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Screening-level assessment of airborne carcinogen risks from uncontrolled waste sites. 不受控制的废物场所空气传播致癌物风险的筛选水平评估。
Pub Date : 1989-04-01 DOI: 10.1080/08940630.1989.10466545
T F Wolfinger

This report presents screening-level estimates of the general level of cancer risks arising from air emission from uncontrolled waste sites. Twenty-five National Priorities List sites were chosen randomly and airborne cancer risks estimated for each site in terms of risk to the maximally exposed individual (MEI risk), average individual risk (AEI risk), and population incidence. The estimates were developed using the EPA Human Exposure Model using assumptions on the rate and toxicity of site emissions. MEI risks ranged from 4 X 10(-9) to 1 X 10(-6) with an average of about 5 X 10(-7). AEI risks for individuals residing within four miles of the sites average about 10(-8), declining significantly for individuals residing at longer distances. Population incidence was low at all sites ranging from 2 X 10(-4) to 1 X 10(-2) cancer cases expected within 60 miles of the sites. Due to the uncertainties in this type of analysis and the underlying study assumptions, these results must be viewed with caution. Nonetheless, some preliminary conclusions can be drawn from the analysis, principally that airborne cancer risks from uncontrolled waste sites are likely to be small in most cases, with the greatest concern being maximally exposed individuals rather than the number of cancer cases expected in the exposed population.

本报告提出了对不受控制的废物场所排放的空气引起的癌症风险一般水平的筛查水平估计。随机选择25个国家重点清单站点,并根据最大暴露个体风险(MEI风险)、平均个体风险(AEI风险)和人群发病率估算每个站点的空气传播癌症风险。这些估计是根据环境保护局人体暴露模型,根据对现场排放的速率和毒性的假设得出的。MEI风险范围从4 × 10(-9)到1 × 10(-6),平均约为5 × 10(-7)。居住在4英里范围内的人的AEI风险平均约为10(-8),居住在较远距离的人的AEI风险显著下降。所有站点的人口发病率都很低,在站点周围60英里范围内,预计癌症病例数为2 × 10(-4)至1 × 10(-2)。由于这种类型的分析和潜在的研究假设的不确定性,这些结果必须谨慎看待。尽管如此,可以从分析中得出一些初步结论,主要是在大多数情况下,来自不受控制的废物场址的空气传播癌症风险可能很小,最令人担忧的是最大程度受照射的个人,而不是受照射人群中预期的癌症病例数。
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引用次数: 11
Adaptation by older individuals repeatedly exposed to 0.45 parts per million ozone for two hours. 老年人反复暴露在百万分之0.45的臭氧环境中两小时的适应能力。
Pub Date : 1989-02-01 DOI: 10.1080/08940630.1989.10466521
J F Bedi, S M Horvath, D M Drechsler-Parks

To test for an increased reaction to ozone (O3) in older individuals following an initial exposure, and to test for adaptation and its duration, we exposed 10 men and 6 women (60-89 years old) in an environmental chamber to filtered air and 3 consecutive days of O3 exposure (0.45 ppm), followed by a fourth O3 exposure day after a two day hiatus. Subjects alternated 20-min exercise (minute ventilation = 27 L) and rest periods for 2 hours during each exposure. Subjects rated from one to five, 16 possible respiratory/exercise symptoms prior to and following the exposure. Pulmonary function tests were performed before, and during each rest period and following the exposure. Metabolic measurements were obtained during each exercise period. No significant changes in any symptom question occurred, in spite of a threefold increase in the total number of reported symptoms during O3 exposure. Small but significant pre-to-post decrements on the first and second O3 days in forced vital capacity (FVC-111 and 104 mL), forced expiratory volume in 1 (FEV1-171 and 164 mL) and 3 seconds (FEV3-185 and 172 mL) occurred without concomitant changes in any flow parameter of the forced expiratory maneuver. No differences in the group mean response in FVC, FEV1 or FEV3 on the third or fourth day of O3 exposure and the filtered air exposure were found. The observed changes were due to significant physiological changes in eight of the subjects. Unlike young subjects, no evidence of an increased pulmonary function response to a second consecutive O3 exposure was observed.(ABSTRACT TRUNCATED AT 250 WORDS)

