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Particle settling after lead-based paint abatement work and clearance waiting period. 含铅涂料清除工作和清除等待期后的颗粒沉降。
K. Choe, M. Trunov, S. Grinshpun, K. Willeke, J. Harney, S. Trakumas, G. Mainelis, R. Bornschein, S. Clark, W. Friedman
This study investigated the evolution of airborne particle concentration and size distribution following abatement work in a controlled environment utilizing direct real-time particle monitoring and used it to project potential lead loadings as those particles settle. An 860 ft3 environmental test chamber with sophisticated ventilation and air purifying systems was built. Wooden doors with lead-based paint were dry sanded or scraped to generate the highest feasible airborne lead concentrations. Size-fractional airborne particle concentrations decreased exponentially with time in all tests, even with no air exchange, consistent with the stirred model of constantly mixed air, which predicts longer settling than for tranquil settling. Very low levels of air mixing generated by temperature gradients and initial room air turbulence affected particle settling. About 90% of airborne lead mass settled within 1 hour after active abatement, before final cleaning began. During the second waiting period of 1 hour, which followed cleaning of the floor, additional dust settled so that the additional potential lead loading from remaining airborne lead was less than 20 microg/ft2. For this worst case scenario, the underestimate of the lead loading done by the clearance sampling did not exceed about 30%. For more realistic conditions, the underestimates are projected to be much lower than the new 40 microg/ft2 Housing and Urban Development (HUD) clearance standards for floor dust lead. These results were obtained for the first waiting period (between the end of active abatement and the beginning of cleaning) of 1 hour, as recommended by HUD guidelines. Thus, this study demonstrates no need to increase either the first or second waiting period.
本研究利用直接实时颗粒监测,在受控环境中研究了减排工作后空气中颗粒浓度和大小分布的演变,并利用它来预测这些颗粒沉降时潜在的铅负荷。建立了一个860平方英尺的环境试验室,配备了先进的通风和空气净化系统。使用含铅涂料的木门被干燥打磨或刮擦,以产生最高的空气铅浓度。在所有试验中,即使没有空气交换,粒径分数空气颗粒浓度也随时间呈指数下降,这与不断混合空气的搅拌模型相一致,该模型预测沉降时间比平静沉降时间更长。由温度梯度和初始室内空气湍流产生的非常低水平的空气混合影响颗粒沉降。大约90%的空气中的铅在主动减排后的1小时内沉淀下来,然后才开始最后的清洁。在清扫地板后的第二次1小时的等待期间,额外的灰尘沉淀下来,因此空气中剩余铅的额外潜在铅负荷低于20微克/平方英尺。在这种最坏的情况下,间隙取样对铅负荷的低估不超过30%。在更现实的情况下,预计低估的水平远低于新的40微克/平方英尺的住房和城市发展(HUD)地板尘铅清除标准。根据HUD指南的建议,这些结果是在第一个等待期(在主动缓解结束和清洁开始之间)1小时获得的。因此,这项研究表明没有必要增加第一或第二次等待期。
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引用次数: 21
Coast Guard exposure to gasoline, MTBE, and benzene vapors during inspection of tank barges. 海岸警卫队在检查油船时暴露在汽油、甲基叔丁基醚和苯蒸气中。
A. Davenport, T. Glynn, H. Rhambarose
A field study was conducted June through August 1996 in an attempt to quantify short-term exposure levels to Coast Guard personnel performing routine inspection activities aboard commercial tank barges carrying gasoline. Transfer and fleeting operations were monitored in the ports of Pittsburgh, Pa., Huntington, W.Va., Baton Rouge, La., and Galveston, Tex. A total of 43 personal and 68 area samples were analyzed for benzene and total hydrocarbons as gasoline ("gasoline"). Results can be summarized as follows: Personal exposure to benzene gave 15-min time-weighted-average (TWA) results ranging from <0.10 to 0.50 ppm. Area benzene levels ranged from <0.04 to 170 ppm. Personal monitoring for gasoline revealed a range of <2.0 to 590 mg/m3 with a GM of 23 mg/m3. Area sample results for gasoline ranged from 1.7 to 90,000 mg/m3. Twelve personal samples were collected for methyl-tert butyl ether (MTBE). Only two of these were above the limit of detection and had 15-min time-weighted averages of 22 ppm and 1.3 ppm. Eighteen MTBE area samples ranged in value from <3.0 to 38 ppm. Although none of the personal samples met or exceeded proposed or established short-term exposure standards, many of the area sampling results indicated that a significant risk of acute exposure exists in the vicinity of valves, pressure lines, and connections. This includes anticipated sources such as pressure vent valves as well as unexpected sources resulting from structural deficiencies onboard the vessels. These results further emphasize the value of safe work practices and proper vessel maintenance in controlling exposure to harmful chemicals.
1996年6月至8月进行了一项实地研究,试图量化在运载汽油的商业油罐驳船上进行例行检查活动的海岸警卫队人员的短期接触水平。在宾夕法尼亚州匹兹堡的港口,转移和短暂的操作受到监控。西弗吉尼亚州亨廷顿市巴吞鲁日,路易斯安那州。以及德克萨斯州的加尔维斯顿。共对43个个人和68个地区样本进行了苯和总碳氢化合物汽油(“汽油”)分析。结果可以总结如下:个人暴露于苯的15分钟时间加权平均(TWA)结果在<0.10到0.50 ppm之间。区域苯含量范围从<0.04到170 ppm。个人对汽油的监测范围为<2.0 ~ 590 mg/m3, GM为23 mg/m3。汽油的面积取样结果为1.7 ~ 90000 mg/m3。收集了12份个人甲基叔丁基醚(MTBE)样品。其中只有两个超过检测极限,15分钟时间加权平均值为22 ppm和1.3 ppm。18个MTBE区域样品的值范围从<3.0 ppm到38 ppm。虽然没有一个个人样本达到或超过建议或建立的短期暴露标准,但许多区域取样结果表明,在阀门、压力管线和连接处附近存在严重的急性暴露风险。这包括预期的来源,如压力排气阀,以及船上结构缺陷导致的意外来源。这些结果进一步强调了安全工作实践和适当的容器维护在控制有害化学品暴露方面的价值。
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引用次数: 11
Environmental Lead Proficiency Analytical Testing (ELPAT) Program. March 2000. 环境铅能力分析测试(ELPAT)计划。2000年3月。
F I Grunder, C Bell
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引用次数: 0
Fatal occupational injuries in the construction industry of a new development area in east China, 1991 to 1997. 1991 ~ 1997年华东新区建筑业致命职业伤害调查。
Z Xia, G S Sorock, J Zhu, T K Courtney, H Fu, Y Liang, D C Christiani

