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Bulk electronic structure of lanthanum hexaboride (LaB6) by hard x-ray angle-resolved photoelectron spectroscopy 硬x射线角分辨光电子能谱法研究六硼化镧(LaB6)的体电子结构
Pub Date : 2020-12-04 DOI: 10.1103/PhysRevMaterials.5.055002
A. Rattanachata, L. Nicolaï, H. Martins, G. Conti, M. Verstraete, M. Gehlmann, S. Ueda, Keisuke L. I. Kobayashi, I. Vishik, C. Schneider, C. Fadley, A. Gray, J. Minár, S. Nemšák
We investigate the bulk electronic structure of lanthanum hexaboride using tender-hard x-ray photoemission spectroscopy, measuring both core-level and angle-resolved valence-band spectra. We compare the La 3d core level spectrum to cluster model calculations in order to understand the bulk-like core-hole screening effects. The results show that the La 3d well-screened peak is at a lower binding energy compared to the main poorly-screened peak and the relative intensity between these peaks depends on how strong the hybridization is between La and B atoms. We show that the recoil effect, negligible in the soft x-ray regime, becomes prominent at higher kinetic energies for lighter elements, such as boron, but is still negligible for heavy nuclei, such as lanthanum. In addition, we report the bulk-like band structure of lanthanum hexaboride determined by tender-hard x-ray angle-resolved photoemission spectroscopy (HARPES). We compare HARPES experimental results to the free-electron final-state calculations and to the more precise one-step photoemission theory including matrix element and phonon excitation effects. The agreement between the features present in the experimental ARPES data and the theoretical calculations is remarkable. In addition, we consider the nature and the magnitude of phonon excitations in order to interpret HARPES experimental data measured at different temperatures and excitation energies. We demonstrate that one step theory of photoemission and HARPES experiments provide, at present, the only approach capable of probing, both experimentally and theoretically, true bulk-like electronic band structure of rare-earth hexaborides and strongly correlated materials.
我们利用软硬x射线光发射光谱研究了六硼化镧的体电子结构,测量了核能级和角分辨价带光谱。我们将La 3d岩心能级谱与聚类模型计算进行了比较,以了解块状岩心孔的筛分效果。结果表明,与屏蔽较差的主峰相比,屏蔽良好的La 3d峰具有较低的结合能,并且这些峰之间的相对强度取决于La和B原子之间杂化的强度。我们发现,在软x射线下可以忽略不计的反冲效应,在动能较高的轻元素(如硼)中变得突出,但在重核(如镧)中仍然可以忽略不计。此外,我们报道了用软硬x射线角分辨光发射光谱(HARPES)测定六硼化镧的块状带结构。我们将HARPES实验结果与自由电子末态计算和更精确的一步光发射理论(包括矩阵元素和声子激发效应)进行了比较。ARPES实验数据的特征与理论计算结果的吻合是显著的。此外,我们考虑了声子激发的性质和大小,以便解释在不同温度和激发能下测量的HARPES实验数据。我们证明了光发射一步理论和HARPES实验提供了目前唯一能够在实验和理论上探测稀土六硼化物和强相关材料的真正块状电子带结构的方法。
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引用次数: 3
Analytical Design for Full-space Spatial Power Dividers Using Metagratings 全空间空间功率分压器的分析设计
Pub Date : 2020-11-29 DOI: 10.1364/JOSAB.437379
Hamid Rajabalipanah, A. Abdolali
We present a rigorous theoretical framework for designing full-space spatial power dividers using metagratings. In our study, the current restrictions of spatial power dividing platforms such as reflection-only performance, operating at normal incidence, and small reflection/refraction angles have been totally relaxed. A modal expansion analysis based on Floquet-Bloch (FB) theorem is established so that a discrete set of spatial harmonics is considered in both reflection and transmission sides of a compound metallic grating in which the unknown coefficients are calculated by applying proper boundary conditions. By eliminating the unwanted scattering harmonics, the proposed metagrating has the ability to realize different functionalities from perfect anomalous refraction to reflection-transmission spatial power dividing, without resorting to full-wave numerical optimizations. The numerical simulations confirm well the theoretical predictions. Our findings not only offer possibilities to realize arbitrary spatial power dividers but also reveal a simple alternative for beamforming array antennas.
