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Dimensional analysis of diffusive association rate equations. 扩散关联速率方程的维度分析。
IF 1.4 4区 物理与天体物理 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-14 eCollection Date: 2024-11-01 DOI: 10.1063/5.0238119
Jixin Chen

Diffusive adsorption/association is a fundamental step in almost all chemical reactions in diluted solutions, such as organic synthesis, polymerization, self-assembly, biomolecular interactions, electrode dynamics, catalysis, chromatography, air and water environmental dynamics, and social and market dynamics. However, predicting the rate of such a reaction is challenging using the equations established over 100 years ago. Several orders of magnitude differences between the theoretical predictions and experimental measurements for various systems, from self-assembled monolayers to protein-protein aggregations, make such calculations meaningless in many situations. I believe the major problem is that the time-dependent evolution curve of Fick's gradient is an ideal assumption in most cases, and its slope is significantly overestimated. This paper digs into Fick's gradient problem for 3D cases and provides a solution using the single-molecule diffusion probability density function discretely.

扩散吸附/结合是稀释溶液中几乎所有化学反应的基本步骤,例如有机合成、聚合、自组装、生物分子相互作用、电极动力学、催化、色谱、空气和水环境动力学以及社会和市场动力学。然而,使用 100 多年前建立的方程式预测此类反应的速率是一项挑战。从自组装单层到蛋白质聚合,各种系统的理论预测与实验测量之间存在几个数量级的差异,使得这种计算在许多情况下毫无意义。我认为主要问题在于,费克梯度随时间变化的演化曲线在大多数情况下是一个理想假设,其斜率被大大高估了。本文深入探讨了三维情况下的菲克梯度问题,并提供了一种使用单分子扩散概率密度函数离散法的解决方案。
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引用次数: 0
Mathematical analysis of the Wiener processes with time-delayed feedback 具有延时反馈的维纳过程的数学分析
IF 1.6 4区 物理与天体物理 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-19 DOI: 10.1063/5.0209241
Miki U. Kobayashi, Kohta Takehara, Hiroyasu Ando, Michio Yamada
It is known that time delays generally make a system unstable. However, it is numerically observed that the diffusion coefficients of the Wiener processes with time-delayed feedback decrease while increasing the time delay τ. In particular, the decay of the diffusion coefficients with the form (11+τ)2 has been confirmed by numerical simulations [Ando et al., Phys. Rev. E 96, 012148 (2017)]. In this paper, we present two analytical derivations for the relation (11+τ)2 by dynamical system approaches using the Laplace transform and stochastic differential equations.
众所周知,时间延迟通常会导致系统不稳定。然而,从数值上可以观察到,具有时间延迟反馈的维纳过程的扩散系数会随着时间延迟τ的增加而减小。特别是,数值模拟已经证实了形式为(11+τ)2 的扩散系数的衰减[Ando 等人,Phys.在本文中,我们通过拉普拉斯变换和随机微分方程的动态系统方法,提出了 (11+τ)2 关系的两种分析推导。
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引用次数: 0
Numerical simulation and experimental study of the dynamic characteristics of a gas turbine rotor system with beam sea and head sea excitation 梁海和顶海激励下燃气轮机转子系统动态特性的数值模拟和实验研究
IF 1.6 4区 物理与天体物理 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-19 DOI: 10.1063/5.0220752
Xin Zhang, YongBao Liu, Qiang Wang, ZhiKai Xing, Mo Li
Vibration analysis is crucial for studying rotor dynamics. The gas turbine rotor system is subjected to complex alternating loads during navigation, resulting in vibrations transmitted to the bearings that alter the system’s dynamic characteristics. Based on the similarity law of the wave resistance test, a hull model was established. Beam sea and head sea tests were conducted in the towing pool to measure the acceleration response at the key positions. A finite element model of the turbine rotor system was established, and the test data were imported into the model after wavelet noise reduction and resampling to calculate the vibration response at the front and rear bearing points. The vibration responses transmitted to different locations and directions caused by beam sea and head sea conditions were analyzed. A comparison and analysis were conducted on the acceleration responses in various locations and directions under beam sea or head sea conditions. The equivalent von Mises stress distribution of the gas turbine rotor system under beam sea and head sea loads was obtained. The vibration transfer model was verified for accuracy and can be used to quickly analyze the vibration response of bearings under wave load transfer. This study provides a theoretical basis and reference for enhancing the stability of the gas turbine rotor system.
