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Detonation inhibition using retardant weight analysis for halogenated compounds 利用卤化化合物的阻燃剂重量分析法抑制爆燃
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2024-05-13 DOI: 10.1007/s00193-024-01175-4
R. K. Singh, A. Dahake, A. V. Singh

The current study numerically evaluates the detonation inhibition effects of a range of halogenated compounds on hydrogen-air gaseous detonations. The halogenated compounds investigated in this research encompass halogen acids (HI, HBr, HCl, HF), halomethanes ((hbox {CH}_{{3}}hbox {I}), (hbox {CH}_{{3}}hbox {Br}), (hbox {CH}_{{3}}hbox {Cl}), (hbox {CH}_{{3}}hbox {F})), haloethenes ((hbox {C}_{{2}}hbox {H}_{{3}}hbox {I}), (hbox {C}_{{2}}hbox {H}_{{3}}hbox {Br}), (hbox {C}_{{2}}hbox {H}_{{3}}hbox {Cl}), (hbox {C}_{{2}}hbox {H}_{{3}}hbox {F})), haloethanes ((hbox {C}_{{2}}hbox {H}_{{5}}hbox {I}), (hbox {C}_{{2}}hbox {H}_{{5}}hbox {Br}), (hbox {C}_{{2}}hbox {H}_{{5}}hbox {Cl}), (hbox {C}_{{2}}hbox {H}_{{5}}hbox {F})), and complex halogenated compounds ((hbox {CF}_{{3}}hbox {I}), (hbox {CF}_{{3}}hbox {Br}), (hbox {CF}_{{3}}hbox {Cl}), (hbox {CF}_{4})). The study employs a one-dimensional ZND model with detailed chemical kinetics to examine the impact on detonation propagation by adding these halogenated compounds to hydrogen-air mixtures. The effectiveness of these inhibitors is evaluated based on their capacity to increase the induction length, the amount of inhibitor needed to attenuate a detonation wave, and their influence on the detonability of the gaseous mixture under both lean and rich conditions. The results indicate that several halogenated compounds exhibit superior inhibition properties compared to Halon 1301 ((hbox {CF}_{{3}}hbox {Br})). Specifically, (hbox {C}_{{2}}hbox {H}_{{5}}hbox {Br}) leads to the most significant increase in the induction length, with HBr and (hbox {C}_{{2}}hbox {H}_{{5}}hbox {I}) following closely, particularly at 20,000 ppmv concentration levels. However, it is worth noting that the inhibition efficiency also varies depending on the concentration of the inhibitor added to the gaseous (hbox {H}_{{2}})-air mixture. Moreover, based on retardant weight analysis, fluorinated compounds were found to be the most effective inhibitors, followed by chlorinated, brominated, and iodinated compounds across all categories of halogenated inhibitors.

目前的研究以数值方式评估了一系列卤代化合物对氢气-空气气态爆轰的抑制效果。本研究中调查的卤素化合物包括卤酸(HI、HBr、HCl、HF)、卤甲烷((hbox {CH}_{{3}}hbox {I})、(hbox {CH}_{3}}hbox {Br})、(hbox {CH}_{3}}hbox {Cl})、((hbox {CH}_{3}}hbox {F})),卤乙烯((hbox {C}_{2}}hbox {H}_{3}}hbox {I}),(hbox {C}_{2}}hbox {H}_{3}}hbox {Br}),(hbox {C}_{2}}hbox {H}_{3}}hbox {Cl})、卤乙烷((hbox {C}_{{2}}hbox {H}_{3}}hbox {F}/))、卤乙烷((hbox {C}_{2}}hbox {H}_{5}}hbox {I}/)、(hbox {C}_{2}}hbox {H}_{5}}hbox {Br}/)、(hbox {C}_{2}}hbox {H}_{5}}hbox {Cl}/)、和复杂的卤代化合物((hbox {CF}_{{3}hbox {I}),(hbox {CF}_{3}hbox {Br}),(hbox {CF}_{3}hbox {Cl}},(hbox {CF}_{4}) )。该研究采用了一个具有详细化学动力学的一维 ZND 模型,以研究在氢气-空气混合物中添加这些卤代化合物对引爆传播的影响。根据这些抑制剂增加诱导长度的能力、减弱爆轰波所需的抑制剂用量以及它们在贫气和富气条件下对气态混合物可爆性的影响,对这些抑制剂的有效性进行了评估。结果表明,与哈龙 1301((hbox {CF}_{{3}}hbox {Br})相比,几种卤代化合物表现出更优越的抑制特性。)具体来说,(hbox {C}_{{2}}hbox {H}_{5}}hbox {Br}) 导致的诱导长度增加最为显著,HBr 和 (hbox {C}_{2}}hbox {H}_{5}}hbox {I}) 紧随其后,尤其是在 20,000 ppmv 的浓度水平上。然而,值得注意的是,抑制效率也会随着添加到气态 (hbox {H}_{{2}})-air 混合物中的抑制剂浓度而变化。此外,根据阻燃剂重量分析,在所有卤化阻燃剂类别中,氟化合物是最有效的阻燃剂,其次是氯化、溴化和碘化化合物。
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引用次数: 0
Characteristic timescales for detonation-based rocket propulsion systems 基于爆炸的火箭推进系统的特征时标
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2024-05-06 DOI: 10.1007/s00193-024-01174-5
R. T. Dave, J. R. Burr, M. C. Ross, C. F. Lietz, J. W. Bennewitz

