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Design and Analysis of a Plasmonic Metasurface-Based Graphene Sensor for Highly Sensitive and Label-Free Detection of COVID-19 Biomarkers 设计和分析基于等离子体元表面的石墨烯传感器,实现 COVID-19 生物标记物的高灵敏度和无标记检测
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-07-27 DOI: 10.1007/s11468-024-02442-x
Nagarajan P., Jacob Wekalao, Ashokkumar N., Shobhit K. Patel

This research presents plasmonic metasurface-based graphene sensor for highly sensitive and label-free detection of COVID-19 biomarkers. The proposed sensor structure integrates graphene with specially engineered metasurface resonators for the detection of SARS-CoV-2 biomarkers through analysis of terahertz spectroscopic signatures. Finite element method simulations were performed to optimize the sensor design, including resonator dimensions, angle of incidence, and graphene chemical potential. The optimized sensor demonstrates a maximum sensitivity of 400 GHzRIU−1, a figure of merit of 0.224 RIU−1, a quality factor of 7.942, and a detection limit of 0.465 RIU. Electric field distribution analysis provides insights into the sensor’s plasmonic modes and light-matter interactions. The sensor also shows potential for 2-bit encoding applications. Compared to existing designs, the proposed sensor exhibits superior performance in key metrics like sensitivity among others. This plasmonic metasurface approach presents a promising platform for rapid, sensitive, and specific detection of SARS-CoV-2 and other viral biomarkers, with potential applications in advanced diagnostic tools and public health monitoring.

本研究提出了基于等离子体元表面的石墨烯传感器,用于高灵敏度和无标记地检测 COVID-19 生物标记物。拟议的传感器结构将石墨烯与专门设计的元表面谐振器集成在一起,通过分析太赫兹光谱特征来检测 SARS-CoV-2 生物标记物。为优化传感器设计,包括谐振器尺寸、入射角和石墨烯化学势,进行了有限元法模拟。优化后的传感器最大灵敏度为 400 GHzRIU-1,优点系数为 0.224 RIU-1,品质因数为 7.942,探测极限为 0.465 RIU。电场分布分析有助于深入了解传感器的等离子模式和光物质相互作用。该传感器还显示出 2 位编码应用的潜力。与现有设计相比,所提出的传感器在灵敏度等关键指标上表现出更优越的性能。这种等离子体元表面方法为快速、灵敏、特异地检测 SARS-CoV-2 和其他病毒生物标记物提供了一个前景广阔的平台,有望应用于先进的诊断工具和公共卫生监测。
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引用次数: 0
Core–Shell Plasmonic Nanostructures for Hyperthermia of Cancer and Tumor Cells 用于癌症和肿瘤细胞热疗的核壳质子纳米结构
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-07-27 DOI: 10.1007/s11468-024-02435-w
Vahid Rajabpour, Karim Abbasian, Mehmet Ertugrul

Plasmonic nanostructures continue to be the most promising alternative to hyperthermia treatment of cancer or tumors by focusing the light locally. Absorption and scattering cross-sections of 48 nanorods encompassing silver and palladium as core and gold and platinum as coating with four different aspect ratios and three different coating thicknesses were examined in an aqueous solution with finite-element method (FEM). According to the highest value of photothermal conversion efficiency (PCE) in each bimetallic compound, three Au@Ag, Pt@Ag, and Au@Pd nanorods, with aspect ratios of 4, 4, and 5, respectively; and all with a coating thickness of 1 nm; were chosen as the best ones named “A,” “B,” and “C”. Each nanorod irradiated by continuous wave (CW) laser radiation with 1 mW·μm−2 intensity at the LSPR wavelength for 200 ns, the temperature of the nanorods increased from 37 to 82.6, 46.34, and 44.33 °C, respectively. To robustly control the temperature in time and locally, the irradiation intensity of the “A” was decreased to 0.5 mW·μm−2, that its ambient temperature increased by 45 °C at a distance of 20 nm, which can selectively cause irreparable damage to the cancer cells. In addition, the nanorods were irradiated by pulsed laser for 200 ns periods. The results show that the bimetallic nanoparticles can convert light into heat locally.

