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Elemental analysis of glass beads from Southeast Asia in the Corning Museum of Glass 康宁玻璃博物馆中来自东南亚的玻璃珠的元素分析
IF 1.5 3区 地球科学 0 ARCHAEOLOGY Pub Date : 2025-04-28 DOI: 10.1111/arcm.13090
Laure Dussubieux, Katherine A. Larson, Kristin Landau

The Corning Museum of Glass in Corning, New York, houses thousands of glass beads acquired in the early 1970s from Alastair Lamb. These materials represent Lamb's research at Kuala Selinsing, Pengkalan Bujang, and Johor Lama (all in Malaysia), and Takua Pa (Thailand), spanning almost two millennia of interactions across the Bay of Bengal interaction sphere. Laser ablation inductively coupled mass spectrometric (LA-ICP-MS) analysis of a subset of material attributed to these sites provides significant comparative data that elucidates the patterns of glass production within the region alongside imported materials from the Middle East and China over the longue durée.

位于纽约康宁的康宁玻璃博物馆收藏了数千颗上世纪70年代初从阿拉斯泰尔·兰姆(Alastair Lamb)手中购得的玻璃珠。这些材料代表了Lamb在Kuala Selinsing, Pengkalan Bujang, and Johor Lama(都在马来西亚)和Takua Pa(泰国)的研究,跨越了孟加拉湾相互作用领域近两千年的相互作用。激光烧蚀电感耦合质谱(LA-ICP-MS)分析了这些地点的一部分材料,提供了重要的比较数据,阐明了该地区玻璃生产的模式,以及长期以来从中东和中国进口的材料。
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引用次数: 0
High-resolution compound-specific δ15N isotope dietary study of humans from the Scottish Mesolithic and Neolithic 苏格兰中石器时代和新石器时代人类高分辨率化合物特异性δ15N同位素饮食研究
IF 1.5 3区 地球科学 0 ARCHAEOLOGY Pub Date : 2025-04-24 DOI: 10.1111/arcm.13089
Valentina Martinoia, Oliver E. Craig, Sophy Charlton, Kate Britton, Alison Sheridan, Annie Bones, Helen Talbot, Rebecca MacDonald, Michael Richards

Numerous isotopic studies of Scottish Mesolithic and Neolithic diets suggest a shift from marine-based to terrestrial-based subsistence strategies. However, bulk collagen isotope analysis may overlook low-level marine food consumption. This study combines bulk collagen stable isotope data from four Neolithic sites (Quanterness, Rattar East, Ness of Brodgar, and Knap of Howar) with nitrogen compound-specific isotope analysis (CSIA-AA) from one Late Mesolithic and five Neolithic sites. CSIA-AA, applied here for the first time to Scottish material, reveals limited but detectable aquatic resource use by some Neolithic individuals in Orkney. These findings highlight the complexities in identifying marine contributions to diet and underscore the value of CSIA-AA in distinguishing direct marine consumption from other sources of elevated nitrogen isotope values, such as seaweed or animals with marine-influenced diets.

对苏格兰中石器时代和新石器时代饮食的大量同位素研究表明,生存策略从以海洋为基础转向以陆地为基础。然而,大量胶原同位素分析可能忽略了低水平的海洋食物消耗。本研究结合了4个新石器时代遗址(Quanterness、Rattar East、Ness of Brodgar和Knap of Howar)的胶原蛋白稳定同位素数据,以及1个晚中石器时代和5个新石器时代遗址的氮化合物特异性同位素分析(CSIA-AA)。CSIA-AA首次应用于苏格兰材料,揭示了奥克尼一些新石器时代个体对水生资源的有限但可检测的利用。这些发现突出了确定海洋对饮食贡献的复杂性,并强调了CSIA-AA在区分直接海洋消费与其他氮同位素值升高来源(如海藻或海洋影响饮食的动物)方面的价值。
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引用次数: 0
Enhancing stone provenance studies through software built with language model artificial intelligence (AI): An example of ancient Calabrian quarries (southern Italy) 利用语言模型人工智能(AI)构建的软件加强石料来源研究:以古卡拉布里亚采石场(意大利南部)为例
IF 1.5 3区 地球科学 0 ARCHAEOLOGY Pub Date : 2025-04-23 DOI: 10.1111/arcm.13091
Domenico Miriello, Raffaella De Luca

