This article examines 10th-century blue and purple glass beads from a Hungarian burial in Lužianky, Slovakia, in order to determine their origin through chemical analysis. The beads are primarily composed of SiO2, Na2O and CaO, identified as soda-lime silica glass made from halophytic plant ash. The K2O content ranges from 2.292% to 3.145%, while the MgO content is between 4.385% and 6.160%. The beads are classified as Mesopotamian type 2. These findings highlight extensive trade between the Near East and Central Europe during the Early Middle Ages, demonstrating the region's integration into broader historical processes through combined archaeological and chemical research methods.
{"title":"Analysis of the medieval glass beads from a conquering Hungarian burial in Lužianky, Slovakia","authors":"Ján Štubňa, Réka Fülöp, Zuzana Borzová","doi":"10.1111/arcm.70007","DOIUrl":"https://doi.org/10.1111/arcm.70007","url":null,"abstract":"<p>This article examines 10th-century blue and purple glass beads from a Hungarian burial in Lužianky, Slovakia, in order to determine their origin through chemical analysis. The beads are primarily composed of SiO<sub>2</sub>, Na<sub>2</sub>O and CaO, identified as soda-lime silica glass made from halophytic plant ash. The K<sub>2</sub>O content ranges from 2.292% to 3.145%, while the MgO content is between 4.385% and 6.160%. The beads are classified as Mesopotamian type 2. These findings highlight extensive trade between the Near East and Central Europe during the Early Middle Ages, demonstrating the region's integration into broader historical processes through combined archaeological and chemical research methods.</p>","PeriodicalId":8254,"journal":{"name":"Archaeometry","volume":"67 6","pages":"1604-1618"},"PeriodicalIF":1.5,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145429328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The enduring mystery of the production, trade, and consumption of the prestigious proto-porcelain wares across northern and southern China has abated in the wake of discovery of kilns for such products in the recent decades. A new cluster of such kilns recently discovered in the Wuyishan Mountain, in particular, supplies a promising candidate for provenancing those of the Western Zhou (1045-771 BCE). To test this possibility, however, it is indispensable to investigate a priori the compositional characteristics of the products of this cluster. To this end, the authors analyzed a number of samples of proto-porcelain wares from three sites and porcelain stone near them with ICP-OES and SEM-EDS. They found that the bodies of the samples are made of porcelain stone available in the vicinity. The discrepancies in the bodies and glazes across different production sites are largely derived from deliberate choices of raw materials and firing technologies.
{"title":"Compositional characteristics of proto-porcelain wares of the Wuyishan cluster in Southeast China","authors":"Zequn Li, Tao Ma, Zelin Yang, Weiqiang Li, Yuqi Li, Fang Yuan, Liangren Zhang","doi":"10.1111/arcm.70004","DOIUrl":"https://doi.org/10.1111/arcm.70004","url":null,"abstract":"<p>The enduring mystery of the production, trade, and consumption of the prestigious proto-porcelain wares across northern and southern China has abated in the wake of discovery of kilns for such products in the recent decades. A new cluster of such kilns recently discovered in the Wuyishan Mountain, in particular, supplies a promising candidate for provenancing those of the Western Zhou (1045-771 BCE). To test this possibility, however, it is indispensable to investigate a priori the compositional characteristics of the products of this cluster. To this end, the authors analyzed a number of samples of proto-porcelain wares from three sites and porcelain stone near them with ICP-OES and SEM-EDS. They found that the bodies of the samples are made of porcelain stone available in the vicinity. The discrepancies in the bodies and glazes across different production sites are largely derived from deliberate choices of raw materials and firing technologies.</p>","PeriodicalId":8254,"journal":{"name":"Archaeometry","volume":"67 6","pages":"1581-1603"},"PeriodicalIF":1.5,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145429327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dan Zhao, Weijuan Zhao, Qinlong Chen, Baohua Zhou, Jianfeng Cui
