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Arnet: research on wood CT image classification algorithm based on multi-scale dilated attention and residual dynamic convolution Arnet:基于多尺度扩张注意和残差动态卷积的木材CT图像分类算法研究
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-04-11 DOI: 10.1007/s00226-025-01649-3
Zhishuai Zheng, Zhedong Ge, Huanqi Zheng, Xiaoxia Yang, Lipeng Qin, Xu Wang, Yucheng Zhou

Addressing the challenges of low classification accuracy and protracted identification times posed by lightweight convolutional neural networks (CNNs) for wood micrograph classification, this study introduces ARNet, a novel model tailored for wood CT image analysis.ARNet significantly enhances the overall image recognition performance by boosting its dynamic feature extraction capabilities and refining its proficiency in processing salient features.The methodology employs residual dynamic convolution that dynamically aggregates convolutional kernels in response to the input image, optimizing adaptability.This optimized field of view across disparate feature layers facilitates the extraction of critical information such as wood texture, pore distribution, and cellular arrangement, thereby enhancing analytical depth.Additionally, ARNet incorporates multi-scale dilated attention mechanisms to capture nuanced feature maps across multiple scales, thereby broadening the scope of feature analysis.This approach not only achieves a profound understanding and efficient processing of the input data but also accentuates critical features, significantly enhancing the distinguishability between diverse image categories.The combination of CNNs and Transformers not only extracts rich local and global information but also captures unique features of images on a point-to-point basis, thereby improving classification accuracy. Experiments were conducted on the Mini-ImageNet, CIFAR100, and CIFAR10 public datasets. The results show that ARNet achieved top-1 accuracies of 65.21%, 78.32%, and 93.39% on Mini-ImageNet, CIFAR100, and CIFAR10, respectively, outperforming other models such as RMT, TCFormer, and SSViT. Additionally, we applied ARNet at the Shandong base of the national wood industry engineering research center to identify transverse section micrographs of 20 precious wood types, achieving an accuracy of 99.50% on the test set. After loading the parameters into the re-parameterized model, the validation set accuracy was 99.20%, with a detection time of 0.024s per image. This demonstrates that by combining residual dynamic convolution with multi-scale dilated attention, the accuracy and real-time performance of wood micrograph classification can be effectively improved.

针对轻量级卷积神经网络(cnn)在木材显微图像分类中分类精度低、识别时间长等问题,本研究引入了一种专门用于木材CT图像分析的新型模型ARNet。ARNet通过增强其动态特征提取能力和改进其处理显著特征的熟练程度,显著提高了整体图像识别性能。该方法采用残差动态卷积,根据输入图像动态聚合卷积核,优化适应性。这种跨不同特征层的优化视野有助于提取关键信息,如木材纹理、孔隙分布和细胞排列,从而提高分析深度。此外,ARNet还结合了多尺度扩张注意机制,以捕获跨多个尺度的细微特征图,从而扩大了特征分析的范围。该方法不仅实现了对输入数据的深刻理解和高效处理,而且突出了关键特征,显著提高了不同图像类别之间的可区分性。cnn和Transformers的结合不仅提取了丰富的局部和全局信息,而且在点对点的基础上捕获了图像的独特特征,从而提高了分类精度。实验在Mini-ImageNet、CIFAR100和CIFAR10公共数据集上进行。结果表明,ARNet在Mini-ImageNet、CIFAR100和CIFAR10上的准确率分别为65.21%、78.32%和93.39%,优于RMT、TCFormer和SSViT等其他模型。此外,我们在国家木材工业工程研究中心山东基地应用ARNet对20种珍贵木材类型的横切面显微图进行了识别,在测试集上的准确率达到99.50%。将参数加载到重新参数化的模型中后,验证集的准确率为99.20%,每张图像的检测时间为0.024s。说明残差动态卷积与多尺度扩张注意相结合,可以有效提高木材显微图像分类的准确率和实时性。
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引用次数: 0
A numerical method to integrate duration-of-load and bacterial deterioration for long-standing timber piles 长期木桩荷载持续时间与细菌劣化的数值计算方法
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-04-10 DOI: 10.1007/s00226-025-01652-8
Changxi Yang, Ani Khaloian-Sarnaghi, Taoyi Yu, Jan-Willem van de Kuilen

The strength degradation resulting from duration-of-load (DOL) effect and bacterial decay poses significant challenges to historical timber piles. Many historical European cities still heavily rely on the infrastructure supported by their original timber foundations. A reliable modelling approach on the structural performance of timber piles is needed to avoid the economic loss caused by closing down infrastructure. In this work, we consider a simplified bacterial decay model and develop a numerical framework to integrate the decay model into a standard DOL model. Two approaches are proposed and compared: one considering the homogenised effect of bacterial decay over the entire cross section, and the other taking into account the localised failure accelerated by bacterial decay and applying stiffness reduction to allow stress redistribution. Although the homogenised failure criterion is found to potentially underestimate the effect of bacterial decay, both approaches are able to capture the designated decay pattern. Ultimately, there is a potential for future extension to more intricate loading conditions and decay patterns.

