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Fundamentals of low-cost aerosol sensor design and operation 低成本气溶胶传感器设计和操作的基本原理
IF 5.2 4区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-20 DOI: 10.1080/02786826.2023.2285935
James Ouimette, W. Patrick Arnott, Philip Laven, Richard Whitwell, Nagarajan Radhakrishnan, Suresh Dhaniyala, Michael Sandink, Jessica Tryner, John Volckens
Most evaluations of low-cost aerosol sensors have focused on their measurement bias compared to regulatory monitors. Few evaluations have applied fundamental principles of aerosol science to increa...
大多数对低成本气溶胶传感器的评估都集中在它们与监管监测仪相比的测量偏差上。很少有评估应用气溶胶科学的基本原理来增加…
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引用次数: 0
Aerosol Photoemission as a Versatile Tool for Nanoparticle Surface Investigations: Evaluation of Metal Oxide Formation and Surface Properties of Multi-Component Particles 气溶胶光发射作为纳米颗粒表面研究的通用工具:多组分颗粒的金属氧化物形成和表面特性的评估
IF 5.2 4区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-17 DOI: 10.1080/02786826.2023.2285307
Vinzent Olszok, Philipp Rembe, Alfred P. Weber
The presented work discusses an analytical setup that is capable of detecting surface alterations of aerosol nanoparticles. Utilizing the photoelectric effect, Aerosol Photoemission Spectroscopy (A...
提出的工作讨论了一种分析装置,能够检测气溶胶纳米颗粒的表面变化。利用光电效应,气溶胶光电发射光谱(A…
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引用次数: 0
Insights into the potential pathogenic bacteria and their interactions with meteorology and atmospheric pollution conditions examined during summer and winter in Xi'an, China 中国西安夏季和冬季潜在致病菌及其与气象和大气污染条件相互作用的研究
IF 5.2 4区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-16 DOI: 10.1080/02786826.2023.2283480
Liu Yang, Yiming Yang, Junqiang Wei, Tao Wang, Lizhen Li, Zhenxing Shen
Bioaerosols can influence the atmospheric environment and human health. In this study, we investigated the diurnal variations of bioaerosols and the bacterial communities in PM2.5 during summer and...
生物气溶胶可以影响大气环境和人类健康。本文研究了夏季和冬季PM2.5中生物气溶胶和细菌群落的日变化。
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引用次数: 0
Proceedings from a special symposium and panel session on the aerosol science of infectious diseases: what we learned and what we still need to know 传染病的气溶胶科学特别研讨会和小组会议记录:我们学到了什么,我们还需要知道什么
4区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-10 DOI: 10.1080/02786826.2023.2273707
Justin Taylor, Shanna Ratnesar-Shumate, Krystal Pollitt, J. Alex Huffman
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引用次数: 0
Rapid bioaerosol detection by measuring circular intensity differential scattering (CIDS) from single flowing through particle 通过单个流动颗粒测量圆强度差散射(CIDS)的快速生物气溶胶检测
4区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-07 DOI: 10.1080/02786826.2023.2279525
Yong-Le Pan, Aimable Kalume, Leonid Beresnev, Chuji Wang, Sean Kinahan, Danielle N. Rivera, Kevin K. Crown, Joshua Santarpia
ABSTRACTWe present an advanced optical method to measure the phase function of circular intensity differential scattering (CIDS), i.e., the normalized Mueller matrix element -S14/S11, from individual single flowing through aerosol particles. Here, a 32-anode photomultiplier tube and its associated electronics, combined with an elliptical reflector, were used to record the scattering phase functions, when a particle were illuminated by a left-handed and a right-handed circular polarization laser beam around the focus of the reflector successively. The new design does not need lock-in amplifier, polarization modulator, and rotating goniometer as the traditional setup. It can reach a particle detection ability with a maximum rate of 50,000 particle/sec. CIDS phase functions from tryptophan particles, polystyrene latex microspheres, aggregates of Escherichia coli, Bacillus subtilis spores, Yersinia rohdei, and bacteriophage MS2 were measured, the results showed that this method has the ability to rapidly discriminate between single bioaerosol and non-bioaerosol particles.Keywords: Circular intensity differential scattering (CIDS)Mueller matrix element -S14/S11 Bioaerosol particlesChiralitySpiralElastic light scatteringScattering phase functionDisclaimerAs a service to authors and researchers we are providing this version of an accepted manuscript (AM). Copyediting, typesetting, and review of the resulting proofs will be undertaken on this manuscript before final publication of the Version of Record (VoR). During production and pre-press, errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal relate to these versions also.
