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SILICA-COPPER OXIDE COMPOSITE THIN FILMS AS SOLAR SELECTIVE COATINGS PREPARED BY DIPPING SOL GEL 用溶胶-凝胶浸渍法制备二氧化硅-氧化铜复合薄膜作为太阳能选择性涂层
4区 材料科学 Q2 Engineering Pub Date : 2008-03-24 DOI: 10.1155/2008/190920
C. Barrera, V. Mendez, L. Ortega
Silica-copper oxide (silica-CuO) composite thin films were prepared by a dipping sol-gel route using ethanolic solutions comprised TEOS and a copper-propionate complex. Sols with different TEOS/Cu-propionate (Si/Cu) molar ratios were prepared and applied on stainless steel substrates using dipping process. During the annealing process, copper-propionate complexes developed into particulate polycrystalline CuO dispersed in a partially crystallized silica matrix, as indicated by the X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses. The gel thermal analysis revealed that the prepared material might be stable up to 400∘C. The silica-CuO/stainless steel system was characterized as a selective absorber surface and its solar selectivity parameters, absorptance (𝛼), and emittance (𝜀) were evaluated from UV-NIR reflectance data. The solar parameters of such a system were mostly affected by the thickness and phase composition of the SiO2-CuO film. Interestingly, the best solar parameters (𝛼 = 0.92 and 𝜀 = 0.2) were associated to the thinnest films, which comprised a CuO-Cu2O mixture immersed in the silica matrix, as indicated by XPS.
采用溶胶-凝胶浸渍法制备了二氧化硅-氧化铜(silica-CuO)复合薄膜。采用浸渍法制备了不同TEOS/Cu-丙酸(Si/Cu)摩尔比的溶胶,并将其涂在不锈钢基体上。x射线衍射(XRD)和x射线光电子能谱(XPS)分析表明,在退火过程中,丙酸铜配合物形成颗粒状多晶CuO,分散在部分结晶的二氧化硅基体中。凝胶热分析表明,所制备的材料在400°C下是稳定的。将二氧化硅- cuo /不锈钢体系表征为选择性吸收体表面,并通过紫外-近红外反射数据评估其太阳选择性参数、吸收率(ρ r)和发射率(ρ r)。该系统的太阳参数主要受SiO2-CuO膜的厚度和相组成的影响。有趣的是,XPS显示,最佳的太阳参数(ρ = 0.92, ρ = 0.2)与最薄的薄膜相关,该薄膜由浸入二氧化硅基体的CuO-Cu2O混合物组成。
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引用次数: 26
Effect of Incorporating Nanoporous Metal Phosphate Materials on the Compressive Strength of Portland Cement 纳米多孔金属磷酸盐材料掺入对硅酸盐水泥抗压强度的影响
4区 材料科学 Q2 Engineering Pub Date : 2008-03-16 DOI: 10.1155/2008/238736
D. Wellman, K. Parker, S. Mattigod, G. Fryxell
Nanoporous metal phosphate (NP-MPO) materials are being developed for removal of contaminant oxyanions (As(OH) O 3 2 − , C r O 4 2 − , and T c O 4 − ), and cations (mercury, cadmium, and lead) from water and waste streams. Following sequestration, incorporation of metal laden NP-MPOs as a portion of cement formulation would provide an efficient and low-cost way to immobilize metal laden NP-MPOs in an easily handled waste form suitable for permanent disposal. There are no known investigations regarding the incorporation of NP-MPOs in concrete and the effects imparted on the physical and mechanical properties of concrete. Results of this investigation demonstrated that incorporating of NP-MPO materials requires additional water in the concrete formulation which decreases the compressive strength. Thus, incorporation of NP-MPOs in concrete may not serve as an efficient means for long-term disposal.