由荷载持续时间效应和细菌腐烂引起的强度退化对历史木桩提出了重大挑战。许多历史悠久的欧洲城市仍然严重依赖原始木材基础的基础设施。为了避免基础设施关闭造成的经济损失,需要一种可靠的木桩结构性能建模方法。在这项工作中,我们考虑了一个简化的细菌腐烂模型,并开发了一个数值框架,将腐烂模型集成到标准DOL模型中。提出并比较了两种方法:一种考虑了细菌腐烂在整个截面上的均匀效应,另一种考虑了细菌腐烂加速的局部破坏,并应用刚度降低来允许应力重新分布。虽然发现均质失效标准可能低估了细菌腐烂的影响,但两种方法都能够捕获指定的腐烂模式。最终,未来有可能扩展到更复杂的加载条件和衰减模式。
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引用次数: 0
Analysis of biological adhesion and biomineralization products on the Yangtze Estuary II shipwreck 长江口沉船上生物黏附与生物矿化产物分析II
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-04-10 DOI: 10.1007/s00226-025-01651-9
Meng Zhao, Hao Zhou, He Huang, Jing Zhao, Qiang Li, Hongjie Luo

Biological deposition is commonly observed on wooden shipwrecks. This study employs analytical techniques, including optical microscopy (OM), scanning electron microscope equipped with an energy dispersive spectrometer (SEM-EDS), X-ray diffraction (XRD) and Fourier infrared transform spectroscopy (FTIR), to investigate the microscopic morphology and structural composition of barnacles and their adhesion to the wooden surface of the Yangtze Estuary II shipwreck. Results indicate that microorganisms like diatoms and Trichoderma spp. were present at the interface between the barnacles and the wooden surface. These microorganisms played a crucial role in the formation of SiO2, CaHPO4•2(H2O), FeO(OH) and CaCO3. Specifically, the bio-mineralized cell walls of diatoms and their cellular contents, including polyphosphates, provided the necessary Si and P for SiO2 and CaHPO4•2(H2O), respectively. Furthermore, during their metabolic processes, diatoms and Trichoderma spp. supply dissolved Fe ions, which contribute to the formation of FeO(OH) on the wooden surface. This study elucidates four types of bio-mineralized products resulting from microbial activity on the salvaged wooden shipwreck.

生物沉积在木制沉船上很常见。本研究采用光学显微镜(OM)、扫描电镜(SEM-EDS)、x射线衍射(XRD)和傅里叶红外变换光谱(FTIR)等分析技术,研究了长江口II号沉船木质表面藤蔓的微观形貌、结构组成及其附着情况。结果表明,藤壶与木质表面的交界面存在硅藻和木霉等微生物。这些微生物在SiO2、CaHPO4•2(H2O)、FeO(OH)和CaCO3的形成中起着至关重要的作用。具体来说,硅藻的生物矿化细胞壁及其细胞内容物(包括多磷酸盐)分别为SiO2和CaHPO4•2(H2O)提供了必需的Si和P。此外,在它们的代谢过程中,硅藻和木霉提供溶解的铁离子,这有助于在木材表面形成FeO(OH)。本研究阐明了在木质沉船残骸上微生物活动产生的四种生物矿化产物。
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引用次数: 0
Optimizing the interface compatibility of transparent wood for green phase-change thermal storage 优化透明木绿色相变储热的界面相容性
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-04-05 DOI: 10.1007/s00226-025-01650-w
Jichun Zhou, Wei Xu