振动分析对于研究转子动力学至关重要。燃气轮机转子系统在航行过程中会受到复杂的交变载荷,导致振动传递到轴承,从而改变系统的动态特性。根据波浪阻力试验的相似律,建立了船体模型。在拖曳水池中进行了梁海和顶海试验,以测量关键位置的加速度响应。建立了涡轮转子系统的有限元模型,并将试验数据导入模型,经过小波降噪和重采样,计算出前后轴承点的振动响应。分析了梁海和顶海条件下传递到不同位置和方向的振动响应。对梁海和顶海条件下不同位置和方向的加速度响应进行了比较和分析。得到了燃气轮机转子系统在梁海和顶海载荷下的等效 von Mises 应力分布。振动传递模型的准确性得到了验证,可用于快速分析轴承在波浪载荷传递下的振动响应。该研究为提高燃气轮机转子系统的稳定性提供了理论依据和参考。
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引用次数: 0
Flexible and anisotropically conductive film by assembly of silicone rubber and cobalt-coated glass fiber composites 通过硅橡胶和钴涂层玻璃纤维复合材料的组装实现柔性和各向异性导电薄膜
IF 1.6 4区 物理与天体物理 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-18 DOI: 10.1063/5.0226566
Ruihua Zhou, Baoyu Tan, Hairu Li
In this study, we prepared electromagnetic cobalt-coated glass fiber (Co@GF) composites via an electroless plating method. Subsequently, a conductive sandwich flexible film consisting of Co@GF composites and liquid silicone rubber (RTV-2) was successfully formed using the tape casting method at room temperature. Based on the perfect coating and excellent electrical conductivity of the Co@GF composites, the resultant RTV-2/Co@GF/RTV-2 sandwich flexible film showed a low volume resistivity of 0.264 Ω·cm and could stretch to 100% (of 4.40 Ω·cm) without obvious fracture. When a magnetic field was applied during the curing process, the electromagnetic Co@GF composites were aligned automatically in the RTV-2 matrix because of their ferromagnetic nature. The as-prepared film exhibited anisotropy in its electrical performance. The volume resistivity parallel to the magnetic field direction is approximately two times lower than that in the perpendicular direction. The maximum difference in the volume resistivity (ρ∥ = 0.768 Ω·cm and ρ⊥ = 1.549 Ω·cm) was obtained at a magnetic field intensity of 800 mT. In addition, a magnetic field intensity of 100 mT helps improve the electrical conductivity of the as-obtained sandwich film. The anisotropic RTV-2/Co@GF/RTV-2 sandwich flexible film is considered a promising flexible electronic sensor, where discrepant inductive sensitivity is required in orthogonal directions.
在这项研究中,我们通过无电解电镀法制备了电磁钴涂层玻璃纤维(Co@GF)复合材料。随后,采用胶带浇注法在室温下成功形成了由 Co@GF 复合材料和液态硅橡胶(RTV-2)组成的导电夹层柔性薄膜。基于 Co@GF 复合材料完美的涂层和优异的导电性能,所制得的 RTV-2/Co@GF/RTV-2 夹层柔性薄膜的体积电阻率低至 0.264 Ω-cm,并且可以拉伸至 100% (4.40 Ω-cm)而无明显断裂。在固化过程中施加磁场时,电磁 Co@GF 复合材料会自动在 RTV-2 基体中排列,这是因为它们具有铁磁性。制备的薄膜在电气性能上表现出各向异性。平行于磁场方向的体积电阻率比垂直于磁场方向的体积电阻率低约两倍。在磁场强度为 800 mT 时,体积电阻率的差异最大(ρ∥ = 0.768 Ω-cm 和 ρ⊥ = 1.549 Ω-cm)。此外,100 mT 的磁场强度有助于提高夹层薄膜的导电性。各向异性的 RTV-2/Co@GF/RTV-2 夹层柔性薄膜被认为是一种很有前途的柔性电子传感器,在这种情况下,需要在正交方向上具有不同的感应灵敏度。
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引用次数: 0
First spectroscopic studies in the plasma-beam installation 等离子体束装置中的首次光谱研究
IF 1.6 4区 物理与天体物理 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-18 DOI: 10.1063/5.0224254
B. Chektybayev, S. Zhunisbek, Ye Kashikbayev, A. Duisen, I. Sokolov, T. Tulenbergenov
This paper presents the results of spectroscopic measurements of plasma in a linear simulator of a plasma-beam installation (PBI) for conducting materials science research. For the first time, non-contact optical diagnostic methods were employed to measure the plasma parameters in the PBI. These measurements were allowed for the clarification of the PBI plasma parameters and the identification of transition zones in different operational modes. Analysis of the plasma emission spectrum enabled the identification of impurity spectral lines and the estimation of key plasma parameters under varying experimental conditions. The spectra were recorded using two optical spectrometers covering a wavelength range of 200–800 nm. The experimental conditions varied in terms of electron beam accelerating voltage (1–5 kV), working gas pressure (1–6 mTorr), and target bias voltage (from −500 to −100 V). The Boltzmann plot method and Stark broadening of the Balmer lines were used to estimate electron temperature and density. Based on the obtained spectroscopic data, the electron density and the electron temperature were determined. The methods described in this study are applicable to linear plasma devices.