The kiln site in Yaogang village is the location of the imperial glazed kiln in Nanjing, China: the Jubaoshan glazed kiln. It mainly supplied the glazed tiles required for the construction of imperial buildings, such as the Ming Imperial Palace and Bao’ensi. A total of 15 samples of glazed tiles were selected and analysed by optical microscopy (OM), X-ray diffraction (XRD), thermal decomposition (TD) and energy dispersive X-ray fluorescence (EDXRF) spectroscopy to determine their apparent morphology, phase composition, firing temperature and chemical composition, respectively. Research indicates that the glaze and body of glazed tiles exhibit distinct characteristics, lacking an intermediate layer. The glaze layer is a vitreous phase with excellent meltability and no residual crystals, while the body primarily consists of a matrix, particulate matter and pores. The phase composition of the body mainly comprises quartz and mullite, with some samples also containing trace amounts of rutile, hematite and sanidine. The firing temperature for ceramic body samples of glazed tiles in Yaogang village reaches approximately 1000°C, indicating a relatively high level of firing. The raw materials used for the body differ from those employed in the Ming Imperial Palace and Bao’ensi and Dangtu; their source remains to be explored. The primary chemical components present in yellow and green glazes on glazed tiles in Yaogang village are PbO and SiO2, respectively. Different colouring elements contribute to various hues observed on glazed tiles: Fe plays a significant role in yellow glaze coloration, while Cu and Fe jointly influence green glaze coloration.
{"title":"The glazed tiles in Yaogang village kiln in the Ming dynasty, Nanjing, China: Unveiling the unique mysteries of their techniques and compositions through comprehensive analysis methods","authors":"Dan Zhao, Weijuan Zhao, Qinlong Chen, Baohua Zhou, Jianfeng Cui","doi":"10.1111/arcm.70003","DOIUrl":"https://doi.org/10.1111/arcm.70003","url":null,"abstract":"<p>The kiln site in Yaogang village is the location of the imperial glazed kiln in Nanjing, China: the Jubaoshan glazed kiln. It mainly supplied the glazed tiles required for the construction of imperial buildings, such as the Ming Imperial Palace and Bao’ensi. A total of 15 samples of glazed tiles were selected and analysed by optical microscopy (OM), X-ray diffraction (XRD), thermal decomposition (TD) and energy dispersive X-ray fluorescence (EDXRF) spectroscopy to determine their apparent morphology, phase composition, firing temperature and chemical composition, respectively. Research indicates that the glaze and body of glazed tiles exhibit distinct characteristics, lacking an intermediate layer. The glaze layer is a vitreous phase with excellent meltability and no residual crystals, while the body primarily consists of a matrix, particulate matter and pores. The phase composition of the body mainly comprises quartz and mullite, with some samples also containing trace amounts of rutile, hematite and sanidine. The firing temperature for ceramic body samples of glazed tiles in Yaogang village reaches approximately 1000°C, indicating a relatively high level of firing. The raw materials used for the body differ from those employed in the Ming Imperial Palace and Bao’ensi and Dangtu; their source remains to be explored. The primary chemical components present in yellow and green glazes on glazed tiles in Yaogang village are PbO and SiO<sub>2</sub>, respectively. Different colouring elements contribute to various hues observed on glazed tiles: Fe plays a significant role in yellow glaze coloration, while Cu and Fe jointly influence green glaze coloration.</p>","PeriodicalId":8254,"journal":{"name":"Archaeometry","volume":"67 6","pages":"1565-1580"},"PeriodicalIF":1.5,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145429524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Francis Albarede, Gillan Davis, Haim Gitler, Janne Blichert-Toft, Liesel Gentelli
This study presents a comprehensive approach to provenancing ancient silver artefacts, introducing a novel algorithm to correct for mass-dependent isotope fractionation. Applied to a Pb isotope database of 281 Hacksilber samples from southern Levantine hoards (1700–600 BCE) and compared with approximately 7000 galena ores from Spain to Iran, the analysis reveals shifting silver sources over time. Trade of the Levantine merchants with the pre- and early-Celtic societies of the western Mediterranean appears to have followed long-established east-west corridors along the northern Mediterranean coast-routes originally opened during the Neolithic expansion of Anatolian farmers and later reused during the Bronze Age and the Iron Age. The reduction in silver remelting reflects more efficient sourcing and trading practices by the end of the Iron Age.
