Pub Date : 2023-01-01DOI: 10.3934/matersci.2023031
Alaa Ebrahiem, S. S. Ibrahim, Ahmed M El-Khaib, A. Doma
This research studies the effect of borax on the thermal stability and thermal kinetic behavior of ethylene-propylene-diene (EPDM) rubber composites. Using a laboratory two-roll mill at room temperature, carbon-black (N-220) as filler, and other additives such as zinc oxide, stearic acid, and paraffin oil were incorporated into the EPDM rubber matrix. The composite was prepared at different borax concentrations (25 and 50 phr). Thermogravimetric analysis was performed to characterize borax's effect onthermal stability before and after borax addition. Added borax to the host composite rubber (EPDM composite without borax) significantly improved the composite's thermal stability. Borax-loaded composites behave differently at various temperatures. To investigate the kinetic-thermal analysis of the prepared samples, three different models were applied. The activation energy (Ea) and frequency factors (A) for the Horowitz-Metzger, Broido and Coats-Redfern models were calculated. These models were compared and discussed based on their results. First-order decomposition also represented the main decomposition stage. Kraus and Cunnen-Russel models were used to test the interaction between rubber and borax based on previously published swelling results. No interaction was found between rubber and borax.
{"title":"Ethylene-propylene-diene (EPDM) rubber/borax composite: kinetic thermal studies","authors":"Alaa Ebrahiem, S. S. Ibrahim, Ahmed M El-Khaib, A. Doma","doi":"10.3934/matersci.2023031","DOIUrl":"https://doi.org/10.3934/matersci.2023031","url":null,"abstract":"This research studies the effect of borax on the thermal stability and thermal kinetic behavior of ethylene-propylene-diene (EPDM) rubber composites. Using a laboratory two-roll mill at room temperature, carbon-black (N-220) as filler, and other additives such as zinc oxide, stearic acid, and paraffin oil were incorporated into the EPDM rubber matrix. The composite was prepared at different borax concentrations (25 and 50 phr). Thermogravimetric analysis was performed to characterize borax's effect onthermal stability before and after borax addition. Added borax to the host composite rubber (EPDM composite without borax) significantly improved the composite's thermal stability. Borax-loaded composites behave differently at various temperatures. To investigate the kinetic-thermal analysis of the prepared samples, three different models were applied. The activation energy (Ea) and frequency factors (A) for the Horowitz-Metzger, Broido and Coats-Redfern models were calculated. These models were compared and discussed based on their results. First-order decomposition also represented the main decomposition stage. Kraus and Cunnen-Russel models were used to test the interaction between rubber and borax based on previously published swelling results. No interaction was found between rubber and borax.","PeriodicalId":7670,"journal":{"name":"AIMS Materials Science","volume":"1 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70090478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.3934/matersci.2023051
Sergey V. Belim
This article describes ordering in a 2D ferromagnetic nanoparticles array by computer simulation. The Heisenberg model simulates the behavior of spins in nanoparticles. Nanoparticles interact using dipole-dipole forces. Computer simulations use the Monte Carlo method and Metropolis algorithm. Two possible types of ordering for the nanoparticles' magnetic moments are detected in the system. The magnetic anisotropy direction for the nanoparticles determines the type of ordering. If the anisotropy direction is oriented perpendicular to the substrate plane, then a superantiferromagnetic phase with staggered magnetization is realized. If the magnetic anisotropy is oriented in the nanoparticle plane, the superantiferromagnetic phase has a different structure. The nanoparticle array is broken into chains parallel to the anisotropy orientations. In one chain of nanoparticles, magnetic moments are oriented in the same way. The magnetic moments of the nanoparticles are oriented oppositely in neighbor chains. The temperature of phase transitions is calculated based on finite dimensional scaling theory. Temperature depends linearly on the intensity of the dipole-dipole interaction for both types of superantiferromagnetic transition.