Phase-change transparent wood (TW/DO-OTS) has the characteristics of energy storage, light transmission and regulates environmental temperature by absorbing or releasing energy during the phase-change process, in line with the double carbon goal. This research proposes an optimization of the interfacial compatibility of TW/DO-OTS, aiming to further improve the photothermal performance and mechanical strength of the samples. The wood templates were obtained by removing lignin in the wood, then the wood templates were modified by octadecyl trichlorosilane (OTS) solution, and finally TW/DO-OTS was prepared by introducing dodecanol/epoxy resin (DO/EP). The setting of OTS processing parameters is the key step of interface optimization, which is determined by single-factor experiment and response surface method. The TW/DO-OTS obtained through interface optimization has the transmittance of 92.50%, the melting temperature of 25.54 °C, and the melting latent heat of 88.96 J/g. It has good dimensional stability and high tensile strength. The energy storage of TW/DO-OTS is jointly provided by dodecanol inside the wood cell cavity and the cell wall. This wood-based green composite with light temperature responsiveness will become an ideal material choice for energy-saving buildings, temperature sensors, and cold chain transportation packaging in the future.

相变透明木(TW/DO-OTS)具有储能、透光的特性,在相变过程中通过吸收或释放能量调节环境温度,符合双碳目标。本研究提出对TW/DO-OTS的界面相容性进行优化,旨在进一步提高样品的光热性能和机械强度。通过去除木材中的木质素得到木模板,然后用十八烷基三氯硅烷(OTS)溶液对木模板进行改性,最后通过引入十二醇/环氧树脂(DO/EP)制备TW/DO-OTS。OTS工艺参数的设置是界面优化的关键步骤,通过单因素试验和响应面法确定。通过界面优化得到的TW/DO-OTS透过率为92.50%,熔化温度为25.54℃,熔化潜热为88.96 J/g。具有良好的尺寸稳定性和较高的抗拉强度。TW/DO-OTS的能量储存是由木胞腔和细胞壁内的十二醇共同提供的。这种具有光温响应性的木质绿色复合材料将成为未来节能建筑、温度传感器和冷链运输包装的理想材料选择。
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引用次数: 0
Hydroxyl radicals production via quinone redox cycling by the ligninolytic bacteria Streptomyces cyaneus and its effectiveness to degrade kraft lignin 木质素降解菌蓝链霉菌醌氧化还原循环产生羟基自由基及其降解硫酸盐木质素的效果
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-03-18 DOI: 10.1007/s00226-025-01643-9
José Manuel Molina-Guijarro, Francisco Guillén, Juana Rodríguez, Carmen Fajardo, Gabriela Domínguez, Andrew S. Ball, María E. Arias, Manuel Hernández

Microbial degradation of lignocellulose is a complex process mainly carried out by filamentous fungi and bacteria. Among prokaryotes, the genus Streptomyces stands out, with laccases playing a key role in its lignocellulolytic enzyme system. However, bacterial laccases have a lower redox potential than fungal laccases, suggesting that their action on lignin is indirect, via high redox potential intermediates. Prominent examples of intermediates are hydroxyl radicals. In Basidiomycota fungi, the production of these radicals occurs through quinone redox cycling, involving a Fenton reaction. This study demonstrates, for the first time, extracellular hydroxyl radical production via quinone redox cycling in the bacterium Streptomyces cyaneus CECT 3335, with laccase playing an essential role. The process begins with the extracellular oxidation of quinones to semiquinones, catalyzed by laccase. In the presence of Fe3+, semiquinones produce hydroxyl radicals via a Fenton reaction. The cycle is restored through quinone reduction by mycelium-associated reductase activity. H2O2 production, Fe3+ reduction, and hydroxyl radical generation were confirmed in S. cyaneus. The key role of laccase was verified using a mutant strain lacking laccase activity, in which hydroxyl radical production was absent. The oxidative potential of this mechanism in S. cyaneus was evidenced by the degradation of non-phenolic lignin-related compounds homoveratric acid and veratraldehyde and by the ability to depolymerize kraft lignin. This novel finding of quinone redox cycling in bacteria has important implications for Streptomyces’ role in lignin degradation, as well as potential biotechnological applications, including lignin biotransformation and bioremediation of organic pollutants.

