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Mechanical Behaviour of Glass Fibre-Reinforced Polymer/Polyvinyl Chloride Foam Cored Sandwich Structures 玻璃纤维增强聚合物/聚氯乙烯泡沫芯夹层结构的力学行为
4区 材料科学 Q2 Engineering Pub Date : 2024-04-27 DOI: 10.1155/2024/5929170
Edwin Cheruiyot Kosgey, Krishnan Kanny, Festus Maina Mwangi
This study focuses on the fabrication and analysis of the mechanical behaviour of unidirectional (UD) glass fibre-reinforced polymer (GFRP) facesheet and polyvinyl chloride (PVC) foam core sandwich structures fabricated by a vacuum-assisted resin infusion method (VARIM). These sandwich structures are commonly used in marine and wind turbine blade applications. To date, relatively little knowledge about the functional behaviour of UD GFRP compared to composites reinforced with bidirectional mats is available for day-to-day applications. The effects of the facesheet orientation, facesheet thickness, and core thickness on the mechanical behaviour of the specimens were examined. The UD fibres were oriented in cross-ply (0/90), angle-ply (+45/−45), and quasi-isotropic orientations. Various mechanical properties such as tensile, flexural, flatwise compression, and edgewise compression tests were examined. Characterization of the tensile properties of the facesheet showed that the cross-ply orientation had a higher strength than the angle-ply and quasi-isotropic orientations. The flexural load-carrying capacity of the cross-ply facesheet orientation was superior to the other orientations. The increase in the core thickness changed the flexural failure mode from face yield and core shear to core indentation. Flatwise compression (FWC) was tested to determine the core characteristics of the sandwich structure, and the peak loads of 4.90, 1.81, and 3.90 kN were obtained for 10-, 15-, and 20 mm core thicknesses, respectively. Edgewise compression (EWC) exhibited stable end crushing for thinner facesheet, whereas thicker facesheet showed core crushing and buckling. When the facesheet thickness was increased from 1.5 mm to 3 mm in the EWC, the buckling load increase ranged from 2.53% to 44.83% for core thicknesses 10-, 15-, and 20 mm, respectively.
本研究的重点是通过真空辅助树脂灌注法(VARIM)制造单向(UD)玻璃纤维增强聚合物(GFRP)面板和聚氯乙烯(PVC)泡沫芯材夹层结构,并分析其机械性能。这些夹层结构通常用于船舶和风力涡轮机叶片。迄今为止,与使用双向毡增强的复合材料相比,人们对 UD GFRP 在日常应用中的功能特性了解相对较少。我们研究了面片取向、面片厚度和芯材厚度对试样机械性能的影响。UD 纤维的取向有交叉层(0/90)、角层(+45/-45)和准各向同性取向。对拉伸、弯曲、平面压缩和边缘压缩试验等各种机械性能进行了检验。面片的拉伸特性表明,交叉层取向的强度高于角层取向和准各向同性取向。交叉层方向面板的抗弯承载能力优于其他方向。芯材厚度的增加改变了弯曲破坏模式,从面层屈服和芯材剪切变为芯材压痕。平向压缩(FWC)测试确定了夹层结构的芯材特性,芯材厚度为 10 毫米、15 毫米和 20 毫米时的峰值载荷分别为 4.90 千牛、1.81 千牛和 3.90 千牛。较薄面板的边缘压缩(EWC)表现出稳定的端部挤压,而较厚面板则表现出夹芯挤压和屈曲。在 EWC 中,当面板厚度从 1.5 毫米增加到 3 毫米时,芯材厚度为 10 毫米、15 毫米和 20 毫米时,屈曲载荷分别增加了 2.53% 到 44.83%。
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引用次数: 0
Physicomechanical and Thermal Properties of Particle Board Produced Using Waste Ceramic Materials and Corncob 使用废陶瓷材料和玉米芯生产的刨花板的物理机械性能和热性能
4区 材料科学 Q2 Engineering Pub Date : 2024-04-18 DOI: 10.1155/2024/8839814
O. J. Aladegboye, O. J. Oyedepo, T. J. Awolola, O. D. Oguntayo, O. Y. Babatunde, O. T. Ilesanmi, P. P. Ikubanni
Waste management and recycling have led to numerous studies on particleboard production. This study attempted to use milled corncob (MCC) and waste ceramic tiles (WCTs) to produce particleboard. The MCC (100−70 wt.%) and WCT (0–30 wt.%) were mixed at different ratios, mixed and compressed at a pressure of 0.25 MPa using urea formaldehyde (UF) resin as adhesive. The physicomechanical and thermal properties of the particleboards produced were investigated. The physical properties (bulk density, water absorption, and thickness swelling) improved with composite particleboard compared to the 100% MCC particleboard. The increase in WCT yielded improved density and lowered the particleboard’s water absorption and thickness swelling. The mechanical tests showed that MOE values were below the recommended standard, which makes them unsuitable for structural use. However, MOR revealed values above the recommended standard. The thermal conductivity of the particleboards was reduced with increased WCT, and the required standard was found to be met. Hence, the particleboards produced are found helpful as thermal wall insulators. Based on the experiments done, sample R7 (70% MCC and 30% WCT) was considered the most preferable since it achieved the most preferable physicomechanical and thermal conductivity performance. The particleboards produced are recommended for wall partitioning and other internal and external purposes.
