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Development of Eu-doped NaCa(PO3)3 red-emitting phosphors for WLED applications WLED用铕掺杂NaCa(PO3)3红发荧光粉的研制
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-07-09 DOI: 10.1007/s11182-025-03490-4
Ajay Narayan Sahu, Piyush Jha

The Eu-doped NaCa(PO3)3 red-emitting phosphors are prepared by the solid-state reaction method in two heating steps. Initially, the phosphor is heated to 300 °C to remove ammonia, followed by further heating at 730 °C temperature. The X‑ray diffraction (XRD) confirms the triclinic structure and surface morphology is detected by scanning electron microscopy (SEM). The Fourier transform infrared spectroscopy (FTIR) detects the molecular vibrations and chemical bonds present within the phosphors. The photoluminescence (PL) emission occurs at wavelengths of 593 and 616 nm when excited with 396 nm light. The PL intensity reaches its maximum at a 4 mol% concentration of Eu doping, and the color purity is high at 98.9% for this concentration.

采用两步加热固相反应法制备了铕掺杂的NaCa(PO3)3发红光荧光粉。最初,将荧光粉加热到300 °C以去除氨,然后在730 °C的温度下进一步加热。X射线衍射(XRD)证实了三斜结构,扫描电子显微镜(SEM)检测了表面形貌。傅里叶变换红外光谱(FTIR)检测分子振动和化学键存在于荧光粉。在396 nm光激发下,在593和616 nm波长处产生光致发光(PL)。当Eu掺杂浓度为4 mol%时,发光强度达到最大,颜色纯度为98.9%。
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引用次数: 0
Effect of spark plasma sintering on the addition of ZrO2 particles to AA7075/B4C composite and its mechanical properties 火花等离子烧结对ZrO2颗粒加入AA7075/B4C复合材料及其力学性能的影响
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-07-09 DOI: 10.1007/s11182-025-03483-3
A L N Arun Kumar, S. Sarveswara Reddy, Thota Rajasekhar

This work investigates microstructural and mechanical properties of hybrid AA7075/B4C/ZrO2 composites with varying ZrO2 reinforcement using spark plasma sintering. The primary objective of the work is to optimize the reinforcement content to achieve a balance between enhanced mechanical properties and microstructural integrity. Composites are characterized by SEM, XRD, and mechanical testing to evaluate tensile strength, compressive strength, hardness, and impact strength. It is shown that 6% ZrO2 is the best reinforcement content, with tensile and compressive strength peak at 468 and 554 MPa, respectively. Beyond this level, mechanical properties degrade due to the formation of brittle phases, including intermetallic carbides (Al4C3), intermetallic compounds (Al3Zr) and increased porosity, as confirmed by the XRD analysis. Hardness values consistently increase with the higher ZrO2 content, reaching the maximum hardness of 129 HV at 8% ZrO2, while the impact strength decreases due to reduced ductility from the intermetallic formation and increased brittleness.

采用火花等离子烧结技术研究了不同ZrO2增强率的AA7075/B4C/ZrO2杂化复合材料的显微组织和力学性能。该工作的主要目标是优化增强含量,以实现增强力学性能和微观组织完整性之间的平衡。复合材料通过SEM、XRD和力学测试进行表征,以评估拉伸强度、抗压强度、硬度和冲击强度。结果表明,6% ZrO2为最佳配筋量,抗拉强度峰值分别为468和554 MPa。XRD分析证实,超过这个水平,由于脆性相的形成,包括金属间碳化物(Al4C3)、金属间化合物(Al3Zr)和孔隙率增加,机械性能会下降。随着ZrO2含量的增加,硬度值不断升高,在ZrO2含量为8%时达到最大硬度129 HV,而由于金属间形成的延性降低和脆性增加,冲击强度下降。
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引用次数: 0
Study of corrosion resistance of two-phase CoNiAl(Fe) single crystals 两相CoNiAl(Fe)单晶的耐蚀性研究
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-07-03 DOI: 10.1007/s11182-025-03482-4
A. S. Eftifeeva, E. A. Bolshevich, S. G. Anikeev, E. I. Yanushonite, E. Yu. Panchenko, Yu. I. Chumlyakov