{"title":"Study of ordering in 2D ferromagnetic nanoparticles arrays: Computer simulation","authors":"Sergey V. Belim","doi":"10.3934/matersci.2023051","DOIUrl":"https://doi.org/10.3934/matersci.2023051","url":null,"abstract":"<abstract> <p>This article describes ordering in a 2D ferromagnetic nanoparticles array by computer simulation. The Heisenberg model simulates the behavior of spins in nanoparticles. Nanoparticles interact using dipole-dipole forces. Computer simulations use the Monte Carlo method and Metropolis algorithm. Two possible types of ordering for the nanoparticles' magnetic moments are detected in the system. The magnetic anisotropy direction for the nanoparticles determines the type of ordering. If the anisotropy direction is oriented perpendicular to the substrate plane, then a superantiferromagnetic phase with staggered magnetization is realized. If the magnetic anisotropy is oriented in the nanoparticle plane, the superantiferromagnetic phase has a different structure. The nanoparticle array is broken into chains parallel to the anisotropy orientations. In one chain of nanoparticles, magnetic moments are oriented in the same way. The magnetic moments of the nanoparticles are oriented oppositely in neighbor chains. The temperature of phase transitions is calculated based on finite dimensional scaling theory. Temperature depends linearly on the intensity of the dipole-dipole interaction for both types of superantiferromagnetic transition.</p> </abstract>","PeriodicalId":7670,"journal":{"name":"AIMS Materials Science","volume":"43 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134884662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.3934/matersci.2023021
G. Golewski
This paper introduced a new concrete composites made by quaternary binder by partially replacing ordinary Portland cement (OPC) with different percentages of supplementary cementitious materials (SCMs). The motivation is to reduce our dependency on OPC to reduce CO2 emission and carbon foot print. As the main substitute for the OPC, siliceous fly ash was used (FA). Moreover, silica fume (SF) and nanosilica (nS) were also used. This study utilized the following contents of SCMs used: 5% of nS; 10% of SF; 0, 15, and 25% of FA. During examinations the main mechanical properties of concrete composites, i.e. compressive strength (fcm) and splitting tensile strength (fctm) were assed. The brittleness of these materials was also analysed. Based on the conducted studies, it was found that concrete composite based on quaternary blended cements, of series Mix3, has shown the best results in terms of good strength parameters, whereas the worst mechanical parameters were characterized by concrete of series Mix4. On the other hand, concrete including only SF and nS (Mix2 series) were characterized by the greatest brittleness. It was observed that fcm of concrete composites for series Mix2, Mix3, and Mix4 increase of 41%, 48%, and 31% respectively compared with the concrete without additives, i.e. series Mix1. In addition, fctm also increase of 39%, 47%, and 30%, respectively, for the three series mentioned above, compared with the control concrete. Concrete of series Mix3, with high mechanical properties and demonstrating the features of quasi-plastic material, i.e. having lower brittleness, can be used in concrete and reinforced concrete structures subjected mainly to dynamic and cyclic loads. Therefore, it can be used, in the construction of foundation structures for machines and other types of structures in which the above-mentioned loads are dominant.
