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Detonation propagation through a diffuse-interface gas layer 通过扩散界面气体层的爆轰传播
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2023-04-27 DOI: 10.1007/s00193-023-01128-3
M. McLoughlin, V. Yousefi-Asli, S. Gray, G. Ciccarelli

Detonation propagation in a stratified layer of combustible gas over an inert gas was investigated experimentally. The layer formed in a 12.7-mm-wide channel by opening a sliding door that initially separated a nitrogen-diluted stoichiometric hydrogen–oxygen mixture from argon, or nitrogen. As the lighter combustible gas layer spreads axially down the channel, diffusion across the interface produces a composition gradient across the layer height. A steady detonation wave, generated by deflagration-to-detonation transition in the driver section before the door location, was transmitted into the combustible layer. The axial distance the layer spreads and the amount of mass diffusion across the layer were controlled by the flame ignition delay time after the door opens. Schlieren video and soot foils were used to measure the extent of detonation propagation through the layer. It was shown that detonation propagation through the layer is self-limiting due to over-mixing at the layer leading edge. Three-dimensional numerical simulations, including viscous and multicomponent mass diffusion effects, predicted the composition distribution within the layer. The cell size distribution, calculated based on the theoretical ZND induction zone length, corresponding to the simulation composition distribution showed that a cell size gradient-based failure criterion successfully predicted the extent of propagation in the layer.

实验研究了在惰性气体上可燃气体层中的爆轰传播。通过打开一个滑动门,最初将氮稀释的化学计量氢-氧混合物与氩气或氮气分开,在一个12.7毫米宽的通道中形成了这一层。当较轻的可燃气体层沿通道轴向扩散时,沿界面扩散产生沿层高的成分梯度。门前驱动段爆燃-爆轰过渡产生的稳定爆轰波传入可燃层。层的轴向扩散距离和层间质量扩散量受门打开后火焰点火延迟时间的控制。用纹影视频和烟灰箔测量了爆轰通过该层的传播程度。结果表明,由于层前缘的过度混合,爆轰在层内的传播是自限的。三维数值模拟,包括粘性和多组分质量扩散效应,预测了层内成分分布。基于理论ZND诱导区长度计算的胞元尺寸分布与模拟组成分布相对应,表明基于胞元尺寸梯度的失效准则成功地预测了层内的传播程度。
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引用次数: 0
Control of separation shock unsteadiness in an incident-shock-induced interaction 碰撞-冲击相互作用中分离冲击非定常的控制
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2023-04-24 DOI: 10.1007/s00193-023-01129-2
C. Manisankar, S. B. Verma

Separation shock unsteadiness in an incident-shock-induced interaction with and without control is evaluated in a Mach 2.05 flow using a (14^{circ }) shock generator. An array of mechanical vortex generators (MVGs) in the form of rectangular vanes (MVG1), ramp vanes (MVG2), and a delta ramp (MVG3) is placed (14delta ) upstream of the interaction region ((delta =5.2,{textrm{mm}}) being the local boundary layer thickness at the interaction). Among all the devices tested, MVG1 shows a maximum reduction of the separation length (about 28% relative to the no-control case). The spectra at separation also show a shift in the dominant frequency from 220 Hz without control to 539 Hz with MVG1. Interestingly, the peak rms (root mean square) value is seen to occur with control at much larger intermittency values ((upgamma _{upsigma ,{textrm{max}}}=0.92) for MVG1) in contrast to the no-control case in which it occurs at (upgamma _{upsigma ,{textrm{max}}}=0.5) as reported so far. The auto-correlation at the separation and reattachment shock locations indicates the presence of relatively small-scale structures with control as compared to the case without control. Out of all the control cases tested, MVG1 exhibits better separation control with a relatively lower unsteadiness level.