Characteristic timescales for rotating detonation rocket engines (RDREs) are described in this study. Traveling detonations within RDREs create a complex reacting flow field involving processes spanning a range of timescales. Specifically, characteristic times associated with combustion kinetics (detonation and deflagration), injection (e.g., flow recovery), flow (e.g., mixture residence time), and acoustic modes are quantified using first-principle analyses to characterize the RDRE-relevant physics. Three fuels are investigated including methane, hydrogen, and rocket-grade kerosene RP-2 for equivalence ratios from 0.25 to 3 and chamber pressures from 0.51 to 10.13 MPa, as well as for a case study with a standard RDRE geometry. Detonation chemical timescales range from 0.05 to 1000 ns for the induction and reaction times; detonation-based chemical equilibrium, however, spans a larger range from approximately 0.5 to (200~upmu )s for the flow condition and fuel. This timescale sensitivity has implications regarding maximizing detonative heat release, especially with pre-detonation deflagration in real systems. Representative synthetic detonation wave profiles are input into a simplified injector model that describes the periodic choking/unchoking process and shows that injection timescales typically range from 5 to (50~upmu )s depending on injector stiffness; for detonations and low-stiffness injectors, target reactant flow rates may not recover prior to the next wave arrival, preventing uniform mixing. This partially explains the detonation velocity deficit observed in RDREs, as with the standard RDRE analyzed in this study. Finally, timescales tied to chamber geometry including residence time are on the order of 100–10,000 (upmu )s and acoustic resonance times are 10–(1000~upmu )s. Overall, this work establishes characteristic time and length scales for the relevant physics, a valuable step in developing tools to optimize future RDRE designs.

本研究描述了旋转引爆火箭发动机(RDRE)的特征时标。旋转爆燃火箭发动机内的行进爆燃产生了一个复杂的反应流场,涉及跨越一系列时间尺度的过程。具体来说,与燃烧动力学(爆轰和爆燃)、喷射(如流动恢复)、流动(如混合物停留时间)和声学模式相关的特征时间都通过第一原理分析进行了量化,以描述 RDRE 的相关物理特性。研究了三种燃料,包括甲烷、氢气和火箭级煤油 RP-2,等效比从 0.25 到 3,腔室压力从 0.51 到 10.13 兆帕,以及标准 RDRE 几何形状的案例研究。诱导和反应时间的引爆化学时间尺度范围为 0.05 到 1000 ns;然而,基于引爆的化学平衡时间尺度范围更大,从大约 0.5 到(200~upmu )s(流动条件和燃料)。这种时间尺度的敏感性对引爆热释放的最大化有影响,特别是在实际系统中的预爆燃。具有代表性的合成爆轰波剖面被输入到一个简化的喷射器模型中,该模型描述了周期性的窒息/起爆过程,并显示喷射时间尺度通常在5到(50~upmu)s之间,这取决于喷射器的刚度;对于爆轰和低刚度喷射器,目标反应物流速可能无法在下一个波到达之前恢复,从而阻碍了均匀混合。这部分解释了在 RDRE 中观察到的起爆速度不足,本研究分析的标准 RDRE 也是如此。最后,与腔室几何形状相关的时间尺度包括停留时间在100-10,000 (upmu )s左右,声共振时间为10-(1000~upmu )s。总之,这项工作为相关物理学建立了特征时间和长度尺度,是开发工具以优化未来 RDRE 设计的重要一步。
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引用次数: 0
Evaluating evidence supporting the relevancy of 4 psi as a blast overpressure value associated with brain health and performance outcomes following low-level blast overpressure exposure 评估支持 4 psi 爆炸超压值与低水平爆炸超压暴露后大脑健康和性能结果相关性的证据
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2024-04-29 DOI: 10.1007/s00193-024-01170-9
S. S. Sloley, S. M. Turner

