首页 > 最新文献

AIHAJ : a journal for the science of occupational and environmental health and safety最新文献

英文 中文
Emissions of chemical compounds and bioaerosols during the secondary treatment of paper mill effluents. 造纸厂废水二次处理过程中化合物和生物气溶胶的排放。
N. Goyer, J. Lavoie
This study identified and quantified the main chemical compounds--the substances responsible for the disagreeable odors--and the bioaerosols emitted during the biological treatment of paper mill effluents. It also identified the characteristics of the process that effects the generation or diffusion of these substances. All treatment stages were evaluated. Measuring sites were located as closely as possible to the potential emission sources. Measurements were taken in the summer in 11 paper mills during a 2- to 3-day period in each mill. Chemical compounds were evaluated by direct-reading instruments; bioaerosols were sampled by impaction and counted. Sulfur compounds, emitted into the air when the effluent or the sludge is stirred, had the highest concentrations; their presence was attributable to such things as kraft-type paper pulp. Next in concentration were the carbon and nitrogen oxides, ammonia, and some organic acids, produced by the action of microorganisms. These acids are found mainly in the sludge environment. Terpenes, which come from wood, are present at various locations in paper mills. Odor perception thresholds for most of these substances are much lower than those established to protect the health of workers. Significant concentrations of total bacteria, total molds, and endotoxins were measured at several sites. Gram-negative bacteria were high at only one site, whereas the mold Aspergillus fumigatus was occasionally present at low concentration. No actinomycetes bacteria were detected. The highest concentrations were measured where there was water or dust aerosolization. Emissions are therefore controlled by controlling the operations that lead to the dispersion of water and particles into the air.
这项研究确定并量化了造纸厂废水在生物处理过程中排放的主要化合物(产生难闻气味的物质)和生物气溶胶。它还确定了影响这些物质产生或扩散的过程的特征。对所有治疗阶段进行评估。测量地点尽可能靠近潜在的排放源。夏季在11家造纸厂进行了2- 3天的测量。用直读仪对化合物进行评价;生物气溶胶通过撞击取样并计数。当污水或污泥被搅拌时,排放到空气中的硫化合物浓度最高;它们的存在可归因于诸如牛皮纸型纸浆之类的东西。其次是由微生物作用产生的碳氧化物、氮氧化物、氨和一些有机酸。这些酸主要存在于污泥环境中。来自木材的萜烯存在于造纸厂的各个位置。大多数这些物质的气味感知阈值远低于为保护工人健康而制定的阈值。在几个地点测量了总细菌,总霉菌和内毒素的显著浓度。革兰氏阴性菌仅在一个位点高,而霉菌烟曲霉偶有低浓度存在。未检出放线菌及细菌。在有水或灰尘雾化的地方测量了最高浓度。因此,通过控制导致水和颗粒扩散到空气中的操作来控制排放。
{"title":"Emissions of chemical compounds and bioaerosols during the secondary treatment of paper mill effluents.","authors":"N. Goyer, J. Lavoie","doi":"10.1080/15298660108984635","DOIUrl":"https://doi.org/10.1080/15298660108984635","url":null,"abstract":"This study identified and quantified the main chemical compounds--the substances responsible for the disagreeable odors--and the bioaerosols emitted during the biological treatment of paper mill effluents. It also identified the characteristics of the process that effects the generation or diffusion of these substances. All treatment stages were evaluated. Measuring sites were located as closely as possible to the potential emission sources. Measurements were taken in the summer in 11 paper mills during a 2- to 3-day period in each mill. Chemical compounds were evaluated by direct-reading instruments; bioaerosols were sampled by impaction and counted. Sulfur compounds, emitted into the air when the effluent or the sludge is stirred, had the highest concentrations; their presence was attributable to such things as kraft-type paper pulp. Next in concentration were the carbon and nitrogen oxides, ammonia, and some organic acids, produced by the action of microorganisms. These acids are found mainly in the sludge environment. Terpenes, which come from wood, are present at various locations in paper mills. Odor perception thresholds for most of these substances are much lower than those established to protect the health of workers. Significant concentrations of total bacteria, total molds, and endotoxins were measured at several sites. Gram-negative bacteria were high at only one site, whereas the mold Aspergillus fumigatus was occasionally present at low concentration. No actinomycetes bacteria were detected. The highest concentrations were measured where there was water or dust aerosolization. Emissions are therefore controlled by controlling the operations that lead to the dispersion of water and particles into the air.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83721107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 17
Computer simulation of particle overlap in fiber count samples. 纤维计数样品中粒子重叠的计算机模拟。
C. C. Chen, T. Yu, T. Shih, P. Baron
Fibrous aerosols are of great importance to industrial hygienists because of the severe health risks that may be associated with inhaling such particles. Previous studies on measurement error due to overloading of fibers and nonfibrous particles on the collected sample indicate that a 100-1300 fiber/mm2 filter area is the best filter loading density to reduce bias in fiber counts. The present study investigated the upper fiber and particle concentration limits for reliable counting and identification and the possibility of a procedure for correcting observed fiber counts to account for fiber masking due to overlapping particles or fibers. A computer-generated grid was used to simulate the light microscope graticule field. The resolution of 2000 x 2000 was found to accurately represent the shape of the fibers and nonfibrous particles. Bivariate lognormal distributions were used to describe the length and width distributions of the fibers. The capability of distinguishing particle-overlapped fibers (defined as the resolution index), the coverage of the graticule field, the filter surface loading density, size distributions of fibers and particles, and the fiber-to-particle concentration ratio were the primary parameters in this study. The counting efficiency was found to consistently decrease with increasing filter surface loading density and decreasing resolution index. The recommended upper limit of filter surface fiber density depended not only on the number concentration ratio but also on the filter surface loading densities and size distributions of fibers and particles. The advantage of using a thoracic preseparator on counting efficiency was calculated and found to improve counting efficiency significantly when the count median diameter of nonfibrous particles was close to or larger than the thoracic 50% cutoff point of 10 microm.
