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Ferritin level and Hb after covid 19 in the city of Baghdad and Karbala-Iraq 伊拉克巴格达市和卡尔巴拉市covid - 19后铁蛋白水平和Hb
Pub Date : 2022-11-17 DOI: 10.32441/kjps.06.02.p3
Hiba Yousef Saleh, Hadeel Ahmed Hasan, G. Kadhim, Sameerah Mustafa
The study was conducted by taking blood samples from those recovering from the Corona virus, specifically 20-28 days after infection. The number of samples was (54) patients, collected from the period among six months (Mars to September). Blood samples were taken from patients recovering from Covid 19 from the hospitals of Karbala and Baghdad, the information of the samples was recorded, and laboratory analyzes were done to measure the level of ferritin, and the complete blood picture was measured. The data of patients were studied Biochemistry lab with biochemical tests. The results were obtained and indicated that most of the recovered patients with Corona virus had symptoms of acute anemia , and after conducting a ferritin analysis, it was found that their ferritin level was high, which caused an increase in stored iron and a lack of iron associated with hemoglobin. The research recommended continues taking vitamins and minerals necessary for the health of the body.
这项研究是通过采集冠状病毒恢复者的血液样本进行的,特别是在感染后20-28天。样本数量为54例,采集时间为6个月(6月至9月)。在卡尔巴拉和巴格达医院采集新冠肺炎恢复期患者血样,记录血样信息,进行实验室分析,测定铁蛋白水平,并测定全血图谱。对患者资料进行生化实验室生化检测。结果表明,大多数冠状病毒康复患者均有急性贫血症状,经铁蛋白分析,发现其铁蛋白水平较高,导致铁储量增加,与血红蛋白相关的铁缺乏。该研究建议继续服用身体健康所必需的维生素和矿物质。
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引用次数: 0
Uterine artery pulsatility index among polycystic ovary disease; case control study 多囊卵巢病的子宫动脉搏动指数病例对照研究
Pub Date : 2022-11-15 DOI: 10.32441/kjps.06.02.p2
Salah Mohi Salih, Sarab K. Abedalrahman, Usama Nahi Hamdi
     Introduction: Polycystic ovarian syndrome is a multiple organ disorder affects 5 to 10 % female population. The world occurrence of PCOS is 105 million in the age ranges from 15 to 45. The polycystic ovarian syndrome is a set of disorders like amenorrhea, infertility, polycystic ovaries, hyperinsulinemia, hirsutism, acne vulgaris and other symptoms of hyperandrogenism. Color Doppler and Pulse Doppler play a major role in evaluation of uterine artery Resistive index for access correlation with PCOS. PCOS patients suffer from primary and secondary infertility. This study aimed to show assess uterine blood flow and whether there is a correlation between these patterns and specific hormonal parameters. A case control study done in Salah Al-Deen governorate during the period of 1st May–1st October 2022. Twenty-five patients with polycystic ovary disease compared with 25 normal healthy women. The ultrasound and Doppler analyses were performed for all women during the follicular phase of the menstrual cycle. Uterine artery blood flow velocities were analyzed and the pulsatility index, were calculated. The current study showed that oligomenorrhea found among (72%) of the patients, clinical/biochemical signs of hyperandrogenism found among (76%). The mean LH (mIU/L) was significantly higher among PCO disease cases and also that the mean FSH (mIU/L) was significantly lower among PCO disease cases  than control group. There was at increased ovarian volume of > 10 cm3 found among (80%), and ≥12 follicles measuring 2-9 mm found in (84%) of the PCO disease patients. The mean Uterine artery PI was significantly higher among PCO disease cases 2.3 ± 0.5 than control group 1.8 ± 0.4 (P value <0.05). The mean ovarian volume was significantly higher among PCO disease cases  than control group. The mean Uterine artery PI was significantly higher among PCO disease cases than control group.