Two hundred thirty-five work-related deaths occurred in the construction industry in a new economic development area in eastern China between 1991 and 1997. These fatalities represented 55% of all occupational deaths. The average annual mortality rate was 51.5 per 100,000 construction workers. Falls were the leading cause of death (46.4%). Falls, collisions, struck by/against something, electrocutions, and excavation cave-ins were the main fatality antecedents, accounting for nearly 93.6% of all fatalities. The most common antecedents for incidents with multiple fatalities were falls, crane-related events, poisoning, and fire. These categories of antecedents were similar to those encountered in the construction industry in the United States. These data suggest that organizations need to focus on these event types when planning their prevention activities. Moreover, improved surveillance systems including computerized databases with narrative descriptions of injury events, antecedent factors, and person-time at-risk data are needed to target interventions more precisely.

1991年至1997年间,中国东部一个新经济开发区的建筑行业发生了235起与工作有关的死亡事件。这些死亡占所有职业死亡的55%。年平均死亡率为每10万建筑工人51.5人。跌倒是主要死亡原因(46.4%)。坠落、碰撞、被某事击中、触电和挖掘塌方是主要的死亡原因,占所有死亡人数的近93.6%。导致多人死亡的事故最常见的原因是跌倒、起重机相关事件、中毒和火灾。这些类别的先行词与美国建筑业遇到的情况类似。这些数据表明,组织在规划预防活动时需要关注这些事件类型。此外,需要改进监测系统,包括具有损伤事件叙述性描述、前因因素和个人风险时间数据的计算机数据库,以更精确地确定干预措施的目标。
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引用次数: 14
An automated system for producing uniform surface deposits of dry particles. 一种生产干燥颗粒表面均匀沉积的自动化系统。
J T Antley, R W Vanderpool, S L Harper