我们提出了一个严谨的理论框架,用于设计全空间空间功率分压器。在我们的研究中,空间分力平台目前的限制,如仅反射性能、正常入射角、小反射/折射角等,已经完全放松。建立了基于Floquet-Bloch (FB)定理的模态展开分析,考虑了复合金属光栅反射侧和透射侧的离散空间谐波集,并采用适当的边界条件计算了未知系数。通过消除不需要的散射谐波,所提出的偏光能够实现从完美的异常折射到反射-透射空间功率划分的不同功能,而无需采用全波数值优化。数值模拟结果很好地证实了理论预测。我们的发现不仅提供了实现任意空间功率分配器的可能性,而且揭示了波束形成阵列天线的简单替代方案。
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引用次数: 4
Topological slow light via coupling chiral edge modes with flatbands 通过与平带耦合手性边缘模式的拓扑慢光
Pub Date : 2020-11-28 DOI: 10.1063/5.0039839
Letian Yu, Haoran Xue, Baile Zhang
Chiral edge modes in photonic topological insulators host great potential to realize slow-light waveguides with topological protection. Increasing the winding of the chiral edge mode around the Brillouin zone can lead to broadband topological slow light with ultra-low group velocity. However, this effect usually requires careful modifications on a relatively large area around the lattice edge. Here we present a simple and general scheme to achieve broadband topological slow light through coupling the chiral edge modes with flat bands. In this approach, modifications inside the topological lattice are not required. Instead, only several additional resonators that support the flat bands need to be attached at the lattice edge. We demonstrate our idea numerically using a gyromagnetic photonic crystal, which is ready to be tested at microwave frequencies.
光子拓扑绝缘体中的手性边缘模式具有实现具有拓扑保护的慢光波导的巨大潜力。增加布里渊带周围的手性边缘模式的缠绕可以产生超低群速度的宽带拓扑慢光。然而,这种效果通常需要在晶格边缘周围相对较大的区域上进行仔细的修改。本文提出了一种简单而通用的方案,通过将手性边缘模式与平带耦合来实现宽带拓扑慢光。在这种方法中,不需要对拓扑晶格内部进行修改。相反,只需要在晶格边缘附加几个支持平坦带的额外谐振器。我们用一个陀螺磁光子晶体在数值上证明了我们的想法,该晶体已经准备好在微波频率下进行测试。
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引用次数: 16
Breaking voltage–bandwidth limits in integrated lithium niobate modulators using micro-structured electrodes 利用微结构电极打破集成铌酸锂调制器的电压带宽限制
Pub Date : 2020-11-26 DOI: 10.1364/OPTICA.416155
P. Kharel, C. Reimer, K. Luke, Lingyan He, Mian Zhang
Electro-optic modulators with low voltage and large bandwidth are crucial for both analog and digital communications. Recently, thin-film lithium niobate modulators have enable dramatic performance improvements by reducing the required modulation voltage while maintaining high bandwidths. However, the reduced electrode gaps in such modulators leads to significantly higher microwave losses, which limit electro-optic performance at high frequencies. Here we overcome this limitation and achieve a record combination of low RF half-wave voltage of 1.3 V while maintaining electro-optic response with 1.8-dB roll-off at 50 GHz. This demonstration represents a significant improvement in voltage-bandwidth limit, one that is comparable to that achieved when switching from legacy bulk to thin-film lithium niobate modulators. Leveraging the low-loss electrode geometry, we show that sub-volt modulators with $>$ 100 GHz bandwidth can be enabled.
