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Reprocessable and Recyclable Self-Healing Natural Rubber/Carbon Black Composite Based on Metal Thiolate Ionic Network 基于硫醇酸金属离子网的可再加工和可回收的自愈合天然橡胶/炭黑复合材料
Pub Date : 2024-02-05 DOI: 10.4028/p-xyvs0h
Noor Faezah Mohd Sani, Lai Mei Fen, R. K. Shuib
Reprocessable and recyclable self-healing rubber composites were fabricated by mixing natural rubber (NR) with carbon black (CB) filler in the presence of zinc thiolate (ZT) to form the ionic association in the rubber system. This work investigated and compared the unfilled and natural rubber filled with 5phr of carbon black. The recycling process was repeated three times, and the mechanical performance was measured each time. Tensile strength was increased by more than 430% for unfilled rubber and 520% for NR/5CB composites after the third recycling process. Tear strength was also increased with the number of the recycling process. According to a welding test ability, the developed materials showed potential for repair. Scanning electron micrographs revealed that as the recycling number increased, the white spot of ZT responsible for generating the ionic network reduced as more ZT was converted into Zn2+ salt bonding.
通过将天然橡胶(NR)与炭黑(CB)填料在硫酸锌(ZT)的存在下混合,在橡胶体系中形成离子结合,制造出了可再加工和可回收的自愈合橡胶复合材料。本研究对未填充和填充 5phr 炭黑的天然橡胶进行了研究和比较。回收过程重复了三次,每次都对机械性能进行了测量。在第三次循环过程后,未填充橡胶的拉伸强度提高了 430%以上,而 NR/5CB 复合材料的拉伸强度提高了 520%。撕裂强度也随着回收处理次数的增加而提高。根据焊接测试能力,所开发的材料具有修复潜力。扫描电子显微照片显示,随着循环次数的增加,负责生成离子网络的 ZT 白点减少,因为更多的 ZT 转化为 Zn2+ 盐键。
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引用次数: 0
Cellulose-Based Oil Palm Empty Fruit Bunch as an Alternative Filler for Latex Application: A Review 纤维素基油棕空果束作为乳胶应用的替代填料:综述
Pub Date : 2024-02-05 DOI: 10.4028/p-5dfzfb
Nuur Syuhada Dzulkafly, Anson Teh Tian Loke, A. Azura
Cellulose is a natural polymer with good properties that have caught researchers' attention to utilize these natural resources' potential. Cellulose also has been widely used as an alternative filler to replace inorganic filler in polymer composites. This review discussed the extraction of cellulose from oil palm empty fruit bunch (OPEFB). This review focused on the OPEFB due to the emergence of palm oil plantations which creates a high amount of biomass, whereas OPEFB is one of the major contributors. The utilization of cellulose application in the polymer focused on alternative fillers in latex application. The postulate crosslink mechanism in latex films is also described to highlight the potential of OPEFB as fillers in latex application. The utilization of OPEFB cellulose has the potential to be explore as bio-fillers with also impact the crosslinks mechanism in latex system which can improved the properties in latex composites.
纤维素是一种天然聚合物,具有良好的特性,这引起了研究人员对利用这些天然资源潜力的关注。纤维素还被广泛用作聚合物复合材料的替代填料,以取代无机填料。本综述讨论了从油棕空果束(OPEFB)中提取纤维素的问题。由于棕榈油种植园的出现产生了大量的生物质,而油棕空果穗是其中的主要贡献者之一,因此本综述将重点放在油棕空果穗上。纤维素在聚合物中的应用侧重于乳胶应用中的替代填料。此外,还介绍了乳胶膜中的假定交联机制,以突出 OPEFB 作为乳胶应用填料的潜力。使用 OPEFB 纤维素具有作为生物填料的潜力,同时还能影响乳胶系统中的交联机制,从而改善乳胶复合材料的性能。
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引用次数: 0
Analytical Studies of Fluid Conveying Pipes on Viscoelastic Foundation Using Differential Transforms Method 利用微分变换法对粘弹性地基上的流体输送管道进行分析研究
Pub Date : 2024-02-05 DOI: 10.4028/p-ts7pbd
O. Adeleye, A. Yinusa, Ihuoma V. Diwe
This study presents an analytical investigation of the vibration of fluid-conveying pipes on viscoelastic foundations using the differential transform method. The effects of a new time dependent viscosity parameter in the modified Winkler viscoelastic foundation is studied and analyzed. The governing equation is a fourth-order partial differential equation with pinned-pinned boundary conditions, which required a special analytical method for solution. The differential transform method was applied to obtain the solution of the governing partial differential equation for the fluid-conveying pipes on viscoelastic foundations. The time-dependent viscosity parameter in the modified Winkler viscoelastic model was implemented and simulated to determine the behavior of the viscoelastic foundation. The obtained analytical solution was validated with Runge-Kutta order four numerical method. The effects of foundation stiffness , coefficient of foundation damping and the frequency mass ratio on the governing model equation were investigated. In addition, the bending and deflection of the pipe on a viscoelastic foundation are compared with those on an elastic foundation. The analytical and the numerical solutions are in good agreement. From the study, it is observed that an increase in the foundation stiffness results in increase in the pipe inherent frequencies. Furthermore, the vibration of the pipe on a viscoelastic foundation shows better control and reduction compared with its vibration on an elastic foundation.