本文介绍了用于材料科学研究的等离子体束装置(PBI)线性模拟器中的等离子体光谱测量结果。这是首次采用非接触式光学诊断方法来测量 PBI 中的等离子体参数。通过这些测量,可以明确 PBI 的等离子参数,并确定不同运行模式下的过渡区。通过分析等离子体发射光谱,可以识别杂质谱线,并估算不同实验条件下的主要等离子体参数。光谱是使用两台波长范围为 200-800 纳米的光学光谱仪记录的。实验条件在电子束加速电压(1-5 kV)、工作气体压力(1-6 mTorr)和靶偏置电压(-500 至 -100 V)方面各不相同。利用玻尔兹曼图法和巴尔默线的斯塔克展宽来估算电子温度和密度。根据获得的光谱数据,确定了电子密度和电子温度。本研究中描述的方法适用于线性等离子体设备。
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引用次数: 0
Design and simulation of a Ka-band frequency doubling gyroklystron amplifier Ka 波段倍频陀螺回旋放大器的设计与仿真
IF 1.6 4区 物理与天体物理 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-18 DOI: 10.1063/5.0190157
Abhijeet Singh, Madan Singh Chauhan, Neelam Srivastava
The design methodology of a Ka-band frequency doubling two cavity gyroklystron has been discussed in this paper. In this study, the amplifier’s design and simulation are accomplished by employing nonlinear analysis and validated using particle-in-cell simulation techniques. The output cavity functions in the TE02 mode at two times the input signal frequency at the second harmonic of the cyclotron frequency, while the input cavity is powered by a 17.5 GHz source and functions in the TE01 mode at the first harmonic of the cyclotron resonance. The device’s performance has been examined both in the presence and in the absence of a beam. A number of factors were taken into account in order to optimize the interaction structure dimension to reach the device’s targeted performance. By adjusting the structural features and electron beam parameters, the device’s RF output power is assessed in an effort to increase efficiency. Simulation results estimate that the device displays a gain of 21.5 dB, an efficiency of 21.6%, a power of 227 kW, and a −3 dB bandwidth of ∼0.3%.
本文讨论了 Ka 波段倍频双腔陀螺回旋加速器的设计方法。在这项研究中,放大器的设计和仿真是通过非线性分析完成的,并利用粒子入胞仿真技术进行了验证。输出腔在回旋频率二次谐波上以两倍于输入信号频率的 TE02 模式工作,而输入腔由 17.5 GHz 信号源供电,在回旋共振的一次谐波上以 TE01 模式工作。该装置的性能在有光束和无光束的情况下都得到了检验。为了优化相互作用结构尺寸以达到装置的目标性能,我们考虑了许多因素。通过调整结构特征和电子束参数,对装置的射频输出功率进行了评估,以提高效率。模拟结果表明,该装置的增益为 21.5 dB,效率为 21.6%,功率为 227 kW,-3 dB 带宽为 0.3%。
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引用次数: 0
Decomposition characteristics and influencing mechanisms of C4F7N/CO2 gas with different metal materials C4F7N/CO2 气体与不同金属材料的分解特性及影响机理
IF 1.6 4区 物理与天体物理 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-18 DOI: 10.1063/5.0214100
Yuan Yang, Keli Gao, Hao Wang, Shuai Yuan, Jinchao Du, Yansong Ji, Dehui Fu, Yin Huang, Guangkai Cui
C4F7N/CO2 gas mixture, as the main new environmentally friendly gas insulation medium, is now being widely used in the ring network switchgear and other gas electrical equipment. In this paper, a test platform was constructed to simulate partial discharge in a gas medium, the decomposition characteristics of the C4F7N/CO2 gas mixture during suspended potential discharge were studied under four different metal electrode materials: stainless steel, purple copper, tungsten copper, and aluminum alloy. The results show that the main decomposition products of the C4F7N/CO2 gas mixture during suspended discharge are CO, CF4, C4F8, C3F8, C3F6, CF3CN, and C2F4 gases, which are independent of the metal material. On the whole, when the metal electrode material is stainless steel, the highest amount of decomposition products are generated from the C4F7N/CO2 gas mixture; when the metal electrode material is aluminum alloy, the amount of decomposition products produced by C4F7N/CO2 gas mixture is the least, and the content difference of some decomposition products between these two metal materials is as high as 70%. The decomposition products of the C4F7N/CO2 gas mixture decreased gradually with the increase in the gas pressure. Finally, the influence mechanism of different metal materials on the decomposition process of the C4F7N/CO2 gas mixture was analyzed from the microscopic perspectives of charge transfer between gas molecules and molecular structural characteristics. In general, the research results can provide technical reference for the design, selection, and optimization of environmental protection gas insulation equipment.
