Pub Date : 2025-12-06DOI: 10.1140/epjp/s13360-025-07107-0
Fawad Khan, Salah Uddin, Ibrahim Khan, Yamin Shah, Sohail Ahmed, Safia Ali, Kefayat Ullah
Normal and anomalous rotary photon drag is investigated in a spinning atomic medium via heat loss and gain. Significant modifications and controls are studied with varying heat loss and heat gain. The anomalous rotary photon is a function of heat loss and heat gain, as well as control field Rabi frequencies and detunings. The maximum rotary photon drag calculated is (pm 399) microradian at a heat loss of (0.8J) and is enhanced with the Rabi frequency of the control field. The relative phase of the control fields tunes anomalous drag to normal drag with heat loss and gain. The maxima of photon drag are shifted with the relative phase of the control fields toward heat loss and heat gain in the medium. The modified results of this manuscript are useful for optical switching and sensing as well as quantum-based Internet of Things (IoT) applications.
{"title":"Coherent manipulation of normal and anomalous rotary photon drag with heat loss and heat gain","authors":"Fawad Khan, Salah Uddin, Ibrahim Khan, Yamin Shah, Sohail Ahmed, Safia Ali, Kefayat Ullah","doi":"10.1140/epjp/s13360-025-07107-0","DOIUrl":"10.1140/epjp/s13360-025-07107-0","url":null,"abstract":"<div><p>Normal and anomalous rotary photon drag is investigated in a spinning atomic medium via heat loss and gain. Significant modifications and controls are studied with varying heat loss and heat gain. The anomalous rotary photon is a function of heat loss and heat gain, as well as control field Rabi frequencies and detunings. The maximum rotary photon drag calculated is <span>(pm 399)</span> microradian at a heat loss of <span>(0.8J)</span> and is enhanced with the Rabi frequency of the control field. The relative phase of the control fields tunes anomalous drag to normal drag with heat loss and gain. The maxima of photon drag are shifted with the relative phase of the control fields toward heat loss and heat gain in the medium. The modified results of this manuscript are useful for optical switching and sensing as well as quantum-based Internet of Things (IoT) applications.</p></div>","PeriodicalId":792,"journal":{"name":"The European Physical Journal Plus","volume":"140 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145730120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-06DOI: 10.1140/epjp/s13360-025-07115-0
Mawaheb Al-Dossari
This report presents the comprehensive investigation of the effect of CuO concentration and thermal treatment on the properties of 60B2O3 + 10Bi2O3 + 10Na2O + 5WO3 + (15 − x)SrO + xCuO, where x = 0, 0.1, 0.3 and 0.5 (BBNWSCu) glasses and glass–ceramics prepared via the melt-quenching method followed by heat treatment. The base glass (BBNWSCu0) exhibited excellent thermal stability, with only 1.5% weight loss up to 850 °C, with a glass transition temperature (Tg) of about 401 °C, and an onset of crystallisation temperature of 500 °C. It was observed that the heat treatment of BBNWSCu glasses at 500 °C for 20 min produced results in the glass–ceramics with Bi2O3 and SrWO4 crystalline phases, although higher CuO content reduced crystallinity. Raman analysis indicated that CuO disrupted the borate network, shifting the BO3 vibrational band from 476 cm−1 (BBNWSCu0) to 441 cm−1 (BBNWSCu0.3). Optical measurements showed a decrease in the indirect band gap (Eg) from 2.50 eV (BBNWSCu0) to 2.14 eV (BBNWSCu0.5) and an increase in disorder energy (EU). On the other hand, in the case of BBNWSCu-GC glass–ceramics, the Eg increased from 2.23 eV (for BBNWSCu0-GC) to 2.53 eV (for BBNWSCu0.5-GC), while EU decreased significantly. PL emission studies revealed Bi3+ emissions at 488 nm (BBNWSCu glasses) and 492 nm (BBNWSCu-GC glass–ceramics), with additional peaks at 522 nm and 547 nm. The maximum PL intensity occurred at 0.1 mol% CuO (BBNWSCu glass), while higher concentrations led to reduced emission. The CIE chromaticity coordinates indicated stable blue–green emission, with colour purity reaching 76.7% in BBNWSCu0.1 glass and stabilised colour purity values in glass–ceramics. These results indicate that optimising CuO concentration and thermal treatment can enhance luminescence efficiency and optical quality in BBNWSCu glasses for solid-state lighting and photonic applications.