Graphical Abstract

质子纳米结构通过在局部聚焦光线,仍然是癌症或肿瘤热疗最有前途的替代方法。利用有限元法(FEM)研究了水溶液中以银和钯为核心、金和铂为涂层的 48 个纳米棒的吸收和散射截面,这些纳米棒具有四种不同的长宽比和三种不同的涂层厚度。根据每种双金属化合物中光热转换效率(PCE)的最高值,选择了三个金@银、铂@银和金@钯纳米棒,它们的长宽比分别为 4、4 和 5,涂层厚度均为 1 nm,并被命名为 "A"、"B "和 "C"。每个纳米棒在 LSPR 波长处接受强度为 1 mW-μm-2 的连续波(CW)激光照射 200 毫微秒后,温度分别从 37 ℃ 升高到 82.6 ℃、46.34 ℃ 和 44.33 ℃。为了在时间上和局部上稳健地控制温度,将 "A "的辐照强度降至 0.5 mW-μm-2,在 20 nm 的距离上,其环境温度升高了 45 ℃,这可以选择性地对癌细胞造成不可修复的损伤。此外,还对纳米棒进行了 200 ns 周期的脉冲激光照射。结果表明,双金属纳米粒子可以在局部将光转化为热。
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引用次数: 0
Detailed Analysis of Size and Shape of TiN Nanostructure on Refractive Index-Based Sensor 基于折射率的传感器上 TiN 纳米结构的尺寸和形状的详细分析
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-07-26 DOI: 10.1007/s11468-024-02444-9
Yashika, Jyoti Katyal

One significant application of this research article is enhancing the sensitivity of refractive index-based localized surface plasmon resonance (LSPR) sensor by using TiN nanostructures. The LSPR-based sensors are highly effective in detecting minute environmental changes and a crucial measure for these sensors is the refractive index sensitivity (RIS). The unique properties of TiN nanoparticles and the precision of the FDTD method drive significant interest in optimizing size and shape of TiN nanoparticles for enhanced RIS. By optimizing above mention parameters, we maximized the RIS to ~979 nm/RIU, thereby improving the performance of LSPR-based sensors. This research is vital for developing highly sensitive and efficient nitride-based LSPR-based sensors, which have applications in biomedical diagnostics, environmental monitoring, and other fields.

本研究文章的一个重要应用是利用 TiN 纳米结构提高基于折射率的局部表面等离子体共振(LSPR)传感器的灵敏度。基于局部表面等离子体共振的传感器在检测微小环境变化方面非常有效,而这些传感器的一个关键指标就是折射率灵敏度 (RIS)。TiN 纳米粒子的独特性质和 FDTD 方法的精确性促使人们对优化 TiN 纳米粒子的尺寸和形状以增强 RIS 产生浓厚兴趣。通过优化上述参数,我们将 RIS 最大化至 ~979 nm/RIU,从而提高了基于 LSPR 的传感器的性能。这项研究对于开发基于氮化物的高灵敏、高效 LSPR 传感器至关重要,该传感器可应用于生物医学诊断、环境监测等领域。
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引用次数: 0
Sensitivity Enhancement of Franckeite-Based Surface Plasmon Resonance Sensors Using A Bimetallic Structure 利用双金属结构提高基于方镁石的表面等离子体共振传感器的灵敏度
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-07-25 DOI: 10.1007/s11468-024-02432-z
Rajeev Kumar, Shivam Singh, Partha Sarkar, Lalit Garia, Varun Kumar Kakar, Abdullah Saad Alsubaie, Amrindra Pal

This study proposes the franckeite layer onto a bimetallic (Au–Cu) based sensor. The proposed sensors use CaF2 prism, Au (39 nm), Cu (5 nm), with/without franckeite, and adsorption layer (sensing medium (SM). All the performance analysis is carried out at 633 nm wavelength. At optimized, the bimetallic layer, the remarkable sensitivity, DA, and FoM of 350.76°/RIU, 0.144/°, and 50.50/RIU are achieved, respectively. The proposed sensor’s computed electric field (EF) intensity and penetration depth (PD) are 2.11 × 105 V/m and 204.28 nm at an RI of 1.330 SM. With a quick response indicated by a significant shift in resonance angle, the suggested structure would help detect the RI between 1.33 and 1.335. A detailed comparison with the most recent publications in biomedical applications confirms the outstanding performance of the proposed SPR sensors. This comparison highlights the significant potential of the sensors in biosensing and biomedicine.