在马赫数为2.05的流动中,利用(14^{circ })激波发生器对有控制和无控制的入射激波相互作用中的分离激波非定常进行了评估。一组机械涡发生器(mvg)以矩形叶片(MVG1)、斜坡叶片(MVG2)和三角洲斜坡(MVG3)的形式放置在相互作用区域的上游(14delta ) ((delta =5.2,{textrm{mm}})为相互作用处的局部边界层厚度)。在所有测试的器件中,MVG1显示出最大的分离长度减少(约28% relative to the no-control case). The spectra at separation also show a shift in the dominant frequency from 220 Hz without control to 539 Hz with MVG1. Interestingly, the peak rms (root mean square) value is seen to occur with control at much larger intermittency values ((upgamma _{upsigma ,{textrm{max}}}=0.92) for MVG1) in contrast to the no-control case in which it occurs at (upgamma _{upsigma ,{textrm{max}}}=0.5) as reported so far. The auto-correlation at the separation and reattachment shock locations indicates the presence of relatively small-scale structures with control as compared to the case without control. Out of all the control cases tested, MVG1 exhibits better separation control with a relatively lower unsteadiness level.
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引用次数: 0
Analysis of shock wave acceleration from normal detonation reflection 法向爆轰反射冲击波加速度分析
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2023-04-21 DOI: 10.1007/s00193-023-01126-5
D. T. Schoeffler, J. E. Shepherd

Normal detonation reflection generates a shock wave that exhibits complicated dynamics as it propagates through the incident detonation and post-detonation flow. Ideal models have historically neglected the influence of a finite detonation thickness on the reflected shock due to its small size relative to laboratory scales. However, one-dimensional numerical simulations show that the reflected shock accelerates to a large shock speed not predicted by ideal theory as it propagates through the incident detonation. Analysis with a derived shock-change equation identifies the principal role of the highly nonuniform upstream flow on producing the large shock acceleration. Simulations of detonation reflection show how a finite detonation thickness affects the entire trajectory of the reflected shock.

正常爆轰反射产生的激波在入射爆轰流和爆轰后流中传播时表现出复杂的动力学特性。理想模型历来忽略了有限爆轰厚度对反射激波的影响,因为它相对于实验室尺度较小。然而,一维数值模拟表明,反射激波在入射爆轰过程中加速到理想理论无法预测的大激波速度。利用推导的激波变化方程进行分析,确定了上游高度不均匀流动对产生大激波加速度的主要作用。爆轰反射的模拟显示了有限爆轰厚度对反射激波的整个轨迹的影响。
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引用次数: 0
Shock detachment from curved wedges by local choking: numerical verification 由局部窒息引起的弯曲楔的激波脱离:数值验证
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2023-04-18 DOI: 10.1007/s00193-023-01122-9
S. Mölder, A. Gulamhussein

Computational fluid dynamics shows that a shock wave can detach from the sharp leading edge of a curved wedge at a wedge angle smaller than the classical maximum flow deflection as well as the sonic wedge angle. This is attributed to the inability of the sonic flow, at the wedge trailing edge, to pass as much mass flow as is being admitted through the shock wave attached at the leading edge. At this condition, the flow is unsteady, causing both the sonic surface and the shock to make adjustments in their shapes and positions to achieve a steady state with mass-flow balance. As a result, the shock wave becomes detached. Time-accurate CFD calculations show the gasdynamic details of the adjustment where the flow and the detached shock assume a steady state as the mass-flow imbalance gradually decreases to zero. This mechanism of shock detachment, occurring near the leading edge, is called local choking to distinguish it from shock detachment due to global choking that occurs because of flow choking at the exit of a convergent duct and to distinguish it as well from detachment due to an excessive leading-edge deflection. The local choking mechanism has been postulated to be a cause of shock detachment from doubly curved wedges. An analysis, based on curved shock theory and confirmed by CFD, shows that local choking and shock detachment from a doubly curved leading edge are dependent on Mach number, wedge angle, wedge curvature (both streamwise and cross-stream), and wedge length.

计算流体力学表明,激波可以在小于经典最大流动偏转角和声速楔角的楔形尖角处脱离弯曲楔。这是由于楔形尾缘处的声波流无法通过前缘处的激波所允许的质量流。在这种情况下,流动是非定常的,使得声面和激波都进行形状和位置的调整,从而达到质量流量平衡的稳态。结果,冲击波被分离了。时间精确的CFD计算显示了调整的气体动力学细节,其中随着质量流量不平衡逐渐减小到零,流动和分离激波呈现稳定状态。这种发生在前缘附近的激波脱离机制被称为局部窒息,以区别于由于汇聚管道出口处的流动窒息而导致的全局窒息所导致的激波脱离,也区别于由于前缘过度偏转而导致的脱离。局部窒息机制被认为是双弯曲楔的激波脱离的原因。基于弯曲激波理论并经CFD验证的分析表明,双弯曲前缘的局部窒息和激波脱离与马赫数、楔形角、楔形曲率(包括顺流和横流)和楔形长度有关。
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引用次数: 0
Development of simple evaluation system for Hugoniot of polymethyl methacrylate 聚甲基丙烯酸甲酯Hugoniot简易评价系统的开发
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2023-04-12 DOI: 10.1007/s00193-023-01121-w
Y. Takahashi, S. Kubota, T. Saburi

