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Synthesis, and studying effect of a solvent on the 1H-NMR chemical shifts of 4-Azido-N-(6-chloro-3-pyridazinyl)benzenesulfonamide 4-叠氮- n -(6-氯-3-吡嗪基)苯磺酰胺的合成及溶剂对其1H-NMR化学位移的影响研究
Pub Date : 2021-08-06 DOI: 10.29350/qjps.2021.26.3.1429
Sadiq Hasan
  The compound 4-Azido-N-(6-chloro-3-pyridazinyl)benzenesulfonamide was synthesized and studied using FTIR, and 1H-NMR . The influence of a solvent on the experimental 1H-NMR chemical shifts of title compound is discussed. Small chemical shift Δδ < 0.1 ppm were observed when switching from DMSO-d6 to CD3OD. Record a marked change in chemical shifts valeues Δδ > 0.3 ppm when transform from high-polar solvents (DMSO-d6,and CD3OD)  to low-polar solvent (CDCl3). The 1H-NMR chemical shifts of C2-H and C6-H were shown to have excellent linear correlation with the dielectric constants of the solvents DMSO-d6, CD3OD,and CDCl3 (r = 0.995). The 1H-NMR chemical shifts of C18-H shows a perfect relationship with solvatochromic parameter β (r = 0.999).
合成了化合物4-叠氮- n -(6-氯-3-吡嗪基)苯磺酰胺,并用傅里叶红外光谱和核磁共振对其进行了研究。讨论了溶剂对标题化合物实验1H-NMR化学位移的影响。从DMSO-d6切换到CD3OD时,化学位移Δδ < 0.1 ppm。当从高极性溶剂(DMSO-d6和CD3OD)转变为低极性溶剂(CDCl3)时,记录化学位移值Δδ > 0.3 ppm的显著变化。C2-H和C6-H的1H-NMR化学位移与溶剂DMSO-d6、CD3OD和CDCl3的介电常数呈良好的线性相关(r = 0.995)。C18-H的1H-NMR化学位移与溶剂致变色参数β有很好的关系(r = 0.999)。
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引用次数: 0
Phytoremediation of a Polluted Soil by Purple Plant (Tradescantia pallida L.) Under Different Organic Amendments 紫色植物对污染土壤的修复作用根据不同的有机修订
Pub Date : 2021-08-02 DOI: 10.29350/qjps.2021.26.4.1343
N. Khudhur
Present investigation was performed to determine the ability of purple plant (Tradescantia pallida L.) for removing heavy metals from a contaminated soil particularly nickel, with the aid of different types of organic amendments. Results of soil heavy metal content after application of different fertilizers were: maximum values (ppm) of V, Cr, Ni, Mn, Cu, Zn, As, Mo, Cd, Pb and Ag were respectively: 275.437, 284.807 (control 1), 265.073, 1071.32, 60.0671 (control 2), 77.8288, 9.5162, 8.5267 (control 1), 5.7943 (control 1), 7.5076 (control 2) and 37.8868 (control 1). Whereas, the minimum values (ppm) of V: 104.644, Cr: 85.7222 (commercial fertilizer), Ni: 164.92, Mn: 711.155 (cow dung), Cu: 15.5141 (cow dung), Zn: 43.3929 (commercial fertilizer), As: 3.7819 (cow dung), Mo: 0.000 (plant residue composite and bird manure), Cd: 0.000 (plant residue composite and bird manure), Pb: 4.1535 (bird manure) and Ag: 2.9181 (plant residue composite). This indicate that the use of organic amendment induce the phytoremediation of polluted soils.