本文综合研究了CuO浓度和热处理对60B2O3 + 10Bi2O3 + 10Na2O + 5WO3 +(15−x)SrO + xCuO (x = 0,0.1, 0.3和0.5)(BBNWSCu)玻璃和微晶玻璃性能的影响。基底玻璃(BBNWSCu0)表现出优异的热稳定性,在850℃下仅损失1.5%的重量,玻璃化转变温度(Tg)约为401℃,开始结晶温度为500℃。结果表明,对BBNWSCu玻璃在500℃下热处理20 min,可得到Bi2O3和SrWO4晶相的微晶玻璃,但CuO含量的增加会降低结晶度。Raman分析表明,CuO破坏了硼酸盐网络,将BO3的振动带从476 cm−1 (BBNWSCu0)移动到441 cm−1 (BBNWSCu0.3)。光学测量表明,间接带隙(Eg)从2.50 eV (BBNWSCu0)减小到2.14 eV (BBNWSCu0.5),无序能(EU)增加。另一方面,对于BBNWSCu-GC微晶玻璃,Eg从2.23 eV (BBNWSCu0-GC)增加到2.53 eV (BBNWSCu0.5-GC),而EU显著降低。发光光谱研究显示,Bi3+在488 nm (BBNWSCu玻璃)和492 nm (BBNWSCu- gc玻璃陶瓷)处发射,在522 nm和547 nm处有附加峰。当浓度为0.1 mol% CuO (BBNWSCu玻璃)时,发光强度最大,而浓度越高,发光强度越低。CIE色度坐标显示稳定的蓝绿色发射,BBNWSCu0.1玻璃的色纯度达到76.7%,玻璃陶瓷的色纯度值稳定。这些结果表明,优化CuO浓度和热处理可以提高用于固态照明和光子应用的BBNWSCu玻璃的发光效率和光学质量。
{"title":"Influence of CuO concentration and crystallisation on the luminescence and colour purity of bismuth–borate–tungstate glasses and glass–ceramics","authors":"Mawaheb Al-Dossari","doi":"10.1140/epjp/s13360-025-07115-0","DOIUrl":"10.1140/epjp/s13360-025-07115-0","url":null,"abstract":"<div><p>This report presents the comprehensive investigation of the effect of CuO concentration and thermal treatment on the properties of 60B<sub>2</sub>O<sub>3</sub> + 10Bi<sub>2</sub>O<sub>3</sub> + 10Na<sub>2</sub>O + 5WO<sub>3</sub> + (15 − <i>x</i>)SrO + <i>x</i>CuO, where <i>x</i> = 0, 0.1, 0.3 and 0.5 (BBNWSCu) glasses and glass–ceramics prepared via the melt-quenching method followed by heat treatment. The base glass (BBNWSCu0) exhibited excellent thermal stability, with only 1.5% weight loss up to 850 °C, with a glass transition temperature (<i>T</i><sub>g</sub>) of about 401 °C, and an onset of crystallisation temperature of 500 °C. It was observed that the heat treatment of BBNWSCu glasses at 500 °C for 20 min produced results in the glass–ceramics with Bi<sub>2</sub>O<sub>3</sub> and SrWO<sub>4</sub> crystalline phases, although higher CuO content reduced crystallinity. Raman analysis indicated that CuO disrupted the borate network, shifting the BO<sub>3</sub> vibrational band from 476 cm<sup>−1</sup> (BBNWSCu0) to 441 cm<sup>−1</sup> (BBNWSCu0.3). Optical measurements showed a decrease in the indirect band gap (<i>E</i><sub>g</sub>) from 2.50 eV (BBNWSCu0) to 2.14 eV (BBNWSCu0.5) and an increase in disorder energy (E<sub>U</sub>). On the other hand, in the case of BBNWSCu-GC glass–ceramics, the <i>E</i><sub>g</sub> increased from 2.23 eV (for BBNWSCu0-GC) to 2.53 eV (for BBNWSCu0.5-GC), while E<sub>U</sub> decreased significantly. PL emission studies revealed Bi<sup>3+</sup> emissions at 488 nm (BBNWSCu glasses) and 492 nm (BBNWSCu-GC glass–ceramics), with additional peaks at 522 nm and 547 nm. The maximum PL intensity occurred at 0.1 mol% CuO (BBNWSCu glass), while higher concentrations led to reduced emission. The CIE chromaticity coordinates indicated stable blue–green emission, with colour purity reaching 76.7% in BBNWSCu0.1 glass and stabilised colour purity values in glass–ceramics. These results indicate that optimising CuO concentration and thermal treatment can enhance luminescence efficiency and optical quality in BBNWSCu glasses for solid-state lighting and photonic applications.</p></div>","PeriodicalId":792,"journal":{"name":"The European Physical Journal Plus","volume":"140 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145675535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-06DOI: 10.1140/epjp/s13360-025-07106-1
S. Saleem, N. Ali