{"title":"Mechanical properties and brittleness of concrete made by combined fly ash, silica fume and nanosilica with ordinary Portland cement","authors":"G. Golewski","doi":"10.3934/matersci.2023021","DOIUrl":"https://doi.org/10.3934/matersci.2023021","url":null,"abstract":"This paper introduced a new concrete composites made by quaternary binder by partially replacing ordinary Portland cement (OPC) with different percentages of supplementary cementitious materials (SCMs). The motivation is to reduce our dependency on OPC to reduce CO2 emission and carbon foot print. As the main substitute for the OPC, siliceous fly ash was used (FA). Moreover, silica fume (SF) and nanosilica (nS) were also used. This study utilized the following contents of SCMs used: 5% of nS; 10% of SF; 0, 15, and 25% of FA. During examinations the main mechanical properties of concrete composites, i.e. compressive strength (fcm) and splitting tensile strength (fctm) were assed. The brittleness of these materials was also analysed. Based on the conducted studies, it was found that concrete composite based on quaternary blended cements, of series Mix3, has shown the best results in terms of good strength parameters, whereas the worst mechanical parameters were characterized by concrete of series Mix4. On the other hand, concrete including only SF and nS (Mix2 series) were characterized by the greatest brittleness. It was observed that fcm of concrete composites for series Mix2, Mix3, and Mix4 increase of 41%, 48%, and 31% respectively compared with the concrete without additives, i.e. series Mix1. In addition, fctm also increase of 39%, 47%, and 30%, respectively, for the three series mentioned above, compared with the control concrete. Concrete of series Mix3, with high mechanical properties and demonstrating the features of quasi-plastic material, i.e. having lower brittleness, can be used in concrete and reinforced concrete structures subjected mainly to dynamic and cyclic loads. Therefore, it can be used, in the construction of foundation structures for machines and other types of structures in which the above-mentioned loads are dominant.","PeriodicalId":7670,"journal":{"name":"AIMS Materials Science","volume":"1 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70090132","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.3934/matersci.2023027
B. Zaidi, M. Althobaiti, Nejmeddine Smida
A simple mechanical dispersion method was used to elaborate new nanocomposite from the combination of single walled carbon nanotubes (SWCNTs) and polyvinylcarbazole (PVK) polymer. The obtained samples were annealed at the moderate temperature of 333 K to achieve good dispersion and inhibit phase separation. Force constants calculations using Density Functional theory were correlated with FTIR measurements to support the interaction between both components. Raman scattering was used to check the dispersion state of SWCNTs on the PVK polymer. Optical absorption analysis and stationary photoluminescence and time resolved photoluminescence technics have been used to elucidate the change of optical properties after SWCNTs adding. The formation of bulk nano-hetero-junction resulting from the extended interfaces, leading to efficient dissociation of the charge pairs was shown by quenching effects in polymer photoluminescence when increasing SWCNTS contents. A noticeable decrease of the life time is observed by time resolved photoluminescence, which reflects the shortness of diffusion pathways and consequently an improvement of the electron transfer.
{"title":"Experimental and computational investigations of structural and photoluminescence properties of PVK/SWCNTs nanocomposites","authors":"B. Zaidi, M. Althobaiti, Nejmeddine Smida","doi":"10.3934/matersci.2023027","DOIUrl":"https://doi.org/10.3934/matersci.2023027","url":null,"abstract":"A simple mechanical dispersion method was used to elaborate new nanocomposite from the combination of single walled carbon nanotubes (SWCNTs) and polyvinylcarbazole (PVK) polymer. The obtained samples were annealed at the moderate temperature of 333 K to achieve good dispersion and inhibit phase separation. Force constants calculations using Density Functional theory were correlated with FTIR measurements to support the interaction between both components. Raman scattering was used to check the dispersion state of SWCNTs on the PVK polymer. Optical absorption analysis and stationary photoluminescence and time resolved photoluminescence technics have been used to elucidate the change of optical properties after SWCNTs adding. The formation of bulk nano-hetero-junction resulting from the extended interfaces, leading to efficient dissociation of the charge pairs was shown by quenching effects in polymer photoluminescence when increasing SWCNTS contents. A noticeable decrease of the life time is observed by time resolved photoluminescence, which reflects the shortness of diffusion pathways and consequently an improvement of the electron transfer.","PeriodicalId":7670,"journal":{"name":"AIMS Materials Science","volume":"1 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70090159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.3934/matersci.2023036
Hyungkwon Park, Y. Jeong, Jinjong Lee, Chang-Hoon Lee, B. Goo, Yonghee Kim
The failure of galvannealed (GA) coatings during press forming is an important issue for steel companies, because it results in a deteriorated product quality and reduced productivity. Powdering and flaking are thought to be the main failure modes in GA steel. However, these two modes currently lack a clear distinction, despite their different failure types. Therefore, in this study, we demonstrate that the different behaviors of these two failure modes are generated by the skin pass mill (SPM) condition and we discuss the underlying mechanism in detail using microstructural and simulation analyses. With the increase in steel elongation from 0% to 4.0% under milling force from 0 to 6 ton, a high compressive stress is produced up to −380 MPa on the surface of the steel sheet and the interface is correspondingly flattened from 0.96 to 0.53 m in Ra. This flattening weakens the mechanical interlocking effect for adhesive bonding, deteriorating the flaking resistance from 41.1 to 65.2 hat-bead contrast index (hci). In addition, the GA coating layer becomes uniformly densified via the filling of pores under compressive stress in the layer. Furthermore, the ζ phase exhibits significant plastic deformation, leading to a uniform coverage of the coating surface; this helps to suppress crack propagation. Accordingly, the powdering resistance gradually improves from 4.2 to 3.5 mm. Consequently, with the increase in SPM-realized steel sheet elongation, the powdering resistance improves whilst the flaking resistance deteriorates. Significantly for the literature, this implies that the two failure modes occur via different mechanisms and it indicates the possibility of controlling the two coating failure modes via the SPM conditions.
