Archaeometry最新文献

We report observations of wear traces and microbotanical analysis of 29 ceramics, one pot of Cucurbita sp., and one wooden spoon—all artifacts of the AZ-6 and AZ-71 cemeteries of the Cabuza cultural phase (900–1200 ce), Azapa Valley, northern Chile—. The results show some unused artifacts (11) besides 21 samples that were positive for starches of Zea mays, Cucurbita sp., Manihot esculenta, Ipomoea batatas, or Phaseolus sp., in addition to vegetable remains (13 cases). This evidence is interpreted as an expression of funerary rites in post-state times, which could be an inheritance of the Andean Tiwanaku State (ca. 500–1000 ce).

Organic residue analysis (ORA) is a valuable tool for the study of ancient diets, but conventional methods remain limited in terms of taxonomic identification or to resolve mixtures. Here, we propose a method to further explore a class of compounds—triacylglycerols (TAGs)—using high-resolution mass spectrometry to overcome these limitations in an attempt to better characterise culinary practices. Over 70 medieval Sicilian pots and a wide range of authentic fresh products were studied by matrix-assisted laser desorption/ionisation–mass spectrometry (MALDI-MS and MALDI-MS/MS). MALDI-MS analysis can distinguish fresh foodstuffs but provides little additional information regarding the contents of archaeological pottery compared to conventional ORA methods. In contrast, product ion analyses were able to deconvolute a range of animal carcass fat mixtures. In addition, detailed analysis of the composition of saturated T₄₄ and unsaturated T₅₀–T₅₄ TAGs was able to provide greater taxonomic resolution regarding dairy products and plant oils.

This study describes the petrographic and geochemical characteristics of pottery collected from Mugharat al-Kahf and WTN02 in Wadi Tanuf, north-central Oman, to clarify interregional similarities and differences in pottery production techniques and examine the existence of interregional trade in pottery with respect to changes in mobile communities. Potsherds from these sites were characterised using thin-section petrography and instrumental neutron activation analysis. Results revealed that several clay fabrics and tempers were used during the Wadi Suq period (2000–1600 BCE). A region-wide similarity exists in pottery-making techniques in terms of the tempering of specific minerals (Oman ophiolite) used in the Early Iron Age (1300–300 BCE). Geochemical results indicate differences in clay sources between the Wadi Suq period and the Early Iron Age in Wadi Tanuf and the unlikelihood of the interregional trade of domestic pottery.

This case study examines the use of X-ray fluorescence (XRF) as an effective method for defining distinct chemical compositions of local basalt stone from different sources in the Roman period, even when their quarries have not been identified. It also deals with the archaeological question if public and monumental structures from a village and urban site shared the same stone sources and stonemason's workshops. Ninety-six samples from the Hippos Territorium, mainly from the polis of Hippos and the village of Majduliyya, were analyzed. XRF was found to be an effective method for defining distinct chemical compositions of local basalt materials from different sources. The distinct composition of the basalt stones between the two sites provided valuable insights into socio-economic relationships, shedding light on the nature of city–village dynamics in the region. Additionally, it aids in discerning whether diverse basalt sources were utilized in both private and public constructions, as well as installations within a single site. Methodological questions and the application of this method in the archaeological research of basalt-based architecture are also addressed.

Micro-X-ray fluorescence (XRF) screening of 244 glass sherds from Ribe, Denmark, identified 23 wood ash glasses. The closely dated finds pinpoint the arrival of the earliest wood ash glass produced in Western Europe in this important North Sea trading hub. This glass type was absent among glass from 700 to 790 CE but feature strongly from 790 to 810 CE. Electron microprobe analysis (EMPA) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis of 24 glasses show the presence of four types. We show the strengths of classifying wood ash glass based on the glass-producing sands and conclude that the earliest production took place on a considerable scale and had a major impact on glass circulation in Northern Europe in the ninth century.

The rise of porcelain industry in northern China and the subsequent emergence of white porcelain production during the Northern dynasties (386–581 CE) played a pivotal role in shaping the historical trajectory of Chinese ceramics. Xing kiln is one of China's earliest and most representative white porcelain kilns. Herein, we investigated 23 porcelain sherds from the Neiqiu Xing kiln site during the late Northern dynasties and the early Sui dynasty (550–600 CE) from the perspective of firing temperature, firing atmosphere, and microstructure using a dilatometer, X-ray photoelectron spectroscopy, and scanning electron microscopy. The results show that the early Xing porcelains were fired at high firing temperatures exceeding 1200°C with a reducing flame, and the adjustment of temperature promotes the emergence of early white porcelain. Moreover, the higher firing temperature of early Xing porcelain leads to the dominance of a glassy phase within the glaze, and the high bonding strength of the glaze and body caused by the body–glaze interaction layer formed with dense anorthite crystals. Overall, these findings provide valuable insights into the firing technology in the Xing kiln and even in North China during the late sixth century.

The discovery of a specific form of Late Neolithic object in northeast Poland, commonly interpreted as reed arrowshaft straighteners, prompted investigation into the possible use of reed for archery in the European past. To examine the archery qualities of this raw material, and thus the likely rationale behind the manufacture and use of reed arrowshafts, a number of mechanical and experimental analyses were conducted. The results presented here indicate that reed was well suited for prehistoric archery. This is demonstrated above all by the arrowshaft stiffness required by this discipline, defined as the spine-force, but also both the technological ease of production of arrows and their ballistic capabilities.

In this study, we compare the patterns of demographic changes in populations from Northwest Patagonia and central-south Chile throughout the Late Pleistocene–Holocene obtained from absolute dates with those resulting from molecular genealogies. We have found that temporal distributions of frequencies of absolute dates constitute a more sensitive demographic indicator than molecular data to make inferences at small spatial scales in the region. Moreover, even though the latter has proven to be very informative about old demographic processes, it represents a less reliable source of information for more recent ones.

The Monastery of Alcobaça houses in reserve the ceramic tiles that adorned the floor of the church's apse. These tiles were removed during rehabilitation works and many preserve part of their original fixing mortars. A comprehensive analysis of 21 samples was conducted using a multi-analytical approach (X-ray fluorescence, X-ray diffraction, scanning electron microscopy–energy-dispersive X-ray spectroscopy, μ-Raman spectroscopy, thermogravimetry–differential thermal analysis, optical microscopy, and colorimetry). Results suggest compositional variations in the samples from the back and sides of the ceramic tiles; however, the mineralogy and general characteristics of the aggregates remained consistent between the samples and are coherent with the local geology, suggesting a shared historical origin.

We present a study of a selection of metal ornaments belonging to archaeological funerary goods from Patagonic Indigenous groups. They are part of the ‘Andrés Giai’ Collection, under the guard of the Museum of Patagonia (Nahuel Huapi National Park [PNNH]; National Parks Administration [APN]), Argentina. The absence of contextual information and its current conservation status motivated the design of an interdisciplinary methodology to develop an Integral Conservation Plan that considered the selection of analytical techniques. Here, we implemented complementary nondestructive characterisation techniques such as particle induced X-ray emission (PIXE), X-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM/EDS). We developed a methodology enabling us to characterise each piece with respect to its metallic composition and degradation products, and in certain cases, their manufacturing process. These findings have contributed with essential information for the tailored conservation treatment proposal. Moreover, they provided key information in regard to the reconstruction of contextual data for each piece. In addition, the methodology proposed for the Integral Conservation Plan takes into account an optimisation of the techniques to be used in order to minimise unnecessary handling of goods whilst ensuring an appropriate use of technological and economic resources whilst minimising time on potentially unconclusive measurements and results.