纤维状气溶胶对工业卫生学家来说非常重要,因为吸入这种颗粒可能带来严重的健康风险。先前关于纤维和非纤维颗粒在采集样品上过载引起的测量误差的研究表明,100-1300纤维/mm2的过滤面积是减少纤维计数偏差的最佳过滤器负载密度。本研究调查了可靠计数和鉴定的纤维和颗粒浓度上限,以及校正观察到的纤维计数以解释由于重叠颗粒或纤维造成的纤维掩蔽的程序的可能性。利用计算机生成的网格模拟光学显微镜的光栅场。发现2000 × 2000的分辨率可以准确地表示纤维和非纤维颗粒的形状。双变量对数正态分布用于描述纤维的长度和宽度分布。区分颗粒重叠纤维的能力(定义为分辨率指数)、光栅场的覆盖率、过滤器表面负载密度、纤维和颗粒的尺寸分布以及纤维与颗粒的浓度比是本研究的主要参数。计数效率随着过滤器表面负载密度的增加和分辨率指数的降低而不断降低。建议的过滤器表面纤维密度上限不仅取决于数浓度比,还取决于过滤器表面负载密度、纤维和颗粒的尺寸分布。计算了胸廓预分离器在计数效率上的优势,发现当非纤维颗粒的计数中位数直径接近或大于胸廓50%截止点10微米时,计数效率显著提高。
{"title":"Computer simulation of particle overlap in fiber count samples.","authors":"C. C. Chen, T. Yu, T. Shih, P. Baron","doi":"10.1080/15298660108984629","DOIUrl":"https://doi.org/10.1080/15298660108984629","url":null,"abstract":"Fibrous aerosols are of great importance to industrial hygienists because of the severe health risks that may be associated with inhaling such particles. Previous studies on measurement error due to overloading of fibers and nonfibrous particles on the collected sample indicate that a 100-1300 fiber/mm2 filter area is the best filter loading density to reduce bias in fiber counts. The present study investigated the upper fiber and particle concentration limits for reliable counting and identification and the possibility of a procedure for correcting observed fiber counts to account for fiber masking due to overlapping particles or fibers. A computer-generated grid was used to simulate the light microscope graticule field. The resolution of 2000 x 2000 was found to accurately represent the shape of the fibers and nonfibrous particles. Bivariate lognormal distributions were used to describe the length and width distributions of the fibers. The capability of distinguishing particle-overlapped fibers (defined as the resolution index), the coverage of the graticule field, the filter surface loading density, size distributions of fibers and particles, and the fiber-to-particle concentration ratio were the primary parameters in this study. The counting efficiency was found to consistently decrease with increasing filter surface loading density and decreasing resolution index. The recommended upper limit of filter surface fiber density depended not only on the number concentration ratio but also on the filter surface loading densities and size distributions of fibers and particles. The advantage of using a thoracic preseparator on counting efficiency was calculated and found to improve counting efficiency significantly when the count median diameter of nonfibrous particles was close to or larger than the thoracic 50% cutoff point of 10 microm.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90316577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Metalworking fluid exposures in small machine shops: an overview. 小型机械车间金属加工液暴露:概述。
G. Piacitelli, W. Sieber, D. O'brien, R. Hughes, R. Glaser, J. Catalano
Sampling was conducted in 79 small machine shops to assess airborne exposures to metalworking fluids (MWFs). Measured exposures were compared with data from the literature and exposure criteria currently recommended by the National Institute for Occupational Safety and Health and the Occupational Safety and Health Administration MWF Standards Advisory Committee. Sixty-two percent of 942 personal samples collected were less than the recommended exposure limit (REL) of 0.50 mg/m3 for total particulate. However, at least 1 sample exceeded the REL in 61 of the 79 facilities studied; 100% of the samples collected in 10 shops were greater than the REL. Similar trends were found for thoracic particulate exposures where 75% of 238 samples were below the thoracic particulate REL of 0.40 mg/m3. The ratio between thoracic and total particulate for 238 paired samples was 0.55 (r2=0.73). Workers exposed to straight fluids had the highest exposures (GM=0.67 mg/m3) when compared with workers exposed to other classes of MWFs. The highest exposures were measured for grinding and hobbing (GM=0.67 and 0.60 mg/m3, respectively). Measurements using personal impactors indicated that particle size distributions of MWF aerosols had an average mass median aerodynamic diameter of 5.3 microm. Straight oils and soluble fluids tended to be associated with larger particles than were other fluid types; grinding and turning produced the largest particles, whereas hobbing resulted in the smallest. In general, exposures were similar in magnitude and particle size to those previously reported in large automotive plants. Therefore, workers in these small shops may have risks of adverse health effects similar to those demonstrated in the automotive industry.