{"title":"Conflicting behavior between powdering and flaking resistance under skin pass mill process in galvannealed interstitial free steel","authors":"Hyungkwon Park, Y. Jeong, Jinjong Lee, Chang-Hoon Lee, B. Goo, Yonghee Kim","doi":"10.3934/matersci.2023036","DOIUrl":"https://doi.org/10.3934/matersci.2023036","url":null,"abstract":"The failure of galvannealed (GA) coatings during press forming is an important issue for steel companies, because it results in a deteriorated product quality and reduced productivity. Powdering and flaking are thought to be the main failure modes in GA steel. However, these two modes currently lack a clear distinction, despite their different failure types. Therefore, in this study, we demonstrate that the different behaviors of these two failure modes are generated by the skin pass mill (SPM) condition and we discuss the underlying mechanism in detail using microstructural and simulation analyses. With the increase in steel elongation from 0% to 4.0% under milling force from 0 to 6 ton, a high compressive stress is produced up to −380 MPa on the surface of the steel sheet and the interface is correspondingly flattened from 0.96 to 0.53 m in Ra. This flattening weakens the mechanical interlocking effect for adhesive bonding, deteriorating the flaking resistance from 41.1 to 65.2 hat-bead contrast index (hci). In addition, the GA coating layer becomes uniformly densified via the filling of pores under compressive stress in the layer. Furthermore, the ζ phase exhibits significant plastic deformation, leading to a uniform coverage of the coating surface; this helps to suppress crack propagation. Accordingly, the powdering resistance gradually improves from 4.2 to 3.5 mm. Consequently, with the increase in SPM-realized steel sheet elongation, the powdering resistance improves whilst the flaking resistance deteriorates. Significantly for the literature, this implies that the two failure modes occur via different mechanisms and it indicates the possibility of controlling the two coating failure modes via the SPM conditions.","PeriodicalId":7670,"journal":{"name":"AIMS Materials Science","volume":"9 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70090648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.3934/matersci.2023039
Itsh'ak Azoulay, Ory Klonsky, Y. Gelbstein, P. Beker
Diamond offers great promise as a solution to some of the limitations of current state of the art semiconductor technologies. Yet, significant challenges associated with the doping process remain a primary impediment to the development of diamond-based electronic devices. At present, it is unclear which simple measurement methods are needed to evaluate the diamond doping process. We propose non-destructive inspection methods for evaluating the polycrystalline chemical vapor deposition (CVD) diamond doping process, by analyzing the wettability, optical absorption, photoluminescence emission spectroscopy and atmospheric scanning electron microscope (Air-SEM) tests. Our results show that the properties of the measured samples are distinctly changed due to the presence of the doping elements, thereby confirming the effectiveness of these non-destructive methods for the diamond production industry.