在不同类型的有机改良剂的帮助下,对紫色植物(Tradescantia pallida L.)从污染土壤中去除重金属特别是镍的能力进行了研究。施用不同肥料后土壤重金属含量的最大值(ppm)分别为:V、Cr、Ni、Mn、Cu、Zn、As、Mo、Cd、Pb、Ag分别为:275.437、284.807(对照1)、265.073、1071.32、60.0671(对照2)、77.8288、9.5162、8.5267(对照1)、5.7943(对照1)、7.5076(对照2)和37.8868(对照1)。而最小值(ppm)分别为:V: 104.644、Cr: 85.7222(商业肥料)、Ni: 164.92、Mn: 711.155(牛粪)、Cu: 15.5141(牛粪)、Zn:43.3929(商品肥料),As: 3.7819(牛粪),Mo: 0.000(植物残渣复合和鸟粪),Cd: 0.000(植物残渣复合和鸟粪),Pb: 4.1535(鸟粪),Ag: 2.9181(植物残渣复合)。这表明有机改剂的使用诱导了污染土壤的植物修复。
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引用次数: 0
Spectrophotometric determination of Valsartan in pure form and in its pharmaceutical preparations 纯缬沙坦及其制剂的分光光度法测定
Pub Date : 2021-07-31 DOI: 10.29350/qjps.2021.26.4.1317
Q. Rashid, Ruwaida Farman Salih
An easy, rapid and economical spectrophotometric method for  determination of  Valsartan (Val), by reaction with 4-chloro-7-nitrobenzofurazan (NBD-Cl) as reagent in an alkaline interemediate. This method is based on the forming of product between (Val) and the chromogenic reagent (NBD-Cl), to produce a brown color at (pH 11.9) and λmax. 470 nm.  Beer’s Law is obeyed at the concentrations range of (0.4-14.8 µg/ml), with molar absorptivity of (1.05×104 L/mol.cm) and correlation coefficient 0.9827, The limit of detection was 0.557 µg/ml. The suggested method was prosperity implement to the determination of (Val) in  pure form and in its pharmaceutical formulations (tablets).
以4-氯-7-硝基苯并呋喃唑(NBD-Cl)为试剂,在碱性中间体中反应,建立了一种简便、快速、经济的测定缬沙坦(Val)的分光光度法。该方法是基于(Val)与显色剂(NBD-Cl)之间形成产物,在(pH 11.9)和λmax下产生棕色。470海里。在(0.4 ~ 14.8µg/ml)浓度范围内符合比尔定律,摩尔吸光度为(1.05×104 L/mol.cm),相关系数0.9827,检出限为0.557µg/ml。本方法是测定缬草单品及其制剂(片剂)含量的简便易行的方法。
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引用次数: 1
Anti-plasmid activity of Chlorpromazine in types of antibiotics resistant pathogenic bacteria 氯丙嗪对几种耐药病原菌的抗质粒活性研究
Pub Date : 2021-07-27 DOI: 10.29350/qjps.2021.26.4.1405
Al-Hassan A. Qasim, M. Essa
This study was performed to evaluate the ability of chlorpromazine compound to cure the plasmids and remove the antibiotic resistance character of multidrug resistance Gram-negative pathogenic bacteria. The curing experiment was done by incubating bacterial strains in nutrient broth with sub MIC concentration of chlorpromazine, and the disc diffusion method was used before and after curing to evaluate antibiotic resistance pattern of bacteria. Synergetic test of chlorpromazine with antibiotics that the studied bacteria showed resistance toward also done. The results showed the ability of chlorpromazine to remove the plasmids from four bacterial genera out of five genera, where the most plasmid removal cases was with E.cloacae, P.aeruginosa, and P.merabilis, and the loss of antibiotics resistance was observed in the same bacterial genera, but P.merabilis showed the most antibiotics resistance losing by three antibiotics out of nine antibiotics that the bacteria were resistant to them before curing. As for the synergistic effect, the compound showed a synergism with only two antibiotic and with the three aforementioned bacterial genera. From results of this study we concluded the possibility of removing bacteria resistance to antibiotics by eliminating plasmids through using chlorpromazine, and the possibility of using this compound in synergism with antibiotics, this will open the way to find new strategies  to treat many diseases caused by resistant bacteria.