为了测试初次暴露后老年人对臭氧(O3)的反应是否增加,并测试适应及其持续时间,我们将10名男性和6名女性(60-89岁)暴露在一个环境室中,连续3天暴露于过滤空气中(0.45 ppm),然后在两天的间歇后进行第4天的O3暴露。每次暴露时,受试者交替进行20分钟运动(每分钟通气27 L)和休息2小时。受试者在接触之前和之后被评为1到5,16种可能的呼吸/运动症状。在暴露前、每次休息期间和暴露后分别进行肺功能检查。在每个运动期间进行代谢测量。尽管在O3暴露期间报告的症状总数增加了三倍,但任何症状问题都没有发生重大变化。强制肺活量(FVC-111和104 mL)、第1天(FEV1-171和164 mL)和第3秒(FEV3-185和172 mL)的强制呼气量在第1天和第2天前后出现了小但显著的下降,而强制呼气操作的任何流量参数均未发生变化。在O3暴露和过滤空气暴露的第3、4天,各组FVC、FEV1和FEV3的平均反应没有差异。观察到的变化是由于8名受试者发生了显著的生理变化。与年轻受试者不同,未观察到连续第二次暴露于O3后肺功能反应增加的证据。(摘要删节250字)
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引用次数: 22
Emission of airborne bacteria from a hospital incinerator. 医院焚化炉排放的空气中细菌。
Pub Date : 1989-02-01 DOI: 10.1080/08940630.1989.10466516
R J Allen, G R Brenniman, R R Logue, V A Strand

Only five studies have been found in the literature which provide any indication of the effectiveness of incineration for rendering infectious hospital waste innocuous. Although there is an indication from these studies for release of bacteria in stack gas, none of the studies identified the bacteria or determined the source of bacteria. The purpose of the present study was to investigate the potential for a hospital incinerator to release human pathogenic bacteria into the ambient environment. In this study, waste spiked with Bacillus subtillis was burned in a hospital incinerator. Although bacteria were found in the incinerator stack gas, (concentrations ranged from not detectable to 1157 colonies/m3 of air) no Bacillus subtilis was recovered from the stack gas. The results suggest that the source of the stack gas bacteria was not from unburned waste or from outdoor air. Analysis of samples of air from the incinerator room (not simultaneous with the stack gas samples) indicates that the source of the stack gas bacteria was most likely the combustion air.

文献中只发现五项研究表明焚烧使感染性医院废物无害化的有效性。虽然这些研究表明烟囱气体中有细菌释放,但没有一项研究确定了细菌或确定了细菌的来源。本研究的目的是调查医院焚化炉向周围环境释放人类致病菌的可能性。在这项研究中,在医院的焚化炉中焚烧含有枯草芽孢杆菌的废物。虽然在焚烧炉烟囱气体中发现了细菌(浓度从无法检测到每立方米空气1157菌落不等),但没有从烟囱气体中回收枯草芽孢杆菌。结果表明,烟气细菌的来源既不是来自未燃烧的废物,也不是来自室外空气。对焚烧炉室空气样本的分析(不与烟囱气体样本同时进行)表明,烟囱气体细菌的来源最有可能是燃烧空气。
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引用次数: 15
Environmental litigation. 环境诉讼。
Pub Date : 1989-01-01 DOI: 10.1007/springerreference_29553
G. A. Rodenhausen
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引用次数: 4
Ozone trends in Atlanta, Georgia: have emission controls been effective? 乔治亚州亚特兰大的臭氧趋势:排放控制是否有效?
Pub Date : 1989-01-01 DOI: 10.1080/08940630.1989.10466505
R W Lindsay, J L Richardson, W L Chameides

Nine years of summertime ozone data from the Atlanta metropolitan area are analyzed and compared to local emissions of volatile organic carbon and nitrogen oxides. Trends from 1979 to 1987 were studied for the number of days per year ozone exceeded the NAAQS standard, the second-highest ozone level observed per year, and the first quartile summertime average ozone observed, as well as the mean difference between the ozone level observed downwind and upwind of the city. Because this last parameter is sensitive to chemical factors but relatively insensitive to the number of days each year with meteorological conditions conducive to ozone formation, its trend may be best suited for determining how effective emission controls have been in reducing O3 in the Atlanta area. In spite of the fact that sizeable reductions have been claimed for volatile organic carbon emissions over the past several years, the data give no indication that ozone levels have decreased and in fact imply that summertime ozone production may have increased. The results imply that either emissions have not decreased as much as has been claimed or that ozone is not sensitive to anthropogenic volatile organic carbon emissions. In either event, a reevaluation of our nation's strategy for O3 abatement in Atlanta and comparable cities is needed.