简介:多囊卵巢综合征是一种多器官疾病,影响5 - 10%的女性人群。PCOS的全球发病率为1.05亿,年龄在15 - 45岁之间。多囊卵巢综合征是一组疾病,如闭经、不孕、多囊卵巢、高胰岛素血症、多毛、寻常痤疮和其他高雄激素症的症状。彩色多普勒和脉冲多普勒是评价子宫动脉阻力指数与PCOS相关性的主要指标。多囊卵巢综合征患者有原发性和继发性不孕。本研究旨在评估子宫血流量以及这些模式与特定激素参数之间是否存在相关性。2022年5月1日至10月1日期间在萨拉赫丁省进行的病例控制研究。25例多囊卵巢病患者与25例正常健康妇女比较。在月经周期的卵泡期对所有妇女进行超声和多普勒分析。分析子宫动脉血流速度,计算脉搏指数。目前的研究显示,在72%的患者中发现了月经减少,在76%的患者中发现了高雄激素的临床/生化征象。PCO组平均LH (mIU/L)显著高于对照组,平均FSH (mIU/L)显著低于对照组。80%的PCO患者卵巢体积增大约10cm3, 84%的PCO患者卵巢体积≥12个,卵泡大小为2- 9mm。PCO组子宫动脉PI均值(2.3±0.5)明显高于对照组(1.8±0.4)(P值<0.05)。PCO患者卵巢平均体积明显高于对照组。PCO患者的平均子宫动脉PI明显高于对照组。
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引用次数: 0
Performance Evaluation of Dispersion Compensation Fiber-based Coherent Optical OFDM-WDM for Long Haul RoF 基于色散补偿光纤的相干光OFDM-WDM长途RoF性能评价
Pub Date : 2022-11-03 DOI: 10.32441/kjps.06.02.p1
R. Yousif, Yazen S. Almashhadani, Basud Mohammed Rasool
     Demanding extra Bandwidth and high data rates has been meet by the integration both of wired and wireless communication systems. For that the Radio over Fiber (RoF) technology has gained a traction. In this article a Coherent Optical Orthogonal Frequency Division Multiplexing (CO-OFDM) is proposed as the main wired system for transmitting data at high rates suffers from the polarization mode dispersion and chromatic dispersion of the optical channel which mitigates the data rates. Thus, to combat these limitations a Desperation Compensation Fiber (DCF) which adds negative attenuation to the optical signals transmitted in optical fiber is suggested. Moreover, the addition of Wavelength- Division- Multiplexing (WDM) to the system of transmission provides better bandwidth saving, high data rates, and better spectral efficiency, and power utilization. The efficiency of high data rate CO-OFDM integrated with RoF for long haul transmission between 100km and 450km with data rates up to 10 Gbps have been investigated in this article with SMF-DCF with 16 DPSK and 16-QAM modulations schemes respectively. The simulation results showed that the proposed system can achieve a high data rate up to 55 Gbps but when integrated with WDM, with a fiber link length can be increased to up to 6600 kilometers, with highest data rate up to 1.65 Tbps.
有线和无线通信系统的集成满足了对额外带宽和高数据速率的要求。因此,光纤无线电(RoF)技术得到了广泛的关注。本文提出了一种相干光正交频分复用(CO-OFDM)作为高速传输数据的主要有线系统,该系统受光信道的偏振模色散和色散的影响而降低了数据速率。因此,为了克服这些限制,提出了一种绝望补偿光纤(DCF),它增加了在光纤中传输的光信号的负衰减。此外,在传输系统中加入波分复用(Wavelength- Division- Multiplexing, WDM)可以更好地节省带宽、提高数据速率、提高频谱效率和功率利用率。本文分别使用16 DPSK和16- qam调制方案的SMF-DCF,研究了高数据速率CO-OFDM与RoF集成在100km ~ 450km之间,数据速率高达10gbps的长距离传输效率。仿真结果表明,该系统可以实现高达55 Gbps的高数据速率,但当与WDM集成时,光纤链路长度可增加到6600公里,最高数据速率可达1.65 Tbps。
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引用次数: 1
Studying the IVF Laboratory Performance Indicators the Vienna Consensus 2017 for the High Institute According to Diagnosis and Assisted Reproductive for Infertility Technologies, Al-Nahrain University, Iraq 研究体外受精实验室性能指标维也纳共识2017根据诊断和辅助生殖不育技术高级研究所,Al-Nahrain大学,伊拉克
Pub Date : 2022-09-30 DOI: 10.32441/kjps.06.01.p6
Zahra A. Hussein, Ali Rahim, Wasan Adnan Abdul-Hameed