木质纤维素的微生物降解是一个复杂的过程,主要由丝状真菌和细菌进行。在原核生物中,链霉菌属尤为突出,其漆酶在其木质纤维素水解酶系统中起着关键作用。然而,细菌漆酶比真菌漆酶具有更低的氧化还原电位,这表明它们对木质素的作用是间接的,通过高氧化还原电位的中间体。中间产物的突出例子是羟基自由基。在担子菌科真菌中,这些自由基的产生是通过醌氧化还原循环发生的,涉及芬顿反应。本研究首次证实了蓝链霉菌CECT 3335通过醌氧化还原循环产生胞外羟基自由基,漆酶在其中发挥了重要作用。这个过程开始于细胞外氧化醌到半醌,由漆酶催化。在Fe3+的存在下,半醌通过芬顿反应产生羟基自由基。这个循环通过菌丝相关还原酶活性还原醌而恢复。结果表明,青藻中H2O2的生成、Fe3+的还原和羟基自由基的生成得到了证实。用缺乏漆酶活性的突变菌株验证了漆酶的关键作用,其中羟基自由基的产生缺失。这一机制的氧化潜力在青霉中被证明是由非酚类木质素相关化合物的降解和木质素解聚的能力。这一新发现对链霉菌在木质素降解中的作用以及潜在的生物技术应用具有重要意义,包括木质素的生物转化和有机污染物的生物修复。
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引用次数: 0
Exploring wood as a sustainable solution for water filtration: nanoparticle removal, size exclusion and molecular adsorption 探索木材作为水过滤的可持续解决方案:纳米颗粒去除,尺寸排除和分子吸附
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-03-14 DOI: 10.1007/s00226-025-01645-7
Antoni Sánchez-Ferrer, Jenifer Guerrero Parra

In regions where microbial contamination of groundwater and surface water remains a significant public health concern, leading to around 505,000 annual deaths, there is an urgent need for accessible, cost-effective, and simple household water treatment solutions. This study investigated the feasibility of wood as a filtration system, with a focus on its ability to remove nanoparticles. The research underscores the remarkable potential of wood filters, particularly in radial and tangential directions, exhibiting superior particle removal capabilities (> 99%) due to extended residence time and intricate microstructures. The study reveals that wood type selection in this study, i.e., yellow poplar (Liriodendron tulipifera), European beech (Fagus sylvatica), Douglas fir (Pseudotsuga menziesii), and silver fir (Abies alba), plays a crucial role in filtration efficiency, with beech emerging as a high-performing option alongside silver fir. Importantly, the optimal range of size exclusion was identified (160–490 nm), aiding in designing wood filters for specific particle size reduction goals. Wood filters also show great potential for removing a broad range of microorganisms, i.e., bacteria and protozoa, as well as nanoplastics and microplastics, which could have profound implications for water treatment and environmental remediation. Furthermore, the study highlights the adsorption/diffusion process through the amorphous domains of the wood biopolymers, i.e., cellulose, hemicelluloses and lignin, enhanced by electrostatic interactions in the filtration efficiency for small organic molecules, providing valuable insights into filtration mechanisms.

在一些地区,地下水和地表水的微生物污染仍然是一个重大的公共卫生问题,每年导致约 505,000 人死亡,因此迫切需要方便、经济、简单的家庭水处理解决方案。这项研究调查了木材作为过滤系统的可行性,重点是木材去除纳米颗粒的能力。研究强调了木材过滤器的巨大潜力,特别是在径向和切向方向上,由于延长了停留时间和复杂的微结构,木材过滤器表现出卓越的颗粒去除能力(99%)。研究表明,在这项研究中,木材类型的选择,即黄杨(Liriodendron tulipifera)、欧洲山毛榉(Fagus sylvatica)、花旗松(Pseudotsuga menziesii)和银杉(Abies alba),对过滤效率起着至关重要的作用,其中山毛榉是与银杉并列的高性能选择。重要的是,我们确定了最佳的粒度排除范围(160-490 纳米),这有助于设计木质过滤器以实现特定的粒度降低目标。木质过滤器还显示出去除各种微生物(即细菌和原生动物)以及纳米塑料和微塑料的巨大潜力,这可能对水处理和环境修复产生深远影响。此外,该研究还强调了通过木材生物聚合物(即纤维素、半纤维素和木质素)的无定形结构域进行的吸附/扩散过程,该过程在静电相互作用的作用下提高了对小分子有机物的过滤效率,为研究过滤机制提供了宝贵的见解。
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引用次数: 0
Variation of quantitative anatomical features due to carbonization and their impact on size classes for charcoal identification 炭化引起的定量解剖特征的变化及其对木炭鉴定大小类别的影响
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-03-14 DOI: 10.1007/s00226-025-01641-x
Valentina Theresia Zemke, Gerald Koch, Volker Haag

Species identification of carbonized wood holds significance for various scientific disciplines, including botany, palaeontology, and archaeology. Identification also contributes to the preservation of endangered wood species and forests, and supports climate research. With regard to the identification of wood and wood products, all international research institutions adhere to the IAWA list of microscopic features for hardwood and softwood identification, established by the IAWA Committee in 1989.