本研究采用微分变换法对粘弹性地基上的流体输送管道的振动进行了分析研究。研究分析了改良温克勒粘弹性地基中新的随时间变化的粘度参数的影响。控制方程是一个四阶偏微分方程,带有针销边界条件,需要一种特殊的分析方法来求解。应用微分变换法求解了粘弹性地基上流体输送管道的支配偏微分方程。在改进的 Winkler 粘弹性模型中实施并模拟了随时间变化的粘度参数,以确定粘弹性地基的行为。所获得的分析解与 Runge-Kutta 四阶数值方法进行了验证。研究了地基刚度、地基阻尼系数和频率质量比对支配模型方程的影响。此外,还比较了粘弹性地基与弹性地基上管道的弯曲和挠度。分析和数值解法非常一致。研究发现,地基刚度的增加会导致管道固有频率的增加。此外,与弹性地基上的管道振动相比,粘弹性地基上的管道振动得到了更好的控制和降低。
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引用次数: 0
A Review on Methods of Cenosphere Separation from Fly Ash 从粉煤灰中分离钙球的方法综述
Pub Date : 2024-02-05 DOI: 10.4028/p-q3damx
Abu Dzar Johar, H. Mohamed, Z. Itam, N. Zahari, Z. C. Muda, A. Syamsir, S. Beddu, M. Zawawi, M. Zainoodin, Shaikh Muhammad Mubin, N. Kamal
Cenospheres are valuable material contained inside the fly ash. Its low weight, low density, and high strength made it very versatile and can be used in various fields. The way of separating the cenosphere from the fly ash consists of two categories, wet and dry separation. For wet separation, it involves submerging the fly ash inside a mixture made either by pure acetone, pure water, or a mixture of water and acetone with different mixing ratios before stirring the mixture. The cenospheres, floating on top of the mix due to low density, can be collected and dried. The dry separation technique involves putting the fly ash into a cyclone separator at a constant velocity. The fly ash will then move into the bottom of the cyclone. Particles can also be separated by diameter sizes by sieving. By manipulating various parameters, cenosphere yield may differ. This paper is written to help gain more understanding on cenosphere properties and its separation method.
