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Hydrogen Sensing Application of Palladium-Coated Silver Double Nanowire System 钯包银双纳米线系统的氢传感应用
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1007/s11468-024-02424-z
Yinqiao Li, Yu Su, Hongbin Jin, Yunfei Zou, Song Wang, Gang Song

We investigate surface plasmon polaritons (SPPs) modes in palladium (Pd)-coated silver double nanowires by using the finite difference time domain (FDTD) method. Since Pd can absorb hydrogen (H(_2)) and converts to Pd-H, its permittivity is completely different from that of Pd-H, so the optical response of the system will be also change. The results of electric field distributions and propagation lengths of seven modes of the designed structure are obtained by calculations. For different modes, it is found that the propagation length increases with the increase of mode order. The propagation lengths of the same mode in the structure of Pd and Pd-H are respectively compared, and it is discovered that it is also different due to the change of dielectric constant before and after H(_2) absorption. The results show that in the double nanowire structure, the propagation lengths of structures with Pd are larger than the ones of structures with Pd-H for each mode. The distance of the two nanowires impacts on the coupling between the two nanowires. By changing the radius of Ag nanowire, the propagation lengths of the fundamental mode increase, while the ones of the harmonic modes decrease. There is an optimal thickness to make the propagation length longest for each mode by changing the thickness of Pd, which shows the competition between the dissipation of the structure and the coupling between SPPs in different layers. The structure we designed can be applied to the direction of the hydrogen sensor to realize the monitoring of its state when using hydrogen energy to ensure safety.

我们利用有限差分时域(FDTD)方法研究了钯(Pd)镀银双纳米线中的表面等离子体极化子(SPPs)模式。由于 Pd 可以吸收氢(H/(_2))并转化为 Pd-H,其介电常数与 Pd-H 完全不同,因此系统的光学响应也会发生变化。通过计算得到了所设计结构的七种模式的电场分布和传播长度。对于不同的模式,可以发现传播长度随着模式阶数的增加而增加。分别比较了 Pd 和 Pd-H 结构中相同模式的传播长度,发现由于 H(_2) 吸收前后介电常数的变化,传播长度也有所不同。结果表明,在双纳米线结构中,Pd 结构的各模式传播长度均大于 Pd-H 结构的各模式传播长度。两根纳米线的距离会影响两根纳米线之间的耦合。通过改变 Ag 纳米线的半径,基波模式的传播长度增加,而谐波模式的传播长度减少。通过改变钯的厚度,每个模式的传播长度都有一个最佳厚度,这表明了结构的耗散与不同层 SPP 之间耦合之间的竞争。我们设计的结构可应用于氢传感器的方向,以实现在使用氢能时对其状态的监测,从而确保安全。
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引用次数: 0
Polarization-insensitive Terahertz Graphene-based Optical Switches 偏振敏感的太赫兹石墨烯基光学开关
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1007/s11468-024-02490-3
Jun Zhu, Jiayuan Xiong

We designed a single-layer patterned graphene metasurface composed of four L-shaped graphene strips, four rectangular graphene strips, and meter-shaped graphene block. Metasurface creates dual plasmon-induced transparency (PIT) through the interaction between light and dark modes. The transmission characteristics of the structure are analyzed using the coupled mode theory and the finite element method, and the structure realizes the function of the dual-frequency optical switch. At frequencies of 3.72 THz and 6.24 THz, the optical switch modulation amplitudes are 98.04% and 95.37%, respectively, and the corresponding insertion losses are 0.16 dB and 0.08 dB respectively. In addition, the proposed structure is insensitive to changes in the polarization angle of the incident light. Under the incidence of x-polarized light and y-polarized light, the PIT effect of the two structures is consistent. This research will present a new idea for the design of terahertz multi-frequency optical switches. The optical switch has great potential for various applications such as terahertz imaging, sensors, photodetectors, and modulators.