具有低电压和大带宽的电光调制器在模拟和数字通信中都是至关重要的。最近,薄膜铌酸锂调制器在保持高带宽的同时降低了所需的调制电压,从而显著提高了性能。然而,这种调制器中减少的电极间隙会导致更高的微波损耗,从而限制了高频下的电光性能。在这里,我们克服了这一限制,实现了1.3 V低射频半波电压的创纪录组合,同时在50 GHz下保持1.8 db滚降的电光响应。该演示在电压带宽限制方面取得了重大进步,与从传统的大块铌酸锂调制器切换到薄膜铌酸锂调制器时所取得的成就相当。利用低损耗电极几何结构,我们证明可以启用带宽> 100 GHz的亚伏特调制器。
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引用次数: 83
Acoustic imaging by three-dimensional acoustic Luneburg meta-lens with lattice columns 带点阵柱的三维吕尼堡元透镜声学成像
Pub Date : 2020-11-25 DOI: 10.1063/5.0037600
Jung-Woo Kim, Seong-Jin Lee, Jun-Yeong Jo, Semyun Wang, Sang-Hoon Kim
A three-dimensional acoustic Luneburg lens, or acoustic Luneburg ball, has the advantage of refracting sound waves for all incident angles and concentrating higher sound pressure compared to a two-dimensional lens. A lens with a radius of 60 mm was designed with thousands of unit atoms comprising lattice columns to maintain its shape. The focusing performance of the lens was simulated using COMSOL Multiphysics, a finite element analysis program. Acoustic imaging was performed at a frequency of 10 kHz using a microphone, transducer, three-axis linear stage, and LabVIEW-based measurement program for a plastic lens made by a selective laser sintering 3D printer. The omnidirectional property was confirmed by measuring the sound pressure level while rotating the lens. The sound pressure level gain was defined to represent the frequency-dependent performance of the lens, and the maximum values were measured at approximately 20 dB and 15 dB in the numerical simulation and the experiment, respectively, at a frequency of 16 kHz. The results suggest that acoustic meta-lenses can be used for acoustic communication, imaging systems, and energy harvesting.
与二维透镜相比,三维声学Luneburg透镜或声学Luneburg球具有对所有入射角的声波进行折射和集中更高声压的优点。设计了一个半径为60毫米的透镜,由数千个单位原子组成晶格柱,以保持其形状。利用有限元分析软件COMSOL Multiphysics对该透镜的聚焦性能进行了仿真。利用麦克风、换能器、三轴线性工作台和基于labview的测量程序,在10 kHz的频率下对选择性激光烧结3D打印机制造的塑料透镜进行声学成像。通过测量旋转透镜时的声压级,证实了其全向特性。定义声压级增益来表示透镜的频率依赖性能,在数值模拟和实验中,在16 kHz频率下,声压级增益的最大值分别约为20 dB和15 dB。结果表明,声学元透镜可用于声学通信、成像系统和能量收集。
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引用次数: 7
Compact and Tunable Forward Coupler Based on High-Impedance Superconducting Nanowires 基于高阻抗超导纳米线的紧凑可调谐正向耦合器
Pub Date : 2020-11-23 DOI: 10.1103/PHYSREVAPPLIED.15.024064
M. Colangelo, Di Zhu, D. Santavicca, B. Butters, J. Bienfang, K. Berggren
Developing compact, low-dissipation, cryogenic-compatible microwave electronics is essential for scaling up low-temperature quantum computing systems. In this paper, we demonstrate an ultra-compact microwave directional forward coupler based on high-impedance slow-wave superconducting-nanowire transmission lines. The coupling section of the fabricated device has a footprint of $416,mathrm{mu m^2}$. At 4.753 GHz, the input signal couples equally to the through port and forward-coupling port (50:50) at $-6.7,mathrm{dB}$ with $-13.5,mathrm{dB}$ isolation. The coupling ratio can be controlled with DC bias current or temperature by exploiting the dependence of the kinetic inductance on these quantities. The material and fabrication-process are suitable for direct integration with superconducting circuits, providing a practical solution to the signal distribution bottlenecks in developing large-scale quantum computers.