C4F7N/CO2 混合气体作为主要的新型环保气体绝缘介质,目前已广泛应用于环网开关柜等气体电气设备中。本文搭建了模拟气体介质局部放电的试验平台,研究了 C4F7N/CO2 混合气体在不锈钢、紫铜、钨铜和铝合金四种不同金属电极材料下悬浮电位放电时的分解特性。结果表明,在悬浮放电过程中,C4F7N/CO2 混合气体的主要分解产物是 CO、CF4、C4F8、C3F8、C3F6、CF3CN 和 C2F4 气体,它们与金属材料无关。总体而言,当金属电极材料为不锈钢时,C4F7N/CO2 混合气体产生的分解产物量最高;当金属电极材料为铝合金时,C4F7N/CO2 混合气体产生的分解产物量最少,两种金属材料之间某些分解产物的含量差异高达 70%。随着气体压力的增加,C4F7N/CO2 混合气体的分解产物逐渐减少。最后,从气体分子间电荷转移和分子结构特征等微观角度分析了不同金属材料对 C4F7N/CO2 混合气体分解过程的影响机理。总之,研究成果可为环保气体保温设备的设计、选型和优化提供技术参考。
{"title":"Decomposition characteristics and influencing mechanisms of C4F7N/CO2 gas with different metal materials","authors":"Yuan Yang, Keli Gao, Hao Wang, Shuai Yuan, Jinchao Du, Yansong Ji, Dehui Fu, Yin Huang, Guangkai Cui","doi":"10.1063/5.0214100","DOIUrl":"https://doi.org/10.1063/5.0214100","url":null,"abstract":"C4F7N/CO2 gas mixture, as the main new environmentally friendly gas insulation medium, is now being widely used in the ring network switchgear and other gas electrical equipment. In this paper, a test platform was constructed to simulate partial discharge in a gas medium, the decomposition characteristics of the C4F7N/CO2 gas mixture during suspended potential discharge were studied under four different metal electrode materials: stainless steel, purple copper, tungsten copper, and aluminum alloy. The results show that the main decomposition products of the C4F7N/CO2 gas mixture during suspended discharge are CO, CF4, C4F8, C3F8, C3F6, CF3CN, and C2F4 gases, which are independent of the metal material. On the whole, when the metal electrode material is stainless steel, the highest amount of decomposition products are generated from the C4F7N/CO2 gas mixture; when the metal electrode material is aluminum alloy, the amount of decomposition products produced by C4F7N/CO2 gas mixture is the least, and the content difference of some decomposition products between these two metal materials is as high as 70%. The decomposition products of the C4F7N/CO2 gas mixture decreased gradually with the increase in the gas pressure. Finally, the influence mechanism of different metal materials on the decomposition process of the C4F7N/CO2 gas mixture was analyzed from the microscopic perspectives of charge transfer between gas molecules and molecular structural characteristics. In general, the research results can provide technical reference for the design, selection, and optimization of environmental protection gas insulation equipment.","PeriodicalId":7619,"journal":{"name":"AIP Advances","volume":"192 1","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142252446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bridgeless modified Cuk–SEPIC power factor correction converter for E-bicycle applications 用于电动自行车应用的无桥改进型 Cuk-SEPIC 功率因数校正转换器
IF 1.6 4区 物理与天体物理 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-18 DOI: 10.1063/5.0229333
Shunmathi M., Julius Fusic S., Shanmugavel Rajesh, Jayant Giri, Sathish T., Abdullah Alarifi, S. M. Mozammil Hasnain
The focus of this scope is on the single phase Cuk and SEPIC power factor correction converter that is attractive to electric bicycle applications. In order to guarantee improved performance, the proposed modified converter is designed to operate in discontinuous conduction mode, which is hidden by changes in supply and load voltage. For rated load, the investigational study achieves reduced input line total harmonic distortion and unity power factor. Line regulation, high efficiency, and load regulation are achieved by means of a closed loop PI control circuit that has a voltage sensor and current loop. The power supply is simulated using MATLAB/Simulink under various operating conditions, and the designed system is validated using a 250 W hardware prototype. The input current is observed to be perfectly sinusoidal, and the IEC 61000-3-2 class A standard is followed in recording the total harmonic distortion of the mains current.