我们设计了一种单层图案化石墨烯元表面,由四条 L 形石墨烯条、四条矩形石墨烯条和米形石墨烯块组成。元表面通过明暗模式之间的相互作用产生了双等离子体诱导透明(PIT)。利用耦合模式理论和有限元法分析了该结构的传输特性,并实现了双频光开关的功能。在 3.72 THz 和 6.24 THz 频率下,光开关调制幅度分别为 98.04% 和 95.37%,相应的插入损耗分别为 0.16 dB 和 0.08 dB。此外,所提出的结构对入射光偏振角的变化不敏感。在 x 偏振光和 y 偏振光的入射条件下,两种结构的 PIT 效应是一致的。这项研究将为太赫兹多频光学开关的设计提供一个新思路。该光学开关在太赫兹成像、传感器、光电探测器和调制器等各种应用中具有巨大潜力。
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引用次数: 0
A Tunable Low-Pass Filter Based on MIM Structure with Kerr Effect 基于具有克尔效应的 MIM 结构的可调谐低通滤波器
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1007/s11468-024-02502-2
JiaQi Song, He Tian, Yu Hao, XinYi Zhang

In this paper, a tunable low-pass optical filter based on metal–insulator-metal (MIM) structure with surface plasmon polaritons (SPPs) is proposed and discussed, which is composed of a bus waveguide containing two silver rods with square section (SRSS) and two semi-elliptical resonators (SERs) partially filled with Kerr material. After optimizing the structural parameters, a relatively ideal low-pass filtering effect is achieved. The minimum transmittance of the passband is 0.76, and the roll off coefficient (ROC) of the filtering barrier is up to 1.55 × 10−7 GHz−1. Furthermore, based on the influence of refractive index on optical modes in the two SERs, the cutoff frequency of the filtering effect can be conveniently adjusted by controlling the external light field irradiated on the Kerr material. The sensitivity of the right cutoff frequency adjustment is 11.6 GHz·μm2/mW, accompanied by an increase in the ROC. The low-pass filter with tunable cutoff frequency may have promising applications in integrated optical communication and information processing.

本文提出并讨论了一种基于表面等离子体极化子(SPPs)的金属-绝缘体-金属(MIM)结构的可调谐低通滤波器,它由包含两根方形截面银棒(SRSS)和两个部分填充克尔材料的半椭圆形谐振器(SERs)的总线波导组成。在优化结构参数后,实现了相对理想的低通滤波效果。通带的最小透过率为 0.76,滤波屏障的滚降系数(ROC)高达 1.55 × 10-7 GHz-1。此外,基于折射率对两个 SER 中光学模式的影响,通过控制照射在 Kerr 材料上的外部光场,可以方便地调节滤波效果的截止频率。正确调整截止频率的灵敏度为 11.6 GHz-μm2/mW,同时 ROC 也有所提高。这种截止频率可调的低通滤波器有望在集成光通信和信息处理领域得到应用。
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引用次数: 0
Grating Coupled Self-referenced SPP Biosensor for Detection of Glucose Level in Urine in Optical Communication Band 用于在光通信波段检测尿液中葡萄糖含量的光栅耦合自参考 SPP 生物传感器
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-08-20 DOI: 10.1007/s11468-024-02494-z
Lopamudra Sen, Bratati Mukhopadhyay

The expeditious growth and development of different optical-based medical and biomedical instruments to detect various diseases nowadays put itself a potential research topic. In recent times, prevalence of diabetes mellitus among people has become alarming and often life-threatening. In this regard, efficient sensors with high sensitivity are extremely necessary for monitoring and quantification of glucose level in the urine samples. A self-referenced surface plasmon polariton sensor using trapezoidal TiO2 grating on thin Au film has been proposed here to detect glucose level in urine samples for the first time. The proposed sensor has been optimized for better sensitivity and can be operated in the optical communication band which can help to achieve existing mature light sources and light detection instruments. The sensor has been designed with a thin dielectric grating on top of thin metal film resulting in generation of two surface plasmons at the two boundaries of the metal film. This technique is fascinating to improve the accuracy of sensitivity of the device and helps to eliminate cross-sensitivity problem. As a result, this type of self-referenced biosensor can be used for a wide range of applications in fields such as biochemistry, biophysics, and environmental monitoring. The proposed sensor shows a higher sensitivity compared to that of other plasmonic sensors reported in recent times due to incorporation of trapezoidal-shaped grating structure for the first time instead of rectangular shape. The spectral sensitivity of the proposed structure was obtained as 666.67 nm/RIU with optimized values of different structural parameters.