The stability of the boundary layer flow due to a stretching sheet with power-law wall velocity is under consideration. The disturbance equations are obtained under the parallel flow assumption. Assuming disturbances in the form of Tollmien–Schlichting waves, we develop a linear differential system with complex coefficients in four unknowns. A spectral method is employed to solve this system, subject to the condition that perturbations vanish both at the wall and in the far field. The neutral stability curves are plotted to identify the stable and unstable regions. Additionally, energy analysis is performed in order to provide a perspective on the actual physical mechanism influencing the instability of the disturbances. The finding indicates that flows induced by accelerated wall velocities ((n>1)) are more stable than those of flows produced by decelerated wall velocities ((n<1)).
{"title":"Onset of instability in viscous flow due to a nonlinear stretching sheet","authors":"S. Saleem, N. Ali","doi":"10.1140/epjp/s13360-025-07106-1","DOIUrl":"10.1140/epjp/s13360-025-07106-1","url":null,"abstract":"<div><p>The stability of the boundary layer flow due to a stretching sheet with power-law wall velocity is under consideration. The disturbance equations are obtained under the parallel flow assumption. Assuming disturbances in the form of Tollmien–Schlichting waves, we develop a linear differential system with complex coefficients in four unknowns. A spectral method is employed to solve this system, subject to the condition that perturbations vanish both at the wall and in the far field. The neutral stability curves are plotted to identify the stable and unstable regions. Additionally, energy analysis is performed in order to provide a perspective on the actual physical mechanism influencing the instability of the disturbances. The finding indicates that flows induced by accelerated wall velocities <span>((n>1))</span> are more stable than those of flows produced by decelerated wall velocities <span>((n<1))</span>.</p></div>","PeriodicalId":792,"journal":{"name":"The European Physical Journal Plus","volume":"140 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145730059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-05DOI: 10.1140/epjp/s13360-025-07110-5
Sunny Dhiman, Akhil Saxena, Jasdeep Kaur
This research examines the viability of fruit waste extract as a sustainable and eco-friendly corrosion inhibitor for mild steel in 0.5 M HCl. The extract, which is abundant in phytochemicals such as nobiletin, caffeic acid, gallic acid, and epicatechin, demonstrated a peak inhibition efficiency of 88.50% at a concentration of 100 ppm. The inhibitor creates a protective layer on the metal surface, which significantly diminishes corrosion. The study employed weight loss analysis, potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), UV–visible spectroscopy, scanning electron microscopy (SEM), and quantum chemical calculations (DFT) to assess the inhibition performance of the extract. Both PDP and EIS measurements were taken in triplicate, and the results include standard deviations and error margins. SEM analysis validated surface protection, while DFT calculations indicated strong adsorption characteristics, which are attributed to the presence of electron-donating functional groups. The results imply that fruit waste extract is a promising, cost-effective, and environmentally friendly alternative to synthetic corrosion inhibitors.