纳米多孔金属磷酸盐(NP-MPO)材料用于去除水和废物流中的污染物氧离子(As(OH) o32−,ccro42−和tco4−)和阳离子(汞,镉和铅)。在隔离之后,将含金属的np - mpo作为水泥配方的一部分,将提供一种有效和低成本的方法,将含金属的np - mpo固定在易于处理的废物形式中,适合永久处置。关于np - mpo在混凝土中的掺入及其对混凝土物理力学性能的影响,目前还没有已知的研究。研究结果表明,加入NP-MPO材料需要在混凝土配方中添加额外的水,这降低了混凝土的抗压强度。因此,在混凝土中掺入np - mpo可能不能作为长期处置的有效手段。
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引用次数: 0
Complex Impedance Spectroscopic Properties of BaVO Ceramics BaVO陶瓷的复阻抗光谱特性
4区 材料科学 Q2 Engineering Pub Date : 2008-03-13 DOI: 10.1155/2008/746256
P. Khatri, B. Behera, V. Srinivas, R. Choudhary
The polycrystalline sample of Ba3V2O8 was prepared by a high-temperature solid-state reaction technique. The effect of temperature on impedance parameters was studied using an impedance analyzer in a wide frequency range (102-106 Hz). The real and imaginary parts of complex impedance trace semicircles in the complex plane. The temperature-dependent plots reveal the presence of both bulk and grain boundary effects above 125∘C. The bulk resistance of the material decreases with rise in temperature. This exhibits a typical negative temperature coefficient of resistance (NTCR) behavior of the material. The modulus analysis suggests a possible hopping mechanism for electrical transport processes of the material. The nature of variation of dc conductivity suggests the Arrhenius type of electrical conductivity.
采用高温固相反应法制备了Ba3V2O8多晶样品。利用阻抗分析仪在宽频率范围(102 ~ 106 Hz)研究了温度对阻抗参数的影响。复阻抗的实部和虚部在复平面上走半圆。温度依赖性图显示,体积和晶界效应在125°C以上都存在。材料的体电阻随温度的升高而减小。这显示了材料典型的负电阻温度系数(NTCR)行为。模量分析表明材料的电输运过程可能存在跳跃机制。直流电导率变化的性质表明电导率属于阿伦尼乌斯型。
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引用次数: 25
Influence of Nanosized Silicon Carbide on Dimensional Stability of Al/SiC Nanocomposite 纳米碳化硅对Al/SiC纳米复合材料尺寸稳定性的影响
4区 材料科学 Q2 Engineering Pub Date : 2008-02-24 DOI: 10.1155/2008/835746
Seyed Mojtaba Zebarjad, S. Sajjadi, E. Karimi
This study concentrated on the role of particle size of silicon carbide (SiC) on dimensional stability of aluminum. Three kinds of Al/SiC composite reinforced with different SiC particle sizes (25 𝜇m, 5 𝜇m, and 70 nm) were produced using a high-energy ball mill. The standard samples were fabricated using powder metallurgy method. The samples were heated from room temperature up to 500∘C in a dilatometer at different heating rates, that is, 10, 30, 40, and 60∘C/min. The results showed that for all materials, there was an increase in length change as temperature increased and the temperature sensitivity of aluminum decreased in the presence of both micro- and nanosized silicon carbide. At the same condition, dimensional stability of Al/SiC nanocomposite was better than conventional Al/SiC composites.
本文主要研究了碳化硅(SiC)粒度对铝尺寸稳定性的影响。采用高能球磨机制备了3种不同SiC粒径(25𝜇m、5𝜇m和70 nm)的Al/SiC复合材料。采用粉末冶金法制备了标准样品。将样品在膨胀计中以不同的升温速率(即10、30、40和60°C/min)从室温加热到500°C。结果表明:在微碳化硅和纳米碳化硅的存在下,铝的温度敏感性随温度的升高而降低;在相同条件下,Al/SiC纳米复合材料的尺寸稳定性优于常规Al/SiC复合材料。
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引用次数: 11
Raman Spectroscopy for the Nondestructive Testing of Carbon Fiber 拉曼光谱在碳纤维无损检测中的应用
4区 材料科学 Q2 Engineering Pub Date : 2008-01-01 DOI: 10.1155/2008/693207
G. Washer, Blum Jr.F.
The goal of this research is to evaluate the potential of Raman spectroscopy as a method of condition assessment for carbon fiber composite materials used in high performance situations such as composite overwrapped pressure vessels (COPVs). There are currently limited nondestructive evaluation (NDE) technologies to evaluate these composite materials in situ. Variations in elastic strain in the composite material can manifest from degradation or damage, and as such could provide a tool for condition assessment. The characterization of active Raman bands and the strain sensitivity of these bands for commercially available carbon fibers are reported.