如今,用于检测各种疾病的各种光学医疗和生物医学仪器发展迅速,成为一个潜在的研究课题。近来,糖尿病在人群中的发病率令人担忧,而且常常危及生命。因此,高灵敏度的高效传感器对于监测和量化尿液样本中的葡萄糖含量极为必要。本文首次提出了一种在金薄膜上使用梯形二氧化钛光栅的自参考表面等离子体极化子传感器,用于检测尿液样本中的葡萄糖含量。该传感器经过优化,灵敏度更高,可在光通信波段工作,有助于实现现有的成熟光源和光检测仪器。该传感器在金属薄膜上设计了一个薄介质光栅,从而在金属薄膜的两个边界产生了两个表面等离子体。这种技术可以提高设备灵敏度的准确性,并有助于消除交叉灵敏度问题。因此,这种自参照生物传感器可广泛应用于生物化学、生物物理学和环境监测等领域。由于首次采用了梯形光栅结构而非矩形结构,与近期报道的其他等离子传感器相比,所提出的传感器具有更高的灵敏度。在对不同结构参数进行优化后,拟议结构的光谱灵敏度为 666.67 nm/RIU。
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引用次数: 0
Synthesis of CuO@ZnO Nanoparticle Core–Shell Formed via Laser Ablation in Liquid for Photocatalytic Applications 在液体中通过激光烧蚀合成用于光催化应用的 CuO@ZnO 纳米粒子核壳
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-08-19 DOI: 10.1007/s11468-024-02488-x
Salah M. Abdul Aziz, Uday M. Nayef, Mohammed Rasheed

This research study specifically examines the CuO@ZnO nanoparticle core–shell colloidal solution that is produced using Nd: YAG laser ablation. The laser used has pulse energies of 900, 700, and 500 mJ, a wavelength of 1064 nm, and repeated pulses of 200. This work demonstrated the characteristics of a colloidal solution containing CuO@ZnO NP core–shell deposited onto Si substrates using the drop-casting process. The TEM, SEM, XRD, and UV–vis spectroscopy techniques were used to investigate the morphological, shape, optical, and structural characteristics of the synthesized CuO@ZnO NP core–shell. The XRD analysis reveals that the CuO@ZnO NP core–shell has sizes ranging from 30 to 93 nm approximately. The nanoparticle core–shell exhibited a combination of spherical and irregular shapes with sizes ranging from 30 to 90 nm. The nanoparticle size appeared to be influenced by the variation in laser pulse energy, as evidenced in SEM pictures. The TEM pictures reveal that the core–shell nanoparticles exhibit a particle size distribution with average sizes of 19, 70, and 30 nm for the nanoparticles produced using laser pulses with energy levels of 900, 700, and 500 mJ, respectively. The TEM pictures also exhibit a dark central region of CuO NPs and a comparatively lighter outside region of the ZnO nanoshell, thereby verifying its core–shell structure. Alteration of the laser energy resulted in a noticeable change in the optical energy band gap in the generated samples. The results of the UV–vis test suggested that a change in the energy of the laser pulse caused a change in the energy gap that ranges from 2.6 to 3 eV. The dye degradation capability of CuO@ZnO NP core–shell has been evaluated using methylene blue (MB), an organic dye. The results indicate that all samples exhibited successful degradation using CuO@ZnO NP core–shell with differentiated activity levels. The blue color of the methylene blue solution vanished within 120 min of exposure to illumination when the CuO@ZnO nanoparticles, generated with a laser energy of 900 mJ, were present. The investigation of CuO@ZnO nanoparticles, synthesized through the use of laser pulse energy, demonstrates its potential as a highly effective substance for water purification.