在79个小型机械车间进行了抽样,以评估空气中接触金属加工液的情况。测量的暴露量与文献数据以及国家职业安全与健康研究所和职业安全与健康管理局MWF标准咨询委员会目前推荐的暴露标准进行了比较。在收集的942个个人样本中,62%的样本低于总颗粒物0.50 mg/m3的建议暴露限值(REL)。然而,在所研究的79个设施中,有61个至少有1个样本超过了REL;在10家商店收集的样本中,100%的样本高于REL。在238个样本中,75%的样本低于0.40 mg/m3的胸部颗粒REL,也发现了类似的趋势。238对样本胸廓颗粒物与总颗粒物之比为0.55 (r2=0.73)。与接触其他种类MWFs的工人相比,接触直液的工人接触量最高(GM=0.67 mg/m3)。磨削和滚齿的暴露量最高(GM分别=0.67和0.60 mg/m3)。使用个人撞击器进行的测量表明,MWF气溶胶的粒径分布平均质量中值气动直径为5.3微米。直油和可溶性流体往往比其他类型的流体具有更大的颗粒;磨削和车削产生的颗粒最大,而滚刀产生的颗粒最小。总的来说,暴露的程度和颗粒大小与以前在大型汽车工厂报道的相似。因此,这些小商店的工人可能面临与汽车工业类似的不利健康影响风险。
{"title":"Metalworking fluid exposures in small machine shops: an overview.","authors":"G. Piacitelli, W. Sieber, D. O'brien, R. Hughes, R. Glaser, J. Catalano","doi":"10.1080/15298660108984638","DOIUrl":"https://doi.org/10.1080/15298660108984638","url":null,"abstract":"Sampling was conducted in 79 small machine shops to assess airborne exposures to metalworking fluids (MWFs). Measured exposures were compared with data from the literature and exposure criteria currently recommended by the National Institute for Occupational Safety and Health and the Occupational Safety and Health Administration MWF Standards Advisory Committee. Sixty-two percent of 942 personal samples collected were less than the recommended exposure limit (REL) of 0.50 mg/m3 for total particulate. However, at least 1 sample exceeded the REL in 61 of the 79 facilities studied; 100% of the samples collected in 10 shops were greater than the REL. Similar trends were found for thoracic particulate exposures where 75% of 238 samples were below the thoracic particulate REL of 0.40 mg/m3. The ratio between thoracic and total particulate for 238 paired samples was 0.55 (r2=0.73). Workers exposed to straight fluids had the highest exposures (GM=0.67 mg/m3) when compared with workers exposed to other classes of MWFs. The highest exposures were measured for grinding and hobbing (GM=0.67 and 0.60 mg/m3, respectively). Measurements using personal impactors indicated that particle size distributions of MWF aerosols had an average mass median aerodynamic diameter of 5.3 microm. Straight oils and soluble fluids tended to be associated with larger particles than were other fluid types; grinding and turning produced the largest particles, whereas hobbing resulted in the smallest. In general, exposures were similar in magnitude and particle size to those previously reported in large automotive plants. Therefore, workers in these small shops may have risks of adverse health effects similar to those demonstrated in the automotive industry.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80037677","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 52
Evaluation of the effectiveness of following up laboratory reports of elevated blood leads in adults. 成人血铅升高实验室报告随访效果评价。
K. Rosenman, A. Sims, A. Hogan, J. Fiałkowski, J. Gardiner
The usefulness of a statewide laboratory-based blood lead surveillance system to initiate workplace enforcement inspections was studied. In particular, the effectiveness of inspection of companies in which at least one worker had a blood lead level (BLL) 30-39 microg/dL but no greater than 39 microg/dL was considered. The surveillance system identified all individuals who had been tested for blood lead. Adults with BLLs > or =30 microg/dL were interviewed. Companies where lead exposures occurred were identified and enforcement inspections performed there. Companies were grouped into four categories: one or more employees with BLL > or =50 microg/dL; one or more employees with highest BLL of 40-49 microg/dL; one or more employees with highest BLL of 30-39 microg/dL; and companies that used lead but from which no blood lead reports were received. The number of citations and amounts of penalties, and BLLs before and after, were compared among the three blood lead groups and with a control group of no lead-using companies. A cost-benefit analysis was performed. Citations and penalties did not differ among the three blood lead groups but were markedly increased compared with the lead using but no blood lead group. Violations of specific lead standard components were similar among the three blood lead groups. Blood lead companies had increased citations and penalties as compared with nonusing lead control companies. No significant decrease in blood leads was seen postinspection. Total cost to identify lead-exposed workers at problem work sites was $125 ($53-$459) per lead-exposed worker. Followup of companies identified through the surveillance system was an effective method to target workplace inspections. It is recommended that routine inspection be instituted for all companies in which an employee is reported to have a blood lead of 30 microg/dL or greater.