分析了亚特兰大市区9年的夏季臭氧数据,并将其与当地挥发性有机碳和氮氧化物的排放进行了比较。研究了1979 ~ 1987年臭氧年平均值超过NAAQS标准的日数、臭氧年第二高值、臭氧年平均值前四分位数的变化趋势,以及北京市上下风向臭氧年平均值差值的变化趋势。由于最后一个参数对化学因素敏感,但对每年有利于臭氧形成的气象条件的天数相对不敏感,因此其趋势可能最适合用于确定亚特兰大地区减少臭氧排放控制的有效程度。尽管在过去几年中,人们声称挥发性有机碳的排放量有了相当大的减少,但数据并没有表明臭氧水平已经下降,实际上表明夏季臭氧产量可能有所增加。研究结果表明,要么臭氧层的排放量并没有像人们声称的那样减少那么多,要么臭氧层对人为的挥发性有机碳排放并不敏感。无论是哪种情况,我们都需要重新评估我们国家在亚特兰大和类似城市的臭氧减排战略。
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引用次数: 35
Monitoring of parts-per-billion levels of formaldehyde using a diffusive sampler. 使用扩散采样器监测十亿分之一的甲醛水平。
Pub Date : 1989-01-01 DOI: 10.1080/08940630.1989.10466506
J O Levin, R Lindahl, K Andersson

A diffusive sampler for formaldehyde originally designed for use in personal monitoring of worker exposure has been evaluated for static measurement of low formaldehyde levels in indoor air. The sampler consists of a 37-mm glass fiber filter impregnated with 2,4-dinitrophenylhydrazine and phosphoric acid and mounted in a polystyrene filter cassette. Formaldehyde is sampled by controlled diffusion and subsequent hydrazone formation on the filter. The hydrazone is eluted from the filter with acetonitrile and analyzed by liquid chromatography and a UV detector. The diffusive sampler was evaluated for static (area) sampling in several industries, offices, and homes with formaldehyde levels of 6-200 ppb. Results from diffusive samplers were compared with results from pumped samplers. Even at low wind velocities (less than 0.01 m.s-1) there was good agreement between pumped and diffusive samples. The sensitivity will be 1 ppb in a 24-h sample, making the sampler especially useful for indoor air monitoring of low formaldehyde levels.

最初设计用于工人接触情况个人监测的甲醛扩散采样器已被评估用于室内空气中低甲醛水平的静态测量。采样器包括一个37毫米玻璃纤维过滤器浸渍2,4-二硝基苯肼和磷酸,并安装在聚苯乙烯过滤盒。通过控制扩散和随后在过滤器上形成腙来取样甲醛。用乙腈从过滤器中洗脱腙,用液相色谱法和紫外检测器进行分析。在甲醛水平为6-200 ppb的几个工业、办公室和家庭中,对扩散采样器进行了静态(区域)采样评估。将扩散采样器的结果与泵送采样器的结果进行了比较。即使在低风速下(小于0.01 ms -1),泵送样品和扩散样品之间也有很好的一致性。灵敏度将为1 ppb在一个24小时的样品,使采样器特别有用的室内空气监测低甲醛水平。
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引用次数: 20
Speciation of arsenic in ambient aerosols collected in Los Angeles. 洛杉矶收集的大气气溶胶中砷的形态。
Pub Date : 1989-01-01 DOI: 10.1080/08940630.1989.10466511
E S Rabano, N T Castillo, K J Torre, P A Solomon

First-time measurements of the potentially toxic inorganic species of arsenic (arsenite and arsenate) have been obtained in fine (less than 2.5 microns AD) and coarse (greater than 2.5 microns AD) atmospheric particles in the Los Angeles area. A recently developed method that includes procedures for sample collection, preparation, and analysis was used in this study. Size-fractionated aerosol samples were collected with a high-volume dichotomous virtual impactor that employed polytetrafluoroethylene filters. Results were obtained for the recovery of arsenic standards added to unexposed and collected filters. Data from this study, indicated that the recently developed speciation method can be used to determine concentrations of As(III) and As(V) in atmospheric particulate matter samples. Size-fractionated aerosol samples were collected in the city of Industry during January and February 1987. In most samples, As(III) and As(V) were above the detection limit (approximately 1 ng m-3 of either species) in both aerosol size fractions. A greater portion (about 75 percent) of the two species were observed in the fine particles. The As(III)/As(V) ratio for both particle sizes was close to 1 (i.e., an equal mixture of both species). Comparison of total suspended particulate arsenic measured by the speciation method to that measured by a routine California Air Resources Board-approved procedure showed good agreement (r = 0.94), indicating both methods were approximately equivalent for the collection and analysis of aerosol arsenic.