仙人球是粉煤灰中含有的宝贵材料。它重量轻、密度小、强度高,因此用途非常广泛,可用于各个领域。将仙人球从粉煤灰中分离出来的方法分为两类,即湿法分离和干法分离。湿法分离是将粉煤灰浸没在由纯丙酮、纯水或水和丙酮按不同比例混合而成的混合物中,然后搅拌混合物。由于密度较低而漂浮在混合物顶部的仙人球可被收集并干燥。干法分离技术是将粉煤灰以恒定的速度放入旋风分离器中。粉煤灰会进入旋风分离器的底部。颗粒也可以通过筛分按直径大小分离。通过调节各种参数,气圈产量可能会有所不同。撰写本文的目的是为了帮助大家更好地了解飞灰层的特性及其分离方法。
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引用次数: 0
Transforming Carbide Lime Waste into Marketable PCC: Effect of Mechanical Disturbance 将硬质合金石灰废料转化为适销对路的 PCC:机械干扰的影响
Pub Date : 2024-02-05 DOI: 10.4028/p-ycuq6s
E. M. Salleh, Rohaya Othman, S. N. M. Sabri, Z. Mahim
The acetylene market is anticipated to be driven by the growing applications across numerous industries particularly chemical synthesis, oxy-acetylene welding, and metal cutting. Attributable to wide-range uses, acetylene witnesses stable growth in the global market. However, the production of acetylene results in increasing generation of carbide lime waste that is classified as a scheduled waste under Malaysian Environmental Quality Act: EQA 1974 (SW427) due to its high alkalinity. The rising amount of the waste has warranted the need for repurposing its usage to avert handling and disposal difficulties. In overcoming this crucial environmental issue, the carbide lime waste was transformed into a more marketable product so-called precipitated calcium carbonate (PCC) via feasible carbonation, promoted using natural sucrose solution. During the carbonation process, stirring rate was manipulated (i.e 300, 500, 700 and 1000 rpm) in investigating its effects on the PCC formation. Increasing the mechanical disturbance resulted in significant time reduction from 28 minutes to only 9 minutes and particle refinement. The production of PCC with purity above 98% suggested that the carbide lime waste was successfully transformed into high-grade PCC, which not only may help in preserving environmental sustainability yet can also offer profitable return to industry.
乙炔市场预计将受到众多行业(尤其是化学合成、氧-乙炔焊接和金属切割)应用增长的推动。由于用途广泛,乙炔在全球市场上保持稳定增长。然而,乙炔的生产会产生越来越多的电石灰废料,根据《马来西亚环境质量法》,电石灰废料被列为表列废料:EQA 1974》(SW427)的规定,因其碱性较高而被列为计划废物。随着废料数量的增加,有必要对其进行重新利用,以避免处理和处置方面的困难。为了解决这一关键的环境问题,我们利用天然蔗糖溶液,通过可行的碳酸化将碳化石灰废料转化为更适销的产品,即沉淀碳酸钙(PCC)。在碳化过程中,对搅拌速率进行了调整(即 300、500、700 和 1000 rpm),以研究其对 PCC 形成的影响。增加机械干扰可使时间从 28 分钟大幅缩短至 9 分钟,并使颗粒细化。生产出纯度超过 98% 的 PCC 表明,硬质合金石灰废料已成功转化为高级 PCC,这不仅有助于保护环境的可持续性,还能为工业带来丰厚的利润回报。
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引用次数: 0
A Survey of Drones in Agriculture Sector 农业领域无人机调查
Pub Date : 2024-02-05 DOI: 10.4028/p-xcmkl4
J. Boopalamani, P. Ayswariya, S. P. Raj, P. Yagnitha, N. Sarrvesh, Abhishek Jha
With the increasing population, the demand for food products is increasing day by day. The agriculture sector is adapting to technological reforms of traditional processes to maintain a proper balance between the demand-supply relationship. The intervention of the technology is resulting in the enhanced productivity of the agricultural process, and at the same time, it is also helping in the workload management of the farmers. In the last two decades, unmanned aerial vehicles (UAVs) or drones have emerged as indispensable tools in modern agricultural processes. Drones and allied smart technologies are being used for a variety of applications in this sector. This work presents a comprehensive survey of drones in the agriculture sector. The latest trends in the usage of drones from agricultural viewpoints are discussed. The work emphasizes the drone’s architectures, sensor integration, and availability in the open market. Furthermore, the challenges associated with this technology are also outlined.