废物管理和回收利用引发了大量关于刨花板生产的研究。本研究尝试使用磨碎的玉米芯(MCC)和废瓷砖(WCT)生产刨花板。以不同的比例混合 MCC(100-70 wt.%)和 WCT(0-30 wt.%),使用脲醛(UF)树脂作为粘合剂,在 0.25 MPa 的压力下混合并压缩。研究了所生产的刨花板的物理机械性能和热性能。与 100% MCC 刨花板相比,复合刨花板的物理性能(体积密度、吸水率和厚度膨胀)得到了改善。WCT 的增加提高了密度,降低了刨花板的吸水率和厚度膨胀率。机械测试表明,MOE 值低于推荐标准,因此不适合用于结构。然而,MOR 值却高于推荐标准。随着 WCT 的增加,刨花板的热传导率也降低了,而且达到了所需的标准。因此,生产出的刨花板可用作隔热墙。根据所做的实验,样品 R7(70% MCC 和 30%WCT)被认为是最理想的,因为它达到了最理想的物理机械性能和导热性能。建议将生产的刨花板用于墙壁隔断和其他内部及外部用途。
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引用次数: 0
Effect of Friction Coefficient in Friction Stir Welding of B4C Reinforced AA5083 Metal Matrix Composites and Use of Fuzzy Clustering Technique for Weld Strength Prediction B4C 增强 AA5083 金属基复合材料摩擦搅拌焊中摩擦系数的影响及使用模糊聚类技术预测焊接强度
4区 材料科学 Q2 Engineering Pub Date : 2024-04-16 DOI: 10.1155/2024/9880686
C. Devanathan, D. Elil Raja, Tushar Sonar, Mikhail Ivanov
The friction stir welding (FSW) method was used to weld B4C reinforced AA 5083 metal matrix composites in this study. By coating titanium nitride (TiN), aluminium chromium nitride (AlCrN), and diamond-like carbon (DLC) to a thickness of 4 microns, three FSW tools with square pin profiles were developed and the friction coefficients of 0.69, 0.32, and 0.2 were maintained. At three levels, the process factors such as tool rotating speed, transverse feed, and axial force were examined. For each tool, 15 samples were made using the central composite design. The influence of the friction coefficient on ultimate tensile strength, microstructural features, and tool condition was studied, and the flower pollination algorithm (FPA) technique was used to find the best process parameters for obtaining maximum ultimate tensile strength of FSW joints. The improved tensile strength of FSW joints was verified using a validation test. The coating has a considerable influence on the ultimate tensile strength, microstructure, and tool condition, according to the results of the tool’s friction coefficient. The results on the prediction of strength using the fuzzy clustering technique showed that the technique is effective in predicting the tensile strength values, with the root mean square error (RSME) of TiN, AlCrN, and DLC being 0.0027, 0.0016, and 0.0015, respectively, and the low RSME indicating that the prediction based on the fuzzy subtractive clustering technique is perfect and effective.