本研究的目的是评估拉曼光谱作为高性能碳纤维复合材料状态评估方法的潜力,如复合材料包覆压力容器(copv)。目前用于原位评价这些复合材料的无损评价技术有限。复合材料中弹性应变的变化可以从降解或损伤中表现出来,因此可以为状态评估提供工具。本文报道了市售碳纤维的活性拉曼带的表征及其应变灵敏度。
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引用次数: 35
Effect of Compatibilizers on the Morphological Properties of ABS and LCP Blends 增容剂对ABS和LCP共混物形态性能的影响
4区 材料科学 Q2 Engineering Pub Date : 2007-12-31 DOI: 10.1155/2007/18160
T. Das, K. Pal, B. Adhikari, C. Das
The blends of acrylonitrile butadiene styrene (ABS) polymer and liquid crystalline polymer (LCP) were prepared using a melt-blending technique in presence and absence of different types of nanosilica. The effect of Zn
采用熔融共混技术制备了丙烯腈-丁二烯-苯乙烯(ABS)聚合物和液晶聚合物(LCP)的共混物。锌的作用
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引用次数: 2
Synthesis and Characterization of Ceramic Nanoparticles System Based on Anatase-Doped Hematite 锐钛矿掺杂赤铁矿纳米陶瓷体系的合成与表征
4区 材料科学 Q2 Engineering Pub Date : 2007-12-31 DOI: 10.1155/2007/48962
M. Sorescu, L. Diamandescu, A. Sanns, D. Proch, J. Wood, V. Teodorescu
The x TiO 2 - ( 1 − x ) α - Fe 2 O 3 ceramic nanoparticles system has been obtained by mechanochemical activation for x = 0.1 and 0.5 and for ball milling times ranging from 2 to 12 hours. Structural and morphological characteristics of the anatase-doped hematite system were investigated by X-ray diffraction (XRD), Mossbauer spectroscopy, and transmission electron microscopy (TEM) combined with electron diffraction (ED). In the XRD patterns, we could evidence the dissolution of anatase in hematite, more pronounced for x = 0.1. The Rietveld structure of the XRD patterns yielded the dependence of the particle size and lattice constants on the amount x of Ti substitutions and as function of the ball milling time. For x = 0.1, we observed line broadening of the Mossbauer resonances and corresponding fit with several subspectra. For x = 0.5, it can be observed that the central doublet corresponding to superparamagnetic particles becomes more prominent. The ball milling route allowed us to reach nanometric particle dimensions, which would make the materials very promising for catalytic and gas sensing applications.
通过机械化学活化,在x = 0.1和0.5条件下,球磨时间为2 ~ 12小时,得到了× tio2 -(1−x) α - fe2o3陶瓷纳米颗粒体系。采用x射线衍射(XRD)、穆斯堡尔能谱(Mossbauer)、透射电镜(TEM)结合电子衍射(ED)研究了锐钛矿掺杂赤铁矿体系的结构和形态特征。在x射线衍射图中,我们可以证明赤铁矿中锐钛矿的溶解,当x = 0.1时更明显。XRD谱图的Rietveld结构表明,颗粒尺寸和晶格常数与Ti取代量x和球磨时间有关。当x = 0.1时,我们观察到穆斯堡尔共振的谱线展宽,并与几个子谱对应拟合。当x = 0.5时,可以观察到超顺磁粒子对应的中心重态变得更加突出。球磨路线使我们能够达到纳米级颗粒尺寸,这将使材料在催化和气体传感应用中非常有前途。
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引用次数: 5
Wear of MgO-CaO-SiO2-P2O5-F-Based Glass Ceramics Compared to Selected Dental Ceramics mgo - cao - sio2 - p2o5 - f基玻璃陶瓷与选定牙科陶瓷的磨损比较
4区 材料科学 Q2 Engineering Pub Date : 2007-12-17 DOI: 10.1155/2007/69897
Jongee Park, G. Pekkan, A. Ozturk
Wear of a glass-ceramic produced through controlled crystallization of a glass in the MgO-CaO-SiO2-P2O5-F system has been evaluated and compared to various commercial dental ceramics including IPS Empress 2, Cergo Pressable Ceramic, Cerco Ceram, and Super porcelain EX-3. Wear tests were performed in accord with the ASTM G99 for wear testing with a pin-on-disk apparatus. The friction coefficient and specific wear rate of the materials investigated were determined at a load of 10 N and at ambient laboratory conditions. Microhardness of the materials was also measured to elucidate the appropriateness of these materials for dental applications.