Evidence suggests that low-level blast (LLB) overpressure exposure from military heavy weapons training is associated with subclinical adverse brain health and performance (H &P) outcomes. Existing DOD safety policies related to blast overpressure exposure are not specific to LLB-related brain health effects. This study sought to synthesize the available literature and analyze the relevancy of a specific blast metric to LLB exposures and the manifestation of adverse brain H &P outcomes. A literature search yielded 311 unique articles, from which 220 were identified as human studies on LLB published from 2010 to 2021. After more exhaustive exclusion criteria were applied, 14 articles met the criteria for inclusion. Findings on brain H &P changes were examined in relation to quantified LLB measurements (e.g., peak overpressure) to identify trends. Overall, the included studies suggested that alterations of reaction time, a metric for neurocognitive performance, as well as symptom reporting can occur following cumulative LLB exposures above 4 psi (27.6 kPa). Biomarkers and neurosensory changes have not demonstrated consistent associations with LLB exposures. These findings suggest that cumulative blast overpressure exposures above 4 psi (27.6 kPa) based on current measurement methodologies for body-worn sensors may be associated with adverse brain H &P outcomes. Current research efforts seek to better quantify LLB exposure, the relationships between LLB (e.g., intensity, duration, dose) and brain health, as well as to assess brain H &P domains more comprehensively. These efforts will serve to promote a better understanding of the interaction between LLB exposures and adverse brain H &P outcomes.

有证据表明,军事重武器训练中的低水平爆炸(LLB)超压暴露与亚临床不良脑健康和性能(H &P )结果有关。国防部现有的与爆炸超压暴露相关的安全政策并未专门针对与 LLB 相关的脑健康影响。本研究试图综合现有文献,分析特定爆炸指标与低爆暴露的相关性以及脑部 H &P 不良后果的表现。通过文献检索获得了 311 篇文章,其中 220 篇被确定为 2010 年至 2021 年间发表的有关低放炮弹的人类研究。在采用更详尽的排除标准后,有14篇文章符合纳入标准。研究人员结合量化的 LLB 测量值(如过压峰值)对大脑 H &P 变化的研究结果进行了分析,以确定趋势。总体而言,纳入的研究表明,在暴露于超过 4 psi(27.6 kPa)的累积 LLB 后,反应时间(一种神经认知性能指标)以及症状报告都会发生变化。生物标志物和神经感觉的变化并未显示出与 LLB 暴露有一致的联系。这些研究结果表明,根据目前的体戴式传感器测量方法,超过 4 psi (27.6 kPa) 的累积爆炸超压暴露可能与不良的脑 H &P 结果有关。目前的研究工作旨在更好地量化 LLB 暴露、LLB(如强度、持续时间、剂量)与大脑健康之间的关系,以及更全面地评估大脑 H &P 领域。这些努力将有助于更好地理解低辐射暴露与不良脑 Hamp;P 结果之间的相互作用。
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引用次数: 0
Quantitative proteomic profiling in brain subregions of mice exposed to open-field low-intensity blast reveals position-dependent blast effects 暴露于开阔地低强度爆炸的小鼠大脑亚区域的定量蛋白质组特征分析揭示了位置依赖性爆炸效应
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2024-04-25 DOI: 10.1007/s00193-024-01169-2
M. Jackson, S. Chen, P. Liu, M. Langenderfer, C. Li, H. R. Siedhoff, A. Balderrama, R. Li, C. E. Johnson, C. Greenlief, I. Cernak, R. G. DePalma, J. Cui, Z. Gu
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引用次数: 1
Blast injury model estimates from multiple overpressure measurement locations on a single person-borne device 从单人携带装置上的多个超压测量位置得出爆炸伤害模型估计值
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2024-04-24 DOI: 10.1007/s00193-024-01166-5
J.-P. Dionne, J. Levine, A. Makris
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引用次数: 0
Correction: Experimental demonstration on detonation initiation by laser ignition and shock focusing in elliptical cavity 更正:椭圆腔内激光点火和冲击聚焦引发爆炸的实验演示
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2024-04-18 DOI: 10.1007/s00193-024-01171-8
T. Sato, K. Matsuoka, A. Kawasaki, N. Itouyama, H. Watanabe, J. Kasahara
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引用次数: 0
Development of a vapor-based method for seeding alkali metals in shock tube facilities 在冲击管设施中开发基于蒸汽的碱金属播种方法
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2024-04-15 DOI: 10.1007/s00193-024-01165-6
J. A. Vandervort, S. C. Barnes, C. L. Strand, R. K. Hanson