The Hugoniot shock wave velocity ((U_{textrm{S}}))–particle velocity ((u_{textrm{p}})) curve of polymethyl methacrylate (PMMA) was measured in an experiment using only 2.5 g of a high explosive. The thickness of the plate was varied to accurately determine (U_{textrm{S}}) at an arbitrary position in the PMMA. Image analysis was conducted to obtain the xt diagram of shock wave propagating in PMMA along the axis of the explosive, and its derivative was used to obtain the on-axis (U_{textrm{S}}) at an arbitrary location. Using the pressure measurement results and (U_{textrm{S}}) values, the Hugoniot (U_{textrm{S}})(u_{textrm{p}}) curve of PMMA was obtained by calculating (u_{textrm{p}}) from the momentum conservation law. The results are in very good agreement with the reported values for flat-plate impact experiments conducted using an impact gun. It was found that the Hugoniot (U_{textrm{S}})(u_{textrm{p}}) curve of PMMA on the low-pressure side ((u_{textrm{p}} < 0.5, {textrm{km}}/{textrm{s}})) can be evaluated with high accuracy using a simple measurement method that does not use plane waves.

用2.5 g烈性炸药测量了聚甲基丙烯酸甲酯(PMMA)的Hugoniot冲击波速度((U_{textrm{S}})) -粒子速度((u_{textrm{p}}))曲线。板的厚度变化,以准确地确定(U_{textrm{S}})在PMMA的任意位置。通过图像分析得到冲击波在PMMA中沿炸药轴向传播的x-t图,并利用其导数得到任意位置上的轴向(U_{textrm{S}})。利用压力测量结果和(U_{textrm{S}})值,根据动量守恒定律计算(u_{textrm{p}}),得到PMMA的Hugoniot (U_{textrm{S}}) - (u_{textrm{p}})曲线。结果与用冲击枪进行的平板冲击实验的报告值吻合得很好。研究发现,采用一种不使用平面波的简单测量方法,可以对PMMA低压侧的Hugoniot (U_{textrm{S}}) - (u_{textrm{p}})曲线((u_{textrm{p}} < 0.5, {textrm{km}}/{textrm{s}}))进行高精度的测量。
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引用次数: 0
Turbulence modeling of 3D high-speed flows with upstream-informed corrections 具有上游信息修正的三维高速流动湍流建模
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2023-04-12 DOI: 10.1007/s00193-023-01123-8
C. Prasad, D. V. Gaitonde

Turbulence modeling has the potential to revolutionize high-speed vehicle design by serving as a co-equal partner to costly and challenging ground and flight testing. However, the fundamental assumptions that make turbulence modeling such an appealing alternative to its scale-resolved counterparts also degrade its accuracy for practical high-speed configurations, especially when fully 3D flows are considered. The current investigation develops a methodology to improve the performance of turbulence modeling for a complex Mach 8.3, 3D shock boundary layer interaction (SBLI) in a double fin geometry.A representative two-equation model, with low-Reynolds-number terms, is used as a test bed. Deficiencies in the baseline model are first elucidated using benchmark test cases involving a Mach 11.1 zero pressure gradient boundary layer and a Mach 6.17 flow over an axisymmetric compression corner. From among different possibilities, two coefficients are introduced to inhibit the non-physical over-amplification of (i) turbulence production and (ii) turbulence length-scale downstream of a shock wave. The coefficients rely on terms already present in the original model, which simplifies implementation and maintains computational costs. The values of the coefficients are predicated on the distribution of turbulence quantities upstream of the shock; this ensures that the modifications do not degrade the model predictions in simpler situations such as attached boundary layers, where they are unnecessary. The effects of the modifications are shown to result in significant improvements in surface pressure and wall heat flux for the 3D SBLI test case, which contains numerous features not observed in 2D situations, such as 3D separation, skewed boundary layers, and centerline vortices. Considerations on the inflow values of turbulence variables and mesh resolution are provided.

