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Removal of Sulphides and Benzene in Fluid Catalytic Cracking Gasoline by Insitu Hydrogenation Over NbFAPSO-5 NbFAPSO-5原位加氢脱除催化裂化汽油中的硫化物和苯
Pub Date : 2019-05-23 DOI: 10.11648/J.AJAC.20190702.13
N. Mominou, Lei Wang, Badohok Sarki
Niobium containing aluminophosphate molecular sieve (NbFAPSO-5) was hydrothermally synthesized with AlPO-5 type structure. Characterization of this catalyst was performed by X-ray diffraction to determine its structure, inductive coupled plasma-atomic emission spectrometry (ICP-AES) for its elemental composition and infrared spectrometry (IR) to access its acidic properties. X-ray diffraction patterns confirmed well AlPO-5 type structure. ICP-AES analysis confirmed the incorporation of silicon (12.9%), aluminium (15.4%), phosphorous (21.9%), iron (5.62%) and niobium (0.39%) into AlPO-5 framework. Infrared spectrometry analysis showed that both Bronsted and Lewis sites were found in the synthesized sample. A fixed-bed reactor was used to investigate the activity of the resulting catalysts in the removal of sulfides and benzene in fluid catalytic cracking gasoline. Under suitable conditions of a metal loading of 15%, a reaction temperature of 423K, a reaction time of 30 min, a space velocity of 3 h-1, and a reaction pressure of 1 MPa; desulfurization and debenzolization ratios reach 100% and 19.9% respectively. Research octane number of the gasoline increased by two units. This remarkable behavior makes NbFAPSO-5 family, a potential candidate for industrial application as catalysts in the clean fuel.
采用水热法合成了AlPO-5型结构的含铌磷酸铝分子筛(nbapso -5)。通过x射线衍射确定其结构,电感耦合等离子体原子发射光谱(ICP-AES)测定其元素组成,红外光谱(IR)测定其酸性。x射线衍射图很好地证实了AlPO-5型结构。ICP-AES分析证实AlPO-5骨架中含有硅(12.9%)、铝(15.4%)、磷(21.9%)、铁(5.62%)和铌(0.39%)。红外光谱分析表明,合成样品中存在Bronsted位点和Lewis位点。用固定床反应器考察了所制催化剂在催化裂化汽油中硫化物和苯的脱除活性。在金属负荷15%、反应温度423K、反应时间30 min、空速3 h-1、反应压力1 MPa的适宜条件下;脱硫率达100%,脱苯率达19.9%。研究汽油的辛烷值提高了两个单位。这种显著的行为使nbapso -5家族成为清洁燃料催化剂工业应用的潜在候选者。
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引用次数: 0
Isolation and Characterization of an Entophytic Ethanol Resistant Bacterium from Sap of Saccharum officinarum for Efficient Fermentation 从甘蔗渣中分离出一株抗乙醇内生细菌并进行高效发酵
Pub Date : 2019-05-09 DOI: 10.11648/J.AJAC.20190702.11
R. Hewawasam, S. Weliwegamage, S. Rajapakse, S. Sotheeswaran
Bio fuel is one of the emerging industries around the world due to arise of crisis in petroleum fuel. Fermentation is a cost effective and eco-friendly process in production of bio-fuel. One major problem in microbial ethanol fermentation is the low resistance of conventional microorganisms to the high ethanol concentrations, which ultimately lead to decrease in the efficiency of the process. In the present investigation, an ethanol resistant bacterium was isolated from sap of Saccharum officinarum (sugar cane). The optimal cultural conditions such as, temperature, incubation period, and microbiological characteristics, morphological characteristics, biochemical characteristics, ethanol tolerance, sugar tolerance were investigated. Isolated microorganism was tolerated to 18% (V/V) of ethanol concentration in the medium and 35% (V/V) glucose concentration in the medium. Biochemical characteristics have revealed as Gram negative, non-motile, negative for Indole test, Methyl Red test, Voges- Proskauer`s test, Citrate Utilization test, and Urease test and positive results for Oxidase test. Sucrose, Glucose, Fructose, Maltose, Dextrose, Arabinose, Raffinose, Lactose, and Sachcharose can be utilized by this particular bacterium. It is a significant feature in effective fermentation. The fermentation process was carried out in glucose medium under optimum conditions; temperature 30°C, and incubated for 72 hours. Maximum ethanol production was recorded as 12.8±0.4% (V/V). Methanol was not detected throughout the fermentation process. This bacterium is especially useful in bio-fuel production due to high ethanol tolerance of this microorganism; it can be used to enhance the fermentation process over conventional microorganisms. Investigations are currently conducted on establishing the identity of the bacterium.