在洛杉矶地区的细微(小于2.5微米)和粗糙(大于2.5微米)大气颗粒中首次测量了潜在有毒的无机砷(亚砷酸盐和砷酸盐)。在本研究中使用了一种最近开发的方法,包括样品收集、制备和分析的程序。采用聚四氟乙烯过滤器的大容量二分虚拟冲击器收集大小分级气溶胶样品。对未暴露和收集的滤水器中添加的砷标准进行了回收。本研究的数据表明,最近发展的物种形成方法可以用于测定大气颗粒物样品中As(III)和As(V)的浓度。1987年1月和2月在工业市收集了大小分级气溶胶样品。在大多数样品中,As(III)和As(V)在两种气溶胶大小的组分中均高于检测限(每一种约为1 ng m-3)。在细颗粒中观察到这两种物质的更大比例(约75%)。两种粒径的As(III)/As(V)比值接近于1(即两种物质的混合均匀)。将物种形成法测量的总悬浮颗粒砷与加州空气资源委员会批准的常规程序测量的总悬浮颗粒砷进行比较,结果显示出良好的一致性(r = 0.94),表明这两种方法对于气溶胶砷的收集和分析大致相同。
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引用次数: 21
Hazardous waste minimization: Part X. The waste minimization assessment: a useful tool for the reduction of industrial hazardous wastes. 尽量减少危险废物:第十部分尽量减少废物评估:减少工业危险废物的有用工具。
Pub Date : 1988-12-01 DOI: 10.1080/08940630.1988.10466494
M. Drabkin
This article describes the “nuts and bolts” of implementing a waste minimization program at an industrial facility which has made a commitment to carry out such a program for waste reduction and/or elimination. Under EPA sponsorship, a waste minimization assessment methodology has been developed and applied in a total often such assessments at industrial and DOD facilities. The article reviews the eleven distinct steps that represent the preferred procedure for carrying out a waste minimization assessment at an industrial site. This procedure is presented in detail in the recently published “The EPA Manual for Waste Minimization Opportunity Assessments.” Two case studies are presented which have employed this methodology to develop waste reduction options in the areas of source reduction and recycle/reuse. Lessons learned during the development and application of this methodology are also presented.
本文描述了在工业设施中实施减少废物计划的“具体细节”,该工业设施已承诺实施减少和/或消除废物的计划。在环境保护署的赞助下,制定了一种尽量减少废物的评估方法,并在工业和国防部设施的所有此类评估中加以应用。文章回顾了11个不同的步骤,这些步骤代表了在工业场地进行废物最小化评估的首选程序。该程序在最近出版的“环保署最小化废物机会评估手册”中有详细介绍。提出了两个案例研究,它们采用这种方法在减少来源和回收/再使用方面制定减少废物的备选办法。本文还介绍了在开发和应用该方法过程中所吸取的经验教训。
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引用次数: 8
Hazardous waste minimization: Part X. The waste minimization assessment: a useful tool for the reduction of industrial hazardous wastes. 尽量减少危险废物:第十部分尽量减少废物评估:减少工业危险废物的有用工具。
Pub Date : 1988-12-01
M Drabkin
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引用次数: 0
Adsorption characteristics of activated carbon and XAD4 resin for the removal of hazardous organic solvents. 活性炭和XAD4树脂对有害有机溶剂的吸附特性研究。
Pub Date : 1988-12-01 DOI: 10.1080/08940630.1988.10466490
K E Noll, J N Sarlis
A comparative study has been conducted on adsorption/desorption of six hazardous organic vapors on synthetic resin (XAD4) and activated carbon, using a differential reactor involving the expansion of a quartz spring. While both sorbents can effectively remove the organic vapors, it was observed that at low concentrations activated carbon adsorbed more organic vapor than synthetic resin. At higher, industrial concentrations, the resins adsorbed more vapor as demonstrated by the slopes of the equilibrium isotherms. The resin also showed much higher desorptlon. The effective Intraparticle diffusion coefficients (De) were observed to be strongly dependent on solute concentration. Pore diffusion dominated the adsorption/desorption of the six organic vapors on XAD4 resin. For the carbon system, pore diffusion dominated the adsorption but surface diffusion contributed to the desorptlon process. This is believed to be due to higher Interaction of the adsorbates with activated carbon.
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引用次数: 6
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