本研究特别考察了使用 Nd: YAG 激光烧蚀法生产的 CuO@ZnO 纳米粒子核壳胶体溶液。所使用的激光脉冲能量为 900、700 和 500 mJ,波长为 1064 nm,重复脉冲为 200。这项工作展示了使用滴铸工艺沉积在硅基底上的含有 CuO@ZnO NP 核壳的胶体溶液的特性。利用 TEM、SEM、XRD 和 UV-vis 光谱技术研究了合成的 CuO@ZnO NP 核壳的形态、形状、光学和结构特征。XRD 分析表明,CuO@ZnO NP 核壳的尺寸约为 30 至 93 nm。纳米粒子核壳呈现出球形和不规则形状的组合,尺寸范围为 30 至 90 nm。纳米粒子的尺寸似乎受激光脉冲能量变化的影响,这一点在扫描电镜图片中得到了证明。TEM 照片显示,使用能量为 900、700 和 500 mJ 的激光脉冲产生的核壳纳米粒子呈现出粒度分布,平均粒度分别为 19、70 和 30 nm。TEM 照片还显示,CuO NPs 的中心区域颜色较深,而 ZnO 纳米壳的外部区域颜色相对较浅,从而验证了其核壳结构。激光能量的改变导致生成样品的光能带隙发生了明显变化。紫外可见光测试结果表明,激光脉冲能量的变化会导致能带隙在 2.6 至 3 eV 之间发生变化。使用有机染料亚甲基蓝(MB)评估了 CuO@ZnO NP 核壳的染料降解能力。结果表明,所有样品都成功地利用 CuO@ZnO NP 核壳进行了降解,且活性水平各不相同。当 CuO@ZnO 纳米粒子在 900 mJ 的激光能量下产生时,亚甲基蓝溶液的蓝色在照射 120 分钟内消失。对利用激光脉冲能量合成的 CuO@ZnO 纳米粒子的研究表明,它具有作为一种高效净水物质的潜力。
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引用次数: 0
Design and Evaluation of Tunable Terahertz Metasurface Biosensor for Malaria Detection with Machine learning Optimization Using Artificial Intelligence 利用人工智能机器学习优化设计和评估用于疟疾检测的可调太赫兹元表面生物传感器
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-08-19 DOI: 10.1007/s11468-024-02491-2
Jacob Wekalao, Ngaira Mandela, Apochi Obed, Abdessalem Bouhenna

Malaria continues to be a major global health issue, impacting millions each year and leading to hundreds of thousands of deaths, especially in less developed areas. Timely and precise diagnosis is essential for effective treatment and management of this parasitic illness. This study presents the design and evaluation of a tunable terahertz (THz) metasurface biosensor tailored for malaria detection, integrating plasmonic materials with artificial intelligence. The biosensor employs a multi-layer structure comprising graphene, gold, and silver to leverage surface plasmon resonance effects. Comprehensive electromagnetic simulations and parameter optimization demonstrate the sensor's ability to detect minute changes in malaria parasite concentrations, achieving a peak sensitivity of 429 GHzRIU−1, detection accuracy of 25.6 and a figure of merit of 10.989 RIU-1. The sensor features tunable elements that allow dynamic performance adjustments. Additionally, the XGBoost machine learning algorithm is harnessed to predict sensor performance across various design parameters, consistently demonstrating maximum R2 ranging up to 100%. This fusion of advanced materials, precise engineering, and predictive analytics represents a significant advancement in biosensing technology for malaria detection, offering substantial potential for early and accurate diagnosis.

疟疾仍然是一个重大的全球健康问题,每年影响数百万人,导致数十万人死亡,尤其是在欠发达地区。及时准确的诊断对于有效治疗和管理这种寄生虫病至关重要。本研究介绍了一种专为疟疾检测量身定制的可调太赫兹(THz)元表面生物传感器的设计和评估,该传感器将等离子体材料与人工智能相结合。该生物传感器采用了由石墨烯、金和银组成的多层结构,以利用表面等离子体共振效应。全面的电磁模拟和参数优化证明,该传感器能够检测疟原虫浓度的微小变化,实现了 429 GHzRIU-1 的峰值灵敏度、25.6 的检测精度和 10.989 RIU-1 的优越性。该传感器采用可调元件,可进行动态性能调整。此外,XGBoost 机器学习算法可用于预测传感器在各种设计参数下的性能,其最大 R2 范围始终高达 100%。先进材料、精密工程和预测分析的融合代表了疟疾检测生物传感技术的重大进步,为早期准确诊断提供了巨大潜力。
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引用次数: 0
Numerical Study of Surface Plasmon Resonance Biosensor Employing Bismuth Ferrite, Black Phosphorus, and Zinc Telluride for Blood Group Detection 利用铁氧体铋、黑磷和碲化锌检测血型的表面等离子共振生物传感器数值研究
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-08-17 DOI: 10.1007/s11468-024-02482-3
Tanjib Ahmed, Md. Kamal Hosain