摘要本文提出了一种先进的光学方法来测量单个气溶胶粒子流动的圆形强度微分散射(CIDS)的相函数,即归一化穆勒矩阵元-S14/S11。利用32阳极光电倍增管及其相关电子器件与椭圆反射器相结合,记录了一个粒子被左旋和右旋圆偏振激光束依次围绕反射器焦点照射时的散射相函数。新设计不需要传统的锁相放大器、偏振调制器和旋转测角仪。最高可达5万个粒子/秒的粒子检测能力。测定了色氨酸颗粒、聚苯乙烯乳胶微球、大肠杆菌、枯草芽孢杆菌孢子、罗氏耶尔森菌和噬菌体MS2聚集物的CIDS相功能,结果表明该方法具有快速区分单一生物气溶胶和非生物气溶胶颗粒的能力。关键词:圆形强度微分散射(CIDS)穆勒矩阵元素-S14/S11生物气溶胶粒子手性螺旋弹性光散射散射相位函数免责声明作为对作者和研究人员的服务,我们提供此版本的接受稿件(AM)。在最终出版版本记录(VoR)之前,将对该手稿进行编辑、排版和审查。在制作和印前,可能会发现可能影响内容的错误,所有适用于期刊的法律免责声明也与这些版本有关。
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引用次数: 0
A comparison of real-world outdoor aging of Bacillus thuringiensis bioaerosols using Goldberg rotating drums and synthetic spider webs in Conroe, Texas 在德克萨斯州Conroe使用Goldberg旋转鼓和合成蜘蛛网对苏云金芽孢杆菌生物气溶胶进行室外老化的比较
4区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-07 DOI: 10.1080/02786826.2023.2271990
Sean M. Kinahan, Gabriel A. Lucero, Matthew S. Tezak, Kevin Hommema, Paul Gemmer, Eric Scribben, Thomas Hawkyard, Don R. Collins, Kevin K. Crown, Joshua L. Santarpia
AbstractThere are two predominant methods for understanding and studying bioaerosol aging: capture on microfibers, and Goldberg rotating drums. There are advantages and disadvantages to each approach depending on the experimental needs, cost, and timeline, but they have rarely been compared in parallel to determine the similarity of results. Experiments that use Goldberg drums have the advantage of studying aerosol particles in suspension, but due time resolution of aging processes is limited by chamber volume, sample volumes, and aerosol loss mechanisms. For microfiber experiments, particles are adhered to the fiber, and so only simulate natural aerosols, but there are significant advantages since particles are not lost during aging and the time resolution is not limited by sampling. In this study, we compared outdoor UV-transmitting Goldberg rotating drums with polymethyl methacrylate (PMMA) synthetic spider web material in a complex real-world environment during a summer near Houston, Texas. Bacillus thuringiensis al hakam spores were aerosolized into UV-transmitting, gas-permeable chambers that allowed relevant exposure to real-world atmospheric conditions while isolating particles of interest. Aging was compared for up to 4 h in both sunlight exposed and protected environments to compare and quantify relative degradation rates. The two disparate methodologies yielded similar results, with no statistical difference found in three out of four combinations of carbon-filtered air vs. ambient air, and protection from sunlight vs. exposure to sunlight, but this could vary for other particle sizes or organisms.Copyright © 2023 American Association for Aerosol ResearchEDITOR: Jonathan P. Reid AcknowledgmentsThe authors would like to acknowledge Dr. Morgan Minyard and Mr. Rick Mathieson for their guidance and technical insight, and the Defense Threat Reduction Agency. Additionally, we acknowledge and thank Dr. James Flynn, and the Department of Earth and Atmospheric Sciences at the University of Houston for gas-phase measurements and site access, along with the staff at the W.G. Jones State Forest.Disclosure statementThe authors report there are no competing interests to declare.Additional informationFundingThe Defense Threat Reduction Agency (DTRA) provided the funding for this research (HDTRA1310184).