开发紧凑、低耗散、低温兼容的微波电子器件对于扩大低温量子计算系统至关重要。在本文中,我们展示了一种基于高阻抗慢波超导纳米线传输线的超紧凑微波定向正向耦合器。所制备器件的耦合部分的占地面积为$416, mathm {mu m^2}$。在4.753 GHz时,输入信号在$-6.7,mathrm{dB}$的隔离度为$-13.5,mathrm{dB}$时均匀耦合到直通端口和前向耦合端口(50:50)。利用动态电感对直流偏置电流或温度的依赖关系,可以控制耦合比。该材料和制造工艺适合与超导电路直接集成,为开发大规模量子计算机中的信号分布瓶颈提供了实用的解决方案。
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引用次数: 4
Machine Learning and High-Throughput Robust Design of P3HT-CNT Composite Thin Films for High Electrical Conductivity 高导电性P3HT-CNT复合薄膜的机器学习和高通量稳健设计
Pub Date : 2020-11-20 DOI: 10.26434/chemrxiv.13265288.v1
Daniil Bash, Yongqiang Cai, Vijila Chellappan, S. L. Wong, Yang Xu, Pawan Kumar, J. Tan, Anas Abutaha, J. Cheng, Y. Lim, S. Tian, D. Ren, Flore Mekki-Barrada, W. Wong, J. Kumar, Saif A. Khan, Qianxiao Li, T. Buonassisi, K. Hippalgaonkar
Combining high-throughput experiments with machine learning allows quick optimization of parameter spaces towards achieving target properties. In this study, we demonstrate that machine learning, combined with multi-labeled datasets, can additionally be used for scientific understanding and hypothesis testing. We introduce an automated flow system with high-throughput drop-casting for thin film preparation, followed by fast characterization of optical and electrical properties, with the capability to complete one cycle of learning of fully labeled ~160 samples in a single day. We combine regio-regular poly-3-hexylthiophene with various carbon nanotubes to achieve electrical conductivities as high as 1200 S/cm. Interestingly, a non-intuitive local optimum emerges when 10% of double-walled carbon nanotubes are added with long single wall carbon nanotubes, where the conductivity is seen to be as high as 700 S/cm, which we subsequently explain with high fidelity optical characterization. Employing dataset resampling strategies and graph-based regressions allows us to account for experimental cost and uncertainty estimation of correlated multi-outputs, and supports the proving of the hypothesis linking charge delocalization to electrical conductivity. We therefore present a robust machine-learning driven high-throughput experimental scheme that can be applied to optimize and understand properties of composites, or hybrid organic-inorganic materials.
将高通量实验与机器学习相结合,可以快速优化参数空间,以实现目标属性。在这项研究中,我们证明了机器学习与多标签数据集相结合,可以额外用于科学理解和假设检验。我们引入了一个自动化的流动系统,用于薄膜制备,具有高通量滴铸,然后是光学和电学性质的快速表征,能够在一天内完成一个周期的学习,完全标记约160个样品。我们将区域规则聚3-己基噻吩与各种碳纳米管结合,以实现高达1200s /cm的电导率。有趣的是,当10%的双壁碳纳米管与长单壁碳纳米管一起添加时,出现了一个非直观的局部最优,其电导率高达700 S/cm,我们随后用高保真光学表征解释了这一点。采用数据集重采样策略和基于图的回归使我们能够考虑相关多输出的实验成本和不确定性估计,并支持证明将电荷离域与电导率联系起来的假设。因此,我们提出了一个强大的机器学习驱动的高通量实验方案,可用于优化和理解复合材料或混合有机-无机材料的性能。
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引用次数: 7
Defect spectroscopy and non-ionizing energy loss analysis of proton and electron irradiated p-type GaAs solar cells 质子和电子辐照p型砷化镓太阳能电池的缺陷光谱和非电离能量损失分析
Pub Date : 2020-11-16 DOI: 10.1063/5.0028029
C. Pellegrino, A. Gagliardi, C. Zimmermann