由于石油燃料危机的出现,生物燃料在世界范围内成为新兴产业之一。发酵是生产生物燃料的一种经济、环保的方法。微生物乙醇发酵的一个主要问题是常规微生物对高浓度乙醇的抵抗力低,这最终导致了工艺效率的降低。本研究从甘蔗汁液中分离出一株乙醇耐药菌。考察了最佳培养条件,如温度、培养时间、微生物特性、形态特性、生化特性、乙醇耐受性、糖耐受性等。分离的微生物对培养基中18% (V/V)的乙醇浓度和35% (V/V)的葡萄糖浓度耐受。生化指标为革兰氏阴性,无运动,吲哚试验、甲基红试验、Voges- Proskauer试验、柠檬酸利用率试验、脲酶试验阴性,氧化酶试验阳性。这种特殊的细菌可以利用蔗糖、葡萄糖、果糖、麦芽糖、葡萄糖、阿拉伯糖、棉子糖、乳糖和蔗糖。这是有效发酵的一个重要特征。在最佳发酵条件下,在葡萄糖培养基中进行发酵;温度30℃,孵育72小时。最大乙醇产量为12.8±0.4% (V/V)。在整个发酵过程中未检测到甲醇。由于这种微生物的高乙醇耐受性,这种细菌在生物燃料生产中特别有用;它可以用来提高发酵过程比传统的微生物。目前正在进行调查,以确定该细菌的身份。
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引用次数: 1
Safety Assessment of Arsenic in Cosmetic Face-creams by Inductively Coupled Plasma Atomic Emission Spectrometer 电感耦合等离子体原子发射光谱仪评价化妆品面霜中砷的安全性
Pub Date : 2019-04-23 DOI: 10.11648/J.AJAC.20190701.14
X. Tan, Hong Cai Liu, Zhuming Wang, Minwu Liu
This paper presented the arsenic determination in four different brands of cosmetic face-creams to provide valuable information on the safety levels for consumers. The cosmetic samples were decomposed by acidic digestion method and then taken for arsenic quantification using inductively coupled atomic emission spectrometry (ICP-AES). The digestion efficiency of acid mixtures including concentrated HNO3, HNO3–HClO4, HNO3–H2O2 and aqua regia was discussed in terms of digestion loss and time consumption. The ICP-AES analyzing results, with determination recoveries of 95.4% ~ 105.2% and relative standard deviations less than 3.0% (n = 5), revealed arsenic contents in the face-creams are in the ranges of 0.68 ~ 3.28 mg·kg−1. Obviously, the arsenic contents in some of the studied brands exceed the maximum recommended value of 2.0 mg·kg−1 set by China. These results lead to the conclusion that constant control of arsenic content in cosmetics should be seriously considered. The successful arsenic determination in cosmetic face-creams by digestion pattern of concentrated HNO3, with simplicity, higher efficiency, less reagent consumption and less analytical time well demonstrates the good analytical capability of this method, promising a great possibility for large batches of cosmetic toxic metal monitoring.