A laboratory system has been constructed that uniformly deposits dry particles onto any type of test surface. Devised as a quality assurance tool for the purpose of evaluating surface sampling methods for lead, it also may be used to generate test surfaces for any contaminant that uses particles or dust as a transport mechanism. Additionally, it may be used to spike surfaces for studies concerning particle transport, resuspension, reentrainment, and exposure. The electromechanical system includes a rugged aluminum chamber housing deposition equipment, a computer-controlled positioning system, and a 0.61 x 0.61 m target surface area (2 x 2 ft). Media used to evaluate the system have included glass beads of various size fractions (physical diameters between 30 and 500 microm), and Arizona Test Dust (aerodynamic diameters between 1 and 80 microm). Presieved particle size fractions may be used individually to study the effects of monodisperse particles, or may be mixed to create custom polydisperse size distributions. Using arrays of 16 coupons placed on the surface to collect representative samples from every test, the uniformity of the particle deposition can be quantified. The system achieved an average coefficient of variation of less than 20% for the 16 coupons for the particle types and sizes mentioned above and for a variety of total surface loadings (0.3-19 g/m2). Calculations of the system's repeatability (as the average coefficient of variation of mass gains for individual coupon locations compared across multiple identically configured runs) yielded approximately 10 +/- 5% (one standard deviation). Tests of the system's accuracy, defined as the absolute percentage difference between predicted surface loadings and actual loadings, yielded 3.7 +/- 1.3% (one standard deviation).

一个实验室系统已经建成,均匀沉积干燥颗粒到任何类型的测试表面。作为一种质量保证工具,用于评估铅的表面采样方法,它也可用于为任何使用颗粒或灰尘作为运输机制的污染物生成测试表面。此外,它还可用于刺穿表面,用于有关粒子传输、再悬浮、再夹带和暴露的研究。机电系统包括一个坚固的铝室外壳沉积设备,一个计算机控制的定位系统,和一个0.61 x 0.61米的目标表面积(2 x 2英尺)。用于评估系统的介质包括各种尺寸的玻璃珠(物理直径在30到500微米之间)和亚利桑那测试粉尘(空气动力学直径在1到80微米之间)。预先的粒度分数可以单独用于研究单分散颗粒的影响,也可以混合使用以创建定制的多分散粒度分布。利用放置在表面的16个薄片阵列,从每次测试中收集有代表性的样品,可以量化颗粒沉积的均匀性。对于上述16种颗粒类型和大小以及各种总表面负荷(0.3-19 g/m2),该系统的平均变异系数小于20%。系统的可重复性计算(即在多个相同配置的运行中比较单个接合面位置的质量增益的平均变异系数)产生了大约10 +/- 5%(一个标准差)。系统的准确度测试,定义为预测表面载荷与实际载荷之间的绝对百分比差,结果为3.7±1.3%(一个标准差)。
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引用次数: 1
Release of lead-containing particles from a wall enclosure. 含铅颗粒从围墙中释放出来。
J Harney, M Trunov, S Grinshpun, K Willeke, K Choe, S Trakumas, W Friedman

The 1995 Department of Housing and Urban Development (HUD) Guidelines for the Evaluation and Control of Lead-Based Paint Hazards in Housing discusses using interior and exterior wall enclosures for lead hazard control. Leaded dust may be aerosolized inside enclosures and released through gaps and cracks into a room. The effects of airflow and mechanical disturbances on dust release were studied using a laboratory wall enclosure model with dust collected from homes with lead-based paint hazards. Airflows relevant to residences were blown down the enclosure and out a 4-, 6-, or 8-mm horizontal gap at its bottom, simulating potential enclosure failure. Then, low-frequency mechanical vibrations also were applied to the enclosure. No significant dust release was found when blowing air down the enclosure even at 37 cm/sec (representing extremely high flow); release occurred only with this high flow and 3 Hz mechanical disturbances. Dust was released primarily from the floor area immediately adjacent to the enclosure gap; the release rate fluctuated over time. Most dust initially settled near the enclosure. Dust release for 1 hour at extreme conditions (high airflow with vibration) yields lead loading above the 1995 HUD clearance level of 100 microg/ft2 only within 3-4 cm of the wall; for the HUD standard (1 ft2) sampling area, the lead loading does not exceed 30 microg/ ft2. Redistributing dust over the room's 16 m2 floor space yields average extreme-condition loading rate of 2 microg/ft2/hour. At less-than-extreme conditions, dust would have to be released for years without cleaning to yield a hazard.