随着人口的增加,对食品的需求也与日俱增。农业部门正在对传统工艺进行技术改革,以保持供求关系的适当平衡。技术的介入提高了农业生产效率,同时也有助于农民的工作量管理。在过去二十年里,无人驾驶飞行器(UAV)或无人机已成为现代农业流程中不可或缺的工具。无人机和相关智能技术在农业领域的应用多种多样。本作品全面介绍了无人机在农业领域的应用。从农业角度讨论了使用无人机的最新趋势。作品强调了无人机的架构、传感器集成以及在公开市场上的可用性。此外,还概述了与该技术相关的挑战。
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引用次数: 0
Characterisation of Water Treatment Sludge (WTS) at a Water Treatment Plant in Melaka 马六甲一家水处理厂水处理污泥 (WTS) 的特性分析
Pub Date : 2024-02-05 DOI: 10.4028/p-bsxzp1
A. R. Saleman, Ridhwan Jumaidin, Al Amin Mohamed Sultan, U. Azlan, Muhammad Zulfattah Zakaria
Water treatment sludge (WTS) is a by-product produced in the process of water treatment plants (WTP). It is estimated that an ordinary WTP produces over 10,000 tonnes of WTS per day, which has become a major concern in the management of WTS. Numerous previous studies have been accomplished to determine a safe disposal method and the potential reuse of WTS. In most investigations, material characterisation was the adopted method. It is known that each WTP produces different chemical composition of WTS according to raw water intake and the treatment process. The aim of this paper is to examine the chemical composition of WTS in the WTP at Melaka. The WTS sample is collected from WTP after the pressing process, where large amounts of water have been removed. The sample is tested using the Scanning Electron Microscopy with energy dispersive X-ray (SEM-EDX) and X-ray Diffraction (XRD). The SEM-EDX results revealed that by weight percentage (%), WTS contains zirconium (Zr) (28 to 46%), oxygen (28 to 40%) and carbon (7 to 26%). Aluminium and silicon have weight percentages ranging from 7 to 8%. The outcomes are then confirmed by XRD, which showed the high intensity of Zr and α-Zr at approximately 35.3 and 36.1. of 2θ. Based on these findings, the suitable and potential reuse of WTS would be the extraction of Zr. However, further research is required to verify the consistency of Zr in WTS.
水处理污泥(WTS)是水处理厂(WTP)生产过程中产生的一种副产品。据估计,一个普通的水处理厂每天产生的水处理污泥超过 10,000 吨,这已成为水处理污泥管理中的一个主要问题。为确定 WTS 的安全处置方法和再利用潜力,此前已完成了大量研究。在大多数研究中,采用的方法都是材料特征描述。众所周知,每个污水处理厂都会根据原水取水量和处理工艺产生不同化学成分的 WTS。本文旨在研究马六甲污水处理厂的 WTS 化学成分。WTS 样品是从压榨工艺后的 WTP 收集的,其中大量的水已被去除。样品使用扫描电子显微镜与能量色散 X 射线(SEM-EDX)和 X 射线衍射(XRD)进行测试。SEM-EDX 结果显示,按重量百分比(%)计算,WTS 含有锆(Zr)(28%-46%)、氧(28%-40%)和碳(7%-26%)。铝和硅的重量百分比为 7%至 8%。X 射线衍射证实了这些结果,X 射线衍射显示在 2θ 的 35.3 和 36.1 左右存在高强度的锆和α-锆。根据这些发现,WTS 的合适和潜在再利用方式是提取锆。不过,还需要进一步研究来验证 WTS 中 Zr 的一致性。
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引用次数: 0
Review on Performance and Emissions Characteristics of Compression Ignition Engine Fueling Non-Edible Vegetable Oil 以非食用植物油为燃料的压燃式发动机性能和排放特性评述
Pub Date : 2024-02-05 DOI: 10.4028/p-cykid1
Kamta Prasad Tiwari, Ram Narayan Singh
The tremendous exhaustion of resources, a surprising price increase of petroleum fuel and worldwide ecological issues implement to find renewable fuel for compression ignition engine. Non-edible vegetable oils have proven consensus to opt as a replacement for diesel fuel due to comparable properties and less-pollutant characteristics. Using Unmixed Untreated Non-edible Vegetable Oil (UUNVO) in the CI engine matches the needs of a sustainable future and restricts the intensifying cost involved in biodiesel production. This paper aims to review the influence of various UUNVO (Karanja, Jatropha, Neem, Linseed, Mahua and Rubber Seed etc.) on the important performance parameters and emission level of diesel engine. UUNVO can be fuelled to the unmodified CI engine. However, the viscosity of UUNVO is reasonably higher compare to diesel fuel at room temperature, which deteriorates the engine performance and exhaust emission. Minor changes in the injection line for preheating the UUNVO and operating parameters are the way to improve it. It can clearly understand here that preheated UUNVOs typically increase NOx emissions and decrease PM, HC, and CO emissions level compared to standard diesel. UUNVO can substitute diesel fuel completely for short-duration operation. With the long-duration operation, UUNVO produces problems like poor engine performance, injector chocking, and erosion of piston crown, rings, cylinder liner, and other internal parts, and degradation of the lubricant. Problems raised due to durability can be minimized by controlling operational parameters.