This study represents the first attempt to develop archaeometric software that enables researchers without programming knowledge to address archaeometric challenges, specifically determining the provenance of rocks extracted from ancient quarries. Through interaction with ChatGPT 4.0, an advanced artificial intelligence (AI) language model, the authors guided the AI to develop StoneScanalyzer 1.0 software in Python programming language. The step-by-step collaborative process resulted in software capable of automatically extracting 43 quantitative variables from sets of images of cut, wet rocks acquired under reflected light, thin sections of rocks acquired under natural and polarized transmitted light using a flatbed scanner. Data elaboration using linear discriminant analysis (LDA) models and principal component analysis (PCA) led to the construction of discriminant diagrams for 250 samples taken from 10 quarries located in Calabria (southern Italy). StoneScanalyzer 1.0 software can be easily used by researchers without basic petrographic or geological knowledge, making it highly appealing as a first step for archaeologists, architects, art historians and anyone interested in studying rock provenance without expertise in mineralogy, geochemistry or petrography.

这项研究首次尝试开发考古测量软件,使没有编程知识的研究人员能够解决考古挑战,特别是确定从古代采石场提取的岩石的来源。通过与先进的人工智能(AI)语言模型ChatGPT 4.0交互,指导人工智能用Python编程语言开发StoneScanalyzer 1.0软件。这个循序渐进的协作过程使得软件能够自动从一系列图像中提取43个定量变量,这些图像包括在反射光下获得的切割、湿岩石,以及在自然光和偏振透射光下获得的岩石薄片,使用平板扫描仪。利用线性判别分析(LDA)模型和主成分分析(PCA)对数据进行细化,构建了来自卡拉布里亚(意大利南部)10个采石场的250个样本的判别图。StoneScanalyzer 1.0软件可以由没有基本岩石学或地质知识的研究人员轻松使用,使其成为考古学家,建筑师,艺术史学家和任何有兴趣研究岩石来源而没有矿物学,地球化学或岩石学专业知识的人的第一步。
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引用次数: 0
Trajectories of adoption for silver and bloomery iron in China from the Spring and Autumn period (c. 770–476 BC) 中国春秋时期(公元前770-476年)对银和铁的采用轨迹
IF 1.5 3区 地球科学 0 ARCHAEOLOGY Pub Date : 2025-04-08 DOI: 10.1111/arcm.13088
Jonathan R. Wood, Yaxiong Liu

We examine the number of sites with silver objects in China over a period of 3500 years to suggest that technologies that stimulated the indigenous exploitation of silver-bearing ores were innovated during the Spring and Autumn period (c. 770–476 BCE), and that increased centralisation and bureaucratisation from the Warring States period (475–221 BCE) advanced their adoption. This culture of innovation should have extended to other prestige metals used for decorative objects, such as bloomery iron. However, bloomery iron, although rare prior to the 5th century BCE, disappears almost entirely from the archaeological record in China after this time. We recognise that the movement of objects and ideas across the Eurasian Steppe was potentially the impetus for both silver- and bloomery iron-production technologies in China, but that the adoption trajectory of bloomery iron diverged from that of silver because of the introduction of mass-produced cast iron. In effect, we propose that bloomery iron's status and value diminished when iron became recognised as a utilitarian material; that is, the Chinese invention of cast iron stymied the adoption of the bloomery process and effectively signed the death warrant of iron as a prestige metal.