An optimized prism-based surface plasmon resonance (SPR) sensor, containing a specific material combination, is represented for the accurate detection of the human blood group at a wavelength of 633 nm. The sensor structure includes a BK7 prism as a substrate followed by sequential deposition of silver (Ag), bismuth ferrite (BiFeO(_{textbf{3}})), black phosphorus (BP), and zinc telluride (ZnTe). The angular interrogation method (ATM) is used to investigate the performance parameters of the sensor, which include sensitivity, detection accuracy, and quality factor. Design and performance analysis is conducted using COMSOL, a finite element method (FEM)-based multiphysics software. Optimization of the thickness of the layers is done to get the highest possible outcome. For resonance and non-resonance conditions, magnetic field propagation and electric field distribution are determined which specifies an enhanced electric field at the metallic layer. The enhanced electric field is produced due to the metallic layer which reflects and redirects the electric field and provides a significant advancement in the performance parameter. The numerical calculations of the sensor parameters are obtained with the sensing medium immobilized with different blood groups (A, B, O). The highest sensitivity, detection accuracy, and quality factor for the detection of blood group A are 298.17 (^{circ })/RIU, 2.2, and 130.1 RIU(^{mathbf {-1}}); for the detection of blood group O are 327.79 (^{circ })/RIU, 1.98, and 95.35 RIU(^{mathbf {-1}}); and for the detection of blood group B are 330.86 (^{circ })/RIU, 1.73, and 81.33 RIU(^{-1}), respectively. The numerical analysis of the sensor parameters assures a significant improvement in the performance compared to previous research studies.

本文介绍了一种优化的基于棱镜的表面等离子体共振(SPR)传感器,其中包含一种特定的材料组合,用于精确检测波长为 633 nm 的人类血型。传感器结构包括一个作为基底的 BK7 棱镜,然后依次沉积银 (Ag)、铁氧体铋 (BiFeO(_{textbf{3}}))、黑磷 (BP) 和碲化锌 (ZnTe)。采用角度询问法(ATM)来研究传感器的性能参数,包括灵敏度、检测精度和品质因数。设计和性能分析使用基于有限元法 (FEM) 的多物理场软件 COMSOL 进行。对各层厚度进行了优化,以获得尽可能高的结果。在共振和非共振条件下,确定了磁场传播和电场分布,从而确定了金属层的增强电场。增强电场的产生是由于金属层反射和重定向了电场,从而显著提高了性能参数。对固定了不同血型(A、B、O)的传感介质的传感器参数进行了数值计算。检测血型 A 的最高灵敏度、检测精度和质量因子分别为 298.17 (^{circ })/RIU, 2.2 和 130.1 RIU(^{mathbf {-1}}); 检测血型 O 的最高灵敏度、检测精度和质量因子分别为 327.79 (^{circ })/RIU, 1.98, and 95.35 RIU(^{mathbf {-1}});检测血型 B 的分别是 330.86 (^{circ })/RIU, 1.73, and 81.33 RIU(^{-1}).与之前的研究相比,传感器参数的数值分析确保了性能的显著提高。
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引用次数: 0
Work Function, Electrostatic Force Microscopy, Tunable Photoluminescence of Gold Nanoparticles, and Plasmonic Interaction of Gold Nanoparticles/Rhodamine 6G Nanocomposite 金纳米粒子的功函数、静电力显微镜、可调光致发光以及金纳米粒子/罗丹明 6G 纳米复合材料的等离子相互作用
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-08-15 DOI: 10.1007/s11468-024-02484-1
Ishaq Musa, Jamal Ghabboun