{"title":"Levantine Hacksilber and the flow of silver in early Mediterranean commerce","authors":"Francis Albarede, Gillan Davis, Haim Gitler, Janne Blichert-Toft, Liesel Gentelli","doi":"10.1111/arcm.70006","DOIUrl":"https://doi.org/10.1111/arcm.70006","url":null,"abstract":"<p>This study presents a comprehensive approach to provenancing ancient silver artefacts, introducing a novel algorithm to correct for mass-dependent isotope fractionation. Applied to a Pb isotope database of 281 Hacksilber samples from southern Levantine hoards (1700–600 BCE) and compared with approximately 7000 galena ores from Spain to Iran, the analysis reveals shifting silver sources over time. Trade of the Levantine merchants with the pre- and early-Celtic societies of the western Mediterranean appears to have followed long-established east-west corridors along the northern Mediterranean coast-routes originally opened during the Neolithic expansion of Anatolian farmers and later reused during the Bronze Age and the Iron Age. The reduction in silver remelting reflects more efficient sourcing and trading practices by the end of the Iron Age.</p>","PeriodicalId":8254,"journal":{"name":"Archaeometry","volume":"67 6","pages":"1547-1564"},"PeriodicalIF":1.5,"publicationDate":"2025-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/arcm.70006","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145429225","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sun Tianqiang, Chen Weidong, Zheng Luhong, Liu Fang, Li Yingfu, Li Yuniu
The Luojiaba site, located in eastern Sichuan Province, unearthed iron smelting-related remains from the Eastern Han Period in 2022, including slag, tuyere fragments, refractory materials, and hammer scales. A comprehensive study of the excavated smelting remains indicates that the site engaged in bloomery iron smelting and forging activities during the Eastern Han Period. By comparing the site with other bloomery iron smelting sites of the Han Dynasty discovered in China, it is suggested that, influenced by social and economic factors, there may have been a tradition of bloomery iron smelting in the southwestern minority regions of China. Additionally, by reviewing the iron artifacts unearthed from the Warring States to the Han Dynasty at the Luojiaba site, the origins and development of the use of iron at Luojiaba are explored.
{"title":"The use and production technologies of iron of the Han Dynasty in eastern Sichuan Province, China","authors":"Sun Tianqiang, Chen Weidong, Zheng Luhong, Liu Fang, Li Yingfu, Li Yuniu","doi":"10.1111/arcm.70001","DOIUrl":"https://doi.org/10.1111/arcm.70001","url":null,"abstract":"<p>The Luojiaba site, located in eastern Sichuan Province, unearthed iron smelting-related remains from the Eastern Han Period in 2022, including slag, tuyere fragments, refractory materials, and hammer scales. A comprehensive study of the excavated smelting remains indicates that the site engaged in bloomery iron smelting and forging activities during the Eastern Han Period. By comparing the site with other bloomery iron smelting sites of the Han Dynasty discovered in China, it is suggested that, influenced by social and economic factors, there may have been a tradition of bloomery iron smelting in the southwestern minority regions of China. Additionally, by reviewing the iron artifacts unearthed from the Warring States to the Han Dynasty at the Luojiaba site, the origins and development of the use of iron at Luojiaba are explored.</p>","PeriodicalId":8254,"journal":{"name":"Archaeometry","volume":"67 6","pages":"1531-1546"},"PeriodicalIF":1.5,"publicationDate":"2025-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145429375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}