Background: Performance indicators are used to assess patient safety, efficacy, equity, patient-centeredness, punctuality, and efficiency. The benchmark values for each Key Performance Indicator are aspirational values, and the minimum performance level values are the number of fertilized oocytes on Day 1 and the Normal Fertilization Rate, respectively (presence of 2Pro Nucleus and 2Polar Body measured at 17 h post-injection) as a Failed fertilization rate is calculated as the proportion of IVF cycles (excluding cycles with intracytoplasmic injection) on Day 1 (17 hours after insemination) with no signs of pregnancy. During fertilization (i.e., 0 oocytes with 2Pro Nucleus). The percentage of zygotes on Day 2 (44 hours after insemination) is known as the cleavage rate, and it can suggest an issue with sperm quality (sperm function, oocyte activation, and gamete receptors), sperm processing, or the quantity of spermatozoa used for insemination. which cleaves to create embryos. The percentage of cleaved embryos per successfully fertilized egg that are at the 4-cell stage on Day 2 (44 hours post-insemination) or at the 8-cell stage on Day 3 (68 hours post-insemination) is known as the embryo development rate. This evaluates the viability and quality of the embryos as well as the capacity of the culture system to promote cleavage at the necessary stages. The critical factor is the proportion of blastocysts observed at 116 hours after insemination as a function of the number of correctly fertilized oocytes. Measures of performance blastocyst development rate. The viability of the embryo as well as the culture system's capacity to support blastocyst formation from fertilized oocytes (i.e., the formation of an intracellular mass and a blastocoele cavity) are both determined by this factor. It should be noted that this phrase only considers blastocyst formation and not blastocyst stage or quality. The damage rate is the proportion of oocytes that are injured or have deteriorated by the time of fertilization assessment on Day 1 as a result of the intracytoplasmic injection. The percentage of biopsied and tubed/fixed samples where DNA is found represents the success rate of the biopsy. It serves as a gauge of the embryologists' ability to transfer biopsied samples to test tubes, as shown by successful DNA amplification. The number of gestational sacs divided by the total number of transplanted embryos is how one calculates the implantation rate, which is dependent on the cleavage stage. By dividing the number of gestational sacs by the total number of transplanted blastocysts, the implantation KPI (blastocyst stage) is calculated.
背景:绩效指标用于评估患者的安全性、有效性、公平性、以患者为中心、准时性和效率。每个关键性能指标的基准值为抽吸值,最低性能水平值分别为第1天的受精卵母细胞数量和正常受精率(注射后17小时测量的2Pro核和2极体的存在)。受精率失败计算为第1天(授精后17小时)无妊娠迹象的IVF周期(不包括胞浆内注射周期)的比例。在受精过程中(即0个卵母细胞带有2Pro核)。第2天(受精后44小时)的受精卵百分比被称为卵裂率,它可以表明精子质量(精子功能、卵母细胞激活和配子受体)、精子加工或用于授精的精子数量的问题。分裂产生胚胎。每个成功受精卵在第2天(授精后44小时)处于4细胞阶段或在第3天(授精后68小时)处于8细胞阶段的卵裂胚胎的百分比称为胚胎发育率。这是为了评估胚胎的活力和质量,以及培养系统在必要阶段促进卵裂的能力。关键因素是在授精116小时后观察到的囊胚比例与正确受精的卵母细胞数量的关系。性能指标囊胚发育速率。胚胎的活力以及培养系统支持受精卵母细胞形成囊胚的能力(即细胞内团块和囊胚腔的形成)都是由这个因素决定的。需要注意的是,这个短语只考虑囊胚的形成,而不考虑囊胚的阶段或质量。损伤率是指在第1天受精评估时由于胞浆内注射而损伤或恶化的卵母细胞的比例。活检和管状/固定样本中发现DNA的百分比代表活检的成功率。它可以作为胚胎学家将活检样本转移到试管中的能力的衡量标准,如成功的DNA扩增所示。用胚胎囊数除以移植胚胎总数就可以计算着床率,而着床率取决于卵裂阶段。用妊娠囊数除以移植囊胚总数,计算着床KPI(囊胚期)。
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引用次数: 0
Association between ICSI cycle outcome and response in women with infertility 不孕妇女ICSI周期结果与反应之间的关系
Pub Date : 2022-09-20 DOI: 10.32441/kjps.06.01.p5
Sara Samir Sadoon, A. Mohammed, Ali Rahim