Our comparative anatomical studies of 30 different species reveal significant dimensional losses of quantitative features during the charring process. Specifically, the findings indicate a shift in size classes, with varying percentages of loss in anatomical features from solid wood to charcoal for most of the taxa analyzed. Consequently, the size classes defined in databases for solid wood differentiation cannot be directly applied to charcoal identification. Furthermore, the present study employs statistical evaluations to illustrate the application of conventional size classes for the parameters: tangential diameter of vessel elements, intervessel pit diameter, ray height, and width. The implications of these findings for charcoal research are discussed in detail.

炭化木材的物种鉴定对包括植物学、古生物学和考古学在内的许多科学学科都具有重要意义。鉴定还有助于保护濒危木材物种和森林,并支持气候研究。关于木材和木制品的鉴定,所有国际研究机构都遵守IAWA委员会于1989年制定的用于硬木和软木鉴定的IAWA显微特征清单。我们对30个不同物种的比较解剖研究揭示了在炭化过程中数量特征的显著尺寸损失。具体来说,这些发现表明了大小类别的变化,在分析的大多数分类群中,解剖特征从实木到木炭的损失百分比不同。因此,在数据库中定义的实木区分大小类别不能直接应用于木炭识别。此外,本研究采用统计评估来说明常规尺寸类别对参数的应用:容器单元的切向直径,容器间坑直径,射线高度和宽度。这些发现对木炭研究的意义进行了详细讨论。
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引用次数: 0
Effect of attached weight on the measurement of the Young’s modulus and loss tangent of solid wood via the free and forced flexural vibration methods 附加重量对实木自由和受迫弯曲振动法测量杨氏模量和损失切线的影响
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-03-12 DOI: 10.1007/s00226-025-01646-6
Hiroshi Yoshihara, Masahiro Yoshinobu, Makoto Maruta

The Young’s modulus and loss tangent of a Sitka spruce wood sample in the longitudinal direction were determined using free flexural vibration (FRFV) and forced flexural vibration (FOFV) tests. During the tests, the attached weight and sample length were varied, and their effects on the Young’s modulus and loss tangent of the sample were examined. The Young’s modulus could be accurately and easily obtained from both the FRFV and FOFV tests using a modified Euler-Bernoulli’s equation, with the effect of the attached weight mitigated. No significant difference was observed between the two values of the Young’s modulus obtained from the two tests. The loss tangent slightly increased as the attached weight increased when the ratio of attached weight/sample weight was below 10%; however, it significantly increased with the increase in the attached weight when the ratio of the attached weight/sample weight exceeded 10%. The values of the loss tangent obtained from the FOFV tests for different samples were often higher than the corresponding values obtained from the FRFV tests, whereas the loss tangent values of different samples obtained from the FOFV tests were lower than the corresponding values obtained from the FRFV tests.

采用自由弯曲振动(FRFV)和强制弯曲振动(FOFV)试验,测定了锡特卡云杉木材样品在纵向上的杨氏模量和损失切线。在试验过程中,改变试样的附着量和长度,考察其对试样的杨氏模量和损失切线的影响。杨氏模量可以使用修正的欧拉-伯努利方程从FRFV和FOFV试验中准确而容易地获得,并且减轻了附加重量的影响。从两次试验中获得的杨氏模量的两个值之间没有观察到显著差异。当附着质量/样品质量比低于10%时,随着附着质量的增加,损失切线略有增加;但当附著质量与样品质量之比超过10%时,随附著质量的增加,其含量显著增加。不同样品的FOFV试验得到的损耗正切值往往高于FRFV试验得到的相应值,而不同样品的FOFV试验得到的损耗正切值低于FRFV试验得到的相应值。
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引用次数: 0
Flame retardancy of chemically surface-modified hardwoods by electron-beam-initiated polymerisation of impregnated acrylate monomers 浸渍丙烯酸酯单体电子束引发聚合化学表面改性硬木的阻燃性
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-03-12 DOI: 10.1007/s00226-025-01644-8
Solène Pellerin, Fabienne Samyn, Jérémy Winninger, Sophie Duquesne, Véronic Landry

