II, and III, respectively. Also, the performance of the reactors was investigated at different EBRTs of 20, 30, 60, and 100 s, and the maximum elimination capacity of 2840 mg/m3.h was achieved at the lowest EBRT (20 s) for the biofilter of configuration II. Increasing the inlet formaldehyde concentration from 20 mg/m3 to 80 mg/m3 led to the maximum formaldehyde removal efficiency of 82% for the biofilter of configuration III. Therefore, a comparison of the results of the biofilters' performances showed that the biofilter of configuration III had the best performance, which was validated by obtaining a higher mass transfer coefficient. However, the biofilter of configurations II and III achieved steady-state conditions in a shorter time.
通过三种不同材料填充的实验室规模的生物过滤器:堆肥和木屑的混合物(І),原始形态的天然沸石沸石颗粒(II)和沸石/活性炭的混合物(III),研究了从污染空气中去除甲醛的生物过滤器。生物过滤器使用好氧污泥接种。当空床停留时间(EBRT)为100 s,进口甲醛浓度为20 mg/m3时,配置І、II和III的生物过滤器的平均去除率分别为97.5%、90%和93.5%。在EBRT为20、30、60和100 s时考察了反应器的性能,构型II的生物滤池在EBRT最低(20 s)时的最大去除能力为2840 mg/m3.h。将进口甲醛浓度从20 mg/m3提高到80 mg/m3,配置III型生物滤池的甲醛去除率最高可达82%。因此,通过对生物滤池性能的比较,构型III的生物滤池的性能最好,并通过获得较高的传质系数来验证这一点。而构型II和构型III的生物滤池在较短的时间内达到稳态状态。
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引用次数: 0
Investigation of effective parameters on adsorption of amoxicillin from aqueous medium onto activated carbon 活性炭吸附阿莫西林的有效参数研究
Pub Date : 2019-04-01 DOI: 10.22104/AET.2020.3781.1187
J. R. Shahrouzi, Sakineh Molaee, Amanollah Ebadi, Farshid Towfighi, Farshad Bakhti
In this study, the adsorption of amoxicillin onto activated carbon was investigated. The effect of particle size and the effluent flow rate was discussed as well as the kinetics and isotherm of adsorption equilibrium. The isotherm equilibrium studies showed that the Langmuir model was appropriate for describing the adsorption equilibrium of amoxicillin onto the activated carbon. Furthermore, the kinetics of adsorption fit the pseudo-second-order model while the highest adsorption amount occurred at pH = 5. Moreover, the change of particle size from 600 microns to 125 microns resulted in increasing the adsorption amount of 102 mg/g to 225 mg/g. Furthermore, the breakthrough curves indicated that the controlling mechanism of mass transfer was intra-particle diffusion. Also, by reducing the length of the bed from 6.8 to 3.4 cm, the breakpoint time decreased from 3.2 hours to 54 minutes at 300 ppm initial concentration. Eventually, the breakpoint time increased from 2 minutes to 55 minutes by decreasing the average particle diameter from 840 to 250 microns.
研究了活性炭对阿莫西林的吸附。讨论了粒径、出水流量以及吸附平衡的动力学和等温线的影响。等温平衡研究表明,Langmuir模型可以很好地描述阿莫西林在活性炭上的吸附平衡。吸附动力学符合拟二级模型,在pH = 5时吸附量最大。当粒径由600微米增加到125微米时,吸附量由102 mg/g增加到225 mg/g。此外,突破曲线表明传质的控制机制是颗粒内扩散。此外,通过将床层长度从6.8 cm减少到3.4 cm,在初始浓度为300 ppm时,断点时间从3.2小时减少到54分钟。最终,通过将平均颗粒直径从840微米降低到250微米,断点时间从2分钟增加到55分钟。
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引用次数: 3
Providing a practical Model of the Waste Management Master Plan with Emphasis on Public Participation “Using the SWOT method and the QSPM matrix and the FAHP method” 提供以公众参与为重点的废物管理总体规划实用模式“运用SWOT法、QSPM矩阵及层次分析法”
Pub Date : 2019-04-01 DOI: 10.22104/AET.2020.3990.1200
Farhad Afshar, M. Abbaspour, A. Lahijanian
The purpose of this study was to present a practical model of strategic waste management via two Strength, Weakness, Opportunity, and Threats (SWOT) models and hierarchical analysis. In this regard, the strengths and weaknesses of the present situation and the factors affecting waste management in Tehran were investigated. In this study, the importance of public participation in waste management was investigated by means of the Delphi method and the Fuzzy Analytic Hierarchy Process (FAHP). Based on the results of the SWOT analysis, a team of experts identified the internal and external factors and rated the primary factors; each factor was weighted, then according to their scores, the proposed waste management framework was developed. Finally, the strategies were quantitatively prioritized by the planning matrix.  Then, using the analysis method, the hierarchy was used in this study as a SWOT supplement. The results of two questionnaires designed in this study identified the socio-economic, educational, cultural, and political factors as first to fourth, respectively. The most viable strategies, which were selected based on the analysis, include the potential use of social networks to encourage society to reduce waste and to promote the separation of waste as well as compliance with the proposed comprehensive waste management program; another choice strategy was providing economic incentives to maximize social participation in reducing waste production waste sorting.