Background: Infertility is the inability to achieve a clinical pregnancy after 12 months of regular and unprotected sexual activity. Increases in child-bearing delay and maternal age at first pregnancy significantly impact the rise of age-related infertility and the demand for treatment using assisted reproduction techniques (ART). As a result, many women with a low ovarian reserve and a poor ovarian response (POR) to conventional stimulation seek medical assistance at infertility clinics. Aim: The study aimed to evaluate the quality of oocytes and embryos, as well as the rates of conception, in infertile women who were candidates for fresh intracytoplasmic sperm injection between good and poor-responder women (ICSI). Patients and methods: The study was conducted on 45 infertile women undergoing ICSI at the High Institute for Infertility Diagnosis and Assisted Reproductive Technologies/ Al-Nahrain University/ Baghdad/ Iraq from October 2021 to April 2022, regardless of whether they had previously undergone ICSI. The morphology of the oocytes and the quality of the resulting embryos were assessed. The patients' ages ranged from 20 to 42 years old. There was primary and secondary infertility ranging from one to 20 years. Every couple had a basic reproductive assessment. The antagonist protocol was used for all infertile females. All females had their serum levels of AMH, luteinizing hormone (LH), follicle-stimulating hormone (FSH), and oestradiol (E2) measured on the second or third day of their cycle. The serum oestradiol (E2) level was re-measured on the day of the hCG injection. Results: The participants in the study were 32.6 ± 5.3 years old. The findings showed that 57.8% of the patients had a well response, and 24.4% of the women were pregnant. In those who became pregnant, anti-müllerian hormone (AMH) levels were significantly higher, and follicle-stimulating hormone (FSH) levels were noticeably lower (p> 0.05). The E2, LH, prolactin, and progesterone levels were not statistically different (P> 0.05). Conclusion: In conclusion, the findings revealed a positive relationship between response and ICSI outcomes in infertile women.
背景:不孕症是指在常规和无保护的性行为12个月后无法实现临床妊娠。生育延迟和产妇首次怀孕年龄的增加显著影响了与年龄有关的不孕症的增加和使用辅助生殖技术(ART)治疗的需求。因此,许多卵巢储备不足和卵巢对常规刺激反应差(POR)的妇女向不孕不育诊所寻求医疗援助。目的:本研究旨在评估在ICSI反应良好和反应不良的女性(ICSI)中接受新鲜卵浆内单精子注射的不孕妇女的卵母细胞和胚胎质量以及受孕率。患者和方法:该研究于2021年10月至2022年4月在伊拉克巴格达的不孕症诊断和辅助生殖技术高级研究所/ Al-Nahrain大学/伊拉克进行了45名接受ICSI的不孕妇女,无论她们之前是否接受过ICSI。评估卵母细胞的形态和胚胎的质量。患者年龄从20岁到42岁不等。有原发性和继发性不孕症,从1年到20年不等。每对夫妇都有一个基本的生殖评估。所有不育雌性均使用拮抗剂方案。所有的女性在月经周期的第二天或第三天测量了她们的血清AMH、黄体生成素(LH)、卵泡刺激素(FSH)和雌二醇(E2)水平。在注射hCG当天再次测定血清雌二醇(E2)水平。结果:研究对象年龄为32.6±5.3岁。结果显示,57.8%的患者有良好的反应,24.4%的妇女怀孕。妊娠组抗勒管激素(AMH)水平显著升高,促卵泡激素(FSH)水平显著降低(p> 0.05)。E2、LH、催乳素、孕酮水平差异无统计学意义(P> 0.05)。结论:总之,研究结果显示不孕妇女的反应与ICSI结果呈正相关。
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引用次数: 0
Emotional Response using Power Spectrum Approach 使用功率谱方法的情绪反应
Pub Date : 2022-09-08 DOI: 10.32441/kjps.06.01.p4
Wafaa Khazaal Shams, Qusay Kanaan Kadhim, Noor Ahmed Hameed, Wijdan Mahommd Khuthqair
The objective of this study is to detect affective response of children to facial expression based on alpha power density of brain activity.  Electroencephalography data were collected from 10 typical children. The alpha power temporal information of active brain regions was extracted.  Performance of the power spectrum feature was evaluated in emotion recognition process using K nearest neighbor, a regularized least square and multilayer perceptron classifier. A statistical analysis indicated right alpha activity during negative and calm emotional states. Statistical results showed significant difference between rest conditions and emotional state. The best accuracy we got to detect emotional states is by using regularized least square that is 70%.