{"title":"A study of doped polycrystalline diamond plates by non-destructive methods","authors":"Itsh'ak Azoulay, Ory Klonsky, Y. Gelbstein, P. Beker","doi":"10.3934/matersci.2023039","DOIUrl":"https://doi.org/10.3934/matersci.2023039","url":null,"abstract":"Diamond offers great promise as a solution to some of the limitations of current state of the art semiconductor technologies. Yet, significant challenges associated with the doping process remain a primary impediment to the development of diamond-based electronic devices. At present, it is unclear which simple measurement methods are needed to evaluate the diamond doping process. We propose non-destructive inspection methods for evaluating the polycrystalline chemical vapor deposition (CVD) diamond doping process, by analyzing the wettability, optical absorption, photoluminescence emission spectroscopy and atmospheric scanning electron microscope (Air-SEM) tests. Our results show that the properties of the measured samples are distinctly changed due to the presence of the doping elements, thereby confirming the effectiveness of these non-destructive methods for the diamond production industry.","PeriodicalId":7670,"journal":{"name":"AIMS Materials Science","volume":"1 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70090776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.3934/matersci.2023052
Gennaro Gelao, Roberto Marani, Anna Gina Perri
In this letter we present a current mode gate based on differential pair as an application of carbon nanotube field effect transistors (CNTFETs). The proposed circuit has two output logic gates: one is NAND, and the other is AND. To simplify the circuit realization we use all CNTFETs of the same type, all with the same lengths and carbon nanotube symmetry indices (n, m). Complex circuits could be obtained in current mode replicating the differential pair CNTFET along the current path. The proposed procedure allows simulation of transfer characteristics from voltage input to current output but also from voltage input to voltage output. Moreover, we can measure simulated power dissipation and delay times.
{"title":"Analysis and design of current mode logic based on CNTFET","authors":"Gennaro Gelao, Roberto Marani, Anna Gina Perri","doi":"10.3934/matersci.2023052","DOIUrl":"https://doi.org/10.3934/matersci.2023052","url":null,"abstract":"<abstract> <p>In this letter we present a current mode gate based on differential pair as an application of carbon nanotube field effect transistors (CNTFETs). The proposed circuit has two output logic gates: one is NAND, and the other is AND. To simplify the circuit realization we use all CNTFETs of the same type, all with the same lengths and carbon nanotube symmetry indices (n, m). Complex circuits could be obtained in current mode replicating the differential pair CNTFET along the current path. The proposed procedure allows simulation of transfer characteristics from voltage input to current output but also from voltage input to voltage output. Moreover, we can measure simulated power dissipation and delay times.</p> </abstract>","PeriodicalId":7670,"journal":{"name":"AIMS Materials Science","volume":"19 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135213075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.3934/matersci.2023022
Pravina Kamini, K. Tee, J. Gimbun, S. C. Chin
Ordinary Portland Cement (OPC) is a crucial building component and a valuable strategic resource. The production of cement accounts for 5% to 10% of global carbon dioxide (CO2) emissions. Over the years, many researchers have been studying ways to reduce the amount of CO2 in the atmosphere caused by cement production. Due to its properties, biochar is found to be an interesting material to be utilised in the construction industry due to its effectiveness in CO2 sequestration. Biochar is a solid residue created by the thermal breakdown of biomass at moderate temperatures (350–700 ℃) without oxygen or with a small amount of oxygen, sometimes known as bio-carbon. Biochar has a wide range of uses, including those for heating and electricity generation, cleaning flue gases, metallurgy, animal husbandry, agriculture, construction materials, and even medicine. The objective of this paper is to review the potential of biochar as a cementitious material by evaluating its physical, chemical, mechanical, and durability properties. Using biochar as a cementitious material makes it possible to conclude that cement production will be reduced over time by partial replacement, which will also promote and encourage sustainable development in the future.