本研究采用搅拌摩擦焊(FSW)方法焊接 B4C 增强 AA 5083 金属基复合材料。通过对氮化钛 (TiN)、氮化铝铬 (AlCrN) 和类金刚石碳 (DLC) 进行厚度为 4 微米的涂层,开发出了三种具有方形针形轮廓的 FSW 工具,并保持了 0.69、0.32 和 0.2 的摩擦系数。在三个级别上,对工具旋转速度、横向进给和轴向力等工艺因素进行了检验。采用中心复合设计法为每种刀具制作了 15 个样本。研究了摩擦系数对极限拉伸强度、微观结构特征和工具条件的影响,并使用花粉授粉算法(FPA)技术找到了获得 FSW 接头最大极限拉伸强度的最佳工艺参数。通过验证试验验证了 FSW 接头抗拉强度的提高。根据工具摩擦系数的结果,涂层对极限拉伸强度、微观结构和工具状态有相当大的影响。使用模糊聚类技术预测强度的结果表明,该技术能有效预测拉伸强度值,TiN、AlCrN 和 DLC 的均方根误差(RSME)分别为 0.0027、0.0016 和 0.0015,较低的 RSME 表明基于模糊减法聚类技术的预测是完美和有效的。
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引用次数: 0
Semicontinuous Blending of Pharmaceutical Ingredients and the Impact of Process Parameters on the Blending Performance of an Integrated Feeder Blender Operating Semicontinuously 制药配料的半连续混合以及工艺参数对半连续运行的集成给料混合器混合性能的影响
4区 材料科学 Q2 Engineering Pub Date : 2024-03-29 DOI: 10.1155/2024/8816672
Sumit Kumar, Yan-Shu Huang, Zoltan Nagy, Gintaras V. Reklaitis, Marcial Gonzalez, Paul Mort
The pharmaceutical industry is looking for new and innovative ways of manufacturing to improve product quality and reduce process complexity. In manufacturing oral solid dosage products, blending is a crucial step in ensuring the homogeneity of active pharmaceutical ingredients (APIs) in the final product. Currently, batch and continuous blending are the two commonly used modes for blending in the industry. However, these methods have limitations in terms of blending time, manual intervention, and flexibility in handling multiple ingredients. To address these limitations, this study aims to explore the feasibility and benefits of using a semicontinuous blending mode in the pharmaceutical industry. A case study is conducted using a binary blend of microcrystalline cellulose and acetaminophen to compare the performance of the semicontinuous mode of blending with the batch and continuous blending modes. The results show that the semicontinuous blending setup can produce blends with good blend uniformity and homogeneity and that the output can be used for both batch and continuous downstream operations. The effect of variation in the three most important process parameters, impeller rotation per minute, blending time, and fill level on the blend uniformity, is also investigated. The semicontinuous blending mode had a higher line rate of 12.5 kg/hour than a similarly sized batch blender at 3.6 kg/hour and less than that of a continuous blender. The benefits of the new blending mode include reduced blending time, minimal manual intervention, flexibility in blending multiple ingredients, easier scale-up, and a smaller footprint. Overall, this study highlights the relative advantages of using this new semicontinuous blending mode in pharmaceutical manufacturing and its potential as a good alternative to the existing blending modes. The semicontinuous mode is well placed between the batch blending and continuous blending mode, with many benefits over the former mode and performance comparable to the latter continuous mode.