1995年住房和城市发展部(HUD)关于评估和控制住房中含铅涂料危害的指导方针讨论了使用内墙和外墙外壳来控制铅危害。含铅粉尘可能在外壳内雾化,并通过缝隙和裂缝释放到房间内。采用室内墙体封闭模型,研究了气流和机械扰动对粉尘释放的影响。与住宅相关的气流被吹下外壳,并在其底部产生4、6或8毫米的水平间隙,模拟潜在的外壳故障。然后,低频机械振动也应用于外壳。即使以37厘米/秒的速度(极高的流量)向外壳吹气,也没有发现明显的粉尘释放;释放只发生在高流量和3hz机械扰动下。灰尘主要是从紧挨着封闭缝隙的地板上释放出来的;释放率随时间波动。大多数灰尘最初都落在围栏附近。粉尘在极端条件下释放1小时(高气流与振动)产生铅负荷高于1995年HUD间隙水平100微克/平方英尺,仅在3-4厘米的墙壁内;对于HUD标准(1 ft2)采样区域,铅负荷不超过30微克/ ft2。在房间16平方米的面积上重新分配灰尘,平均极端条件加载率为2微克/平方英尺/小时。在不太极端的条件下,灰尘必须在不清洁的情况下释放数年才能产生危害。
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引用次数: 8
Review of Legionnaires' disease. 军团病综述。
B G Shelton, W Kerbel, L Witherell, J D Millar

This review seeks to assist industrial hygienists in the prevention of Legionnaires' disease caused by Legionella bacteria. Breathing water droplets contaminated with Legionella bacteria, in which the organism has been permitted to amplify, causes this disease. Possible sources of transmission include nearly all manmade building water systems. Legionella organisms, found in most natural water sources but at very low concentrations, can thrive under conditions of warmth in these manmade systems. Primary prevention of Legionnaires' disease requires prevention of amplification of Legionella in water systems. This, in turn, requires familiarity with the system and all its components, and effective maintenance and water treatment. However, good maintenance and water treatment regimens alone cannot assure that amplification will not occur somewhere in the system. Systematic microbiological testing for Legionella and appropriate interpretation of the testing results can be powerful assets in prevention by enabling the detection and control of amplification. The occurrence of a confirmed or suspected case of Legionnaires' disease in a building occupant may indicate transmission within the facility; this poses an immediate crisis for the facility manager. An aggressive intervention is indicated to search for previously unknown additional cases of illness, to detect potential sources of transmission, and to decontaminate any suspected sources of transmission on an emergency basis. Once adequate remediation has been achieved and confirmed by microbiological testing, on-going control measures are essential with periodic microbiological investigation to assure continuing prevention of amplification.

本综述旨在协助工业卫生工作者预防由军团菌引起的军团病。吸入被军团菌污染的水滴(军团菌在其中被允许繁殖)会导致这种疾病。可能的传播源包括几乎所有的人造建筑供水系统。军团菌存在于大多数天然水源中,但浓度极低,可在这些人造系统的温暖条件下茁壮成长。军团病的一级预防需要预防水系统中军团菌的扩增。这反过来又要求熟悉系统及其所有组件,并进行有效的维护和水处理。然而,仅靠良好的维护和水处理方案并不能保证在系统的某个地方不会发生放大。军团菌的系统微生物检测和对检测结果的适当解释可通过检测和控制扩增而成为预防的有力资产。楼宇内的住户如出现军团病确诊或怀疑个案,可能表明该疾病在该设施内传播;这给设备经理带来了直接的危机。建议采取积极的干预措施,寻找以前未知的其他疾病病例,发现潜在的传播源,并在紧急情况下对任何疑似传播源进行消毒。一旦取得适当的补救措施并经微生物学检测确认,就必须采取持续的控制措施,定期进行微生物学调查,以确保继续预防扩增。
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引用次数: 17
Permeation of substituted silanes and siloxanes through selected gloves and protective clothing. 取代硅烷和硅氧烷通过选定的手套和防护服的渗透性。
G O Nelson, S J Priante, M Strong, D Anderson, J Fallon-Carine