本研究的重点是对电动自行车应用具有吸引力的单相 Cuk 和 SEPIC 功率因数校正转换器。为了保证性能的提高,所提出的改进型转换器被设计为在不连续传导模式下运行,这种模式不受电源和负载电压变化的影响。在额定负载情况下,调查研究降低了输入线路总谐波失真和功率因数。线路调节、高效率和负载调节是通过具有电压传感器和电流环路的闭环 PI 控制电路实现的。使用 MATLAB/Simulink 对各种工作条件下的电源进行了仿真,并使用 250 W 硬件原型对所设计的系统进行了验证。观察到输入电流为完全正弦波,并按照 IEC 61000-3-2 A 级标准记录了电源电流的总谐波失真。
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引用次数: 0
Leakage current in GaN-on-GaN vertical GaN SBDs grown by HVPE on native GaN substrates 在原生氮化镓衬底上通过 HVPE 生长的氮化镓基垂直氮化镓 SBD 中的泄漏电流
IF 1.6 4区 物理与天体物理 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-17 DOI: 10.1063/5.0208706
Weiyi Jin, Yumin Zhang, Songyuan Xia, Qizhi Zhu, Yuanhang Sun, Juemin Yi, Jianfeng Wang, Ke Xu
This study investigates leakage mechanisms in vertical GaN-on-GaN Schottky barrier diodes (SBDs) and demonstrates effective mitigation strategies. The fabricated devices exhibit low reverse leakage current (1 × 10−5 A/cm2 at −200 V) and a high Ion/Ioff ratio (∼1010), surpassing the performance of GaN SBDs on foreign substrates. We elucidate dominant leakage mechanisms—thermionic emission, Poole–Frenkel emission, and variable-range hopping—and their evolution with temperature and bias. Optimized fabrication processes, including defect etching and a novel dual-layer passivation technique, achieve over a 1000-fold reduction in leakage current.
本研究调查了垂直氮化镓-氮化镓肖特基势垒二极管(SBD)的漏电机制,并展示了有效的缓解策略。所制备的器件具有较低的反向漏电流(-200 V 时为 1 × 10-5 A/cm2 )和较高的离子/关断比(∼1010),其性能超过了国外衬底上的 GaN SBD。我们阐明了主要的漏电机制--热离子发射、普尔-弗伦克尔发射和变程跳变--及其随温度和偏压的演变。优化的制造工艺(包括缺陷蚀刻和新型双层钝化技术)使漏电流降低了 1000 多倍。
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引用次数: 0
Differences in microstructure and properties of Ti-based amorphous composites between recrystallization and partial remelting and semi-solid isothermal treatment 再结晶和部分重熔与半固态等温处理之间钛基无定形复合材料微观结构和性能的差异
IF 1.6 4区 物理与天体物理 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-17 DOI: 10.1063/5.0226545
Xin-hua Huang, Jin-heng Chen, Yu-huai Wang, Yong-xin Luo, Yue-jun Ouyang
The as-cast specimens of Ti48Zr18V12Cu5Be17 amorphous composites were prepared by copper mold suction casting. Next, the as-cast specimens were treated using semi-solid isothermal treatment (SSIT) and recrystallization and partial remelting (RAP). The effects of SSIT and RAP on the microstructure and plasticity were analyzed. The results showed that the microstructure changed from fine crystals in the as-cast specimens to coarse bar crystals and near-spherical crystals in the SSIT and RAP specimens, respectively. The crystals of RAP specimens were finer and rounder than those of SSIT specimens due to recrystallization. In addition, the RAP specimens had high plasticity (20.93%), which is 428.5% and 45.2% higher than the as-cast and SSIT specimens, respectively. By observing the shear bands of the fractured specimens, it was found that the expansion of shear bands could not be impeded by the fine β-Ti crystals in the as-cast specimens, leading to an infinite extension that induces brittle fracture in the specimens. The essential cause of the poor plasticity of the as-cast specimens was revealed. In addition, the coarse β-Ti crystals effectively blocked the shear band expansion in the SSIT specimens, and a large number of shear bands were generated in these crystals. In contrast, the crystals of the RAP specimens had a greater number and density of shear bands compared to those of the SSIT specimens, and these shear bands intersected with each other in different directions. This revealed the mechanism by which the SSIT and RAP methods enhance the plasticity of amorphous composites.