制药业一直在寻找新的创新生产方式,以提高产品质量和降低工艺复杂性。在口服固体制剂产品的生产过程中,混合是确保最终产品中活性药物成分(API)均匀性的关键步骤。目前,批量混合和连续混合是业内常用的两种混合模式。然而,这些方法在混合时间、人工干预和处理多种成分的灵活性方面存在局限性。为了解决这些局限性,本研究旨在探讨在制药行业使用半连续混合模式的可行性和益处。本研究使用微晶纤维素和对乙酰氨基酚的二元混合进行了案例研究,以比较半连续混合模式与间歇和连续混合模式的性能。结果表明,半连续混合装置可生产出混合均匀度和均质性良好的混合物,其产出可用于间歇式和连续式下游操作。此外,还研究了三个最重要的工艺参数(叶轮每分钟转数、混合时间和填充量)的变化对混合均匀度的影响。半连续式混合模式的线速度为 12.5 千克/小时,高于类似规模的间歇式混合机的 3.6 千克/小时,也低于连续式混合机的线速度。新混合模式的优点包括:混合时间缩短、人工干预最少、可灵活混合多种配料、更容易扩大规模以及占地面积更小。总之,这项研究强调了在药品生产中使用这种新型半连续混合模式的相对优势,以及它作为现有混合模式良好替代品的潜力。半连续混料模式介于间歇式混料和连续式混料模式之间,与前者相比有许多优点,其性能可与后者的连续式混料模式相媲美。
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引用次数: 0
Efficient Bioelectrochemical Cell Generation and Green Synthesis of Silver Nanoparticles Using Pomegranate and Pineapple Peel Extracts: A Comprehensive Characterization Study 利用石榴皮和菠萝皮提取物生成高效生物电化学电池并绿色合成银纳米粒子:综合表征研究
4区 材料科学 Q2 Engineering Pub Date : 2024-03-28 DOI: 10.1155/2024/6681559
Shamima Mehrin, Nilufer Yesmin Tanisa, Rabiul Awal, Md. Kamrul Alam Khan, Abdus Shaqur, Shamim Ahmed, Shahidul Islam, Asad Mia
The present study investigates an environmentally conscious method for synthesizing silver nanoparticles (AgNPs) by employing extracts from pomegranate peel (PgP) and pineapple peel (PnP). This green synthesis approach offers a sustainable alternative to traditional chemical methods, thereby reducing the ecological footprint associated with nanoparticle production. The PgP and PnP extracts serve as both reducing and capping agents during the synthesis process, enhancing the biocompatibility of the resultant AgNPs. Various characterization techniques, including UV-Vis spectroscopy, Raman analysis, X-ray diffraction (XRD), dynamic light scattering (DLS), Fourier transform infrared (FTIR), and transmission electron microscopy (TEM), were utilized to analyze the synthesized AgNPs. UV-Vis spectroscopy confirmed the formation of AgNPs through characteristic surface plasmon resonance peaks, while FTIR examined the interaction between biomaterial components and the oxidation and coating of silver nanoparticles. Raman analysis elucidated the functional groups responsible for reducing and stabilizing AgNPs, while XRD provided insights into their crystalline structure. TEM images revealed the size and morphology of the nanoparticles, while DLS characterized their average size and morphology. In addition, the synthesized AgNPs were utilized in a bioelectrochemical cell to leverage their unique properties for enhanced electrochemical performance, showcasing their potential application in energy storage and conversion systems. Overall, this study demonstrates the feasibility of utilizing agricultural waste products such as PgP and PnP for sustainable AgNP synthesis, offering promising prospects for environmentally friendly nanotechnology advancement.
本研究采用石榴皮(PgP)和菠萝皮(PnP)提取物,研究了一种具有环保意识的银纳米粒子(AgNPs)合成方法。这种绿色合成方法为传统化学方法提供了一种可持续的替代方法,从而减少了与纳米粒子生产相关的生态足迹。在合成过程中,PgP 和 PnP 提取物既是还原剂,又是封端剂,从而提高了生成的 AgNPs 的生物相容性。利用各种表征技术,包括紫外可见光谱、拉曼分析、X 射线衍射 (XRD)、动态光散射 (DLS)、傅立叶变换红外 (FTIR) 和透射电子显微镜 (TEM) 来分析合成的 AgNPs。紫外可见光谱通过特征性的表面等离子共振峰确认了 AgNPs 的形成,而傅立叶变换红外光谱则检测了生物材料成分之间的相互作用以及银纳米粒子的氧化和包覆。拉曼分析阐明了负责还原和稳定 AgNPs 的官能团,而 XRD 则提供了对其晶体结构的深入了解。TEM 图像显示了纳米颗粒的尺寸和形态,而 DLS 则描述了它们的平均尺寸和形态。此外,还将合成的 AgNPs 用于生物电化学电池,利用其独特的性质提高电化学性能,展示了它们在能量存储和转换系统中的潜在应用。总之,这项研究证明了利用 PgP 和 PnP 等农业废弃物进行可持续 AgNP 合成的可行性,为环境友好型纳米技术的发展提供了广阔的前景。
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引用次数: 0
Temperature Effects on Physiochemical Characteristics of Sugar-Based Natural Deep Eutectic Solvents 温度对糖基天然深共晶溶剂理化特性的影响
4区 材料科学 Q2 Engineering Pub Date : 2024-03-22 DOI: 10.1155/2024/6641317
Mohammad Tarikuzzaman, Viral Sagar, Mark James Wong, Joan G. Lynam
Phase behavior, density, viscosity, conductivity, pH, and surface tension were measured, and FTIR was performed for a series of mixtures of sugar (glucose, fructose, xylose, and sucrose), water, and choline chloride (ChCl) at specific molar ratios. These mixtures, called sugar-based natural deep eutectic solvents (NADESs), were investigated as a function of temperature. Contact angle measurements indicated that NADES exhibited slightly lower wettability but higher surface tension than water. Temperature was found to greatly impact density, viscosity, and conductivity. The optimum water molar ratio for lower viscosity was found at ratios higher than those reported in the literature, indicating that the NADES investigated may have industrial process applications.