The work function and tunable photoluminescence of gold nanoparticles (AuNPs) and their interaction with Rhodamine 6G (R6G) molecules were characterized using scanning probe microscopy (SPM) and spectroscopy techniques. Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy (KPFM) were employed to analyze the surface roughness and work function of AuNPs ranging in size from 3 to 21 nm. According to measurements with Kelvin Probe Force Microscopy (KPFM), the work functions for AuNPs are approximately 5.17 eV, 5.14 eV, and 5.13 eV for the range of sizes of nanoparticles. It was observed that larger AuNPs have increased surface roughness and consequently decreased work function. Additionally, phase imaging and Electrostatic Force Microscopy (EFM) were utilized to further investigate the AuNPs/R6G composites, revealing their surface nanoscale distribution and their electrical properties. In addition, the tunable photoluminescence of AuNPs based on excitation wavelength was studied, showing that as the excitation wavelength increases, the photoluminescence shifts to higher emission wavelengths and the peak intensity increases. Furthermore, UV–visible absorption and photoluminescence spectroscopy were employed to investigate the optical properties of AuNPs added to Rhodamine 6G molecules, revealing an enhancement in absorption and a reduction in photoluminescence.

利用扫描探针显微镜(SPM)和光谱技术对金纳米粒子(AuNPs)的功函数和可调光致发光及其与罗丹明6G(R6G)分子的相互作用进行了表征。采用原子力显微镜(AFM)和开尔文探针力显微镜(KPFM)分析了尺寸从 3 纳米到 21 纳米的 AuNPs 的表面粗糙度和功函数。根据开尔文探针力显微镜(KPFM)的测量结果,在各种尺寸的纳米粒子中,AuNPs 的功函数分别约为 5.17 eV、5.14 eV 和 5.13 eV。据观察,较大的 AuNPs 表面粗糙度增加,因而功函数降低。此外,还利用相成像和静电力显微镜(EFM)进一步研究了 AuNPs/R6G 复合材料,揭示了其表面纳米级分布及其电学特性。此外,还研究了基于激发波长的 AuNPs 可调光致发光,结果表明随着激发波长的增加,光致发光会向更高的发射波长转移,峰值强度也会增加。此外,还利用紫外可见吸收和光致发光光谱研究了添加到罗丹明 6G 分子中的 AuNPs 的光学特性,结果表明吸收增强,光致发光减弱。
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引用次数: 0
Generalized Fiber-Optic Surface-Plasmon-Resonance Modeling Through Ray-Tracing 通过光线跟踪进行广义光纤表面等离子共振建模
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-08-15 DOI: 10.1007/s11468-024-02474-3
Wouter Vandezande, Annelies Dillen, Jeroen Lammertyn, Maarten B. J. Roeffaers

Fiber-optic surface plasmon resonance (FO-SPR) sensors look at the absorbance of reflected light to measure changes in refractive index (RI). FO-SPR sensor modeling is essential in understanding the underlying processes that induce such RI changes. Despite two types of rays, i.e., skew and meridional rays, an FO-SPR model has been developed in the literature that only considers meridional rays. This meridional model has proven its applicability in several publications using pass-through FO-SPR sensors. However, this simplified FO-SPR model fails to simulate back-reflecting FO-SPR sensors properly, where diffuse light is delivered and collected at the same optical fiber end. Here, it is shown that a generalized FO-SPR model that includes skew rays more accurately simulates the spectra obtained in back-reflecting FO-SPR sensors. With the changing incidence plane of a skew ray in mind, the generalized FO-SPR model was built with three-dimensional polarization ray-tracing calculus. The necessary angular ray distribution of the back-reflecting FO-SPR sensor was acquired by a Monte Carlo three-dimensional ray-tracing simulation. Next, the effect of including optical components and deviations and model optimization by adjusting the gold relative permittivity and thickness was evaluated. The generalized model simulated FO-SPR absorbances with smaller widths than the experimental FO-SPR absorbances. The cause of this difference in absorbance is unclear and demands more research. Nevertheless, the skew ray incorporation in the generalized FO-SPR model enabled its application to a greater diversity of FO-SPR sensors compared to the simplified FO-SPR model both as a predictive and an analytic tool in the development of FO-SPR sensors.