Testing of the permeation resistance of eight glove and suit barriers against commercially available substituted silanes and siloxanes was performed using the ASTM F739-96 standard test method. In addition to barrier performance to the pure organosilanes, the permeation rates of the hydrolysis product (usually ethanol or methanol) were investigated. The silanes and siloxanes used as the challenge agents were N-2-(aminoethyl)-3-aminopropyltrimethoxysilane; 3-aminopropyltriethoxysilane; 3-chloropropyltrimethoxysilane; ethyltriacetoxysilane; 3-glycidoxypropyltrimethoxysilane; 1,1,1,3,3,3-hexamethyldisilazane; hexamethyldisiloxane; 3-methacryloxypropyltrimethoxysilane; methyltriacetoxysilane (50%)/ethyltriacetoxysilane (50%); methyltrimethoxysilane; methyltris(methylethylketoxime)silane; phenyltrimethoxysilane; polydimethyl siloxanes (PS 340); octamethylcyclotetrasiloxane (D4); tetraethoxysilane; tetramethoxysilane; 1,1,3,3-tetramethyl disiloxane; triethoxysilane; trimethoxysilane; vinyltrimethoxysilane; and vinyltris(methylethylketoxime)silane. Protective gloves tested were nitrile rubber, neoprene rubber, butyl rubber, 4H laminate, and polyvinyl chloride. Garments tested included Tyvek/Saranex 23P, CPF 2, and Responder, all made by Kappler Safety Group. In all cases the protective suit materials lasted 8 hours or more. The only glove that lasted 8 hours against all chemicals was the 4H laminate. The polyvinyl chloride glove lasted 10 min to 8 hours or more depending on the chemical. The nitrile, neoprene, and butyl rubber gloves lasted from 53 min to 8 hours or more depending on the chemical. The alcohol permeation was similar to the organosilicon compounds. The suit materials and the butyl glove all lasted more than 8 hours for both methanol and ethanol.

使用ASTM F739-96标准测试方法测试了八种手套和西装屏障对市售取代硅烷和硅氧烷的渗透性。除了对纯有机硅烷的阻隔性能外,还研究了水解产物(通常是乙醇或甲醇)的渗透速率。作为攻毒剂的硅烷和硅氧烷为N-2-(氨基乙基)-3-氨基丙基三甲氧基硅烷;3-aminopropyltriethoxysilane;3-chloropropyltrimethoxysilane;ethyltriacetoxysilane;3-glycidoxypropyltrimethoxysilane;1, 1, 1, 3, 3, 3-hexamethyldisilazane;hexamethyldisiloxane;3-methacryloxypropyltrimethoxysilane;甲基三乙酰氧基硅烷(50%)/乙基三乙酰氧基硅烷(50%);methyltrimethoxysilane;methyltris (methylethylketoxime)硅烷;phenyltrimethoxysilane;聚二甲基硅氧烷(ps340);octamethylcyclotetrasiloxane (D4);tetraethoxysilane;tetramethoxysilane;1, 1, 3, 3-tetramethyl disiloxane;triethoxysilane;trimethoxysilane;vinyltrimethoxysilane;和vinyltris (methylethylketoxime)硅烷。测试的防护手套有丁腈橡胶、氯丁橡胶、丁基橡胶、4H层压板和聚氯乙烯。测试的服装包括Tyvek/Saranex 23P、CPF 2和Responder,均由卡普勒安全集团生产。在所有情况下,防护服材料持续8小时或更长时间。唯一能在所有化学物质作用下持续8小时的手套是4H层压板。聚氯乙烯手套持续10分钟至8小时或更长时间,具体取决于化学物质。丁腈橡胶、氯丁橡胶和丁基橡胶手套的使用时间从53分钟到8小时不等,视化学物质而定。乙醇的渗透性与有机硅化合物相似。在甲醇和乙醇条件下,西服材料和丁基手套的使用寿命均在8小时以上。
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引用次数: 6
The 2000 Donald E. Cummings Memorial Award Lecture. Decline and fall of the IH empire? Ten steps to assure the survival of the profession. 2000年唐纳德·卡明斯纪念奖演讲。帝国的衰亡?确保行业生存的十个步骤。
D J Burton
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引用次数: 0
Proficiency Analytical Testing (PAT) Program June 2000. 熟练分析测试(PAT)计划2000年6月。
F I Grunder, C Bell
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引用次数: 0
期刊
AIHAJ : a journal for the science of occupational and environmental health and safety
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