摘要对生物气溶胶老化的认识和研究主要有两种方法:微纤维捕集法和哥德堡旋转鼓法。根据实验需要、成本和时间,每种方法都有优缺点,但很少将它们并行比较以确定结果的相似性。使用Goldberg鼓的实验在研究悬浮中的气溶胶颗粒方面具有优势,但由于老化过程的时间分辨率受到室体积、样品体积和气溶胶损失机制的限制。对于超细纤维实验,由于颗粒粘附在纤维上,只能模拟天然气溶胶,但由于颗粒不会在老化过程中丢失,且时间分辨率不受采样的限制,具有明显的优势。在这项研究中,我们在德克萨斯州休斯顿附近的一个复杂的现实环境中,比较了户外紫外线传输Goldberg旋转鼓和聚甲基丙烯酸甲酯(PMMA)合成蛛网材料。苏云金芽孢杆菌哈卡姆孢子被雾化到紫外线透射,透气性室,允许相关暴露在真实的大气条件下,同时分离感兴趣的颗粒。在阳光照射和受保护的环境中,比较了长达4小时的老化,以比较和量化相对降解率。这两种不同的方法产生了类似的结果,在碳过滤空气与环境空气的四种组合中,有三种没有发现统计差异,以及防晒与暴露在阳光下,但这可能因其他颗粒大小或生物体而异。版权所有©2023美国气溶胶研究协会编辑:Jonathan P. Reid致谢作者要感谢Morgan Minyard博士和Rick Mathieson先生的指导和技术见解,以及国防威胁减少局。此外,我们感谢詹姆斯·弗林博士和休斯敦大学地球与大气科学系的气相测量和现场访问,以及W.G.琼斯州立森林的工作人员。作者报告无利益竞争需要申报。国防威胁减少局(DTRA)为这项研究提供了资金(HDTRA1310184)。
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引用次数: 0
Electrospray synthesis and in-situ sizing of nanoparticulate CsH 2 PO 4 纳米颗粒csh2po4的电喷雾合成及原位施胶
4区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-03 DOI: 10.1080/02786826.2023.2279528
Áron Varga, Andrew J. Downard, Vanessa Evoen, Konstantinos P. Giapis, Richard C. Flagan, Sossina M. Haile
ABSTRACTNanometer-sized particles of the solid acid electrolyte material CsH2PO4 have been prepared by electrospray synthesis. Using a differential mobility analyzer to provide real-time particle-size information, the role of electrospray parameters, such as precursor solution composition, surface tension, and conductivity, sheath gas temperature and flow rate, and solution flow rate, were evaluated. The results are compared with particle sizes calculated using well-established scaling laws. The much smaller sizes of the detected particles in comparison to the sizes expected from the predicted initial droplet sizes suggests that droplets undergo fission along the path towards deposition. In flight fission events may also explain the observed counterintuitive result that aerosol particle size decreases with increasing solvent concentration. The in situ feedback provided by this system enabled rapid identification of solution and process parameters that result in mean particle sizes of ∼ 15 nm, substantially smaller than any prior results.DisclaimerAs a service to authors and researchers we are providing this version of an accepted manuscript (AM). Copyediting, typesetting, and review of the resulting proofs will be undertaken on this manuscript before final publication of the Version of Record (VoR). During production and pre-press, errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal relate to these versions also.
摘要采用电喷雾合成方法制备了固体酸电解质材料CsH2PO4的纳米颗粒。利用差分迁移率分析仪提供实时粒径信息,评估电喷雾参数的作用,如前驱体溶液组成、表面张力和电导率、鞘层气温度和流速以及溶液流速。将所得结果与采用已建立的标度定律计算的粒径进行了比较。与预测的初始液滴尺寸相比,检测到的颗粒尺寸要小得多,这表明液滴在沉积过程中发生了裂变。飞行中的裂变事件也可以解释观测到的违反直觉的结果,即气溶胶粒径随着溶剂浓度的增加而减小。该系统提供的原位反馈能够快速识别溶液和工艺参数,结果平均粒径为~ 15 nm,大大小于任何先前的结果。免责声明作为对作者和研究人员的服务,我们提供了这个版本的已接受的手稿(AM)。在最终出版版本记录(VoR)之前,将对该手稿进行编辑、排版和审查。在制作和印前,可能会发现可能影响内容的错误,所有适用于期刊的法律免责声明也与这些版本有关。
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引用次数: 0
Development of the Reiss theory for binary homogeneous nucleation of aerosols 气溶胶二元均匀成核的Reiss理论的发展
4区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-03 DOI: 10.1080/02786826.2023.2279527
M. S. Veshchunov
AbstractThe Reiss theory for binary homogeneous nucleation in binary gas mixtures is critically analysed and further developed. Based on the analysis of phase space trajectories in the supercritical zone of the phase transition, carried out within the framework of the theory of two-dimensional dynamical systems and supplemented by the flux matching condition at the boundary of the critical zone, it is shown how the theory should be modified. The proposed modification is equivalent to the earlier modifications by Langer and Stauffer, based on additional trial assumptions (ansatz) for solving the steady state equation for the non-equilibrium size distribution function, but reveals and substantiates the approximation underlying their approach. The extension of the Reiss theory to binary vapours in inert carrier (atmospheric) gases is justified.DisclaimerAs a service to authors and researchers we are providing this version of an accepted manuscript (AM). Copyediting, typesetting, and review of the resulting proofs will be undertaken on this manuscript before final publication of the Version of Record (VoR). During production and pre-press, errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal relate to these versions also.