湍流建模作为昂贵且具有挑战性的地面和飞行测试的合作伙伴,有可能彻底改变高速车辆的设计。然而,使湍流建模成为比尺度解析模型更有吸引力的替代方案的基本假设,也降低了其在实际高速配置中的准确性,特别是在考虑全三维流动时。目前的研究开发了一种方法,以提高紊流建模的性能,复杂的马赫8.3,三维激波边界层相互作用(SBLI)在双翅几何。采用具有代表性的低雷诺数项双方程模型作为试验平台。基线模型的缺陷首先通过涉及马赫数11.1的零压力梯度边界层和马赫数6.17的轴对称压缩角流的基准测试案例加以阐明。从不同的可能性中,引入了两个系数来抑制(i)湍流产生和(ii)激波下游湍流长度尺度的非物理过度放大。系数依赖于原始模型中已经存在的项,这简化了实现并保持了计算成本。这些系数的值是根据激波上游湍流量的分布来确定的;这确保了在简单的情况下,如附加边界层,修改不会降低模型预测,在那里它们是不必要的。3D SBLI测试用例的表面压力和壁面热流密度显著改善,其中包含许多在2D情况下未观察到的特征,如3D分离、倾斜边界层和中心线涡。给出了湍流变量入流值和网格分辨率的考虑。
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引用次数: 0
Three-dimensional full-field simulation of sonic boom emanating from complex geometries over buildings 建筑物上空复杂几何形状声爆的三维全场模拟
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2023-04-12 DOI: 10.1007/s00193-023-01125-6
R. Yamashita, N. Nikiforakis

Full-field direct simulation of sonic boom has only been applied to the analysis of axisymmetric geometries. In this work, a more realistic analysis of complex geometries over buildings is achieved by employing a combination of the following four numerical approaches: (i) a hierarchical structured adaptive mesh refinement method, (ii) a ghost fluid method for incorporating the immersed boundary conditions on the solid–fluid interfaces, (iii) a well-balanced finite volume method to allow stable stratification of the atmosphere, and (iv) a segmentation method of the computational domain to increase the efficiency of the computations. The three-dimensional Euler equations with a gravitational source term are solved over a stratified atmosphere. The simulation is split into two stages. Firstly, the entire flow field that involves a delta wing body is solved without buildings. Thereafter, the flow behaviors near the ground are recomputed considering rectangular and L-type buildings. Computational results show that the near- and far-fields waveforms are comparable to those from the wind tunnel experiment and the waveform parameter method, respectively. The waveform shape behind the shock waves is spiked due to the diffracted waves around buildings, with the spiking effect in L-type buildings being stronger than that in rectangular buildings. The pressure rises for rectangular and L-type buildings are significantly amplified due to double and triple reflections, respectively, each with an amplification factor comparable to the theoretical value. These results indicate that full-field simulation is promising for analyzing three-dimensional characteristics of sonic boom emanating from complex geometries passing over buildings.

音爆的全场直接模拟只应用于轴对称几何形状的分析。在这项工作中,通过采用以下四种数值方法的组合,可以对建筑物上的复杂几何形状进行更现实的分析:(i)一种分层结构自适应网格细化方法,(ii)一种包含固体-流体界面浸入边界条件的鬼流体方法,(iii)一种平衡良好的有限体积方法,允许大气的稳定分层,以及(iv)一种计算域分割方法,以提高计算效率。在分层大气中求解了带引力源项的三维欧拉方程。仿真分为两个阶段。首先,在不考虑建筑物的情况下,对涉及三角翼体的整个流场进行求解。然后,重新计算了考虑矩形和l型建筑物的近地流动特性。计算结果表明,近场和远场波形分别与风洞实验和波形参数法的结果相当。由于建筑物周围绕射波的作用,激波后的波形形状呈尖峰状,且l型建筑物的尖峰效应强于矩形建筑物。矩形和l型建筑的压力上升分别由于双重和三重反射而被显著放大,每种放大系数与理论值相当。这些结果表明,利用全场模拟分析复杂几何形状的建筑物上空声爆的三维特性是有希望的。
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引用次数: 0
On the effect of characterised initial conditions on the evolution of the mixing induced by the Richtmyer–Meshkov instability 论特征初始条件对由richmyer - meshkov不稳定性引起的混合演化的影响
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2023-04-12 DOI: 10.1007/s00193-023-01124-7
M. Rasteiro dos Santos, Y. Bury, S. Jamme, J. Griffond