研究了全州以实验室为基础的血铅监测系统启动工作场所执法检查的有效性。特别是,对至少有一名员工血铅水平(BLL)在30 ~ 39微克/分升,但不超过39微克/分升的企业进行检查的有效性进行了考虑。监测系统确定了所有接受血铅检测的个人。对bll >或=30微克/分升的成年人进行了访谈。查明了发生铅暴露的公司,并在那里进行了执法检查。公司分为四类:一名或多名员工的BLL >或=50微克/分升;一名或多名BLL最高达40-49微克/分升的员工;一名或多名员工BLL最高为30-39微克/分升;以及使用铅但没有收到血铅报告的公司。在三个血铅组和一个不使用铅的公司的对照组之间,比较了被引用的次数和罚款金额,以及前后的bll。进行了成本效益分析。引用和处罚在三个血铅组之间没有差异,但与使用铅但没有血铅的组相比显着增加。在三个血铅组中,违反特定铅标准成分的情况相似。与不使用铅控制的公司相比,血铅公司的引用和处罚增加了。检查后血铅未见明显下降。在问题工作场所确定铅暴露工人的总成本为每位铅暴露工人125美元(53- 459美元)。对通过监测系统确定的公司进行跟踪是针对工作场所检查的有效方法。建议对所有报告员工血铅大于或等于30微克/分升的公司进行例行检查。
{"title":"Evaluation of the effectiveness of following up laboratory reports of elevated blood leads in adults.","authors":"K. Rosenman, A. Sims, A. Hogan, J. Fiałkowski, J. Gardiner","doi":"10.1080/15298660108984639","DOIUrl":"https://doi.org/10.1080/15298660108984639","url":null,"abstract":"The usefulness of a statewide laboratory-based blood lead surveillance system to initiate workplace enforcement inspections was studied. In particular, the effectiveness of inspection of companies in which at least one worker had a blood lead level (BLL) 30-39 microg/dL but no greater than 39 microg/dL was considered. The surveillance system identified all individuals who had been tested for blood lead. Adults with BLLs > or =30 microg/dL were interviewed. Companies where lead exposures occurred were identified and enforcement inspections performed there. Companies were grouped into four categories: one or more employees with BLL > or =50 microg/dL; one or more employees with highest BLL of 40-49 microg/dL; one or more employees with highest BLL of 30-39 microg/dL; and companies that used lead but from which no blood lead reports were received. The number of citations and amounts of penalties, and BLLs before and after, were compared among the three blood lead groups and with a control group of no lead-using companies. A cost-benefit analysis was performed. Citations and penalties did not differ among the three blood lead groups but were markedly increased compared with the lead using but no blood lead group. Violations of specific lead standard components were similar among the three blood lead groups. Blood lead companies had increased citations and penalties as compared with nonusing lead control companies. No significant decrease in blood leads was seen postinspection. Total cost to identify lead-exposed workers at problem work sites was $125 ($53-$459) per lead-exposed worker. Followup of companies identified through the surveillance system was an effective method to target workplace inspections. It is recommended that routine inspection be instituted for all companies in which an employee is reported to have a blood lead of 30 microg/dL or greater.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77415630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
Development of an integrated microanalytical system for analysis of lead in saliva and linkage to a physiologically based pharmacokinetic model describing lead saliva secretion. 开发用于分析唾液中铅的集成微量分析系统,并与描述唾液中铅分泌的基于生理学的药代动力学模型相联系。
C. Timchalk, T. Poet, Y. Lin, K. Weitz, R. Zhao, K. Thrall
There is a need to develop reliable portable analytical systems for biomonitoring lead (Pb) in noninvasively collected saliva samples. In addition, appropriate pharmacokinetic analyses are used to quantitate systemic dosimetry based on the saliva Pb concentrations. A portable microfluidics/electrochemical device was developed for the rapid analysis of Pb based on square wave anodic stripping voltammetry, in which a saliva sample flows over an electrode surface, Pb2+ is chemically reduced and accumulated, and the electric potential of the electrode scanned. The system demonstrates a good linear response over a broad Pb concentration range (1-2000 ppb). To evaluate the relationship between saliva and blood Pb, rats were treated with single oral doses ranging from 20 to 500 mg Pb/kg of body weight, and 24 hours later were administered pilocarpine, a muscarinic agonist to induce salivation. To correlate saliva levels with internal dose, blood and saliva were collected and quantitated for Pb by inductively coupled plasma-mass spectrometry (ICP-MS) and by the microanalytical system. The quantitation with the microanalytical system was slightly less (approximately 75-85%) than with ICP-MS; however, the response was linear, with concentration suggesting that it can be used for the quantitation of salivary Pb. To facilitate modeling, a physiologically based pharmacokinetic (PBPK) model for Pb was modified to incorporate a salivary gland compartment. The model was capable of predicting blood and saliva Pb concentration based on a limited data set. These results are encouraging, suggesting that once fully developed the microanalytical system coupled with PBPK modeling can be used as important tools for real-time biomonitoring of Pb for both occupational and environmental exposures.