本研究旨在评价复方氯丙嗪对多重耐药革兰氏阴性致病菌的治愈质粒和去除耐药性的能力。采用亚MIC浓度氯丙嗪的营养液培养菌株进行养护实验,养护前后采用圆盘扩散法评价细菌的耐药模式。并进行了氯丙嗪与所研究细菌耐药抗生素的协同试验。结果表明,氯丙嘧啶能够去除5种细菌属中的4种细菌的质粒,其中去除质粒最多的是cloacae、P.aeruginosa和P.merabilis,并且在同一细菌属中观察到抗生素耐药性的丧失,但P.merabilis在治愈前对9种抗生素中的3种抗生素的耐药性丧失最多。在协同作用方面,该化合物仅与两种抗生素和上述三种细菌属具有协同作用。根据本研究结果,我们得出氯丙嗪通过消除质粒来去除细菌对抗生素的耐药性的可能性,以及该化合物与抗生素协同使用的可能性,这将为寻找治疗耐药细菌引起的许多疾病的新策略开辟道路。
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引用次数: 0
Isolation and Identification of Fungal Isolates caused Otomycosis from some Hospitals and Clinics in Mosul with Determination of Their Virulence Factors 摩苏尔部分医院和诊所耳真菌病分离鉴定及其毒力因子测定
Pub Date : 2021-07-27 DOI: 10.29350/qjps.2021.26.4.1413
Nabeel Al-Sharrad, Muhammad A. Al-Kataan, Maha A. Al-Rejaboo
Otomycosis is a fungal infection that frequently involves the external auditory canal. In this study, we aimed to isolation and identification the fungal isolates as etiological agents of otomycosis from some hospitals and clinics in Mosul with determination of their virulence factors of fungal etiological agents. Positive fungal infection was found in (43) samples (71.6%). The most common fungal pathogens were Candida and Aspergillus species, with Candida parapsilosis being the predominant isolates in (11) samples (16.6%). Otomycosis was more common in Female in (26) samples (43.3%).Otomycosis was the highest prevalence aged group 15-40 years (19) samples (31.3%). The present study of virulence factors revealed that the highest biofilm formation isolates were C. parapsilosis is (10) isolates which were distributed between (2) strong and (8) weak biofilm formation.Where C.trpicales, was recorded as least isolates for biofilm production.
耳真菌病是一种真菌感染,经常累及外耳道。在这项研究中,我们旨在从摩苏尔的一些医院和诊所分离和鉴定作为耳霉菌病病原的真菌分离株,并测定其真菌病原的毒力因子。真菌感染阳性43例(71.6%)。最常见的真菌病原菌为念珠菌和曲霉菌,其中假丝酵母(Candida parapsilosis)在11份样本中占主导地位(16.6%)。耳真菌病以女性多见(26例,43.3%)。15 ~ 40岁年龄组(19例)耳真菌病患病率最高(31.3%)。目前对毒力因子的研究表明,生物膜形成率最高的菌株是C. parapsilosis(10)菌株,分布在(2)强生物膜和(8)弱生物膜之间。其中三角梭菌为产膜最少的分离株。
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引用次数: 0
The Environmental Impact Assessment of the Spent Engine Oil Recycling Plant by using Leopold Matrix: Case Study Recycling Plant in Al-Diwaniyah City – Iraq 基于利奥波德矩阵的废机油回收厂环境影响评价——以伊拉克迪瓦尼耶市废机油回收厂为例
Pub Date : 2021-07-27 DOI: 10.29350/qjps.2021.26.4.1391
Mohammed K. Alkasser, Mukhtar D. Abbas
The study achieve to make an environmental impact assessment for a spent engine oil recycling plant in AL-Diwaniyah city – Iraq. The assessment has been carried out using Leopold matrix. The studied plant deals with the bentonite clay as adsorbent material for removing the impurities from spent oil. The waste of bentonite clay which has been discharged as by- product waste without any minimal level of remediation which is harmful to the all environmental components in addition to that, the plant discharges air pollutants during the operation. Leopold matrix is a simple method in terms of applying and using, it can be used easily for a comparison among different projects and gives clarified results. Moreover, the significant characteristic is its ability to covering biological, physical, economic and social environment.  From the results of Leopold matrix analysis, it can be observed that the maximum impact of the plant was on physical components in both quantity and importance, while there are some positive impacts on social components. Generally, all the impacts that caused from the plant is low on the environment by the comparison with maximum locally index of environmental impact value.