本文介绍了四种不同品牌化妆品面霜的砷含量测定,为消费者提供有价值的安全水平信息。化妆品样品经酸消化法分解后,采用电感耦合原子发射光谱法(ICP-AES)测定砷含量。从消化损失和时间等方面考察了浓HNO3、HNO3 - hclo4、HNO3 - h2o2和王水混合酸的消化效率。ICP-AES测定回收率为95.4% ~ 105.2%,相对标准偏差小于3.0% (n = 5),样品中砷含量在0.68 ~ 3.28 mg·kg−1之间。很明显,一些被研究品牌的砷含量超过了中国规定的最大推荐值2.0 mg·kg−1。这些结果表明,应重视化妆品中砷含量的持续控制。用浓HNO3消解法成功测定化妆品面霜中的砷,方法简单、效率高、试剂用量少、分析时间短,证明了该方法具有良好的分析能力,为大批量化妆品有毒金属的监测提供了可能。
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引用次数: 2
Neuroprotective Efficacy of Maytenus emarginata (Wild.) Ding Hou Against Paraquat Induced Oxidative Stress and Neurotoxicity in Drosophila Model System 野马柳的神经保护作用百草枯对果蝇氧化应激和神经毒性的影响
Pub Date : 2019-04-18 DOI: 10.11648/J.AJAC.20190701.13
Leelaja Bhadravathi Chandrappa, Panduranga Murthy Govinda Shetty, Ravishankar Doddarasinakere Kempaiah, Jayaramu Neelakantanalli, Dharshan Raj Chenna Govindaraju, Rayankula Naidu
An investigation has been made to find out the disease altering therapies against a somber ailment called ‘early aging’ which is due to the formation of free radicals during the natural course of metabolism, also act randomly and indiscriminately to damage the cell components. On the contrary, the natural antioxidants in dietetic practice can diminish these free radicals which can perturb further, the progression of these age-related neurodegenerative disorders such as Alzheimer's disease (AD), Parkinson's disease (PD), and Huntington's disease (HD) followed by Canine Cognitive dysfunction. As a consequence, a tribal medicinal plant; Maytenus emarginata (Wild.) Ding Hou (family-‘ Celastraceae ’) was identified which is commonly called ‘Thorny staff tree’ a potent ethno-medicinal plant drug was opted during the interactions held with tribal healers. This candidate plant drug is being practiced as memory-enhancing factor in their tribal medicinal system at Biligirirangana Hills (B. R. Hills) of Chamarajanagara district, India. Hence, the biological screening with Methanol extract of Maytenus emarginata (MEM) was attempted initially for Physico-chemical, Phyto-chemical properties followed by in vitro , in vivo antioxidant and neuroprotective activities using Drosophila melanogaster (Oeragon K) strain adult male flies. In the result, the extract of M exhibited concentration dependent DPPH scavenging activity. The oxidative stress markers employed to access in vivo antioxidant property of M included lipid peroxidation products malondialdehyde (MDA) and hydroperoxide (HP), reduced glutathione (GSH). The modulatory effect of M on superoxide dismutase (SOD) and catalase (CAT) was also determined. The oxidative stress was induced by using paraquat at 15 mM. The concentration of extract for studies was fixed based on LC 50 values. There was a significant demolition in the levels of MDA and HP in co-exposure of M with Par treated flies homogenate. The level of SOD and CAT was brought to near basal level in the homogenate of flies co-exposed with M and Par. In negative geotaxis assay it was found that M was able to rescue the flies significantly from deteriorating locomotors dysfunctions. The M extract exhibited significant modulatory activity in regulating oxidative stress markers and antioxidants in the fly homogenate. The extract M also exhibited significant antibacterial property against tested microbial strains. Therefore, the findings point out that, MEM plant drug was found to be most promising in its efficacy which may act as compelling antioxidant agent that can intensify the locomotors functions. Thus, the MEM plant drug therapy can regulate the occurrence of CCD, AD, PD and HD and the normal condition may be reinstalled in the biological system.