The effect of a two-phase (B2+γ/γ′)-structure on the corrosion rate is studied in single crystals of the CoNiAl and CoNiAlFe ferromagnetic shape memory alloys. It is shown that the smaller the volume fraction of the secondary γ/γ′-phases, the lower the corrosion rate. It is found out that the Co35Ni35Al30 and Co35Ni35Al28Fe2 single crystals with small volume fractions of γ/γ′-phases have a lower corrosion rate, Ccorr = 1.20–1.86∙10−3 mm/year, compared to that of the Co40Ni33Al27 and Co39Ni32Al27Fe2 single crystals with a large volume fraction of the secondary phases (Ccorr = 1.83–2.98∙10−3 mm/year). This is achieved due to a short length of the interphase B2-γ/γ′-boundary and Fe alloying. The crystals under study demonstrate pitting and intercrystalline corrosion.

研究了两相(B2+γ/γ′)结构对CoNiAl和CoNiAlFe铁磁形状记忆合金单晶腐蚀速率的影响。结果表明,二次γ/γ′相的体积分数越小,腐蚀速率越低。结果表明,含有少量γ/γ′相的Co35Ni35Al30和Co35Ni35Al28Fe2单晶的腐蚀速率为Ccorr = 1.20 ~ 1.86∙10−3 mm/年,而含有大量次级相的Co40Ni33Al27和Co39Ni32Al27Fe2单晶的腐蚀速率为Ccorr = 1.83 ~ 2.98∙10−3 mm/年。这是由于界面相B2-γ/γ′-边界和Fe合金化的长度较短。所研究的晶体表现出点蚀和晶间腐蚀。
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引用次数: 0
Fast SR beam position and intensity monitor for the experiments to study fast-flowing processes 快速SR光束位置和强度监测仪,用于研究快速流动过程的实验
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-07-03 DOI: 10.1007/s11182-025-03454-8
V. M. Aulchenko, A. A. Glushak, M. A. Kornievsky, L. I. Shekhtman, O. P. Tolbanov, A. V. Tyazhev, A. N. Zarubin

A Fast Processes station is proposed for studying the detonation and shock wave processes as part of the experimental stations at the SKIF Center for Shared Use. The station includes a number of DIMEX detectors (Detector IMaging EXplosions). A DIMEX is capable of detecting synchrotron radiation (SR) from each electron bunch in the storage ring. Since the bunches can deviate from the equilibrium orbit and differ in current, a fast monitor of the SR beam position and intensity is needed to increase the accuracy of signal magnitude measurements and to measure the relative position and power of the beam radiation from each electron bunch in the storage ring. The readings from this monitor would allow correcting the measurements of the DIMEX detectors. As part of the fast SR beam position monitor, it is planned to place 4 sensors to measure the signal in the vicinity of the beam on the top, bottom, right and left. The signal ratios in the corresponding pairs of sensors are supposed to change with the beam position, and the sum of the signals from all sensors will change with the change of the total SR flux. During the experiment, the beam monitor will record the signals from all sensors synchronously with the DIMEX detector. After the experiment, the results recorded from the DIMEX detector will be adjusted in accordance with the monitor sensor signals.