需要开发可靠的便携式分析系统,用于无创采集唾液样本中的铅(Pb)生物监测。此外,适当的药代动力学分析被用于定量基于唾液铅浓度的全身剂量学。研制了一种基于方波阳极溶出伏安法的便携式微流体/电化学装置,用于快速分析铅。该装置采用唾液样品在电极表面流动,化学还原和积累Pb2+,并扫描电极的电势。该系统在较宽的铅浓度范围内(1-2000 ppb)表现出良好的线性响应。为了评估唾液和血铅之间的关系,我们给大鼠单次口服20 ~ 500 mg Pb/kg体重,24小时后给药一种毒菌碱激动剂匹罗卡平诱导唾液分泌。为了将唾液水平与内剂量联系起来,收集血液和唾液,并通过电感耦合等离子体质谱(ICP-MS)和微量分析系统定量测定铅。微量分析系统的定量略低于ICP-MS(约75-85%);结果表明,该方法可用于唾液中铅的定量分析。为了便于建模,对基于生理的铅药代动力学(PBPK)模型进行了修改,加入了唾液腺腔室。该模型能够基于有限的数据集预测血液和唾液中的铅浓度。这些结果是令人鼓舞的,表明一旦充分开发了结合PBPK建模的微量分析系统,可以作为实时生物监测Pb职业和环境暴露的重要工具。
{"title":"Development of an integrated microanalytical system for analysis of lead in saliva and linkage to a physiologically based pharmacokinetic model describing lead saliva secretion.","authors":"C. Timchalk, T. Poet, Y. Lin, K. Weitz, R. Zhao, K. Thrall","doi":"10.1080/15298660108984631","DOIUrl":"https://doi.org/10.1080/15298660108984631","url":null,"abstract":"There is a need to develop reliable portable analytical systems for biomonitoring lead (Pb) in noninvasively collected saliva samples. In addition, appropriate pharmacokinetic analyses are used to quantitate systemic dosimetry based on the saliva Pb concentrations. A portable microfluidics/electrochemical device was developed for the rapid analysis of Pb based on square wave anodic stripping voltammetry, in which a saliva sample flows over an electrode surface, Pb2+ is chemically reduced and accumulated, and the electric potential of the electrode scanned. The system demonstrates a good linear response over a broad Pb concentration range (1-2000 ppb). To evaluate the relationship between saliva and blood Pb, rats were treated with single oral doses ranging from 20 to 500 mg Pb/kg of body weight, and 24 hours later were administered pilocarpine, a muscarinic agonist to induce salivation. To correlate saliva levels with internal dose, blood and saliva were collected and quantitated for Pb by inductively coupled plasma-mass spectrometry (ICP-MS) and by the microanalytical system. The quantitation with the microanalytical system was slightly less (approximately 75-85%) than with ICP-MS; however, the response was linear, with concentration suggesting that it can be used for the quantitation of salivary Pb. To facilitate modeling, a physiologically based pharmacokinetic (PBPK) model for Pb was modified to incorporate a salivary gland compartment. The model was capable of predicting blood and saliva Pb concentration based on a limited data set. These results are encouraging, suggesting that once fully developed the microanalytical system coupled with PBPK modeling can be used as important tools for real-time biomonitoring of Pb for both occupational and environmental exposures.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83080369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 24
Pressure drop and service life predictions for respirator canisters. 呼吸器罐的压降和使用寿命预测。
N. M. Osmond, P. Phillips
Respirator canister designers and manufacturers have a responsibility to provide canisters with increasingly higher capacity and longer service life due to rising safety standards in the workplace. Optimizing the service life of conventional canisters is not about simply increasing the depth of adsorbent present in the canister because this will lead to an increased resistance to airflow, and a greater physiological burden on the user. To optimize canister design it is necessary to establish how the physical dimensions of the adsorbent bed affect breathing resistance and adsorption performance. The study presented in this article investigated both the pressure drop and cyanogen chloride chemisorption performance of a granular activated carbon adsorbent. Results obtained show relationships that correlate adsorption performance and pressure drop to the quantity of adsorbent, the linear flow velocity, and, where applicable, the challenge vapor concentration. Altering the linear velocity by increasing cross-sectional surface area has a more beneficial impact on canister performance than altering the adsorbent bed depth. The application of these relationships to the design of canisters is demonstrated.
由于工作场所的安全标准不断提高,呼吸器的设计者和制造商有责任提供容量越来越大、使用寿命越来越长的呼吸器。优化传统罐体的使用寿命并不是简单地增加罐体中吸附剂的深度,因为这将导致气流阻力增加,并且对用户造成更大的生理负担。为了优化吸附罐设计,有必要确定吸附床的物理尺寸如何影响呼吸阻力和吸附性能。本文研究了颗粒活性炭吸附剂的压降和氯氰化学吸附性能。得到的结果表明,吸附性能和压降与吸附剂的数量、线性流速以及(在适用的情况下)挑战蒸汽浓度有关。通过增加截面积来改变线速度比改变吸附剂床层深度对筒体性能的影响更有利。证明了这些关系在罐体设计中的应用。
{"title":"Pressure drop and service life predictions for respirator canisters.","authors":"N. M. Osmond, P. Phillips","doi":"10.1080/15298660108984630","DOIUrl":"https://doi.org/10.1080/15298660108984630","url":null,"abstract":"Respirator canister designers and manufacturers have a responsibility to provide canisters with increasingly higher capacity and longer service life due to rising safety standards in the workplace. Optimizing the service life of conventional canisters is not about simply increasing the depth of adsorbent present in the canister because this will lead to an increased resistance to airflow, and a greater physiological burden on the user. To optimize canister design it is necessary to establish how the physical dimensions of the adsorbent bed affect breathing resistance and adsorption performance. The study presented in this article investigated both the pressure drop and cyanogen chloride chemisorption performance of a granular activated carbon adsorbent. Results obtained show relationships that correlate adsorption performance and pressure drop to the quantity of adsorbent, the linear flow velocity, and, where applicable, the challenge vapor concentration. Altering the linear velocity by increasing cross-sectional surface area has a more beneficial impact on canister performance than altering the adsorbent bed depth. The application of these relationships to the design of canisters is demonstrated.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77161135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