一项调查发现,针对一种被称为“早衰”的严重疾病的改变疗法,这种疾病是由于自然代谢过程中自由基的形成而引起的,也会随机和不加选择地损害细胞成分。相反,饮食中的天然抗氧化剂可以减少这些自由基,从而进一步扰乱与年龄相关的神经退行性疾病的进展,如阿尔茨海默病(AD)、帕金森病(PD)和亨廷顿病(HD),随后是犬的认知功能障碍。因此,一种部落药用植物;野生鱼(野生)丁侯(家族-“Celastraceae”)被确定为通常被称为“荆棘杖树”,是一种有效的民族药用植物药物,在与部落治疗师的互动中被选择。这种候选植物药物在印度查玛拉贾纳加拉地区Biligirirangana Hills (B. R. Hills)的部落医疗系统中被用作增强记忆的因素。因此,本研究首先尝试用Maytenus emarginata (MEM)甲醇提取物对黑腹果蝇(Drosophila melanogaster, Oeragon K)成年雄蝇进行理化、植物化学特性的筛选,然后进行体外、体内抗氧化和神经保护活性的筛选。结果表明,M提取物具有浓度依赖性的DPPH清除活性。测定M体内抗氧化性能的氧化应激标志物包括脂质过氧化产物丙二醛(MDA)、氢过氧化物(HP)、还原性谷胱甘肽(GSH)。测定了M对超氧化物歧化酶(SOD)和过氧化氢酶(CAT)的调节作用。采用15mm的百草枯诱导氧化应激,提取液浓度以lc50为基准确定。M与Par处理的蝇浆共暴露后,MDA和HP水平显著降低。与M和Par共同暴露的果蝇匀浆中SOD和CAT的水平接近基础水平。阴性地向性实验发现,M能显著拯救运动功能障碍恶化的果蝇。M提取物对果蝇匀浆中氧化应激标志物和抗氧化剂具有显著的调节作用。提取物M对所测试的微生物菌株也表现出显著的抑菌性能。因此,研究结果表明,MEM植物药可能作为增强运动功能的强抗氧化剂,具有较好的抗氧化作用。因此,MEM植物药物治疗可以调节CCD、AD、PD和HD的发生,使生物系统恢复正常状态。
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引用次数: 1
Kinetics and Thermodynamic Studies for Rhodamine B Dye Removal onto Graphene Oxide Nanosheets in Simulated Wastewater 模拟废水中氧化石墨烯纳米片去除罗丹明B染料的动力学和热力学研究
Pub Date : 2019-03-29 DOI: 10.11648/J.AJAC.20190701.12
O. Bankole, O. Oyeneyin, Segun Esan Olaseni, O. K. Akeremale, Pelumi Adanigbo
This report describes for the first time the kinetics, thermodynamic and optimized conditions for maximum removal of Rhodamine B in aqueous solution onto nanosheets of graphene oxides. Results from the GONS characterizations: UV, TEM, FTIR, EDX and XRD, revealed successful introduction of oxygen functionalities on the pristine graphite lattices. Adsorptive behaviour of RhB dye onto GONS under different experimental conditions such as pH, initial concentrations, adsorbent dosage, temperature, and contact time, were fully discussed in this work. The study showed that ≈93% of RhB was removed from simulated wastewater at; sorbent mass of 16.67mg; pH of 6.5; temperature of 298K; contact time of 60min; and concentrations ranging from 2.5 to 30mg/L. Experimental data tested against results of the kinetics and adsorption isotherm models, revealed that the sorption of RhB were best described by pseudo-second order and Freundlich models, respectively. Regeneration of the spent adsorbent was investigated using water, methanol and methanol/acetic acid (9:1) solution, as desorbing eluents. Methanol solution of acetic acid was observed to remove up to 94% of adsorbed RhB from GO surface compared to water (71.36%), and methanol (45.52%). The ease at which RhB was eluted from RhB-loaded GO using methanol/acetic acid (9:1), methanol and water shows that the adsorption mechanism is best described by physisorption.
本报告首次描述了将水溶液中的罗丹明B最大限度地去除到氧化石墨烯纳米片上的动力学、热力学和优化条件。通过紫外、透射电镜、红外光谱、EDX和x射线衍射等表征结果表明,在原始石墨晶格上成功引入了氧官能团。研究了RhB染料在pH、初始浓度、吸附剂用量、温度、接触时间等不同实验条件下对GONS的吸附行为。研究表明:模拟废水中RhB的去除率约为93%;吸附剂质量16.67mg;pH为6.5;温度298K;接触时间60min;浓度范围为2.5至30mg/L。实验数据与动力学和吸附等温线模型的结果对比表明,拟二阶模型和Freundlich模型分别最能描述RhB的吸附。以水、甲醇和甲醇/乙酸(9:1)为解吸剂,对废吸附剂的再生进行了研究。与水(71.36%)和甲醇(45.52%)相比,醋酸甲醇溶液对氧化石墨烯表面吸附的RhB去除率高达94%。用甲醇/乙酸(9:1)、甲醇和水从负载RhB的氧化石墨烯中轻松洗脱RhB,表明吸附机制最好用物理吸附来描述。
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引用次数: 8
K-Dynamics in a Continuously Submerged Limed and the Corresponding Unlimed Soil Subjected to One and Two Cycles of Drying Phase 连续浸没石灰土和相应的无石灰土在一个和两个干燥周期下的k动力学
Pub Date : 2019-01-31 DOI: 10.11648/J.AJAC.20180606.11
T. Debnath, S. Majumder, D. Saha
A laboratory experiment was carried out to study the effect of drying phases on transformation of different fractions of K in submerged limed and the corresponding unlimed soil in presence and absence of N and K fertilizers. Changes in different fractions of K were monitored with time. Results showed that irrespective of treatments, available K increased in the limed soil throughout the period of incubation. However, non-exchangeable K showed an exactly opposite trend of results particularly in limed situation indicating a dynamic equilibrium between these forms of K in soils. Although, the trend of results of both available and non-exchangeable forms are totally different in unlimed situation. The decrease in 1N boiling HNO3 extractable K is comparatively more in limed soil subjected to single drying phase. No drastic variation in lattice and total K is observed under different treatment combinations. It indicates, maintenance of drying phase has little effect on lattice and total K in soils.