作为SKIF共享使用中心实验站的一部分,提出了一个用于研究爆轰和激波过程的快速过程站。该站包括许多DIMEX探测器(探测器成像爆炸)。DIMEX能够检测存储环中每个电子束的同步辐射(SR)。由于电子束会偏离平衡轨道,且电流存在差异,因此需要对电子束的位置和强度进行快速监测,以提高信号量级测量的精度,并测量存储环中每个电子束的相对位置和辐射功率。这个监视器的读数将允许修正DIMEX探测器的测量值。作为快速SR波束位置监测仪的一部分,计划在波束附近的顶部、底部、右侧和左侧放置4个传感器来测量信号。假设相应传感器对的信号比随波束位置的变化而变化,所有传感器的信号之和随总SR通量的变化而变化。在实验过程中,光束监测器将与DIMEX探测器同步记录来自所有传感器的信号。实验结束后,DIMEX探测器记录的结果将根据监测传感器信号进行调整。
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引用次数: 0
A compact circular slotted radiator for ISM and wireless bands 一个紧凑的圆形开槽散热器,用于ISM和无线频段
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-07-03 DOI: 10.1007/s11182-025-03494-0
Abhilash S. Vasu, N. R. Lakshmi, T. K. Sreeja

A compact coplanar waveguide radiator is formed by two ground plane and a slotted central signal strip. The radiating patch is printed on FR4 substrate 1 mm thick. The circular slot on the central strip improves the bandwidth and decreases the return loss. The measured results show that it covers 4.25–7.95 GHz bandwidth with −24.80 dB return loss at a resonance frequency of 6.00 GHz. The fabricated radiator produces nominal value of co-pol at the resonance frequency. The Z-parameter of the proposed radiator is correlated with 50 Ω matching condition. The magnitude of voltage standing wave ratio at 6.00 GHz tends to unity, which implies that the reflected signal is zero and leads to a perfect matching radiator. The measured average gain and radiation efficiency are 2.44 dBi and 94.50%, respectively. The fabricated radiator covers 5.20/5.80 GHz wireless local area network (WLAN), 5.50 GHz worldwide interoperability for microwave access (WiMAX), 5.80 GHz industrial, scientific, and medical (ISM) band, 5G sub 6 GHz band, and 5 GHz wireless fidelity (WiFi) bands.

一个紧凑的共面波导辐射体由两个接地面和一个开槽的中央信号带组成。辐射贴片印刷在1 mm厚的FR4衬底上。中心带上的圆形槽提高了带宽,降低了回波损耗。测量结果表明,在6.00 GHz的谐振频率下,其带宽为4.25-7.95 GHz,回波损耗为- 24.80 dB。所制备的散热器在谐振频率处产生标称共pol值。该散热器的z参数与50 Ω匹配条件相关。在6.00 GHz处,电压驻波比的幅值趋于一致,这意味着反射信号为零,从而导致了一个完美匹配的辐射体。测得的平均增益和辐射效率分别为2.44 dBi和94.50%。制作的散热器涵盖5.20/5.80 GHz无线局域网(WLAN), 5.50 GHz全球微波接入互操作性(WiMAX), 5.80 GHz工业,科学和医疗(ISM)频段,5G sub 6 GHz频段和5 GHz无线保真(WiFi)频段。
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引用次数: 0
Computational analysis of phase-transformation-induced deformation in coated polycrystalline titanium nickelide 涂层多晶镍化钛相变致变形的计算分析
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-07-03 DOI: 10.1007/s11182-025-03485-1
R. R. Balokhonov, E. S. Marchenko, V. R. Balokhonov, V. A. Romanova

Numerical simulation of deformation in the surface layer of coated polycrystalline titanium nickelide is performed. The coating is synthesized from a layered Ti/Ni/Ti nanolaminate. The polycrystalline microstructure is studied by electron backscatter diffraction (EBSD) analysis. Based on the available experimental data, a model microstructure of the polycrystalline composite assuming the grain orientation is created. An anisotropic constitutive model of composite elastoplastic deformation is developed taking into account the cubic syngony, slip systems, and phase transition. The microstructure and model are integrated into ABAQUS/Explicit. Finite element calculations of tension and subsequent unloading of the microstructure are performed. The interrelated processes of nucleation and propagation of elastic phase transformation in titanium nickelide and elastoplastic flow in the coating layer are studied. It is found that the phase transition in the base material contributes to a more uniform distribution of strains, while the plastic flow in the coating leads to the formation of residual martensite in the titanium nickelide surface layer.