对一系列特定摩尔比的糖类(葡萄糖、果糖、木糖和蔗糖)、水和氯化胆碱 (ChCl) 混合物进行了相行为、密度、粘度、电导率、pH 值和表面张力测量,并进行了傅立叶变换红外光谱分析。这些混合物被称为糖基天然深共晶溶剂(NADES),研究了它们与温度的关系。接触角测量结果表明,NADES 的润湿性略低于水,但表面张力高于水。温度对密度、粘度和电导率有很大影响。为降低粘度而发现的最佳水摩尔比率高于文献报道的比率,这表明所研究的 NADES 可用于工业加工。
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引用次数: 0
Influence of Tool Pin Profiles on Aluminium Alloy A356 and Ceramic-Based Nanocomposites for Light Weight Structures by Friction Stir Processing 工具销轮廓对通过摩擦搅拌加工制造轻质结构的铝合金 A356 和陶瓷基纳米复合材料的影响
4区 材料科学 Q2 Engineering Pub Date : 2024-03-18 DOI: 10.1155/2024/2494900
L. Karthick, Mruthunjaya M., Srinivas. S., Prasanna Venkatesh R., Naveen Kumar Gurajala, Meghavath Mothilal, Hari Banda
In this research, the main aim is to focus the enhancement of aluminium-based metal matrix composites for improving the attributes of light weight metals, aerospace structures and other tailor blank material properties. By this way, the friction stir processing (FSP) was the suited alternate technique to enhancing the mechanical attributes and superior microstructural amendment in the processed MMCs. Therefore, this study investigates the dispersion of ceramic-based strengthening particles of chromium oxide (Cr2O3) in the aluminium base matrix of A356 alloy. During the processing, the different tool pin sizes having the conical threaded tool pin profiles. Similarly, the tool spinning speed and tool travel speed also varied while in FSP. Before the processing, the A356 alloy was prepared by the grooved surfaces for packing the chromium oxide particles to compose the aluminium metal matrix composites. The tensile strength and hardness was employed to carry out from the friction stir processed A356 alloy with influencing of Cr2O3. The maximum occurred tensile processing parameters are 1500 rpm of spinning speed, 6 mm of tool pin sizes and 90 mm/min of tool travel speed. Similarly, the maximum obtained hardness processing parameter are 2000 rpm of spinning speed, 5 mm of tool pin sizes and 90 mm/min of tool travel speed. A scanning electron microscope was utilized to investigate the dispersed Cr2O3 in the A356 alloy for confirming the refinement grains in the nugget zones of FSPed A356 alloy. The increased grain boundary by the influence of different tool pin sizes was the major reason to produces the better mechanical properties in the processed A356/Cr2O3.