本研究提出在基于双金属(金-铜)的传感器上添加钫石层。拟议的传感器使用 CaF2 棱镜、金(39 nm)、铜(5 nm)、有/无钫石和吸附层(传感介质 (SM))。所有性能分析都是在 633 纳米波长下进行的。在优化双金属层时,灵敏度、DA 和 FoM 分别达到 350.76°/RIU、0.144/° 和 50.50/RIU。在 RI 为 1.330 SM 时,拟议传感器的计算电场(EF)强度和穿透深度(PD)分别为 2.11 × 105 V/m 和 204.28 nm。共振角的显著偏移显示了快速响应,建议的结构将有助于检测 1.33 至 1.335 之间的 RI。与最新发表的生物医学应用论文进行的详细比较证实了所建议的 SPR 传感器的卓越性能。这种比较凸显了传感器在生物传感和生物医学方面的巨大潜力。
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引用次数: 0
Feasibility of All Single-Qubit Gates with Four InGaAs Quantum Dots Coupled to Two Silver Nanowires 利用耦合到两条银纳米线的四个 InGaAs 量子点实现所有单ubit 栅极的可行性
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-07-24 DOI: 10.1007/s11468-024-02415-0
Chol-Min Kim, Nam-Chol Kim, Myong-Chol Ko, Ju-Song Ryom, Su-Ryon Ri

We have proposed all single-qubit logic gates with four InGaAs quantum dots (QDs) coupled to a T-type plasmonic waveguides (PWs) wherein binary qubits are encoded by frequency of photons. Our results reveal that by adjusting distance between QDs, coupling strength and frequency detuning in a proper manner, an arbitrary single-qubit gates can be achieved. We investigated schemes theoretically via the real-space approach and estimated feasibilities of a proposed one by fidelities for a variety of parameters. Under the present technology and high fidelities, our proposed schemes are feasible, opening the promising perspectives for constructing quantum computation and quantum information processing.

我们提出了用四个 InGaAs 量子点(QDs)耦合到 T 型等离子体波导(PWs)的所有单量子比特逻辑门,其中二进制量子比特由光子频率编码。我们的研究结果表明,通过适当调整 QD 之间的距离、耦合强度和频率失谐,可以实现任意的单量子比特门。我们通过实空间方法从理论上研究了各种方案,并通过各种参数的保真度估算了所提出方案的可行性。在现有技术和高保真条件下,我们提出的方案是可行的,为构建量子计算和量子信息处理开辟了广阔的前景。
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引用次数: 0
Design and Performance of Ultrathin MXene Nano-Absorber for Visible and Infrared Spectra 用于可见光和红外光谱的超薄 MXene 纳米吸收器的设计与性能
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-07-24 DOI: 10.1007/s11468-024-02428-9
Zhipeng Gao

This paper introduces an ultrathin metamaterial absorber based on MXene, consisting of a subwavelength-sized periodic square-ring-shaped nano-cylinder operating in the visible-infrared regime. The proposed absorber consists of a three-layer standard configuration, featuring a top layer comprising a MXene nano-square cylinder, a middle dielectric material, and a bottom ground plane. It is observed that the proposed nano-absorber presents a broadband response and illustrates an absorption value of 90% across a large wavelength spectrum ranging from 400 to 2400 nm. This notable absorption is attributed to the localized surface plasmonic resonances (LSPR) induced at the top metasurface composed of periodic structures. The designed absorber exhibits a polarization-insensitive response and its due to the inherent symmetric nature of the constituent top unit cell. Furthermore, the absorber maintains stable absorption even at oblique angles up to 60°. The presented nano-absorber displays promising prospective for diverse applications, including solar cells, energy harvesting, and thermal imaging.

本文介绍了一种基于 MXene 的超薄超材料吸收器,它由一个亚波长尺寸的周期性方环形纳米圆柱体组成,可在可见光-红外线范围内工作。拟议的吸收器由三层标准配置组成,顶层包括一个 MXene 纳米方形圆柱体、中间的介电材料和底部的接地平面。据观察,拟议的纳米吸收器具有宽带响应,在 400 纳米到 2400 纳米的大波长光谱范围内,吸收值高达 90%。这种显著的吸收归因于由周期性结构组成的顶部元表面诱发的局部表面等离子体共振(LSPR)。所设计的吸收器表现出极化不敏感的响应,其原因在于组成顶层单元的固有对称性。此外,该吸收器即使在高达 60° 的斜角下也能保持稳定的吸收。所展示的纳米吸收器在太阳能电池、能量收集和热成像等多种应用领域前景广阔。
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引用次数: 0
Synthesis and Characterization of Nickel Ferrite Nanostructures by DC Reactive Sputtering Technique Using New Target Configuration 使用新靶配置的直流反应溅射技术合成镍铁氧体纳米结构并对其进行表征
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-07-23 DOI: 10.1007/s11468-024-02439-6
Noor E. Naji, Ali A. Aljubouri, Raid A. Ismail

In this work, nickel ferrite thin films were prepared using dc reactive sputtering technique. A new geometrical configuration of the sputtered target is proposed. It includes coating of an iron target with nickel thin film with lower area and then used it as a co-sputtering target to prepare nickel ferrite thin films on glass substrates. This configuration can be considered a novel method to prepare this material with a one-step process using the same deposition system. The structural and spectroscopic characteristics of the prepared material were determined and the formation of the nanostructures within the deposited films was confirmed. The prepared nanomaterial showed high structural purity with energy band gap in the typical range.