Test methods for evaluating the filtration and particulate emission characteristics of vacuum cleaners. 评价真空吸尘器的过滤和微粒排放特性的试验方法。
K. Willeke, S. Trakumas, S. Grinshpun, T. Reponen, M. Trunov, W. Friedman
The overall filtration efficiency of a vacuum cleaner traditionally has been tested by placing the vacuum cleaner in a test chamber and measuring aerosol concentrations at the chamber inlet and outlet. The chamber test method was refined and validated in this study. However, this chamber test method shows an overall filtration efficiency of close to 100% for most of the industrial vacuum cleaners and for most of the newly developed household vacuum cleaners of midprice range or higher because all these vacuum cleaners have a high-efficiency particulate air (HEPA) or other highly efficient filter installed at the exhaust. A new test method was therefore developed through which the vacuum cleaner was probed in various internal locations so that the collection efficiency of the individual components could be determined. For example, the aerosol concentration upstream of the final HEPA filter can thus be measured, which permits one to estimate the life expectancy of this expensive component. The probed testing method is particularly suitable for field evaluations of vacuum cleaners because it uses compact, battery-operated optical particle size spectrometers with internal data storage. Both chamber and probed tests gave the same results for the aerosol filtration efficiency. The probed testing method, however, also gives information on the performance of the individual components in a vacuum cleaner. It also can be used to determine the dust pickup efficiency and the degree of reaerosolization of particles collected in the vacuum cleaner.
传统上,真空吸尘器的整体过滤效率是通过将真空吸尘器放在测试室中并测量室入口和出口的气溶胶浓度来测试的。本研究对试验方法进行了改进和验证。然而,这种室内测试方法显示,对于大多数工业吸尘器和大多数新开发的中等或更高价格的家用吸尘器,总体过滤效率接近100%,因为所有这些吸尘器都在排气处安装了高效微粒空气(HEPA)或其他高效过滤器。因此,开发了一种新的测试方法,通过在不同的内部位置探测真空吸尘器,以便确定单个组件的收集效率。例如,可以测量最终HEPA过滤器上游的气溶胶浓度,从而可以估计这种昂贵组件的预期寿命。探针测试方法特别适用于真空吸尘器的现场评估,因为它使用紧凑的,电池供电的光学粒度光谱仪与内部数据存储。对于气溶胶过滤效率,腔室试验和探针试验给出了相同的结果。然而,探针测试方法也提供了真空吸尘器中各个部件性能的信息。它还可以用来确定吸尘效率和收集在吸尘器中的颗粒的再雾化程度。
{"title":"Test methods for evaluating the filtration and particulate emission characteristics of vacuum cleaners.","authors":"K. Willeke, S. Trakumas, S. Grinshpun, T. Reponen, M. Trunov, W. Friedman","doi":"10.1080/15298660108984633","DOIUrl":"https://doi.org/10.1080/15298660108984633","url":null,"abstract":"The overall filtration efficiency of a vacuum cleaner traditionally has been tested by placing the vacuum cleaner in a test chamber and measuring aerosol concentrations at the chamber inlet and outlet. The chamber test method was refined and validated in this study. However, this chamber test method shows an overall filtration efficiency of close to 100% for most of the industrial vacuum cleaners and for most of the newly developed household vacuum cleaners of midprice range or higher because all these vacuum cleaners have a high-efficiency particulate air (HEPA) or other highly efficient filter installed at the exhaust. A new test method was therefore developed through which the vacuum cleaner was probed in various internal locations so that the collection efficiency of the individual components could be determined. For example, the aerosol concentration upstream of the final HEPA filter can thus be measured, which permits one to estimate the life expectancy of this expensive component. The probed testing method is particularly suitable for field evaluations of vacuum cleaners because it uses compact, battery-operated optical particle size spectrometers with internal data storage. Both chamber and probed tests gave the same results for the aerosol filtration efficiency. The probed testing method, however, also gives information on the performance of the individual components in a vacuum cleaner. It also can be used to determine the dust pickup efficiency and the degree of reaerosolization of particles collected in the vacuum cleaner.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76838704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
Inhalable dust exposures, tasks, and use of ventilation in small woodworking shops: a pilot study. 小型木工车间的可吸入粉尘暴露、任务和通风使用:一项试点研究。
L. Brosseau, D. Parker, D. Lazovich, S. Dugan, T. Milton, W. Pan
Measures of workers' inhalable dust exposures, tasks, and ventilation use were made in five small woodworking shops prior to the start of an intervention effectiveness study aimed at lowering personal wood dust exposures. The data were used to (1) design a sampling protocol for an intervention success measure, (2) identify targets for intervention among the tasks and activities responsible for high dust levels, and (3) develop shop-level measures as tools for tailoring intervention activities. Geometric mean dust concentrations ranged from 1.6 to 9.9 mg/m3 in the five shops, with the highest levels occurring in a cabinet shop. All shops had centralized dust collection systems and workers generally used dust control on stationary tools (60-100% of the time) when it was available. Sanding with both stationary and handheld powered tools, cleaning with methods that can disperse dust (e.g., brushes, compressed air), and miscellaneous tasks were all responsible for significant personal exposures. The positive association between miscellaneous tasks and exposures probably reflects the high background levels generated by nearby processes. Sanding with both stationary tools and handheld powered tools represents the most significant influence on personal exposures in small woodworking shops. The authors conclude that pilot studies are useful tools for designing occupational health and safety intervention effectiveness studies.