通过室内试验,研究了在施氮、施钾和不施氮、不施钾的情况下,不同干燥阶段对浸没石灰土和相应的无底土中不同组分钾转化的影响。监测不同组分K随时间的变化。结果表明,无论处理方式如何,石灰土的速效钾在整个孵育期间都有所增加。而非交换性钾表现出完全相反的结果趋势,特别是在石灰条件下,这表明土壤中这些形式的钾之间存在动态平衡。然而,在无限情况下,可交换形式和不可交换形式的结果趋势是完全不同的。在石灰土中,经过单一干燥阶段,1N沸腾HNO3可萃取K的下降幅度较大。在不同的处理组合下,晶格和总钾没有明显的变化。结果表明,维持干燥期对土壤晶格和全钾的影响不大。
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引用次数: 1
Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger 黑色柠檬酸聚合物(PN) Pozzolana活化- Na-PN-Pozzolana-CE材料的合成及其作为阳离子交换剂的试验
Pub Date : 2019-01-01 DOI: 10.11648/j.ajac.20190706.11
Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana
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引用次数: 0
Efficiency of Animal (Cow, Donkey, Chicken and Horse) Bones, in Removal of Hexavalent Chromium from Aqueous Solution as a Low Cost Adsorbent 动物(牛、驴、鸡和马)骨头作为低成本吸附剂去除水溶液中六价铬的效率
Pub Date : 2019-01-01 DOI: 10.11648/j.ajac.20190701.11
Nworu Jerome Sunday
{"title":"Efficiency of Animal (Cow, Donkey, Chicken and Horse) Bones, in Removal of Hexavalent Chromium from Aqueous Solution as a Low Cost Adsorbent","authors":"Nworu Jerome Sunday","doi":"10.11648/j.ajac.20190701.11","DOIUrl":"https://doi.org/10.11648/j.ajac.20190701.11","url":null,"abstract":"","PeriodicalId":7605,"journal":{"name":"American Journal of Applied Chemistry","volume":"20 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83294401","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Production and Evaluation of Biogas from Mixed Fruits and Vegetable Wastes Collected from Arba Minch Market Arba Minch市场果蔬混合废弃物沼气的生产与评价
Pub Date : 2019-01-01 DOI: 10.11648/j.ajac.20190706.16
Alemu Mekonnen Tura, Tesfaye Seifu Lemma
{"title":"Production and Evaluation of Biogas from Mixed Fruits and Vegetable Wastes Collected from Arba Minch Market","authors":"Alemu Mekonnen Tura, Tesfaye Seifu Lemma","doi":"10.11648/j.ajac.20190706.16","DOIUrl":"https://doi.org/10.11648/j.ajac.20190706.16","url":null,"abstract":"","PeriodicalId":7605,"journal":{"name":"American Journal of Applied Chemistry","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76834420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Black Citric Acid Polymer (PN) Capacity as Raw Material for Cationic Exchanger Realization 以黑柠檬酸聚合物(PN)容量为原料实现阳离子交换
Pub Date : 2019-01-01 DOI: 10.11648/j.ajac.20190702.12
Andry Tahina Rabeharitsara
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引用次数: 0
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American Journal of Applied Chemistry
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