我们研究了3500年来中国银器遗址的数量,表明刺激含银矿开采的技术是在春秋时期(公元前770-476年)创新的,而战国时期(公元前475-221年)中央集权和官僚主义的增加促进了它们的采用。这种创新文化应该延伸到其他用于装饰物品的高级金属,比如灯笼铁。然而,虽然在公元前5世纪之前很少见,但在此之后,中国的考古记录几乎完全消失了。我们认识到,欧亚草原上物品和思想的流动可能是中国银铁和铁制品生产技术的推动力,但由于大规模生产铸铁的引入,铁制品的采用轨迹与银制品的采用轨迹有所不同。实际上,我们认为,当铁被认为是一种实用材料时,开花铁的地位和价值就会下降;也就是说,中国铸铁的发明阻碍了bloomery工艺的采用,并有效地签署了铁作为威望金属的死刑令。
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引用次数: 0
Tracing the origin of Roman mosaic tiles in Aquileia: Petrographic analysis of specimens from the suburbium 追寻阿奎莱亚罗马马赛克瓷砖的起源:郊区标本的岩石学分析
IF 1.5 3区 地球科学 0 ARCHAEOLOGY Pub Date : 2025-04-02 DOI: 10.1111/arcm.13082
Neva M. E. Stucchi, Giulia Franceschin, Chiara Coletti, Andrea Vavasori, Claudio Mazzoli, Arianna Traviglia

This research represents the most extensive characterisation of Roman mosaic tesserae (tiles) from Aquileia, Italy, to date, examining 153 specimens. The study aimed to identify the lithotypes used in mosaics production through a multi-analytical approach, which included colorimetric analysis, polarised light microscopy and scanning electron microscopy. The results showcase a variety of materials, particularly limestone sourced from the Italian and the Slovenian Karst regions, as well as colourful lithic materials from distant locations. These findings expand current knowledge beyond the limited scientific literature on Aquileian mosaics and can inform further studies on sourcing strategies, local socio-economic connections and craftsmanship of the Roman era.

这项研究代表了迄今为止意大利阿奎莱亚的罗马马赛克(瓷砖)最广泛的特征,检查了153个标本。该研究旨在通过多种分析方法,包括比色分析、偏振光显微镜和扫描电子显微镜,确定马赛克生产中使用的石版。结果展示了各种材料,特别是来自意大利和斯洛文尼亚喀斯特地区的石灰石,以及来自遥远地方的彩色岩屑材料。这些发现扩展了目前关于阿奎莱拉马赛克的有限科学文献的知识,并可以为进一步研究采购策略、当地社会经济联系和罗马时代的工艺提供信息。
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引用次数: 0
Comparative effectiveness of techniques for examining the canvas, paint, and the pictorial structure of 16th- and 17th-century Chinese paintings 16世纪和17世纪中国画的画布、颜料和图案结构的比较效果
IF 1.5 3区 地球科学 0 ARCHAEOLOGY Pub Date : 2025-04-02 DOI: 10.1111/arcm.13079
Lingyu Zhao

The paper primarily examines and compares the effectiveness of techniques for analyzing the paint, canvas, and pictorial structure of a painting to determine its condition, age, and authenticity. The study was conducted in four phases. In the first phase, the study employed a stereo microscope, UV–Vis–NIR reflectance spectroscopy, X-ray imaging, X-ray fluorescence, and biochemical analysis in order to examine a sample of paintings. During the second phase, the results of analyzing authentic paintings and reproductions were compared to understand the distinctive features that aid in determining a piece's authenticity. During the third phase, the test findings and scores (in terms of compositional arrangement, the depiction of shapes using color, proficiency in painting techniques, color, and harmonic solution) assigned to these paintings were compared. The fourth phase included a survey conducted among experts to obtain their opinions on special programs and technologies for examining the canvas, paints, and pictorial structure. Research findings revealed the analysis methods preferred by experts and the domains of painting research in which these methods prove to be most effective.