资源的大量消耗、石油燃料价格的惊人上涨以及全球范围内的生态问题,都促使人们寻找用于压燃式发动机的可再生燃料。事实证明,非食用植物油具有可比性和低污染的特点,可以作为柴油的替代品。在 CI 发动机中使用未经混合处理的非食用植物油(UUNVO)符合可持续发展的未来需求,并限制了生物柴油生产中不断增加的成本。本文旨在综述各种 UUNVO(卡兰札、麻风树、印楝、亚麻籽、马花籽和橡胶籽等)对柴油发动机重要性能参数和排放水平的影响。UUNVO 可用于未改装的 CI 发动机。但是,在室温下,UUNVO 的粘度比柴油高,会降低发动机性能和废气排放。对用于预热 UUNVO 的喷射管路和操作参数进行微小改动是改善其性能的方法。从这里可以清楚地了解到,与标准柴油相比,预热过的 UUNVO 通常会增加氮氧化物的排放,而降低 PM、HC 和 CO 的排放水平。在短时间运行时,UUNVO 可以完全替代柴油。在长时间运行时,UUNVO 会产生发动机性能不佳、喷油器堵塞、活塞冠、活塞环、气缸套和其他内部零件腐蚀以及润滑油降解等问题。通过控制运行参数,可以最大限度地减少因耐用性引起的问题。
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引用次数: 0
Evaluation of Mechanical Properties with the Use of EPS Polymer for the Preparation of Sustainable Composite Based on Concrete 使用 EPS 聚合物制备基于混凝土的可持续复合材料的力学性能评估
Pub Date : 2024-02-05 DOI: 10.4028/p-gr00jv
D. F. dos Santos
The civil construction area is one of the activities with the highest consumption of raw materials, presenting a large generation of waste. The use of EPS polymer (expanded polystyrene), in addition to being technological, has a low environmental impact by reducing the use of traditional concrete inputs, in addition to being 100% recyclable, cost-effective. The study enabled the elaboration of the composite based on concrete with different contents of recycled expanded polystyrene (EPS) added (0.20; 0.10 and 0.05%, in % weight/weight). The use of this material allowed the partial replacement of standard sand in the composite aggregate, obtaining an environmentally sustainable material, with low specific mass, thermal resistance with insulating, hydrophobic properties that allow low water absorption, with a low impact manufacturing process. This addition of EPS to the fresh concrete mixture showed a reduction in water penetration, making the construction material more hydrophobic, minimizing infiltration problems, reducing the physical process of absorption. The specimens for the concentration of 0.10% (weight/weight) showed better axial mechanical performance, with an average of 11.4 kgf, 52% in gain of reinforcement effect, in relation to the concentration of 0.20% (weight/weight). For this concentration of 0.20 (weight/weight), the EPS beads obtained greater homogeneity in the dispersion in the cementitious matrix, promoting better impact absorption during mechanical efforts. The absorption test was carried out for 10 and 20 minutes, and with that the percentage of water absorbed for each composite was verified. The specimens prepared with higher contents of styrofoam (0.20% and 0.10%), with 0.98 and 1.29%, respectively, of absorbed water, showed a more hydrophobic character due to the higher percentage of presence of pearls. EPS, making the material less permeable to water. The absorption results were quite satisfactory, showing values ​​below 20%, as recommended in the NBR 8491 standard.