本研究的目的是对伊拉克AL-Diwaniyah市某废机油回收厂进行环境影响评价。利用利奥波德矩阵进行了评价。以膨润土为吸附剂,对废油中的杂质进行脱除。膨润土废渣作为副产物排放,没有进行任何最低限度的治理,对环境各组分都有危害,而且在运行过程中还排放大气污染物。利奥波德矩阵在应用和使用上是一种简单的方法,它可以很容易地用于不同项目之间的比较,并给出明确的结果。此外,其显著特点是能够涵盖生物、物理、经济和社会环境。从利奥波德矩阵分析的结果可以看出,在数量和重要性上,植物对物理成分的影响最大,而对社会成分的影响也有一定的积极影响。总的来说,与当地环境影响值指数最大值相比,工厂对环境造成的所有影响都是低的。
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引用次数: 0
Concentrations of Polychlorinated Biphenyls (PCBs) in Phragmites australis of Shatt AL-Arab River. South of Iraq 阿拉伯河芦苇中多氯联苯的含量伊拉克南部
Pub Date : 2021-07-23 DOI: 10.29350/qjps.2021.26.4.1422
Rafid Ahmed Taha Al-Zabad, A. H. Al-Khafaji, Hamid T.AL-Saad
ABSTRACT The concentrations of polychlorinated biphenyls (PCBs) were determined from Autumn season 2019 to summer season 2020 at six sites they are: ( Al-Qurna, Al-Deer, Al-Qarma, Al-Ashar, Abu-Al-khasib, Al-Fao )  in Shatt Al-Arab river, Basrah city, south of Iraq. water samples were taken at each site and were analyzed using gas chromatography-mass spectrometry (GC–MASS) type of Agilent 7890A for PCBs levels. The results indicate that PCBs are detected in all Phragmites australis  samples and its concentrations range from 1.45 ng/g to 4.11 ng/g , 5.34 ng/g to 7.99 ng/g, 2.19 ng/g to 3.59 ng/g and 0.45 ng/g to 8.09 ng/g in Autumn, Winter, Spring and Summer seasons, respectively. The Al-Qurna and Al-Ashar sites were found to have the lowest and highest mean levels of PCBs concentrations 0.035 ng/g and 0.622 ng/g, respectively. Total congeners PCBs (PCB 18, 29, 31, 28, 44, 52, 101, 141, 149, 138,153, 189, and 194) concentrations at the Phragmite australis  samples for all sites ranged from 0.45 ng/g in Al-Qurna station during summer season to 8.09 ng/g in Al-Ashar station during summer season. Σhexa-PCBs and Σtri-PCBs were dominating in comparison with others PCBs congeners. This study is a first of its kind in the region and could have available information and could be used as a baseline study in the future.