{"title":"Biochar in cementitious material—A review on physical, chemical, mechanical, and durability properties","authors":"Pravina Kamini, K. Tee, J. Gimbun, S. C. Chin","doi":"10.3934/matersci.2023022","DOIUrl":"https://doi.org/10.3934/matersci.2023022","url":null,"abstract":"Ordinary Portland Cement (OPC) is a crucial building component and a valuable strategic resource. The production of cement accounts for 5% to 10% of global carbon dioxide (CO2) emissions. Over the years, many researchers have been studying ways to reduce the amount of CO2 in the atmosphere caused by cement production. Due to its properties, biochar is found to be an interesting material to be utilised in the construction industry due to its effectiveness in CO2 sequestration. Biochar is a solid residue created by the thermal breakdown of biomass at moderate temperatures (350–700 ℃) without oxygen or with a small amount of oxygen, sometimes known as bio-carbon. Biochar has a wide range of uses, including those for heating and electricity generation, cleaning flue gases, metallurgy, animal husbandry, agriculture, construction materials, and even medicine. The objective of this paper is to review the potential of biochar as a cementitious material by evaluating its physical, chemical, mechanical, and durability properties. Using biochar as a cementitious material makes it possible to conclude that cement production will be reduced over time by partial replacement, which will also promote and encourage sustainable development in the future.","PeriodicalId":7670,"journal":{"name":"AIMS Materials Science","volume":"1 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70090201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.3934/matersci.2023037
G. El-Awadi
The status of current advances in modifying surfaces for the protection of materials is reviewed in this research. The main goal of material selection is to improve and reinforce surface functionalities. A few examples of surface modification techniques include sol-gel, cladding, electroplating, plasma and thermal spraying, physical deposition of vapors (PVD), vapor chemical deposition (CVD) and beam electron physical vapor deposition (EB-PVD). Strengthening by flame, induction, laser or electron beam is one type of surface modification procedure. Other types include plasma-immersed ion implantation and ion implantation at high energies, as well as diffusion treatments like carburizing and nitriding. Friction control, improved surface corrosion and wear resistance and changes to a component's mechanical or physical qualities are all possible using surface modification methods. The study also contains contemporary research in laser therapy, PVD, EB-PVD, thermal spraying and ion implantation. Additionally, magnetron sputtering (MS) is a widely used and successful approach for thin film coating in the current study. It is crucial to remember that each approach has a distinct set of restrictions, and the method's parameters might change based on the one that is selected, such as deposition targets, overall vacuum substrate temperature, reactive or mixed gas type, pressure percentage and bias voltage, which all have impacts on the PVD technique's layer qualities. Phase formation, change in phase, hardness and film structure of monolayer and multilayer films formed on the substrate under various circumstances also cause variations in the characteristics. Additionally, ion implantation enhances the surface characteristics of layers by implanting ions such as N+, B+, C+, etc. The study shows that the higher layers of multilayer enhance the degree of hardness and lower friction coefficients. To enhance the protection of thermal resistance, a thermal spraying barrier coating was coated on substrate nickel-base alloys, and the surface materials' texture, hardness and wear rate were altered by laser beam. Additionally, a heat pipe's performance was improved by a factor of 300 by adding a tiny coating of gold.
{"title":"Review of effective techniques for surface engineering material modification for a variety of applications","authors":"G. El-Awadi","doi":"10.3934/matersci.2023037","DOIUrl":"https://doi.org/10.3934/matersci.2023037","url":null,"abstract":"The status of current advances in modifying surfaces for the protection of materials is reviewed in this research. The main goal of material selection is to improve and reinforce surface functionalities. A few examples of surface modification techniques include sol-gel, cladding, electroplating, plasma and thermal spraying, physical deposition of vapors (PVD), vapor chemical deposition (CVD) and beam electron physical vapor deposition (EB-PVD). Strengthening by flame, induction, laser or electron beam is one type of surface modification procedure. Other types include plasma-immersed ion implantation and ion implantation at high energies, as well as diffusion treatments like carburizing and nitriding. Friction control, improved surface corrosion and wear resistance and changes to a component's mechanical or physical qualities are all possible using surface modification methods. The study also contains contemporary research in laser therapy, PVD, EB-PVD, thermal spraying and ion implantation. Additionally, magnetron sputtering (MS) is a widely used and successful approach for thin film coating in the current study. It is crucial to remember that each approach has a distinct set of restrictions, and the method's parameters might change