摘要对二元气体混合物中二元均形核的Reiss理论进行了批判性的分析和进一步的发展。在二维动力系统理论框架内对相变超临界区相空间轨迹进行分析,并辅以临界区边界的通量匹配条件,说明了该理论应如何修正。所提出的修正相当于Langer和Stauffer早先的修正,基于求解非平衡尺寸分布函数的稳态方程的附加试验假设(ansatz),但揭示并证实了其方法所隐含的近似。将赖斯理论推广到惰性载体(大气)气体中的二元蒸汽是合理的。免责声明作为对作者和研究人员的服务,我们提供了这个版本的已接受的手稿(AM)。在最终出版版本记录(VoR)之前,将对该手稿进行编辑、排版和审查。在制作和印前,可能会发现可能影响内容的错误,所有适用于期刊的法律免责声明也与这些版本有关。
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引用次数: 0
Volatile propellant droplet evaporation measurements in metered dose inhaler sprays 计量吸入器喷雾中挥发推进剂液滴蒸发的测量
4区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-10-20 DOI: 10.1080/02786826.2023.2271079
Daniel J. Duke, Harry N. Scott, Anesu J. Kusangaya, Alan Kastengren, Jan Ilavsky, Brandon Sforzo, Benjamin Myatt, Phil Cocks, Stephen Stein, Paul Young, Damon Honnery
ABSTRACTMany aerosol products rely on the rapid vaporization of volatile propellants to produce a fine spray. In the simplest case, these are binary mixtures of propellant and a delivered product which undergo a flash-evaporation process leaving only the less volatile product in the resultant droplet. In more complex applications such as pressurized metered-dose inhalers, the non-propellant component may contain dissolved or suspended drug which precipitates or dries to form a matured particle. The size and morphology of the particles depends strongly on the time-history of the droplet as the propellant evaporates. However, measuring the dynamic evaporation processes which occur in dense sprays containing millions of droplets is challenging. In this paper, we demonstrate a novel application of Ultra Small Angle X-ray Scattering to measure the bulk composition of volatile HFC134a–ethanol sprays, and compare the obtained results with simple evaporation models in a dry nitrogen environment. The data reveal that diffusion-limiting processes inside the droplet are equally important as external convection and mixing-limited factors in determining evaporative timescales.DisclaimerAs a service to authors and researchers we are providing this version of an accepted manuscript (AM). Copyediting, typesetting, and review of the resulting proofs will be undertaken on this manuscript before final publication of the Version of Record (VoR). During production and pre-press, errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal relate to these versions also. Additional informationFundingThis work was supported by the Australian Research Council under Grants LP190100938 and DP200102016, and by Kindeva Drug Delivery.