Time-resolved schlieren photography was used to visualise mixing zones induced by the Richtmyer–Meshkov instability. These were initiated with four different initial conditions: three of them with monotonic, single-mode shapes and one with a non-monotonic, multi-mode shape. These initial conditions were generated by an innovative experimental concept, the Micro Rotating Shutter System. The results of this experimental campaign reveal that the shape of the initial air–helium interface influences the subsequent development of the resulting mixing zone. Over the measurement time range, the width of the mixing zone induced by this instability is correctly fitted by a power law. Its growth exponent depends on the monotonicity of the initial air–helium interface: while mixing widths originating from single-mode initial conditions are almost superimposed, a lesser growth exponent is found for the multi-mode initial condition. The Reynolds number based on the width of the mixing zone suggests that both flows initiated with single- and multi-mode initial conditions reach a fully turbulent state after the interaction with the reflected shock wave (reshock). The schlieren photography visualisations presented here also allow to illustrate the structure of the induced mixing and highlight the effect of the initial conditions on the large-scale structures of the Richtmyer–Meshkov instability-induced mixing.

时间分辨纹影摄影用于观察由richhtmyer - meshkov不稳定性引起的混合区。它们由四种不同的初始条件启动:其中三种具有单调单模态形状,另一种具有非单调多模态形状。这些初始条件是由一个创新的实验概念产生的,即微旋转快门系统。实验结果表明,初始空气-氦界面的形状影响混合区的后续发展。在测量时间范围内,由这种不稳定性引起的混合区宽度可以用幂律正确地拟合。它的增长指数取决于初始气氦界面的单调性:单模初始条件下产生的混合宽度几乎是叠加的,而多模初始条件下的增长指数较小。基于混合区宽度的雷诺数表明,在与反射激波(再激波)相互作用后,以单模态和多模态初始条件启动的流动均达到完全湍流状态。这里展示的纹影摄影可视化也可以说明诱导混合的结构,并突出了初始条件对richhtmyer - meshkov不稳定诱导混合的大尺度结构的影响。
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引用次数: 0
Experimental results for 25-mm and 51-mm rotating detonation rocket engine combustors 25-mm和51-mm旋转爆轰火箭发动机燃烧室实验结果
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2023-04-12 DOI: 10.1007/s00193-023-01120-x
C. Knowlen, T. Mundt, M. Kurosaka

An ongoing rotating detonation rocket engine program is investigating the influence of combustor annulus radii on RDRE operating characteristics with flat-faced impinging injectors. To facilitate the isolation of all but the radius of curvature effects in the experiments, the annular gap was kept constant at 5 mm in combustors having either 25-mm or 51-mm outer diameter. The mixing processes were kept similar by utilizing injectors with the same net injector-to-annular gap area ratio (AR = 0.11), same radial separation distance of the orifices, and same center-of-gap impingement distance from the front-end wall. The wave dynamics, plenum pressure, and axial pressure profiles in these RDREs were compared over the mass flux and equivalence ratio ranges of (80{-}400,text {kg/s/m}^{2}) and 0.26(-)2.6, respectively, with gaseous methane–oxygen propellant. Experiments showed that stable one-wave operation would occur in the 25-mm RDRE at most mass fluxes where stable two-wave operation was established in the 51-mm RDRE. Stable one-wave operation with a single counter-rotating wave was maintained in the 51-mm RDRE at mass fluxes of (240,text {kg/s/m}^{2}) and below. Under these fueling conditions in the 25-mm RDRE, a counter-rotating wave also appeared while it operated with a single dominant wave. The wave spin speeds were typically 20–40% less than the Chapman–Jouguet detonation speed of the propellant and depended only on mass flux and wave number rather than the annulus diameter.

