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High Quality Au-carbon Nitride Catalyst for Monitoring of Anti-prostate Cancer Drug (Flutamide) 用于监测抗前列腺癌药物(氟他胺)的高质量氮化金碳催化剂
IF 3.6 3区 化学 Q2 Chemistry Pub Date : 2024-05-23 DOI: 10.1007/s11244-024-01973-1
Xiao Fan, Wen Liu, Li Feng
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引用次数: 0
Treating NOx gas Pollution by Visible Light Photocatalytic Reaction of S-doped TiO2 Nanotubes 利用掺杂 S 的二氧化钛纳米管的可见光光催化反应处理氮氧化物气体污染
IF 3.6 3区 化学 Q2 Chemistry Pub Date : 2024-05-23 DOI: 10.1007/s11244-024-01972-2
Pho Thi Le, T. Cao, Tin Chanh Duc Doan, Viet Van Pham
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引用次数: 0
Roles of Solvent in the Catalytic Hydrogen Release from Liquid Organic Hydrogen Carriers: Chemical, Thermodynamical and Technological Aspects 溶剂在液态有机载氢体催化释氢中的作用:化学、热力学和技术方面
IF 3.6 3区 化学 Q2 Chemistry Pub Date : 2024-05-20 DOI: 10.1007/s11244-024-01950-8
Ba L. Tran, Mark Bowden, T. Autrey, Mi Yeon Byun, Karsten Müller
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引用次数: 0
Simultaneous Electro-Sensing of Guanine and Adenine on GO/Fe3O4-PMDA@Bi Nanocomposite 在 GO/Fe3O4-PMDA@Bi 纳米复合材料上同时电传感鸟嘌呤和腺嘌呤
IF 3.6 3区 化学 Q2 Chemistry Pub Date : 2024-05-18 DOI: 10.1007/s11244-024-01960-6
Mehdi Baghayeri, Marzieh Nodehi, Amirhasan Amiri, Habib Ashena, Fatemeh Abedi, Roya Mehrkhah

Herein, we report developing an electrochemical sensor based on a glassy carbon electrode modified by bismuth nanoparticles, graphene oxide, iron oxide, and poly-methyldopa namely Bi@Fe3O4-PMDA/GO/GCE for detecting guanine and adenine. Under optimized conditions (5 μL of Fe3O4-PMDA/GO, 0.5 mg mL−1 of Fe3O4-PMDA/GO solution, water as solvent of Fe3O4-PMDA/GO and acetate buffer (0.1 M, pH 6) as electrolytes), the electrochemical behaviors of guanine and adenine on the prepared modified electrode were investigated by cyclic voltammetry and differential pulse voltammetry. With a high specific surface area and numerous active sites, Bi@Fe3O4-PMDA/GO/GCE exhibited outstanding electrocatalytic properties enabling the determination of guanine and adenine over a wide concentration range with the low detection limit. The Bi@Fe3O4-PMDA/GO/GCE possessed the advantages of simplicity, speed, good sensitivity, and anti-interference performance. Using the DPV method, the resulting sensor exhibited an excellent response with a wide linear ranges from 0.5 to 300 μM for both analytes with LODs 0.027 and 0.032 µM for adenine and guanine, respectively. The designed electrode was satisfactorily employed for the analysis of the real sample. Therefore, Bi@Fe3O4-PMDA/GO/GCE demonstrating sufficient selectivity and sensitivity for the individual and simultaneous study could be applied in widespread fields, including biotechnology or microbiology.