本研究的目的是通过两个优势,劣势,机会和威胁(SWOT)模型和层次分析,提出一个实用的战略废物管理模型。在这方面,调查了目前情况的优点和缺点以及影响德黑兰废物管理的因素。本研究采用德尔菲法和模糊层次分析法(FAHP)探讨公众参与在垃圾管理中的重要性。根据SWOT分析的结果,专家团队确定了内部因素和外部因素,并对主要因素进行了评级;对每个因素进行加权,然后根据其得分,制定拟议的废物管理框架。最后,利用规划矩阵对各策略进行定量排序。然后,运用分析方法,运用层次分析法作为SWOT分析法的补充。本研究设计的两份问卷的结果分别确定了社会经济、教育、文化和政治因素为第一至第四。根据分析选出的最可行的战略包括可能利用社会网络鼓励社会减少废物和促进废物分类,以及遵守拟议的综合废物管理方案;另一种选择战略是提供经济奖励,使社会最大限度地参与减少废物产生和废物分类。
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引用次数: 5
Removal of Anionic Surfactant from Residential Laundry Wastewater using Jackfruit (Artocarpus heterophyllus) seeds 利用菠萝蜜种子去除生活洗衣废水中的阴离子表面活性剂
Pub Date : 2019-01-01 DOI: 10.22104/AET.2020.3841.1189
Shimeles Addisu Kitte, Solomon Dressa, Hailu Endale, D. Dadi
The study presented in this article investigated the removal of a long chain anionic surfactant from residential laundry wastewater using jackfruit (Artocarpus heterophyllus) seeds. The main ingredients of laundry wastewater are the surfactants. Therefore, great attention should be given to the treatment and disposal of laundry wastewater. The use of natural substitutes in treating wastewater has no harmful effects, and it is considered an effective step towards protecting the environment and promoting sustainability. Jar test experiments were conducted in order to determine the optimum conditions for the removal of surfactants, chemical oxygen demand (COD), biological oxygen demand (BOD), turbidity in terms of effective dosage, and pH control. The surfactant, COD, BOD, and turbidity removal efficiencies were 91.66%, 82.86%, 77.66%, and 85.14% at the optimum initial pH value of 6, the optimum dose of 2.5 g/L, and optimum mixing time of 25 minutes, respectively. It can be concluded that Artocarpus heterophyllus seed powder was a feasible and cost-effective natural coagulant for the removal of anionic surfactant from laundry wastewater. The results showed that the pseudo-second-order equation is the suitable model for this system.
本文研究了利用菠萝蜜种子去除生活洗衣废水中的一种长链阴离子表面活性剂。洗衣废水的主要成分是表面活性剂。因此,应高度重视洗衣废水的处理和处置。使用天然替代品处理废水没有有害影响,被认为是保护环境和促进可持续发展的有效步骤。为了确定表面活性剂的去除、化学需氧量(COD)、生物需氧量(BOD)、浊度(有效投加量)和pH控制的最佳条件,进行了罐子试验。在最佳初始pH值为6、最佳投加量为2.5 g/L、最佳混合时间为25 min时,表面活性剂去除率为91.66%、82.86%、77.66%、85.14%,COD、BOD去除率为82.86%。综上所述,槐籽粉是一种可行且经济的天然混凝剂,可用于去除洗涤废水中的阴离子表面活性剂。结果表明,伪二阶方程是该系统的合适模型。
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引用次数: 2
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