一个正在进行的旋转爆轰火箭发动机项目正在研究燃烧室环空半径对平面撞击喷油器RDRE工作特性的影响。为了在实验中隔离除曲率半径外的所有影响,在外径为25mm或51mm的燃烧室中,环形间隙保持在5mm不变。使用相同净喷口与环空间隙面积比(AR = 0.11)、相同孔口径向分离距离和相同间隙中心与前壁撞击距离的喷嘴,可以保持混合过程相似。分别在质量通量(80{-}400,text {kg/s/m}^{2})和等效比0.26 (-) 2.6范围内比较了这些气体甲烷-氧气推进剂的波动动力学、充气压力和轴向压力分布。实验表明,在大多数质量通量下,25mm rdrre会出现稳定的一波运行,而51 mm rdrre则会出现稳定的两波运行。在质量通量为(240,text {kg/s/m}^{2})及以下的51-mm rdrre中,保持了稳定的单波反向旋转波运行。在这些加注条件下,在25毫米rdrre中,当它以单一主导波运行时,也出现了反向旋转波。波的自旋速度通常在20-40之间% less than the Chapman–Jouguet detonation speed of the propellant and depended only on mass flux and wave number rather than the annulus diameter.
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引用次数: 0
Real gas effect on ignition in ideal and non-ideal reactors 理想和非理想反应器中实际气体对点火的影响
IF 2.2 4区 工程技术 Q2 Engineering Pub Date : 2023-02-17 DOI: 10.1007/s00193-022-01118-x
I. Farias, Z. Weng, R. Mével

We studied the real gas effect on the ignition characteristics in chemical reactors with one-step irreversible reaction. The real gas effects were characterized by the inter-molecular attraction term ((alpha )) and the finite molecular volume term ((beta )). The Noble-Abel and van der Waals equations of state were employed to derive non-dimensional reactor models. In addition to ideal reactors, i.e., constant volume and constant pressure, non-ideal reactors that account for the non-ideal pressure variation in shock tube and rapid compression machine were also considered. For all reactors, low value of (alpha /beta ) and high value of (beta ) (approximately (alpha /beta <{{1.0}}) and (beta >{{0.1}})) induce a decrease of the ignition delay-time, while high value of both (alpha /beta ) and (beta ) (approximately (alpha /beta >{{2.0}}) and (beta >{{0.1}})) induces an increase of the ignition delay-time. The variations of the ignition delay-time induced by real gas effects are mainly related to the change of the fugacity coefficient with (alpha ) and (beta ). Additional contributions are due to the real gas heat capacity at constant pressure when considering a constant pressure reactor and to non-ideal volume variation when considering non-ideal reactors. The impact of various parameters was also investigated, including the heat capacity ratio of perfect gas, the reduced activation energy of the one-step reaction, and the heat content of the mixtures. Comparison with simulation performed with detailed reaction mechanisms and considering real gas models demonstrates that the present approach constitutes a rapid and simple, yet qualitatively or even quantitatively accurate method to assess the need of accounting for real gas effects to model chemical kinetics under high-pressure conditions.

研究了一步不可逆反应中真实气体对化学反应器着火特性的影响。实际气体效应由分子间引力项((alpha ))和有限分子体积项((beta ))表征。利用Noble-Abel和van der Waals状态方程推导了无量纲反应堆模型。除了理想反应器,即定容定压外,还考虑了激波管和快速压缩机中造成非理想压力变化的非理想反应器。对于所有反应堆来说,低(alpha /beta )值和高(beta )值(约为(alpha /beta <{{1.0}})和(beta >{{0.1}}))导致点火延迟时间减少,高(alpha /beta )和(beta )值(约为(alpha /beta >{{2.0}})和(beta >{{0.1}}))导致点火延迟时间增加。实际气体效应引起的点火延迟时间的变化主要与逸度系数(alpha )和(beta )的变化有关。当考虑定压反应器时,额外的贡献是由于恒压下的实际气体热容量,当考虑非理想反应器时,是非理想体积变化。考察了理想气体的热容比、一步反应的还原活化能、混合物的热含量等参数对反应的影响。与详细反应机理的模拟和考虑真实气体模型的模拟比较表明,本方法是一种快速、简单、定性甚至定量准确的方法,可以评估在模拟高压条件下化学动力学时考虑真实气体效应的必要性。
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引用次数: 1
期刊
Shock Waves
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