Underground hydrogen storage (UHS) in porous aquifers is a promising solution for large-scale renewable energy storage. Despite growing interest in underground hydrogen storage, a fundamental gap remains in understanding whether hydrogen behaves distinctly from other subsurface gases at the pore scale. This study employs in situ micro-CT imaging to directly compare gas injection and withdrawal of H₂, N₂, and CO₂ in Bentheimer sandstone. The results confirm a water-wet system for all gases, with contact angles between 50° and 70°. However, significant differences in gas trapping and distribution emerged. After gas injection, the initial gas saturations were 33 % for H₂, 37 % for N₂, and 36 % for CO₂. After imbibition (withdrawal), H₂ exhibited the lowest residual saturation (14 %), compared to N₂ (25 %), while CO₂ was completely dissolved. Low residual saturation of H₂ indicate high recovery efficiency, which is a favorable for hydrogen storage. Analysis of gas ganglia revealed that H₂'s low viscosity and density promote capillary fingering and heterogeneous redistribution. In contrast, N₂'s higher viscosity facilitates stable displacement and higher residual saturation, making it a suitable candidate as a cushion gas. The capillary pressure for H₂ was found to be approximately 1.2 times higher than for N₂, a difference not fully explained by interfacial tension alone. These findings demonstrate that gas properties, particularly solubility and viscosity, govern pore-scale distribution and trapping mechanisms. Consequently, N₂ and CO₂ are poor proxies for predicting H₂ behavior, and accurate forecasting of UHS performance requires models that account for H₂'s mobility and its propensity for unstable flow.
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