土木建筑领域是原材料消耗量最大的活动之一,会产生大量废物。使用 EPS 聚合物(发泡聚苯乙烯),除了技术上的优势外,还能减少传统混凝土的使用,对环境影响较小,而且 100% 可回收,具有成本效益。这项研究以混凝土为基础,添加了不同含量的再生发泡聚苯乙烯(EPS)(0.20%、0.10% 和 0.05%,重量/重量百分比),从而制作出了复合材料。使用这种材料可以部分替代复合骨料中的标准砂,从而获得一种环境可持续材料,具有低比重、隔热、憎水等特性,吸水率低,生产过程对环境影响小。在新拌混凝土中添加发泡聚苯乙烯(EPS)可减少水的渗透,使建筑材料更疏水,最大限度地减少渗透问题,减少吸水的物理过程。浓度为 0.10%(重量/重量)的试样显示出更好的轴向机械性能,平均为 11.4 kgf,与浓度为 0.20%(重量/重量)的试样相比,增强效果提高了 52%。在 0.20%(重量/重量)的浓度下,EPS 微珠在水泥基质中的分散更加均匀,从而在机械作用时能更好地吸收冲击力。吸水试验分别进行了 10 分钟和 20 分钟,从而验证了每种复合材料的吸水百分比。发泡胶含量较高的试样(0.20% 和 0.10%)吸水率分别为 0.98% 和 1.29%,由于珍珠的存在比例较高,因此显示出更强的疏水性。EPS 使材料的透水性降低。根据 NBR 8491 标准的建议,吸水率值低于 20%,吸水效果相当令人满意。
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引用次数: 0
Experimental Analysis of Cryogenic-Treated Single Tubular Electrodes in Micro-EDM Using CRITIC-MOORA Based Integrated Approach 使用基于 CRITIC-MOORA 的集成方法对微线切割中低温处理的单管电极进行实验分析
Pub Date : 2024-02-05 DOI: 10.4028/p-ria4fs
Nivin Vincent, F. R. John
The current research focuses on the viability of rotating, single tubular brass electrodes undergoing shallow cryogenic treatment (at -140°C) before micro-drilling austenitic stainless steel SS316L with the electrical discharge machining process. In order to study and achieve a better rate of material removal and a lower rate of electrode wear, the Taguchi L18 experimental matrix representing the four variables, current, duty cycle, capacitance level, and gap voltage was examined. Regular tap water served as the dielectric fluid to uphold the sustainability concept of the machining experiments and an integrated hybrid approach incorporating CRITIC (criteria importance through inter-criteria correlation) weight determination method and MOORA (multi-objective optimization by the ratio analysis) was applied for decision making. The weight fractions (significance) for MRR and EWR were found to be 0.5532 and 0.4467, respectively and the MOORA method converted multiple objective parameters into a single objective function with weight fractions assigned to each of them. An ideal parameter combination highlighting the dominant significance of duty cycle, pulse current, capacitance level and gap voltage with corresponding values of 70%-18A-1-34V was obtained and the results were substantiated with relevant confirmation experiments. The highest MRR achieved is 10.0961 mm³/min and the lowest EWR is found to be 3.9640 mm³/min. Moreover, the electrode tip regions, the micro holes, and the surrounding workpiece surfaces were also thoughtfully scrutinized and contrasted using scanning electron micrographs (SEM), which validates the worth and significance of cryogenically frozen electrodes in successful micro-drilling of SS316L material.
目前的研究重点是旋转式单管黄铜电极在使用放电加工工艺对奥氏体不锈钢 SS316L 进行微钻孔之前进行浅低温处理(-140°C)的可行性。为了研究并实现更高的材料去除率和更低的电极磨损率,研究人员采用了代表电流、占空比、电容水平和间隙电压四个变量的 Taguchi L18 实验矩阵。为坚持加工实验的可持续性理念,采用了普通自来水作为介电流体,并结合 CRITIC(通过标准间相关性确定标准重要性)权重确定法和 MOORA(通过比率分析进行多目标优化)的综合混合方法进行决策。结果发现,MRR 和 EWR 的权重分数(重要性)分别为 0.5532 和 0.4467,MOORA 方法将多个目标参数转换为一个单一的目标函数,并为每个参数分配了权重分数。得出了一个理想的参数组合,突出了占空比、脉冲电流、电容水平和间隙电压的主导地位,其相应值为 70%-18A-1-34V,并通过相关的确认实验证实了结果。最高 MRR 为 10.0961 mm³/min,最低 EWR 为 3.9640 mm³/min。此外,还使用扫描电子显微镜(SEM)对电极尖端区域、微孔和周围工件表面进行了细致的检查和对比,从而验证了低温冷冻电极在成功微钻 SS316L 材料方面的价值和意义。
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引用次数: 0
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