通过在MgO-CaO-SiO2-P2O5-F体系中控制玻璃结晶生产的玻璃陶瓷的磨损进行了评估,并与各种商用牙科陶瓷(包括IPS Empress 2, Cergo Pressable Ceramic, Cerco Ceram和Super porcelain EX-3)进行了比较。磨损试验按照ASTM G99使用针盘式设备进行磨损试验。在10 N载荷和环境实验室条件下测定了所研究材料的摩擦系数和比磨损率。还测量了材料的显微硬度,以阐明这些材料在牙科应用中的适用性。
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引用次数: 4
An Analytical Description of the Frictional Behaviour of a Titanium Alloy 钛合金摩擦行为的解析描述
4区 材料科学 Q2 Engineering Pub Date : 2007-12-12 DOI: 10.1155/2007/92170
N. Christakis, A. Vairis
In recent years, significant effort has been put in the enhancement of our understanding of the physics and mechanics of moving objects under contact. Developed theoretical models can not fully account for the observed frictional behaviour of materials due to the lack of understanding of the interaction processes which occur at the microscopic level. In this paper, an analytical contact model will be described and its application to a titanium alloy will be presented. Conclusions will be drawn on the ability of this model to describe different friction regimes. The inclusion of additional factors which impact on frictional behaviour will be discussed, as well as the derivation of constitutive equations and their utilisation in continuum models.
近年来,在提高我们对接触运动物体的物理和力学的理解方面已经付出了巨大的努力。由于缺乏对发生在微观水平上的相互作用过程的理解,发达的理论模型不能完全解释观察到的材料的摩擦行为。本文将描述一种解析接触模型,并介绍其在钛合金中的应用。结论将得出该模型的能力,以描述不同的摩擦制度。将讨论影响摩擦行为的附加因素,以及本构方程的推导及其在连续介质模型中的应用。
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引用次数: 4
Growth and Characterization of Cd1−XZnXTe-Sintered Films Cd1−xznxte烧结薄膜的生长与表征
4区 材料科学 Q2 Engineering Pub Date : 2007-12-06 DOI: 10.1155/2007/63702
V. Kumar, G. S. Sandhu, T. Sharma, M. Hussain
The II-VI polycrystalline semiconducting materials have come under increased scrutiny because of their wide use in the cost reduction of devices for photovoltaic applications. Cd 1 − X Zn X Te is one of the II-VI ternary semiconductor materials whose bandgap can be tailored to any value between 1.48–2.26 eV as X varies from 0 to 1. It is promising material for high-efficiency solar cells, switching, and other optoelectronic devices. Polycrystalline thin film of Cd 1 − X Zn X Te with variable composition ( 0 ≤ X ≤ 1 ) has been deposited on ultraclean glass substrates by screen printing method followed by sintering process. The optical and structural properties of Cd 1 − X Zn X Te thin films have been examined. The optical bandgap of these films is studied using reflection spectra in wavelength range of 350–900 nm by using double beam spectrophotometer. The structure of sample was determined from X-ray diffraction patterns. The films were polycrystalline in nature having wurtzite (Hexagonal) structure over the whole range studied. The lattice parameters vary almost linearly with the composition parameter X , following Vegard's law. Sintering is a very simple and viable method compared to other cost-intensive methods. The results of the present investigation will be useful in characterizing the material CdZnTe for its applications in photovoltaics.
II-VI型多晶半导体材料因其在降低光电器件成本方面的广泛应用而受到越来越多的关注。Cd 1−X Zn X Te是一种II-VI型三元半导体材料,当X从0到1变化时,其带隙可以在1.48 ~ 2.26 eV之间任意调整。它是高效太阳能电池、开关和其他光电器件的有前途的材料。采用丝网印刷法和烧结工艺在超净玻璃基板上沉积了可变成分(0≤X≤1)的Cd 1−X Zn X Te多晶薄膜。研究了Cd 1−X Zn X Te薄膜的光学性质和结构性质。利用双光束分光光度计在350 ~ 900 nm波长范围内的反射光谱研究了这些薄膜的光学带隙。通过x射线衍射图确定了样品的结构。在整个研究范围内,薄膜本质上是多晶的,具有纤锌矿(六角形)结构。晶格参数与组成参数X几乎呈线性变化,遵循维加德定律。与其他成本密集的方法相比,烧结是一种非常简单可行的方法。本研究结果将有助于表征CdZnTe材料在光伏领域的应用。
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引用次数: 6
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Advances in Materials Science and Engineering
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