This note presents a vapor-based seeding apparatus, named the external alkali seeding instrument (EASI), which is designed to introduce alkali metal vapors into experimental facilities without using precursors or large auxiliary equipment. The device vaporizes small amounts of alkali metals, potassium in this work, which are then carried away by an inert gas. In a benchtop flow cell, carrier gas flow rate (6–(200~hbox {cm}^3/hbox {s})) and device temperature (150–(250,^{circ }hbox {C})) most strongly affected potassium-vapor concentrations. Higher values of either quantity lead to increased potassium-vapor concentrations. When using the EASI to seed a shock tube experiment, vapor-phase potassium was detected immediately after the incident and reflected shockwaves using a laser absorption diagnostic. Mole fraction time histories stay within a factor of 2 over the test time as compared with those from a precursor-based seeding approach, which may span multiple orders of magnitude. This suggests potassium is nearly homogeneously distributed throughout the test gas. This design can be extended to other low-vapor-pressure elements, such as other alkalis or sulfur, with minimal modifications. The EASI simplifies seeding for laboratory experiments targeting potassium and other alkali metals—enabling advances in fundamental spectroscopy, diagnostic development, and chemical kinetics.

本说明介绍了一种基于蒸气的播种设备,名为外部碱金属播种仪(EASI),其设计目的是在不使用前驱体或大型辅助设备的情况下,将碱金属蒸气引入实验设施。该装置可蒸发少量碱金属(在本研究中为钾),然后由惰性气体带走。在台式流动池中,载气流速(6-(200~hbox {cm}^3/hbox {s})和设备温度(150-(250,^{circ }hbox {C})对钾蒸汽浓度的影响最大。这两个数值越大,钾蒸汽浓度越高。当使用 EASI 作为冲击管实验的种子时,在入射和反射冲击波之后立即使用激光吸收诊断仪检测气相钾。与基于前驱体的播种方法相比,摩尔分数时间历程在测试时间内保持在 2 倍的范围内,而前驱体播种方法的时间历程可能跨越多个数量级。这表明钾几乎均匀地分布在整个测试气体中。这种设计可以扩展到其他低气压元素,如其他碱或硫,只需做极少的修改。EASI 简化了以钾和其他碱金属为目标的实验室实验的播种过程,从而推动了基础光谱学、诊断开发和化学动力学方面的进步。
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引用次数: 0
Effect of shock impingement location on the fluid–structure interactions over a compliant panel 冲击撞击位置对顺应性面板上流体与结构相互作用的影响
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2024-04-15 DOI: 10.1007/s00193-024-01162-9
A. Tripathi, J. Gustavsson, K. Shoele, R. Kumar

An experimental investigation was carried out to study the fluid–structure interactions on a compliant panel subjected to an impinging shock wave and an incoming turbulent boundary layer. These experiments were aimed at understanding the time-averaged and unsteady characteristics of fluid–structure interaction at Mach 2. Two shock impingement locations on the panel (aspect ratio of 2.82), namely the central and three-fourths of the panel length, were tested. The shock boundary layer interactions on a rigid flat plate served as a baseline case. Measurements include shadowgraph and surface oil flow visualizations, panel deflections using a capacitance probe, cavity acoustics using a pressure sensor, surface pressures using discrete pressure sensors, and pressure-sensitive paints. Results show that the interaction on the compliant panel is relatively three-dimensional as compared to a rigid plate with a nominally two-dimensional interaction. Pressure fluctuations on the compliant panel are significantly higher than on the rigid plate, and the fluctuation spectra are multi-modal. Strong coupling at some frequencies was observed between the shock and the panel for both shock impingement locations. The present study suggests that for a compliant panel, the shape of pressure spectra is sensitive to the measurement location on the panel, the panel modifies the pressure distribution around the interaction, and the energy in dominant modes depends on the shock impingement location.