在开始一项旨在降低个人木尘暴露的干预有效性研究之前,在五个小型木工车间对工人的可吸入粉尘暴露、任务和通风使用进行了测量。这些数据用于(1)设计干预成功措施的抽样方案,(2)在造成高粉尘水平的任务和活动中确定干预目标,以及(3)制定车间级措施,作为定制干预活动的工具。五个车间的几何平均粉尘浓度在1.6 - 9.9 mg/m3之间,橱柜车间的浓度最高。所有车间都有集中的集尘系统,工人通常在固定工具可用时(60-100%的时间)对其进行除尘。使用固定式和手持式电动工具进行打磨,使用可以分散灰尘的方法进行清洁(例如,刷子,压缩空气),以及其他任务都是造成重大个人暴露的原因。杂项任务和暴露之间的积极联系可能反映了附近过程产生的高背景水平。在小型木工车间,用固定工具和手持式电动工具打磨对个人暴露的影响最大。作者得出结论,试点研究是设计职业健康与安全干预有效性研究的有用工具。
{"title":"Inhalable dust exposures, tasks, and use of ventilation in small woodworking shops: a pilot study.","authors":"L. Brosseau, D. Parker, D. Lazovich, S. Dugan, T. Milton, W. Pan","doi":"10.1080/15298660108984634","DOIUrl":"https://doi.org/10.1080/15298660108984634","url":null,"abstract":"Measures of workers' inhalable dust exposures, tasks, and ventilation use were made in five small woodworking shops prior to the start of an intervention effectiveness study aimed at lowering personal wood dust exposures. The data were used to (1) design a sampling protocol for an intervention success measure, (2) identify targets for intervention among the tasks and activities responsible for high dust levels, and (3) develop shop-level measures as tools for tailoring intervention activities. Geometric mean dust concentrations ranged from 1.6 to 9.9 mg/m3 in the five shops, with the highest levels occurring in a cabinet shop. All shops had centralized dust collection systems and workers generally used dust control on stationary tools (60-100% of the time) when it was available. Sanding with both stationary and handheld powered tools, cleaning with methods that can disperse dust (e.g., brushes, compressed air), and miscellaneous tasks were all responsible for significant personal exposures. The positive association between miscellaneous tasks and exposures probably reflects the high background levels generated by nearby processes. Sanding with both stationary tools and handheld powered tools represents the most significant influence on personal exposures in small woodworking shops. The authors conclude that pilot studies are useful tools for designing occupational health and safety intervention effectiveness studies.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78727438","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 18
An evaluation of short-term exposures to metalworking fluids in small machine shops. 小型机械车间短期接触金属加工液的评估。
D. O'brien, G. Piacitelli, W. Sieber, R. Hughes, J. Catalano
In a study of 23 small machining shops using metalworking fluids (MWFs), real-time air monitoring using an aerosol photometer was performed to investigate the temporal nature of the exposure and to examine the relationship between the instrumental measurements and traditional sampling methods. Time-weighted averages were calculated from the aerosol photometer data and the results were compared to collocated thoracic and 37-mm closed face cassette samplers. The filter samples were analyzed for total mass and the solvent extractable fraction. Depending on the averaging period used, short-term MWF concentrations exceeded 2.0 mg/m3 in 13 to 39% of the plants studied. High short-term exposures were as likely to be found in plants with average concentrations below 0.4 mg/m3 (thoracic-gravimetric) as those above. Regression analyses indicated that the aerosol photometer most closely matched the data obtained from the thoracic fraction of the total mass. In general, the aerosol photometer overestimated the levels determined using the thoracic cyclone and filter, especially when measuring concentrations of water-based fluids. Use of a calibration factor of 0.7 for straight oils or 0.5 for water-based fluids may assist in the interpretation of aerosol photometer measurements if field calibration data are not readily available. Several approaches to determining the calibration factor from field data were evaluated; more complex calibration techniques improved the accuracy of the measurements.