本研究的目的是基于大脑活动的阿尔法能量密度来检测儿童对面部表情的情感反应。收集10例典型儿童的脑电图数据。提取脑活动区域的阿尔法功率时间信息。利用K近邻、正则化最小二乘和多层感知器分类器对功率谱特征在情绪识别过程中的性能进行了评价。一项统计分析表明,在消极和平静的情绪状态下,右α活动。统计结果显示休息状态与情绪状态有显著性差异。我们检测情绪状态的最佳准确度是使用70%的正则化最小二乘。
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引用次数: 0
The Effect of CO2, CH4, N2O Gases Emissions on Agricultural Grounds in Iraq After 2003 By Using Neural Networks 基于神经网络的2003年后伊拉克农业用地CO2、CH4、N2O排放效应
Pub Date : 2022-02-16 DOI: 10.32441/kjps.05.02.p4
N. Al-Fakhry, Ramadan M. Ramo
Exacerbating the environmental impacts of pollution and leaving them unchanged will ultimately lead to disastrous environmental disasters Consequences, in addition to incurring a lot of human and material losses in addition to wasting and dissipating a lot of energies and foreshadow in the end a threat to the human existence and the great danger it poses to the future of Iraq. The research attempts to identify the impact of environmental pollution on health, agriculture, economy and development and threatening the lives of the population. For the purpose of reaching this goal, the research included in its theoretical part the concept of pollution and its types, and the Iraqi environment, especially after 2003, while the practical part dealt with the impact of methane emissions, and dioxide Carbon and nitrous oxide on the soil in Iraq using the Quick Back Propagation artificial neural network.
加剧污染对环境的影响而不加以改变,除了造成大量的人力和物力损失以及浪费和耗散大量的能源外,最终将导致灾难性的环境灾难后果,并最终预示着对人类生存的威胁和对伊拉克未来的巨大危险。该研究试图确定环境污染对健康、农业、经济和发展的影响以及对人口生命的威胁。为了实现这一目标,研究的理论部分包括污染的概念和类型,以及伊拉克的环境,特别是2003年以后,而实践部分则使用快速反向传播人工神经网络处理甲烷排放,二氧化碳和一氧化二氮对伊拉克土壤的影响。
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引用次数: 0
A Solar Disinfection Water Treatment System for Rural Areas / Jordan 农村太阳能消毒水处理系统/约旦
Pub Date : 2022-01-15 DOI: 10.32441/kjps.05.02.p5
Yasmeen Smadi, Emad Alsood, Mohammad Aljaradin
The present study was conducted to assess the efficiency of solar energy in treating any potential pollution of drinking water in dam lakes caused by human activity in rural areas. The water quality parameters include temperature, pH, conductivity, total suspended solids, total nitrogen, total phosphorus, NH4-N, NO3-N, HCO3, Cl-, Na+, Mg2+, Ca2+, SAR, B, K+, SO42-, and E-coli were monitored. Samples was collected during the summer and winter (during the filling period). The results showed a rapid decrease in microbial counts upon exposure to solar radiation. More than 98% reductions were achieved after 8 hours for the bacterial communities tested under different conditions. The rate of inactivation, however, varied and was mainly affected by water turbidity and temperature during the experiments. The results indicated that turbidity affected the efficiency of water disinfection, and the efficiency improves with longer exposure duration, implying that in high turbidity and severe weather conditions, exposure time must be increased to compensate for the effects of these factors. The water in the system should be exposed to at least eight hours before leaving to the storage tanks. When scaled up, the proposed method could be a vital tool in solar water disinfection technologies, particularly in isolated and rural locations. Using solar energy to disinfect polluted water will certainly reduce the usage of chlorination and or filtration in water treatment, reducing treatment costs while also protecting the environment.