Monomer impregnation is a great strategy to modify various wood properties. By choosing the right impregnant, it may lead to a higher flame retardancy of treated wood, contributing to its use in specific sectors such as building interior finishes. Yellow birch (Betula alleghaniensis Britt.) and sugar maple (Acer saccharum Marsh.) were surface-impregnated with an acrylate and a phosphorus acrylate monomer under vacuum and exposed to an electron beam for polymerisation. A surface chemical retention of 100 g.m− 2 was obtained for sugar maple, while the impregnation of yellow birch samples reached one around 200 g.m− 2. X-ray densitometry confirmed an asymmetric density profile due to the monomer penetration concentrated in the first millimetres of the samples. Microtomography and Raman spectroscopy highlighted the penetration path of the monomers in the wood, mainly through the vessels. The lumens of the cells close to the surface were also filled with polymers. The phosphorus monomer surface impregnation positively impacted the thermal and fire properties of the modified wood. A 25% decrease in the peak of heat release rate was observed, and the residual mass was multiplied by two compared to the reference. The phosphorus monomer contributed to the char formation.

单体浸渍是改变木材各种性能的好方法。通过选择正确的浸渍剂,它可以使处理过的木材具有更高的阻燃性,有助于其在特定部门的使用,如建筑内部饰面。黄桦树(Betula alleghaniensis Britt.)和糖枫(Acer saccharum Marsh.)在真空下表面浸渍丙烯酸酯和丙烯酸酯磷单体,并暴露在电子束下进行聚合。糖枫的表面化学保留率为100 g m−2,而黄桦样品的浸渍率约为200 g m−2。x射线密度测定证实了不对称的密度分布,因为单体渗透集中在样品的前毫米。显微断层扫描和拉曼光谱显示了单体在木材中的渗透路径,主要是通过血管。靠近表面的细胞腔内也充满了聚合物。磷单体表面浸渍对改性木材的热性能和防火性能有积极影响。观察到放热率峰值降低了25%,剩余质量与参考相比乘以2。磷单体有助于炭的形成。
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引用次数: 0
Wood pyrolysis modeling based on the pyrolysis characteristics of wood extracted and pseudo components 基于木材热解特征提取和伪组分的木材热解建模
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-02-25 DOI: 10.1007/s00226-025-01630-0
Ziling Shen, Jing Zhang, Chusheng Qi, Jun Mu

Wood pyrolysis is a complex process, and understanding its mechanism is challenging due to the interaction of multiple components. In this study, the pyrolysis kinetic properties of experimentally extracted wood components and wood pseudo components simulated via Fraser–Suzuki function deconvolution methods were analyzed. Additionally, the differences between the independent parallel reaction model (IPRM) and the deconvolution method were compared to investigate the pyrolysis characteristics of wood. The activation energy (E) and pre-exponential factor (A) were calculated using the Flynn-Wall-Ozawa (FWO) method. The results indicated that the average E for chemically extracted cellulose from Chinese fir was 165.4 kJ/mol and 157.1 kJ/mol for birch cellulose. The corresponding values for their pseudo-cellulose were 109.9 kJ/mol and 153.8 kJ/mol, respectively. Within the range of conversion rates less than 0.8, the pseudo components required a higher temperature to achieve the same conversion rate as the experimentally extracted components. The IPRM method accurately predicted the pyrolysis properties by combining holocellulose and lignin. However, its accuracy was low when combining cellulose, hemicellulose, and lignin, which was attributed to the interaction between in-situ components influencing wood pyrolysis.

木材热解是一个复杂的过程,由于多种组分的相互作用,对其机理的理解具有挑战性。本研究对实验提取的木材组分和用Fraser-Suzuki函数反卷积方法模拟的木材伪组分的热解动力学性质进行了分析。此外,比较了独立平行反应模型(IPRM)和反褶积方法的差异,研究了木材的热解特性。采用Flynn-Wall-Ozawa (FWO)法计算活化能E和指前因子A。结果表明,化学提取杉木纤维素的平均E值为165.4 kJ/mol,桦木纤维素的平均E值为157.1 kJ/mol。其伪纤维素的对应值分别为109.9 kJ/mol和153.8 kJ/mol。在转化率小于0.8的范围内,伪组分需要更高的温度才能达到与实验提取组分相同的转化率。IPRM方法通过将全新纤维素与木质素结合,准确预测了热解性能。然而,当结合纤维素、半纤维素和木质素时,其准确性较低,这是由于原位组分之间的相互作用影响了木材的热解。
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Wood Science and Technology
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