在这项工作中,使用直流反应溅射技术制备了镍铁氧体薄膜。提出了一种新的溅射靶几何结构。它包括在铁靶上镀一层面积较小的镍薄膜,然后将其用作共溅射靶,在玻璃基底上制备镍铁氧体薄膜。这种配置可被视为使用同一沉积系统一步制备这种材料的新方法。测定了所制备材料的结构和光谱特性,并确认了沉积薄膜中纳米结构的形成。所制备的纳米材料结构纯度高,能带隙在典型范围内。
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引用次数: 0
Surface Plasmon Polaritons in Graphene Material–Based Reconfigurable Antennas for Advanced Environmental Monitoring Applications 石墨烯材料中的表面等离子体极性子--基于可重构天线的先进环境监测应用
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-07-23 DOI: 10.1007/s11468-024-02422-1
Rajesh Yadav, Harsha Mann, V. S. Pandey, Preeti Verma

This paper presents surface plasmon polaritons in graphene material–based reconfigurable antennae for advanced environmental monitoring applications. The antenna consists of multiple elements which are made up of graphene material. It enhances the antenna’s performance, enabling tunability and adaptability in response to environmental conditions. Additionally, the defective ground structure has been incorporated into the antenna characteristics that contribute to improving the radiation patterns and frequency selectivity. The proposed antenna is excited through a silver nanostrip feedline coupled through vias to the radiated elements. The antenna is resonating at 5.046 THz, with a bandwidth of 7.611 (mathbf{%}) (5.21–4.828 THz). The reconfigurable antenna provides an acceptable limit of directivity along with high efficiency. Here, the reconfigurability is obtained by disabling and enabling the topmost radiating elements systematically. Moreover, the resonant frequency can be adjusted by modifying the external biasing voltage applied to the graphene material. The antenna generates the higher-order ({mathrm{TM}}_{65}) mode. Furthermore, a parametric analysis has been conducted to achieve impedance matching and antenna tuning by changing the external bias voltage applied to graphene elements. The proposed reconfigurable antenna system demonstrates promising capabilities for versatile environmental sensing applications including monitoring parameters such as temperature, humidity, and pollutant levels.

本文介绍了基于石墨烯材料的可重构天线中的表面等离子体极化子,用于先进的环境监测应用。该天线由石墨烯材料构成的多个元件组成。它增强了天线的性能,实现了可调谐性和对环境条件的适应性。此外,有缺陷的接地结构已被纳入天线特性,有助于改善辐射模式和频率选择性。拟议的天线通过银纳米带馈线进行激励,并通过通孔耦合到辐射元件。该天线的谐振频率为 5.046 THz,带宽为 7.611 (mathbf{%})(5.21-4.828 THz)。可重构天线提供了可接受的指向性极限和高效率。在这里,可重构性是通过系统地禁用和启用最顶端的辐射元件来实现的。此外,谐振频率可通过改变施加在石墨烯材料上的外部偏置电压来调整。天线产生了高阶 ({mathrm{TM}}_{65}) 模式。此外,还进行了参数分析,通过改变施加在石墨烯元件上的外部偏置电压来实现阻抗匹配和天线调谐。所提出的可重构天线系统为多功能环境传感应用展示了良好的能力,包括监测温度、湿度和污染物水平等参数。
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引用次数: 0
A Broadband D-Shaped Photonic Crystal Fiber Sensor via Surface Plasmon Resonance for Different Analytes with a Large Range of Refractive Index Detection 通过表面等离子体共振实现的宽带 D 形光子晶体光纤传感器,可用于不同分析物的大范围折射率检测
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-07-22 DOI: 10.1007/s11468-024-02425-y
Deyang Zhou, Fang Ren, Yidan Li, Yingjuan Ci, Jianping Wang