本文主要考察和比较了分析一幅画的颜料、画布和图案结构的技术的有效性,以确定其状况、年代和真实性。这项研究分四个阶段进行。在第一阶段,研究采用立体显微镜、UV-Vis-NIR反射光谱、x射线成像、x射线荧光和生化分析来检查画作样本。在第二阶段,对真迹和复制品的分析结果进行比较,以了解有助于确定作品真实性的独特特征。在第三阶段,对分配给这些绘画的测试结果和分数(就构图安排、使用颜色描绘形状、熟练掌握绘画技巧、颜色和调和解决方案而言)进行比较。第四阶段包括对专家进行调查,以获得他们对检查画布、颜料和图像结构的特殊程序和技术的意见。研究结果揭示了专家和绘画研究领域的首选分析方法,这些方法被证明是最有效的。
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引用次数: 0
Tracking Bronze Age ‘itinerant smiths’ in western Poland: insights from Nd and Sr isotope data 追踪波兰西部青铜时代的“流动铁匠”:来自Nd和Sr同位素数据的见解
IF 1.5 3区 地球科学 0 ARCHAEOLOGY Pub Date : 2025-04-01 DOI: 10.1111/arcm.13085
Mateusz Stróżyk, Łukasz Pospieszny, Zdzislaw Belka, Aldona Garbacz-Klempka, Patrycja Silska, Marta Wardas-Lasoń

The neodymium (Nd) isotope composition of stone casting moulds found in graves of Bronze Age ‘itinerant smiths’ in western Poland was analysed to determine the provenance of their raw materials. For the first time in archaeological research, the Nd model age (TDM)—a highly useful parameter in studying the provenance of geological materials—has been applied. Nd data revealed that the material for making casting moulds came from the Sudetes. Additionally, the results of strontium isotope analysis in human remains indicated that the metallurgists were neither born nor spent their early childhood in the areas where they were buried.

在波兰西部的青铜时代“流动铁匠”的坟墓中发现的石头铸造模具的钕(Nd)同位素组成进行了分析,以确定其原材料的来源。Nd模式年龄(TDM)在考古研究中首次得到应用,这是研究地质物质物源的重要参数。数据显示,制造铸造模具的材料来自苏台德地区。此外,对人类遗骸的锶同位素分析结果表明,冶金学家既不是在他们被埋葬的地区出生,也不是在他们被埋葬的地区度过童年。
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引用次数: 0
Accessory minerals: a provenancing tool for steatite quarries 辅助矿物:滑石采石场的物源鉴定工具
IF 1.5 3区 地球科学 0 ARCHAEOLOGY Pub Date : 2025-04-01 DOI: 10.1111/arcm.13087
Riia Chmielowski, Kamal Badreshany, Karen Milek

Steatite has been a widely traded material across a range of archaeological contexts. Yet, challenges inherent to determining its provenance limits our understanding of the networks and mechanisms of its exchange. We present a robust new accessory mineral provenancing “fingerprint” method based their specific growth history. We use laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to produce detailed trace-element maps of minerals that reveal changes in the composition across individual crystals, which arose due to changes in their location-specific growing conditions. Our case study presents results from Scandinavian steatite quarries that feature spinel and iron oxide accessory minerals.

在一系列考古背景下,滑石一直是一种广泛交易的材料。然而,确定其来源的固有挑战限制了我们对其交换网络和机制的理解。基于其特定的生长历史,我们提出了一种新的辅助矿物物源识别“指纹”方法。我们使用激光烧蚀电感耦合等离子体质谱(LA-ICP-MS)来生成详细的矿物微量元素图,揭示了单个晶体成分的变化,这些变化是由于其特定位置生长条件的变化而产生的。我们的案例研究展示了斯堪的纳维亚滑石采石场的结果,这些采石场具有尖晶石和氧化铁辅助矿物。
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引用次数: 0
Characterisation of Jewellery with glass and garnet inlays from the Bohemian region and Great Migration Period 波西米亚地区和大迁徙时期玻璃和石榴石镶嵌珠宝的特征
IF 1.5 3区 地球科学 0 ARCHAEOLOGY Pub Date : 2025-03-30 DOI: 10.1111/arcm.13083
Zuzana Zlámalová Cílová, Viktoria Čisťakova, Zdeněk Beneš, Pavel Horník, Tomáš Kmječ, Ladislav Lapčák

The research focuses on jewellery finds uncovered in the region of today's Czech Republic dated to the Great Migration Period. The metals and garnet inlays detected were examined with μ-EDXRF, whereas, for glass samples, LA-ICP-MS was used. The paper presented is supplemented with data concerning the technological processing of the jewellery (documented with optical microscopy) and information dealing with analogies to the artifacts studied. Based on the chemical composition combined with the results of Raman spectroscopy, the study has identified several types of garnets with varying geological origins. The occurrence frequency of the types represented differs from previously published data.