2019年秋季至2020年夏季,在伊拉克南部巴士拉市Shatt Al-Arab河的6个地点(Al-Qurna、Al-Deer、Al-Qarma、Al-Ashar、Abu-Al-khasib、Al-Fao)测定了多氯联苯(PCBs)的浓度。在每个站点采集水样,使用Agilent 7890A型气相色谱-质谱(GC-MASS)分析多氯联苯水平。结果表明,所有芦苇样品中均检测到多氯联苯,其浓度在秋、冬、春、夏4个季节分别为1.45 ~ 4.11 ng/g、5.34 ~ 7.99 ng/g、2.19 ~ 3.59 ng/g和0.45 ~ 8.09 ng/g。发现Al-Qurna和Al-Ashar站点的多氯联苯平均浓度最低和最高水平分别为0.035 ng/g和0.622 ng/g。各监测点芦苇样品中同源多氯联苯(PCB 18、29、31、28、44、52、101、141、149、138,153、189和194)的浓度变化范围从夏季Al-Qurna站的0.45 ng/g到夏季Al-Ashar站的8.09 ng/g。与其他多氯联苯同系物相比,Σhexa-PCBs和Σtri-PCBs占主导地位。这项研究是该地区首次开展此类研究,可以获得可用信息,并可在未来用作基线研究。
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引用次数: 0
A Quasi-Hilbert Space and Its Properties 拟希尔伯特空间及其性质
Pub Date : 2021-07-22 DOI: 10.29350/qjps.2021.26.4.1388
J. Al-Delfi
This  paper  studies concept  of a  quasi-inner product space  and its  completeness  to get and  prove some properties of quasi-Hilbert spaces. The best examples of  this notion are spaces   where  0
本文研究了拟内积空间的概念及其完备性,得到并证明了拟希尔伯特空间的一些性质。这个概念最好的例子是0
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引用次数: 0
A Evaluate the biological activity of Citrullus Colocynthis extract (In vitro study) A评价瓜蒌提取物的生物活性(体外研究)
Pub Date : 2021-07-22 DOI: 10.29350/qjps.2021.26.4.1400
H. Yousif, Z. Shaker, H. H. Abed
The plant of c. colocynthis is perennial herbal of the Cucurbitaceous types that isused as a traditional medicinal plant on a Mediterranean tub and equatorialnations.Studies on the antibacterial properties of Citrullus colocynthis leaf extract,Medicinal plants have conventional been used in abortifacient and treatsconstipation, edema, Infection caused by bacteria, cancer and diabetesproblems.The antibacterial efficacy of citrullus colocynthesis (L.) was investigatedin this work using five species of pathogenic bacteria isolated from urinary tractinfections: E. coli, Klebsiella pneumoniae, Streptococcus spp, Psudomonasauroginosa, and Staphylococcus aureus. For the antibacterial test, water andethanol extract were employed.The ethanolic extract showed inhibitory activityagainst Escherichia Coli at (100 °C, 80 °C, 60 °C) while Staphylococcus aureus at(100 °C, 80 °C), Streptococcus spp. at (100 °C). Water extract exhibited less or noactivity against all types of bacteria.The findings of this investigation indicate thatC. colocynthis might be utilized to treat disorders caused by the test organisms.
秋葵属植物是葫芦科的多年生草本植物,在地中海浴盆和赤道国家被用作传统的药用植物。药用植物古瓜叶提取物的抑菌性研究。古瓜叶提取物常被用于流产和治疗便秘、水肿、细菌感染、癌症和糖尿病等问题。本研究利用从尿路感染中分离的大肠杆菌、肺炎克雷伯菌、链球菌、假单胞菌和金黄色葡萄球菌等5种病原菌,研究了柑橘酸合成菌的抑菌效果。抗菌试验采用水和乙醇提取物。乙醇提取物对大肠杆菌(100°C、80°C、60°C)、金黄色葡萄球菌(100°C、80°C)、链球菌(100°C)均有抑制作用。水提取物对所有类型的细菌均表现出较低或无活性。这项调查的结果表明,c。Colocynthis可用于治疗由试验生物引起的疾病。
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引用次数: 1
Solving Riccati type q-Difference Equations via Difference Transform Method 用差分变换法求解Riccati型q-差分方程
Pub Date : 2021-07-22 DOI: 10.29350/qjps.2021.26.4.1318
Ayad R. Khudair, Ahmed Y. Abdulmajeed
In this paper, we deal on the time scale that its delta derivative of graininess function is a nonzero positive constant. Based on the Taylor formula for this time scale, we investigate the difference transform method (DTM). This method has been applied successfully to solve Riccati type difference equations in quantum calculus. To demonstrate the ability and efficacy of this method, some examples have been provided.
本文讨论了粒度函数的δ导数为非零正常数的时间尺度。基于泰勒公式,我们研究了差分变换方法(DTM)。该方法已成功地应用于求解量子微积分中的Riccati型差分方程。为了证明该方法的能力和有效性,给出了一些算例。
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引用次数: 1
期刊
Al-Qadisiyah Journal Of Pure Science
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