Ti48Zr18V12Cu5Be17 非晶态复合材料的铸件试样是通过铜模吸铸法制备的。然后,使用半固态等温处理(SSIT)和再结晶与部分重熔(RAP)对无定形铸造试样进行处理。分析了 SSIT 和 RAP 对微观结构和塑性的影响。结果表明,在 SSIT 和 RAP 试样中,微观结构分别从原样浇铸试样中的细小晶体转变为粗棒状晶体和近球形晶体。由于再结晶,RAP 试样的晶体比 SSIT 试样的晶体更细、更圆。此外,RAP 试样具有较高的塑性(20.93%),分别比原样浇铸试样和 SSIT 试样高出 428.5% 和 45.2%。通过观察断裂试样的剪切带可以发现,在原样浇铸的试样中,β-钛的细小晶体无法阻碍剪切带的扩展,导致剪切带无限扩展,从而诱发试样脆性断裂。这就揭示了现浇试样塑性差的根本原因。此外,粗大的 β-Ti 晶体有效阻止了 SSIT 试样中剪切带的扩展,并在这些晶体中产生了大量剪切带。相反,与 SSIT 试样相比,RAP 试样晶体中剪切带的数量和密度更大,而且这些剪切带在不同方向上相互交叉。这揭示了 SSIT 和 RAP 方法增强无定形复合材料塑性的机理。
{"title":"Differences in microstructure and properties of Ti-based amorphous composites between recrystallization and partial remelting and semi-solid isothermal treatment","authors":"Xin-hua Huang, Jin-heng Chen, Yu-huai Wang, Yong-xin Luo, Yue-jun Ouyang","doi":"10.1063/5.0226545","DOIUrl":"https://doi.org/10.1063/5.0226545","url":null,"abstract":"The as-cast specimens of Ti48Zr18V12Cu5Be17 amorphous composites were prepared by copper mold suction casting. Next, the as-cast specimens were treated using semi-solid isothermal treatment (SSIT) and recrystallization and partial remelting (RAP). The effects of SSIT and RAP on the microstructure and plasticity were analyzed. The results showed that the microstructure changed from fine crystals in the as-cast specimens to coarse bar crystals and near-spherical crystals in the SSIT and RAP specimens, respectively. The crystals of RAP specimens were finer and rounder than those of SSIT specimens due to recrystallization. In addition, the RAP specimens had high plasticity (20.93%), which is 428.5% and 45.2% higher than the as-cast and SSIT specimens, respectively. By observing the shear bands of the fractured specimens, it was found that the expansion of shear bands could not be impeded by the fine β-Ti crystals in the as-cast specimens, leading to an infinite extension that induces brittle fracture in the specimens. The essential cause of the poor plasticity of the as-cast specimens was revealed. In addition, the coarse β-Ti crystals effectively blocked the shear band expansion in the SSIT specimens, and a large number of shear bands were generated in these crystals. In contrast, the crystals of the RAP specimens had a greater number and density of shear bands compared to those of the SSIT specimens, and these shear bands intersected with each other in different directions. This revealed the mechanism by which the SSIT and RAP methods enhance the plasticity of amorphous composites.","PeriodicalId":7619,"journal":{"name":"AIP Advances","volume":"65 1","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142252449","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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