A D-shaped photonic crystal fiber (PCF) refractive index (RI) sensor based on surface plasmon resonance (SPR) is proposed. We used an open-ring channel coated with a gold film to excite the plasmonic modes. The coupling properties and sensing performance of this structure are analyzed using the finite element method. Different from the related D-shaped PCF refractive sensor, the sensing performance of different positions of analyte placement is investigated. Through simulation analysis by different positions of analyte placement, it is revealed different RI detection. When the analyte is distributed across the entire outer ring region, the sensor exhibits the RI detection range from 1.2 to 1.34. The sensor achieves a maximum spectral sensitivity of 2000 nm/RIU and a resolution of 2 × 10−3 RIU. When the analyte is confined exclusively to the upper aperture, the sensor’s RI detection range extends from 1.33 to 1.46. The simulated results show that the proposed sensor achieves a maximum spectral sensitivity of 5600 nm/RIU and a resolution of 8 × 10−4 RIU. Regardless of which of the two positions the analyte is placed, the proposed D-shaped photonic crystal fiber (D-PCF) sensor has a broad operating wavelength. The excellent sensing performance makes the proposed SPR sensor a competitive candidate in RI detection applications.

本文提出了一种基于表面等离子体共振(SPR)的 D 型光子晶体光纤(PCF)折射率(RI)传感器。我们使用涂有金膜的开环通道来激发等离子体模式。我们使用有限元法分析了这种结构的耦合特性和传感性能。与相关的 D 型 PCF 折射传感器不同的是,研究了不同分析物放置位置的传感性能。通过对不同分析物放置位置的仿真分析,发现了不同的 RI 检测结果。当分析物分布在整个外环区域时,传感器的 RI 检测范围为 1.2 至 1.34。传感器的最大光谱灵敏度为 2000 nm/RIU,分辨率为 2 × 10-3 RIU。当分析物完全被限制在上光圈时,传感器的 RI 检测范围从 1.33 扩展到 1.46。模拟结果表明,该传感器的最大光谱灵敏度为 5600 nm/RIU,分辨率为 8 × 10-4 RIU。无论分析物被放置在两个位置中的哪一个,拟议的 D 形光子晶体光纤(D-PCF)传感器都具有很宽的工作波长。出色的传感性能使所提出的 SPR 传感器在 RI 检测应用中具有很强的竞争力。
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引用次数: 0
Si3N4 Dielectric Hemi-sphere Arrayed Plasmonic Metasurface With Top Metal Coating for Multiresonant Absorption in NIR Regime 带顶层金属涂层的 Si3N4 介电半球阵列质子元表面,用于近红外波段的多共振吸收
IF 3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL Pub Date : 2024-07-20 DOI: 10.1007/s11468-024-02427-w
Prasanta Mandal

Present report focuses on the design and optical perfect absorption/reflection properties of novel plasmonic metasurface made of square array of Si3N4 hemi-spheres on flat Si3N4 surface. The whole structure is sandwiched between flat gold layer and top gold coating. Theoretical study using Finite Difference Time Domain (FDTD) computation shows multiple near perfect absorptions (80–100%) with narrow line width (~ 50 nm) between 550 to 1500 nm. Four distinct absorption peaks (or reflection dips) are observed at 1020 nm (A1), 888 nm (A2), 614 nm (A3), 740 nm (A4) which can be manipulated by varying structural parameters such as period, hemi-sphere diameter and top gold coating thickness. These multiple absorptions arise due to electric dipolar resonance, magnetic resonance, excitation of various surface plasmon modes (such as (1,0); (2,0); (1,1)) and cavity mode, as evident from near-field analysis. With appropriate structural parameters, multiband well resolved near perfect absorptions are achieved at desired wavelengths. The proposed metasurface is insensitive to the polarization of excitation beam, and has relatively large launch angle tolerance (~ 20°), making it suitable for optical and optoelectronic device integration.

本报告的重点是新型等离子体元表面的设计和完美的光学吸收/反射特性,该表面是在平坦的 Si3N4 表面上由 Si3N4 半球组成的方形阵列。整个结构夹在平面金层和顶层金涂层之间。使用有限差分时域(FDTD)计算方法进行的理论研究显示,在 550 至 1500 纳米之间有多个近乎完美的吸收(80%-100%),线宽较窄(约 50 纳米)。在 1020 nm (A1)、888 nm (A2)、614 nm (A3)、740 nm (A4) 处观察到四个不同的吸收峰(或反射凹点),可通过改变周期、半球直径和顶部金涂层厚度等结构参数来调节。从近场分析可以看出,这些多重吸收是由于电偶极共振、磁共振、各种表面等离子体模式(如 (1,0);(2,0);(1,1))和空腔模式的激发而产生的。通过适当的结构参数,可在所需波长实现多波段良好分辨的近乎完美的吸收。所提出的元表面对激发光束的偏振不敏感,并且具有相对较大的发射角公差(~ 20°),因此适合光学和光电器件集成。
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引用次数: 0
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