光纤表面等离子体共振(FO-SPR)传感器通过观察反射光的吸收率来测量折射率(RI)的变化。光纤表面等离子体共振传感器建模对于了解引起这种 RI 变化的基本过程至关重要。尽管存在两种类型的光线,即偏斜光线和经向光线,但文献中已开发出一种只考虑经向光线的 FO-SPR 模型。这种经向模型已在一些使用直通式 FO-SPR 传感器的出版物中证明了其适用性。然而,这种简化的 FO-SPR 模型无法正确模拟背反射式 FO-SPR 传感器,在这种情况下,漫射光在同一光纤端传输和收集。这里的研究表明,包含倾斜光线的广义 FO-SPR 模型能更准确地模拟背向反射 FO-SPR 传感器获得的光谱。考虑到偏斜光线入射面的变化,利用三维偏振光线追踪计算建立了广义 FO-SPR 模型。通过蒙特卡洛三维光线跟踪模拟,获得了背反射式 FO-SPR 传感器所需的角光线分布。接着,评估了加入光学元件和偏差的效果,以及通过调整金的相对介电常数和厚度对模型进行优化的效果。广义模型模拟出的 FO-SPR 吸光度宽度小于实验中的 FO-SPR 吸光度宽度。造成这种吸光度差异的原因尚不清楚,需要进行更多的研究。尽管如此,与简化 FO-SPR 模型相比,将倾斜射线纳入广义 FO-SPR 模型使其能够应用于更多样化的 FO-SPR 传感器,成为开发 FO-SPR 传感器的预测和分析工具。
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引用次数: 0
Optical-Based Aqueous Solution Detection by Graphene Metasurface Surface Plasmon Resonance Biosensor with Behavior Prediction Using Polynomial Regression 利用多项式回归进行行为预测的石墨烯金属表面表面等离子体共振生物传感器的水溶液光学检测技术
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-08-14 DOI: 10.1007/s11468-024-02464-5
Jacob Wekalao, Shobhit K. Patel, Sana Ben Khalifa, Saleh Chebaane, Ammar Armghan, Taoufik Saidani

Aqueous solutions are fundamental to a wide range of chemical and biological processes, serving as a critical medium for both natural phenomena and technological advancements. This study presents the design and modelling of a metasurface-based biosensor for aqueous solution detection. The sensor architecture comprises multiple resonators deposited on a silicon dioxide substrate, with materials selected for their specific optical properties. Finite element analysis was employed to simulate the sensor’s signal transduction mechanisms. The optimized design exhibits a sensitivity of 500 GHzRIU−1 and a figure of merit of 10.638 RIU−1. Comprehensive characterization of the sensor’s performance includes evaluation of its detection limit, dynamic range, and signal-to-noise ratio, all of which demonstrate superior target detection accuracy. The sensor’s versatility is further illustrated through its application in encoding operations, leveraging on the transmittance values to perform logic functions. A polynomial regression model was developed to interpolate absorption values at intermediate frequencies, achieving an R2 value of 1.0, indicating perfect correlation between predicted and simulated data. These results suggest significant potential for the sensor’s application in high-precision biomolecular detection across various fields, including biomedical diagnostics and environmental monitoring.

水溶液是各种化学和生物过程的基础,是自然现象和技术进步的关键介质。本研究介绍了一种用于水溶液检测的基于元表面的生物传感器的设计和建模。传感器结构由沉积在二氧化硅基底上的多个谐振器组成,所选材料具有特定的光学特性。有限元分析被用来模拟传感器的信号传导机制。优化设计的灵敏度为 500 GHzRIU-1,优点系数为 10.638 RIU-1。对传感器性能的全面鉴定包括对其探测极限、动态范围和信噪比的评估,所有这些都证明了其卓越的目标探测精度。传感器在编码操作中的应用进一步说明了它的多功能性,利用透射率值执行逻辑功能。开发了一个多项式回归模型来内插中间频率的吸收值,R2 值达到 1.0,表明预测数据和模拟数据之间具有完美的相关性。这些结果表明,该传感器在生物医学诊断和环境监测等多个领域的高精度生物分子检测中具有巨大的应用潜力。
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