对涂层多晶镍化钛的表层变形进行了数值模拟。该涂层由层状Ti/Ni/Ti纳米层合物合成。用电子背散射衍射(EBSD)分析了多晶的微观结构。在现有实验数据的基础上,建立了假设晶粒取向的多晶复合材料微观结构模型。建立了考虑三次共形、滑移系统和相变的复合材料弹塑性变形各向异性本构模型。将微观结构和模型集成到ABAQUS/Explicit中。对微观结构的拉伸和后续卸载进行了有限元计算。研究了镍化钛中弹性相变的成核和扩展与涂层中弹塑性流动的相互关系。结果表明,基体中的相变使应变分布更加均匀,而涂层中的塑性流动导致镍化钛表层形成残余马氏体。
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引用次数: 0
Effect of heat treatment on structure formation of pre-compacted titanium and silicon powder mixtures 热处理对预压钛硅粉混合物结构形成的影响
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-06-26 DOI: 10.1007/s11182-025-03486-0
G. A. Pribytkov, I. A. Firsina, A. V. Baranovskiy

Metal matrix titanium composites reinforced with a silicide phase are produced by hot compaction and subsequent high-temperature annealing of titanium and 5 wt.% silicon powder mixtures. An X‑ray diffraction analysis and optical and scanning electron microscopy are used to study their microstructure and the elemental and phase compositions. The strength properties of the annealed samples are evaluated by measuring the microhardness. It is found out that the annealing temperature affects the microstructure, the phase composition and the microhardness of the powder compacts. An increase in the annealing temperature within the range of 800–1200 °C results in the completed silicon and titanium reaction and the formation of Ti5Si3 silicide, which constitute a net-like structure along the boundaries of the titanium grains. The structure evolution with the increasing temperature results in a progressive hardness increase. In order to increase the strength properties, the hardening phase distribution homogeneity and a more uniform material density, a fine titanium powder and a high hot compaction pressure are required.

采用热压实法对钛和5 wt进行高温退火,制备了硅化相增强金属基钛复合材料。%硅粉混合物。用X射线衍射分析、光学和扫描电子显微镜研究了它们的微观结构、元素和相组成。通过测量显微硬度来评价退火试样的强度性能。结果表明,退火温度对粉末坯的显微组织、相组成和显微硬度有影响。当退火温度在800 ~ 1200 ℃范围内升高,硅钛反应完成,形成Ti5Si3硅化物,Ti5Si3硅化物沿钛晶粒边界呈网状结构。随着温度的升高,组织的演变导致硬度的逐渐增大。为了提高钛粉的强度性能、硬化相分布均匀性和材料密度更均匀,需要细钛粉和高热压实压力。
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引用次数: 0
Mechanical and electronic properties of ternary alloys XY3Ti11 三元合金XY3Ti11的力学和电子性能
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-06-25 DOI: 10.1007/s11182-025-03450-y
S. O. Kasparyan, A. E. Ordabaev, A. V. Bakulin, S. E. Kulkova

The electronic structure and elastic properties of four series of titanium alloys of composition XY3Ti11, where X and Y are elements of IIIA, IVA, IVB–VIB groups, is studied by the projector augmented-wave method using the cluster-plus-glue-atom model. The smallest values of the Young’s modulus in each series are 37.30 GPa for InHf3Ti11, 36.52 GPa for SnHf3Ti11, 65.72 GPa for CrIn3Ti11, and 52.39 GPa for WSn3Ti11. The peculiarities of the electronic structure of alloys due to their chemical composition are discussed. It is shown that s, p‑elements do not affect the character of the Young’s modulus anisotropy in the alloy series: the lowest value corresponds to the < 100> direction, and the highest one—the < 111> direction, while d‑elements can change it.