这项研究的主要目的是提高铝基金属基复合材料的性能,以改善轻质金属、航空航天结构和其他定制毛坯材料的属性。因此,摩擦搅拌加工(FSP)是提高加工后金属基复合材料机械属性和微观结构修正性能的合适替代技术。因此,本研究调查了陶瓷基强化颗粒氧化铬(Cr2O3)在 A356 合金铝基体中的分散情况。在加工过程中,不同尺寸的工具销具有锥形螺纹工具销轮廓。同样,刀具旋转速度和刀具移动速度也在快削加工过程中发生变化。加工前,A356 合金的表面开槽,以便填入氧化铬颗粒,从而形成铝金属基复合材料。拉伸强度和硬度是通过影响 Cr2O3 的摩擦搅拌加工 A356 合金来实现的。最大拉伸加工参数为旋转速度 1500 rpm、工具销钉尺寸 6 mm 和工具移动速度 90 mm/min。同样,获得的最大硬度加工参数为旋转速度 2000 rpm、刀具针脚尺寸 5 mm 和刀具移动速度 90 mm/min。利用扫描电子显微镜研究了 A356 合金中分散的 Cr2O3,以确认 FSPed A356 合金金块区的细化晶粒。受不同刀针尺寸的影响,晶界增大,这是加工后的 A356/Cr2O3 具有更好机械性能的主要原因。
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引用次数: 0
A Practical Swelling Constitutive Model of Anhydrite and Its Application on Tunnel Engineering 无水石膏的实用膨胀构造模型及其在隧道工程中的应用
4区 材料科学 Q2 Engineering Pub Date : 2024-03-14 DOI: 10.1155/2024/7961951
Jianxun Wu, Fei Lin, Xiaohong Zhou, Zhigang Zhang, Jinyang Fan, Zhenkun Hou
Swelling of anhydrite rock causes serious damage to the tunnel and generates high additional costs in the process of tunnel construction and operation and has gradually become one of the main factors that threaten the safety of the tunnel. It is extremely difficult to predict swelling pressures and deformations accurately based on conventional swelling constitutive models. Thus, a new practical swelling constitutive model of anhydrite for tunnel engineering has been developed. First, swelling tests of natural anhydrite samples focusing on the time effect have been designed and conducted, whose test results show that swelling strain-time can be described by the S-curve model and that swelling stress-strain can be described by the quadratic model. Second, a swelling constitutive model with considering the time effect has been developed to reproduce the swelling behavior of anhydrite observed in swelling tests. This model can track the evolution of swelling activity in tunneling, which has practical significance for process simulation and process control of swelling disaster. Then, this model has been implemented within ANSYS for numerical simulation of the Lirang tunnel. Based on simulation results, useful measures have been proposed. Satisfactory results have been achieved according to the feedback from the site.
无水岩的膨胀会对隧道造成严重破坏,并在隧道建设和运营过程中产生高昂的额外成本,已逐渐成为威胁隧道安全的主要因素之一。根据传统的膨胀构造模型,要准确预测膨胀压力和变形是非常困难的。因此,我们开发了一种用于隧道工程的新型实用无水石膏膨胀构造模型。首先,设计并进行了以时间效应为重点的天然无水石膏样品膨胀试验,试验结果表明,膨胀应变-时间可以用 S 曲线模型描述,膨胀应力-应变可以用二次模型描述。其次,建立了考虑时间效应的膨胀构成模型,以再现膨胀试验中观察到的无水石膏的膨胀行为。该模型可跟踪隧道中膨胀活动的演变,对膨胀灾害的过程模拟和过程控制具有实际意义。随后,该模型在 ANSYS 中实现,用于里郎隧道的数值模拟。根据模拟结果,提出了一些有用的措施。根据现场反馈,取得了令人满意的结果。
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引用次数: 0
Effect of Codoping Zinc Oxide Nanoparticles with Sulfur and Nitrogen on Its Energy Bandgap, Antioxidant Properties, and Antibacterial Activity 氧化锌纳米颗粒与硫和氮的共轭对其能带隙、抗氧化特性和抗菌活性的影响
4区 材料科学 Q2 Engineering Pub Date : 2024-02-26 DOI: 10.1155/2024/4275035
Diriba Yadesa, Jabessa Nagasa Guyasa, Tamene Tadesse Beyene
Zinc oxide nanoparticles (ZnO-NPs) are used in various fields such as industrial, environmental remediation, catalytic, and antibacterial applications. However, their ability to absorb visible light is limited due to their high-energy bandgap and fast electron-hole recombination, which restricts their use. To enhance the efficiency of ZnO-NPs in medical and other applications, surface functionality can be modified through doping. Here, we investigated the effects of S and N doping on the energy bandgap of ZnO-NP and their antimicrobial and antioxidant activities. The results showed that the optical bandgap energy of pure ZnO-NPs was 2.98 eV while that of 6% N-ZnO, 4% S-ZnO, and S4-N6-ZnO was 2.78, 2.69, and 2.63 eV, respectively. The energy bandgap reduction is attributed to the changes in the electronic level of zinc oxide as the result of doping. The crystal size of pure ZnO-NPs, 6% N-ZnO, 4% S-ZnO, and S4-N6-ZnO was 29.06, 27.05, 29.02, and 25.06 nm, respectively, as calculated from XRD data using FWHM. Following the bandgap and particle size reduction, the antimicrobial activities of the dual-doped ZnO-NPs surpassed that of the pure ZnO-NPs. Moreover, dual doping improved the antioxidant activity of ZnO-NPs from 52.45% to 88.89% for the optimized concentration. Therefore, incorporating S and N as dual dopants can enhance the functionality and efficiency of ZnO-NPs in various fields.