本研究旨在评估太阳能在处理农村地区人类活动造成的坝湖饮用水潜在污染方面的效率。监测水质参数包括温度、pH、电导率、总悬浮物、总氮、总磷、NH4-N、NO3-N、HCO3、Cl-、Na+、Mg2+、Ca2+、SAR、B、K+、SO42-和大肠杆菌。在夏季和冬季(灌装期)采集样品。结果显示,暴露在太阳辐射下,微生物数量迅速减少。在不同条件下测试的细菌群落在8小时后达到98%以上的减少。然而,在实验过程中,失活速率是不同的,主要受水浊度和温度的影响。结果表明,浊度影响水的消毒效率,且暴露时间越长,消毒效率越高,说明在高浊度和恶劣天气条件下,必须增加暴露时间以补偿这些因素的影响。系统中的水在进入储罐之前应至少暴露8小时。如果扩大规模,所提出的方法可能成为太阳能水消毒技术的重要工具,特别是在偏远和农村地区。利用太阳能对受污染的水进行消毒,肯定会减少水处理中氯化和/或过滤的使用,降低处理成本,同时也保护了环境。
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引用次数: 11
Non-Human-Machine Interaction for Power Transmission Lines Protection Design and Enhancement of Under Voltage Relay 输变电线路非人机交互保护设计及低压继电器增强
Pub Date : 2022-01-07 DOI: 10.32441/kjps.05.02.p3
A. T. Hussain
The continuous monitoring of transmission line protection relay is desirable to ensure the system disturbance such as fault inception is detected in transmission line. Therefore, fault on transmission line needs to be detected, classified, and located accurately to maintain the stability of system. This project presents design enhancement and development under voltage relay in power system protection using MATLAB/Simulink. The under-voltage relay is a relay that has contacts that operate when voltage drops below a set voltage which is used for protection against voltage drops to detect short circuit and others. This study is carried out for all types of faults which only related with one of the parallel lines. For the overall of operation conditions, the sample data were generated for the system by varying the different fault types and fault location. This design system proposes the use of MATLAB/ Simulink based method for fast and reliable fault classification and location for a various type of fault.
对输电线路保护继电保护进行连续监测,是检测输电线路故障启动等系统扰动的重要手段。因此,需要对输电线路上的故障进行准确的检测、分类和定位,以维护系统的稳定。本课题利用MATLAB/Simulink对电力系统保护中的欠压继电器进行了改进和开发。欠压继电器是一种具有触点的继电器,当电压降至低于设定电压时,触点会工作,用于防止电压降,以检测短路和其他情况。本研究适用于仅与一条平行线有关的所有类型的断层。对于整体运行情况,通过改变不同的故障类型和故障位置,为系统生成样本数据。本设计系统提出了采用基于MATLAB/ Simulink的方法对各种类型的故障进行快速可靠的故障分类和定位。
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引用次数: 0
Transmission of dipolar substituent effects: ionization of a series 3-(7-substituted-1-naphthyl) propynoic acid (E)-3-(7-substituted-1-naphthyl) propenoic acids and their Esterification with Diazodiphenylmethane 偶极取代基效应的传递:一系列3-(7-取代-1-萘基)丙酸(E)-3-(7-取代-1-萘基)丙烯酸的电离及其与重氮二苯甲烷的酯化反应
Pub Date : 2021-12-30 DOI: 10.32441/kjps.05.02.p1
Ghadir Khalaf, Sameerah Mustafa, G. Kadhim, Hadeel A. Hasan
Alkaline hydrolysis rates coefficients for the series of methyl 3-(7-substituted-1-naphthyl) propynoate was calculated in 70%v/v dimethylsulphoxide-water at various temperatures (25,30,40, and 50̊ C). The pKa values of 3-(7-substituted-1-naphthyl) propynoic acid and (E)- 3-(7-substituted-1-naphthyl) propenoic acid calculated in 80%w/w 2-methoxyethanol-water at room temperature (25.0̊ C). logk2 of esterification rate coefficients for 3-(7-substituted-1-naphthyl) propynioc acid and (E)-3(7-substituted-1-naphthyl) propenioc acid with DDM have been measured at 30.0̊ C. Reversed substituent dipolar effects were found in the ionization reaction. In the esterification reaction with DDM the result show similar but reduced substituted effects. Rate retardations was found in the alkaline hydrolysis. It could be result from steric effect or reversal of substituent dipolar effect with a combination of steric effect.
计算了3-(7-取代-1-萘基)丙酸甲酯系列在70%v/v二甲亚砜水溶液中不同温度(25,30,40,室温(25.0℃)下,在80%w/w的2-甲氧基乙醇-水中计算了3-(7-取代-1-萘基)丙酸和(E)-3 -(7-取代-1-萘基)丙烯酸的pKa值,在30.0℃下测定了3-(7-取代-1-萘基)丙酸和(E)-(7-取代-1-萘基)丙烯酸与DDM的酯化速率系数logk2。在与DDM的酯化反应中,取代效应相似,但有所降低。在碱性水解过程中发现速率减慢。它可能是位位效应的结果,也可能是取代基偶极效应的逆转与位位效应的结合。
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引用次数: 0
期刊
Al-Kitab Journal for Pure Sciences
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