这项研究的重点是在今天的捷克共和国地区发现的珠宝,这些珠宝可以追溯到大迁徙时期。金属和石榴石镶嵌体采用μ-EDXRF检测,玻璃样品采用LA-ICP-MS检测。本文还补充了有关珠宝工艺处理的数据(用光学显微镜记录)和处理与所研究的人工制品相似的信息。根据化学成分和拉曼光谱结果,该研究确定了几种具有不同地质起源的石榴石。所代表的类型的发生频率与以前发表的数据不同。
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引用次数: 0
Unveiling diverse copper trace element profiles from a single smelting site through laser ablation–inductively coupled plasma–mass spectrometric analysis 通过激光烧蚀-电感耦合等离子体质谱分析揭示单一熔炼现场多种铜微量元素剖面
IF 1.5 3区 地球科学 0 ARCHAEOLOGY Pub Date : 2025-03-26 DOI: 10.1111/arcm.13077
Junling Lin, Siran Liu, Guisen Zou, Tao Cui

As an important provenance indicator, trace element profile has been widely used to reveal the origin and mixing history of archaeological bronzes. However, due to the lack of chemical characterization of raw copper from smelting sites, there has been little understanding about the variation of trace element concentration within one copper source. This has significantly confined discussion on copper circulation in prehistoric societies. This research developed a method to analyze copper prills embedded in smelting slag based on laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS). A series of tests have proved that a relative error of less than 20% can be achieved for most elements with appropriate choice of analytical parameters and reference materials. This method is then used to analyze the Early–Middle Shang (1500–1200 BC) period copper smelting slag from the site of Tongling in northern Jiangxi province, China. The results show that the copper smelted from different ores of the same site has systematically different trace element characteristics, and copper prills of this site are highly varied in terms of Ag, Ni, Co, As, and Bi content. When plotting Tongling prills together with the bronze artifacts from the Panlongcheng site, also in the Middle Yangtze River valley, it is found that the trace element concentration of these two sites correspond well with each other, and the Panlongcheng bronzes with highly varied trace element profile could have been manufactured with copper from one source. This analysis demonstrates the potentially heterogeneous nature of the copper trace element profiles produced at one smelting site, and calls for more analysis of copper prills using LA-ICP-MS to establish a new foundation for future discussions on copper provenance based on trace element data.

微量元素剖面作为一种重要的物源指标,已被广泛用于揭示考古青铜器的来源和混合历史。然而,由于缺乏冶炼现场原铜的化学特征,对同一铜源内微量元素浓度的变化了解甚少。这极大地限制了对史前社会铜流通的讨论。本研究建立了一种基于激光烧蚀-电感耦合等离子体质谱(LA-ICP-MS)分析熔渣中铜丸的方法。一系列试验证明,在选择适当的分析参数和标准物质的情况下,大多数元素的相对误差可小于20%。该方法随后被用于分析中国江西省北部铜陵遗址中商早期(公元前1500-1200年)时期的铜冶炼渣。结果表明,同一地点不同矿石熔炼铜具有系统不同的微量元素特征,该地点铜丸的Ag、Ni、Co、As和Bi含量差异较大。将铜陵铜器与盘龙城遗址青铜器进行对比,发现两者的微量元素含量吻合较好,表明盘龙城青铜器的微量元素含量差异较大,可能是同一来源的铜器。该分析表明,在同一熔炼地点产生的铜微量元素剖面具有潜在的异质性,并呼吁使用LA-ICP-MS对铜颗粒进行更多分析,为未来基于微量元素数据讨论铜的来源奠定新的基础。
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引用次数: 0
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Archaeometry
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