氧化锌纳米粒子(ZnO-NPs)可用于工业、环境修复、催化和抗菌等多个领域。然而,由于其高能带隙和快速电子-空穴重组,其吸收可见光的能力受到限制,从而限制了其应用。为了提高 ZnO-NPs 在医疗和其他应用中的效率,可以通过掺杂来改变其表面功能。在此,我们研究了 S 和 N 掺杂对 ZnO-NP 能带隙及其抗菌和抗氧化活性的影响。结果表明,纯 ZnO-NPs 的光带隙能为 2.98 eV,而 6% N-ZnO、4% S-ZnO 和 S4-N6-ZnO 的光带隙能分别为 2.78、2.69 和 2.63 eV。能带隙的减小是由于掺杂后氧化锌的电子水平发生了变化。根据 XRD 数据并使用 FWHM 计算,纯 ZnO-NPs、6% N-ZnO、4% S-ZnO 和 S4-N6-ZnO 的晶体尺寸分别为 29.06、27.05、29.02 和 25.06 nm。随着带隙和粒径的减小,双掺杂 ZnO-NPs 的抗菌活性超过了纯 ZnO-NPs。此外,在优化浓度下,双掺杂 ZnO-NPs 的抗氧化活性从 52.45% 提高到 88.89%。因此,加入 S 和 N 作为双掺杂剂可以提高 ZnO-NPs 在各个领域的功能和效率。
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引用次数: 0
Mathematical Modeling and Finite Element Analysis of Residual Stress (RS) Field after Multipass Ultrasonic Surface Rolling 多通道超声波表面滚压后残余应力 (RS) 场的数学建模和有限元分析
4区 材料科学 Q2 Engineering Pub Date : 2024-02-16 DOI: 10.1155/2024/4083427
Jinggan Shao, Zhanshu He, Genshang Wu, Zhi Zhang, Chao Li
In order to achieve the change rule of the induced residual stress (RS) field after multipass ultrasonic surface rolling (USR), a mathematical model of the induced residual stress (RS) field after multipass ultrasonic surface rolling is first established. Then, the coupling mechanisms of the RS field after dual-pass USR and multipass USR are analyzed, respectively. Subsequently, a finite element (FE) model is established, and the influence of the interval between two adjacent rolling paths is investigated. Finally, both the mathematical model and the FE model are experimentally verified. The results show that both the mathematical model and the FE model can predict the RS field after multipass USR. Two adjacent RS fields will couple with each other in their overlapping regions. For a relatively small interval , the RS field after multipass USR can be fully coupled, so as to form a uniform compressive RS layer. In this study, when  = 0.05 mm, the values of the surface compressive RS, the maximum compressive RS, the depth of the maximum compressive RS, and the depth of the compressive RS layer reach 426.71 MPa, 676.54 MPa, 0.05 mm, and 0.54 mm, respectively.
为了实现多通道超声表面轧制(USR)后诱导残余应力(RS)场的变化规律,首先建立了多通道超声表面轧制后诱导残余应力(RS)场的数学模型。然后,分别分析了双通道 USR 和多通道 USR 后 RS 场的耦合机制。随后,建立了有限元(FE)模型,并研究了相邻两条轧制路径之间间隔的影响。最后,对数学模型和 FE 模型进行了实验验证。结果表明,数学模型和 FE 模型都能预测多通道 USR 后的 RS 场。两个相邻的 RS 场将在其重叠区域内相互耦合。对于相对较小的间隔,多路 USR 后的 RS 场可以完全耦合,从而形成均匀的压缩 RS 层。在本研究中,当 = 0.05 mm 时,表面压缩 RS 值、最大压缩 RS 值、最大压缩 RS 深度和压缩 RS 层深度分别达到 426.71 MPa、676.54 MPa、0.05 mm 和 0.54 mm。
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Advances in Materials Science and Engineering
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