为了研究受冲击波和进入的湍流边界层影响的柔性面板上的流固相互作用,进行了一项实验研究。这些实验旨在了解 2 马赫时流体与结构相互作用的时间平均特性和非稳定特性。测试了面板上的两个冲击撞击位置(长宽比为 2.82),即面板长度的中央和四分之三处。刚性平板上的冲击边界层相互作用作为基线案例。测量包括阴影图和表面油流可视化、使用电容探头的面板偏转、使用压力传感器的空腔声学、使用离散压力传感器的表面压力以及压敏涂料。结果表明,与名义上具有二维相互作用的刚性板相比,顺应性面板上的相互作用是相对三维的。顺应性面板上的压力波动明显高于刚性板上的压力波动,而且波动频谱是多模式的。在冲击撞击的两个位置,都观察到冲击与面板之间在某些频率上的强耦合。本研究表明,对于顺应性面板,压力频谱的形状对面板上的测量位置很敏感,面板会改变相互作用周围的压力分布,主要模式的能量取决于冲击撞击位置。
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引用次数: 0
Semi-confined blast loading: experiments and simulations of internal detonations 半密闭爆破加载:内部爆炸的实验和模拟
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2024-04-08 DOI: 10.1007/s00193-024-01161-w
M. Kristoffersen, F. Casadei, G. Valsamos, M. Larcher, K. O. Hauge, A. Minoretti, T. Børvik

Far-field blast loading has been studied extensively for decades. Close-in, confined, and semi-confined detonations less so, partly because it is difficult to obtain good experimental data. The increase in computational power in recent years has made it possible to conduct studies of this kind numerically, but the results of such simulations ultimately depend on experimental validation and verification. This work thus aims at using reliable experiments to validate and verify numerical models developed to represent blast loading in general. Test rigs consisting of massive steel cylinders with pressure sensors were used to measure the pressure profiles of semi-confined detonations with different charge sizes. The experimental data set was then used to assess numerical models appropriate for simulating blast loading. In general, the numerical results were in excellent agreement with the experimental data, in both qualitative and quantitative terms. These results may in turn be used to analyse structures exposed to internal blast loads, which constitutes the next phase of this research project.

几十年来,人们对远场爆破加载进行了广泛的研究。对近距离、封闭和半封闭爆炸的研究较少,部分原因是难以获得良好的实验数据。近年来计算能力的提高使得以数值方式进行此类研究成为可能,但此类模拟的结果最终取决于实验的验证和确认。因此,这项工作旨在利用可靠的实验来验证和核实为表示一般爆破加载而开发的数值模型。试验台由装有压力传感器的大型钢筒组成,用于测量不同装药量的半密闭爆炸的压力曲线。实验数据集随后用于评估适合模拟爆破加载的数值模型。总体而言,数值结果与实验数据在定性和定量方面都非常吻合。这些结果可反过来用于分析暴露于内部爆炸荷载的结构,这是本研究项目的下一阶段。
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引用次数: 0
Breakdown regime of a shielded vortex interacting with a standing normal shock: a numerical study 与静止法向冲击相互作用的屏蔽漩涡的破裂机制:数值研究
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2024-04-05 DOI: 10.1007/s00193-024-01163-8
A. Kundu

Numerical simulation results of a convecting shielded vortex interacting with a normal shock using a compact scheme in the convecting upwind and split pressure framework are presented. We explore the parameter space spanned by vortex Mach number and incident Mach number to look for combinations of the parameters which lead to vortex breakdown. The incident and vortex Mach numbers covered are on the higher side, where relatively less information is available. It is well known that for a weak shock, the vortex retains its original shape and for stronger shocks it breaks down. In-between these two extremes, there is a region where the vortex neither retains its original shape nor does it break into small pieces. We determine the vortex breakdown and transition regions that have not so far been reported in shock–vortex interaction studies. A number of cases have been studied, and a vortex breakdown criterion for the cases considered is proposed.

本文介绍了对流屏蔽涡与法向冲击相互作用的数值模拟结果,采用了对流上风和分压框架下的紧凑方案。我们探索了由涡旋马赫数和入射马赫数构成的参数空间,以寻找导致涡旋崩溃的参数组合。所涉及的入射马赫数和涡旋马赫数偏高,可获得的信息相对较少。众所周知,对于较弱的冲击,涡旋会保持原来的形状,而对于较强的冲击,涡旋则会破裂。在这两个极端之间的区域,涡旋既不会保持原来的形状,也不会碎裂成小块。我们确定了迄今为止在冲击-涡旋相互作用研究中尚未报道的涡旋破裂和过渡区域。我们研究了多种情况,并提出了针对所考虑情况的涡破标准。
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引用次数: 0
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Shock Waves
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