在对23个使用金属加工液的小型机加工车间进行的一项研究中,使用气溶胶光度计进行了实时空气监测,以调查接触的时间性质,并检查仪器测量与传统采样方法之间的关系。根据气溶胶光度计数据计算时间加权平均值,并将结果与配置的胸椎和37-mm闭式盒式采样器进行比较。对过滤样品的总质量和溶剂可萃取率进行了分析。根据所使用的平均时间,所研究的植物中有13%至39%的短期MWF浓度超过2.0 mg/m3。在平均浓度低于0.4 mg/m3(胸重)的植物中,短期高暴露的可能性与上述植物一样高。回归分析表明,气溶胶光度计与从总质量的胸廓部分获得的数据最接近。总的来说,气溶胶光度计高估了使用胸廓旋风和过滤器确定的水平,特别是在测量水基流体的浓度时。如果现场校准数据不容易获得,对直油使用0.7或对水基流体使用0.5的校准系数可能有助于解释气溶胶光度计的测量结果。评估了几种从现场数据确定校准因子的方法;更复杂的校准技术提高了测量的准确性。
{"title":"An evaluation of short-term exposures to metalworking fluids in small machine shops.","authors":"D. O'brien, G. Piacitelli, W. Sieber, R. Hughes, J. Catalano","doi":"10.1080/15298660108984636","DOIUrl":"https://doi.org/10.1080/15298660108984636","url":null,"abstract":"In a study of 23 small machining shops using metalworking fluids (MWFs), real-time air monitoring using an aerosol photometer was performed to investigate the temporal nature of the exposure and to examine the relationship between the instrumental measurements and traditional sampling methods. Time-weighted averages were calculated from the aerosol photometer data and the results were compared to collocated thoracic and 37-mm closed face cassette samplers. The filter samples were analyzed for total mass and the solvent extractable fraction. Depending on the averaging period used, short-term MWF concentrations exceeded 2.0 mg/m3 in 13 to 39% of the plants studied. High short-term exposures were as likely to be found in plants with average concentrations below 0.4 mg/m3 (thoracic-gravimetric) as those above. Regression analyses indicated that the aerosol photometer most closely matched the data obtained from the thoracic fraction of the total mass. In general, the aerosol photometer overestimated the levels determined using the thoracic cyclone and filter, especially when measuring concentrations of water-based fluids. Use of a calibration factor of 0.7 for straight oils or 0.5 for water-based fluids may assist in the interpretation of aerosol photometer measurements if field calibration data are not readily available. Several approaches to determining the calibration factor from field data were evaluated; more complex calibration techniques improved the accuracy of the measurements.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77408134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 17
Characterization of metalworking fluid aerosols in bearing grinding operations. 轴承磨削作业中金属加工流体气溶胶的表征。
F. Rosenthal, B. L. Yeagy
The concentrations and size distribution of metalworking fluid aerosols were investigated in grinding operations in the bearing manufacturing industry. Fifteen paired open- and closed-face cassette samples and five cascade impactor samples were obtained in each of three types of grinding machinery (face, microcentric, and progressive). Aerosol mass concentration as measured by open-face filter sampling ranged from 0.34 to 2.43 mg/m3. As measured by closed-face sampling the range was 0.14 to 2.01 mg/m3. For each grinding process, open-face concentration was significantly higher than the closed-face concentration (paired t-test, p <0.05). Mass median aerodynamic diameter (MMAD) ranged from 3.33 to 6.26 microm. The percentage of mass greater than 9 microm ranged from 8.0 to 45.3. The MMAD and fraction greater than 9 microm were significantly greater for the aerosol produced by the face grinder compared with the other two processes. The results indicate that (1) closed-face sampling results in a lower aerosol mass concentration, as compared with open-face sampling, with the degree of difference being somewhat dependent on grinding process; and (2) the particle size distribution and concentration of metalworking fluid aerosols may vary with the type of grinding operation sampled.
研究了轴承制造业磨削过程中金属加工液气溶胶的浓度和粒径分布。在三种类型的磨削机械(面磨、微心磨和渐进磨)中分别获得了15个成对的开式和闭式箱体样品和5个级联冲击器样品。采用露天过滤器取样测量的气溶胶质量浓度范围为0.34 ~ 2.43 mg/m3。闭式采样测量的范围为0.14 ~ 2.01 mg/m3。各磨矿工艺中,露天磨矿浓度显著高于封闭式磨矿浓度(配对t检验,p <0.05)。空气动力质量中值直径(MMAD)为3.33 ~ 6.26微米。大于9微米的质量百分率为8.0 ~ 45.3。与其他两种工艺相比,平面磨床产生的气溶胶的MMAD和大于9微米的分数显著大于其他两种工艺。结果表明:(1)与露天取样相比,封闭式取样的气溶胶质量浓度较低,差异程度与磨削工艺有关;(2)金属加工液气溶胶的粒径分布和浓度可能随取样的磨削操作类型而变化。
{"title":"Characterization of metalworking fluid aerosols in bearing grinding operations.","authors":"F. Rosenthal, B. L. Yeagy","doi":"10.1080/15298660108984640","DOIUrl":"https://doi.org/10.1080/15298660108984640","url":null,"abstract":"The concentrations and size distribution of metalworking fluid aerosols were investigated in grinding operations in the bearing manufacturing industry. Fifteen paired open- and closed-face cassette samples and five cascade impactor samples were obtained in each of three types of grinding machinery (face, microcentric, and progressive). Aerosol mass concentration as measured by open-face filter sampling ranged from 0.34 to 2.43 mg/m3. As measured by closed-face sampling the range was 0.14 to 2.01 mg/m3. For each grinding process, open-face concentration was significantly higher than the closed-face concentration (paired t-test, p <0.05). Mass median aerodynamic diameter (MMAD) ranged from 3.33 to 6.26 microm. The percentage of mass greater than 9 microm ranged from 8.0 to 45.3. The MMAD and fraction greater than 9 microm were significantly greater for the aerosol produced by the face grinder compared with the other two processes. The results indicate that (1) closed-face sampling results in a lower aerosol mass concentration, as compared with open-face sampling, with the degree of difference being somewhat dependent on grinding process; and (2) the particle size distribution and concentration of metalworking fluid aerosols may vary with the type of grinding operation sampled.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82121940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
期刊
AIHAJ : a journal for the science of occupational and environmental health and safety
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1