Graphical abstract

在此,我们报告了基于纳米铋、氧化石墨烯、氧化铁和聚甲基多巴修饰的玻璃碳电极(即 Bi@Fe3O4-PMDA/GO/GCE)开发的用于检测鸟嘌呤和腺嘌呤的电化学传感器。在优化的条件下(5 μL Fe3O4-PMDA/GO、0.5 mg mL-1 Fe3O4-PMDA/GO 溶液、水作为 Fe3O4-PMDA/GO 的溶剂、醋酸盐缓冲液(0.1 M,pH 6)作为电解质),通过循环伏安法和差分脉冲伏安法研究了鸟嘌呤和腺嘌呤在制备的修饰电极上的电化学行为。Bi@Fe3O4-PMDA/GO/GCE 具有高比表面积和大量活性位点,表现出卓越的电催化性能,可在较宽的浓度范围内测定鸟嘌呤和腺嘌呤,且检出限较低。Bi@Fe3O4-PMDA/GO/GCE 具有简便、快速、灵敏度高、抗干扰性强等优点。采用 DPV 方法,所设计的传感器具有良好的响应性能,对两种分析物的线性范围都很宽,从 0.5 μM 到 300 μM,对腺嘌呤和鸟嘌呤的检测限分别为 0.027 和 0.032 µM。所设计的电极在实际样品分析中的应用效果令人满意。因此,Bi@Fe3O4-PMDA/GO/GCE 具有足够的选择性和灵敏度,可用于单独和同时研究,可广泛应用于生物技术或微生物学等领域。
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引用次数: 0
Application of Biochar-Based Catalysts for Soil and Water Pollution Control 生物炭催化剂在土壤和水污染控制中的应用
IF 3.6 3区 化学 Q2 Chemistry Pub Date : 2024-05-16 DOI: 10.1007/s11244-024-01962-4
Meiqing Jin, Qingwei Zhou, Li Fu, Weihong Wu
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引用次数: 0
Unveiling Seasonal Fluctuations in Air Quality Using Google Earth Engine: A Case Study for Gujarat, India 利用谷歌地球引擎揭示空气质量的季节性波动:印度古吉拉特邦案例研究
IF 3.6 3区 化学 Q2 Chemistry Pub Date : 2024-05-15 DOI: 10.1007/s11244-024-01957-1
Keval H. Jodhani, Nitesh Gupta, Aditya D. Parmar, Jimit D. Bhavsar, Dhruvesh Patel, Sudhir Kumar Singh, Umank Mishra, P. J. Omar, Ganesh Ji Omar
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引用次数: 0
Recent Progress in Electrochemical Synthesis and Conversion of Nitrates in Aqueous Electrolyte 水电解质中硝酸盐的电化学合成与转化的最新进展
IF 3.6 3区 化学 Q2 Chemistry Pub Date : 2024-05-15 DOI: 10.1007/s11244-024-01949-1
Fanghua Liu, Chizhong Wang, Lei Qiu, Huazhen Chang
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引用次数: 0
Rice Straw Derived Mesoporous Biochar for the Removal of Coomassie Brilliant Blue Dye 用于去除库马西亮蓝染料的稻草衍生介孔生物炭
IF 3.6 3区 化学 Q2 Chemistry Pub Date : 2024-05-14 DOI: 10.1007/s11244-024-01961-5
Jagpreet Singh, Monika Bhattu, Meenakshi Verma
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引用次数: 0
Preparation of a New and Effective Heterogeneous Catalyst for Treatment of Organic Pollutant Using Fenton Process 利用 Fenton 工艺制备处理有机污染物的新型有效异相催化剂
IF 3.6 3区 化学 Q2 Chemistry Pub Date : 2024-05-14 DOI: 10.1007/s11244-024-01959-z
Meng Xu, Qiping Tian, Yuankang Quan, Liya Xu, Melika Namadchian

In the present study, the fabrication and application of a magnetically separable catalyst for degradation of rhodamine B (RhB) dye using Fenton process were explored using an efficient octahedral Fe3O4-graphene oxide (OFe-GO) nanocomposite. By employing a simple ultrasonic process, the OFe-GO catalyst was successfully prepared through the immobilization of OFe onto the GO support. Various characterization methods were used to fully explore the crystalline character, morphological surface, chemical state and magnetic property of the prepared catalyst substances. In the presence of hydrogen peroxide (H2O2) as a green oxidant, the catalytic performance of RhB degradation using the proposed magnetic catalyst was explored. The experimental factors affected on the Fenton performance such as solution pH, catalyst concentration and H2O2 concentration were evaluated and optimized. Using the established protocol, 50 mg mL−1 of RhB can be completely at 15 min reaction time. Additionally, the used OFe-GO catalyst can be regenerated without losing the degradation performance for at least five cycles. Because of notable catalytic efficiency, fast degradation, and operational stability, the OFe-GO can be considered as an effective and separable catalyst for decolorization of dye-containing wastewater.

Graphical Abstract

本研究利用高效八面体 Fe3O4-氧化石墨烯(OFe-GO)纳米复合材料,探索了利用 Fenton 工艺降解罗丹明 B(RhB)染料的磁性可分离催化剂的制备和应用。通过采用简单的超声波工艺,将 OFe 固定在 GO 载体上,成功制备了 OFe-GO 催化剂。研究人员采用多种表征方法对所制备催化剂物质的结晶性质、形貌表面、化学状态和磁性能进行了充分的研究。在过氧化氢(H2O2)作为绿色氧化剂存在的条件下,探讨了利用所提出的磁性催化剂降解 RhB 的催化性能。对影响 Fenton 性能的实验因素(如溶液 pH 值、催化剂浓度和 H2O2 浓度)进行了评估和优化。按照既定方案,在 15 分钟的反应时间内可完全分解 50 mg mL-1 的 RhB。此外,所使用的 OFe-GO 催化剂可以再生,至少可循环使用五次而不会失去降解性能。由于催化效率高、降解速度快、操作稳定,OFe-GO 可被视为一种有效的可分离催化剂,用于含染料废水的脱色。
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引用次数: 0
Catalytic Conversion for Clean Energy: From Basics to Applications 清洁能源的催化转换:从基础到应用
IF 3.6 3区 化学 Q2 Chemistry Pub Date : 2024-05-09 DOI: 10.1007/s11244-024-01954-4
Hao Chen, Ji Yang, Ji Su, Miquel Salmeron
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引用次数: 0
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Topics in Catalysis
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