采用团簇-胶合原子模型,采用投影增强波法研究了X和Y分别为IIIA、IVA、IVB-VIB基团元素的四系XY3Ti11钛合金的电子结构和弹性性能。各系列杨氏模量最小值分别为:InHf3Ti11 37.30 GPa, SnHf3Ti11 36.52 GPa, CrIn3Ti11 65.72 GPa, WSn3Ti11 52.39 GPa。讨论了合金的化学成分所引起的电子结构的特殊性。结果表明,s、p元素不影响合金系杨氏模量各向异性的特征,最小值对应于<; 100>;方向,最大值对应于<; 111>;方向,而d元素可以改变杨氏模量各向异性。
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引用次数: 0
Improved CMA tracking mode algorithm based on eigenvalue, eigenvector, and frequency adjustment 基于特征值、特征向量和频率调整的改进CMA跟踪模式算法
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-06-25 DOI: 10.1007/s11182-025-03493-1
Tuan Phuong Dang

The characteristic mode analysis (CMA) is a modern method for optimizing antennas and scatterers. Tracking mode algorithms are developed to correctly track the characteristic currents and fields when performing the CMA over a frequency range. Although these algorithms are widely used, they still have drawbacks in terms of speed and accuracy. This paper presents a new approach to improving the speed and accuracy of the tracking mode algorithm by combining characteristics of eigenvectors, eigenvalues, and using an adaptive frequency range. This approach focuses on breaking down frequency intervals with complex changes in the eigenvalue, thus reducing the overall tracking time while maintaining the high accuracy. To verify the method effectiveness, it is applied to various structures, from simple to complex ones, such as dipole, crossed wire, wire grid patch, and horn antennas. It is shown that the proposed method can significantly improve the speed and accuracy of the tracking mode results.

特征模分析(CMA)是一种优化天线和散射体的现代方法。跟踪模式算法的发展,以正确地跟踪特征电流和场,当执行CMA在一个频率范围内。虽然这些算法被广泛使用,但它们在速度和准确性方面仍然存在缺点。本文提出了一种结合特征向量、特征值特征和自适应频率范围来提高跟踪模式算法速度和精度的新方法。该方法侧重于分解特征值变化复杂的频率区间,从而在保持高精度的同时减少了整体跟踪时间。为了验证该方法的有效性,将其应用于从简单到复杂的各种结构,如偶极子、交叉线、线栅贴片和喇叭天线。实验结果表明,该方法能显著提高跟踪模式结果的速度和精度。
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引用次数: 0
Effect of heat input on structure and mechanical properties of an electron beam additively manufactured Ti–6Al–4V alloy 热输入对电子束增材制备Ti-6Al-4V合金组织和力学性能的影响
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-06-25 DOI: 10.1007/s11182-025-03481-5
N. N. Shamarin, A. V. Filippov, N. V. Semenchuk, V. M. Semenchuk, A. O. Panfilov, S. Yu. Tarasov, A. V. Chumaevskii

Working out of technological recommendations for modern additive manufacturing of titanium alloys is an important scientific and technical task for modern industry. The paper presents results of experimental studying the effect of heat input during wire and electron beam additive manufacturing (WEBAM) on the structural-phase composition and mechanical properties of a WEBAM-built Ti–6Al–4V alloy. Characteristic morphological and structural features of the as-built metal have been established. The as-built metal was represented by α‑Ti (HCP) and β‑Ti (BCC) lath structures. It has been shown that an increase in the heat input contributes to a higher ductility of the as-built metal with lower strength and microhardness values.

制定钛合金现代增材制造技术建议是现代工业的一项重要科技任务。本文介绍了线材和电子束增材制造(WEBAM)过程中热输入对Ti-6Al-4V合金结构相组成和力学性能影响的实验研究结果。建立了成品金属的特征形态和结构特征。构建的金属由α‑Ti (HCP)和β‑Ti (BCC)板条结构表示。研究表明,热输入的增加有助于在较低强度和显微硬度值的情况下提高成品金属的延展性。
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引用次数: 0
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Russian Physics Journal
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