许多气溶胶产品依靠挥发性推进剂的快速汽化来产生精细的喷雾。在最简单的情况下,这些是推进剂和交付产品的二元混合物,它们经历闪蒸过程,只在所得液滴中留下挥发性较小的产品。在诸如加压计量吸入器等更复杂的应用中,非推进剂组分可能含有溶解或悬浮的药物,其沉淀或干燥形成成熟颗粒。颗粒的大小和形态在很大程度上取决于推进剂蒸发时液滴的时程。然而,测量包含数百万液滴的密集喷雾中发生的动态蒸发过程是具有挑战性的。在本文中,我们展示了一种新的应用超小角x射线散射来测量挥发性hfc134a -乙醇喷雾的体积组成,并将所得结果与干燥氮气环境下的简单蒸发模型进行了比较。数据表明,在确定蒸发时间尺度时,液滴内部的扩散限制过程与外部对流和混合限制因素同样重要。免责声明作为对作者和研究人员的服务,我们提供了这个版本的已接受的手稿(AM)。在最终出版版本记录(VoR)之前,将对该手稿进行编辑、排版和审查。在制作和印前,可能会发现可能影响内容的错误,所有适用于期刊的法律免责声明也与这些版本有关。本研究由澳大利亚研究委员会(Australian Research Council)资助LP190100938和DP200102016,以及Kindeva Drug Delivery提供支持。
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引用次数: 1
Effects of ventilation rate and social distancing on risk of transmission of disease: A numerical study using Eulerian-Lagrangian method 通风率和社会距离对疾病传播风险的影响:用欧拉-拉格朗日方法的数值研究
4区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-10-18 DOI: 10.1080/02786826.2023.2271954
Wonseok Oh, Ryozo Ooka, Hideki Kikumoto, Sihwan Lee
ABSTRACTThis study utilized the Eulerian-Lagrangian method to investigate the risk of transmission of disease by tracking particles generated through coughing. The effects of ventilation rates (0.5, 5.0, and 10 ACH) and social distancing (0.9 and 1.8 m) were examined in a small office room using a displacement ventilation system. Numerical simulations considered different particle sizes (1, 5, 10, 20, 40, and 80 μm) to understand particle behavior and transmission routes. The airflow resulting from human coughing was validated with experimental data. Results showed that at a social distance of 0.9 m, increasing the ventilation rate led to a higher fraction of particles directly inhaled by susceptible individuals, potentially causing droplet and airborne transmission. However, maintaining a social distance of 1.8 m and a ventilation rate of 10 ACH significantly reduced the fraction of inhaled particles. Larger particles tended to deposit on floors and surfaces, while smaller particles remained suspended in the air. Higher ventilation rates increased particle deposition on the body surface of susceptible individuals, whereas increasing social distance reduced particle deposition. These findings highlight the importance of appropriate ventilation rates and social distancing in reducing the risk of infection transmission. Maintaining a social distance of 1.8 m combined with increased ventilation effectively reduced the fraction of inhaled particles. Larger particles were more likely to deposit on surfaces, emphasizing the need for regular disinfection. Understanding the dynamics of infectious particles and implementing effective ventilation and distancing measures can help mitigate the spread of infectious diseases in indoor environments.DisclaimerAs a service to authors and researchers we are providing this version of an accepted manuscript (AM). Copyediting, typesetting, and review of the resulting proofs will be undertaken on this manuscript before final publication of the Version of Record (VoR). During production and pre-press, errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal relate to these versions also. AcknowledgementsThis research was supported by JSPS KAKEHI (Grant Number 21K18763).Supplementary informationThe supplementary information includes Appendix A, Appendix B, and Appendix C.Supplementary data for this article is available online at the provided DOI: https://doi.org/10.1080/02786826.2023.2271954.
摘要本研究采用欧拉-拉格朗日方法,通过追踪咳嗽产生的颗粒来研究疾病传播的风险。采用置换通风系统,在一间小型办公室内研究了换气率(0.5、5.0和10 ACH)和社交距离(0.9和1.8 m)的影响。数值模拟考虑了不同粒径(1、5、10、20、40和80 μm)的颗粒,以了解颗粒的行为和传输路径。用实验数据验证了人体咳嗽产生的气流。结果表明,在社交距离为0.9 m时,通风量的增加会导致易感个体直接吸入颗粒物的比例增加,可能导致飞沫和空气传播。然而,保持1.8 m的社交距离和10 ACH的通气率显著降低了吸入颗粒的比例。较大的颗粒倾向于沉积在地板和表面,而较小的颗粒则悬浮在空气中。通气量越大,易感个体体表颗粒沉积增加,而社会距离越远,易感个体体表颗粒沉积减少。这些发现强调了适当的通气率和社会距离对降低感染传播风险的重要性。保持1.8米的社交距离并增加通风,有效地降低了吸入颗粒物的比例。较大的颗粒更有可能沉积在表面上,这强调了定期消毒的必要性。了解传染性颗粒的动力学,实施有效的通风和隔离措施,有助于减轻传染病在室内环境中的传播。免责声明作为对作者和研究人员的服务,我们提供了这个版本的已接受的手稿(AM)。在最终出版版本记录(VoR)之前,将对该手稿进行编辑、排版和审查。在制作和印前,可能会发现可能影响内容的错误,所有适用于期刊的法律免责声明也与这些版本有关。本研究得到了JSPS KAKEHI(授权号21K18763)的支持。补充信息补充信息包括附录A、附录B和附录c。本文的补充数据可在网站提供的DOI: https://doi.org/10.1080/02786826.2023.2271954上获取。
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引用次数: 0
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Aerosol Science and Technology
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