based on the one that is selected, such as deposition targets, overall vacuum substrate temperature, reactive or mixed gas type, pressure percentage and bias voltage, which all have impacts on the PVD technique's layer qualities. Phase formation, change in phase, hardness and film structure of monolayer and multilayer films formed on the substrate under various circumstances also cause variations in the characteristics. Additionally, ion implantation enhances the surface characteristics of layers by implanting ions such as N+, B+, C+, etc. The study shows that the higher layers of multilayer enhance the degree of hardness and lower friction coefficients. To enhance the protection of thermal resistance, a thermal spraying barrier coating was coated on substrate nickel-base alloys, and the surface materials' texture, hardness and wear rate were altered by laser beam. Additionally, a heat pipe's performance was improved by a factor of 300 by adding a tiny coating of gold.","PeriodicalId":7670,"journal":{"name":"AIMS Materials Science","volume":"1 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70090705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.3934/matersci.2023010
Jaafar Sh. AbdulRazaq, A. F. Hassan, Nuha H. Jasim
A functionally graded material (FGM) was prepared using epoxy resin reinforced with silicon dioxide with a particle size of 100 μm and weight percentages of 0, 20, 40, 60, and 80 wt%. In a gravity-molding process using the hand layup technique, specimens with international standard (ASTM)-calculated dimensions were created in a mold of poly(methyl methacrylate), which is also known as acrylic. Tensile, flexural, impact, infrared wave, and thermal conductivity tests, and X-ray diffraction (XRD) were conducted on specimens of the five layers of the FGM. The XRD and infrared spectroscopy demonstrated that the compositions of the silica particles and epoxy had a strong association with their physical structures. The findings of experimental tests indicated that increasing the ratio of silicon dioxide enhanced the mechanical properties, and the increase in modulus of elasticity was directly related to the weight percentage of the reinforcement material. The composite with 80% silica had a 526.88% higher modulus of elasticity than the pure epoxy specimen. Both tensile and flexural strengths of the composite material were maximal when 40 wt% of the particle silicon dioxide was utilized, which were 68.5% and 67.8% higher than those of the neat epoxy, respectively. The test results also revealed that the impact resistance of the FGM increased when the silica proportion increased, with a maximum value of 60 wt% silica particle content, which was an increase of 76.98% compared to pure epoxy. In addition, the thermal properties of epoxy resin improved when SiO2 was added to the mixture. Thus, the addition of silica filler to composite materials directly proportionally increased their thermal conductivity to the weight ratio of the reinforcement material, which was 32.68–383.66%. FGM composed of up to 80% silica particles had the highest thermal conductivity.
{"title":"Characterization of the mechanical properties and thermal conductivity of epoxy-silica functionally graded materials","authors":"Jaafar Sh. AbdulRazaq, A. F. Hassan, Nuha H. Jasim","doi":"10.3934/matersci.2023010","DOIUrl":"https://doi.org/10.3934/matersci.2023010","url":null,"abstract":"A functionally graded material (FGM) was prepared using epoxy resin reinforced with silicon dioxide with a particle size of 100 μm and weight percentages of 0, 20, 40, 60, and 80 wt%. In a gravity-molding process using the hand layup technique, specimens with international standard (ASTM)-calculated dimensions were created in a mold of poly(methyl methacrylate), which is also known as acrylic. Tensile, flexural, impact, infrared wave, and thermal conductivity tests, and X-ray diffraction (XRD) were conducted on specimens of the five layers of the FGM. The XRD and infrared spectroscopy demonstrated that the compositions of the silica particles and epoxy had a strong association with their physical structures. The findings of experimental tests indicated that increasing the ratio of silicon dioxide enhanced the mechanical properties, and the increase in modulus of elasticity was directly related to the weight percentage of the reinforcement material. The composite with 80% silica had a 526.88% higher modulus of elasticity than the pure epoxy specimen. Both tensile and flexural strengths of the composite material were maximal when 40 wt% of the particle silicon dioxide was utilized, which were 68.5% and 67.8% higher than those of the neat epoxy, respectively. The test results also revealed that the impact resistance of the FGM increased when the silica proportion increased, with a maximum value of 60 wt% silica particle content, which was an increase of 76.98% compared to pure epoxy. In addition, the thermal properties of epoxy resin improved when SiO2 was added to the mixture. Thus, the addition of silica filler to composite materials directly proportionally increased their thermal conductivity to the weight ratio of the reinforcement material, which was 32.68–383.66%. FGM composed of up to 80% silica particles had the highest thermal conductivity.","PeriodicalId":7670,"journal":{"name":"AIMS Materials Science","volume":"1 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70089625","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：