Admittance spectroscopy combined with non-ionizing energy loss (NIEL) analysis is shown to be a powerful tool for analyzing solar cell radiation degradation, not relying on the change of macroscopic cell parameters. GaAs component cells, representative of the middle sub-cell in Ga 0.5 In 0.5 P / GaAs / Ge solar cells, were irradiated with protons and electrons in the 0.5–3 MeV energy range. Four irradiation-induced defects are identified in the p-type base layer. The nature of each defect is assessed by analyzing the dependence of its introduction rate on the NIEL deposited by electrons in the semiconductor. The expected linear relationship is only achieved if a unique threshold energy E d is ascribed to each defect, which ranges from 9 to 38 eV. An electron NIEL with E d = 21 eV, customarily used for GaAs-based solar cell degradation analysis, is an approximation of the relative abundance of these four defects. The 21 eV value is thus a GaAs material-specific parameter, independent of the electrical device design. In addition, the type and energy of the incident particle is correlated with the relative abundance of high E d defects. The impact of each defect on the macroscopic electrical parameters of the cell, namely, the open-circuit voltage V OC, the short-circuit current density J SC, and the recombination current density J 02, is assessed with the help of a Pearson analysis. The different effectiveness of electron and proton irradiation on parameters dominated by recombination in the depleted region, such as V OC or J 02, is attributed in part to the influence of the particle recoil spectra on the defect capture cross section.
导纳光谱与非电离能量损失(NIEL)分析相结合是分析太阳电池辐射退化的有力工具,不依赖于电池宏观参数的变化。采用质子和电子在0.5 ~ 3 MeV的能量范围内辐照GaAs组件电池,作为Ga 0.5 in 0.5 P / GaAs / Ge太阳能电池中间亚电池的代表。在p型基层中发现了四个辐照缺陷。每个缺陷的性质是通过分析其引入率对半导体中电子沉积的NIEL的依赖来评估的。期望的线性关系只有在将一个唯一的阈值能量E d归因于每个缺陷时才能实现,其范围从9到38 eV。ed = 21 eV的电子NIEL通常用于gaas基太阳能电池的降解分析,是这四种缺陷相对丰度的近似值。因此,21 eV值是GaAs材料特定的参数,与电气器件设计无关。此外,入射粒子的类型和能量与高能谱缺陷的相对丰度有关。通过Pearson分析,评估了各缺陷对电池宏观电参数的影响,即开路电压V OC、短路电流密度jsc和复合电流密度j02。电子和质子辐照对贫区以复合为主的参数(如V OC或j02)的不同效果部分归因于粒子反冲谱对缺陷捕获截面的影响。
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引用次数: 7
Surface corrugated laminates as elastic grating couplers: Splitting of SV- and P-waves by selective diffraction 作为弹性光栅耦合器的表面波纹层压板:通过选择性衍射分离SV波和p波
Pub Date : 2020-11-16 DOI: 10.1063/5.0037804
G. Chaplain, R. Craster
The phenomenon of selective diffraction is extended to in-plane elastic waves and we design surface corrugated periodic laminates that incorporate crystal momentum transfer which, due to the rich physics embedded within the vector elastic system, results in frequency, angle and wave-type selective diffraction. The resulting devices are elastic grating couplers, with additional capabilities as compared to analogous scalar electromagnetic couplers, in that the elastic couplers possess the ability to split and independently redirect, through selective negative refraction, the two body waves present in the vector elastic system: compressional (P) and shear-vertical (SV) elastic waves. The design paradigm, and interpretation, is aided by obtaining isofrequency contours via a non-dimensionalised transfer matrix method.
选择性衍射现象扩展到平面内弹性波,我们设计了包含晶体动量传递的表面波纹周期性层叠板,由于矢量弹性系统中嵌入了丰富的物理,导致频率,角度和波型选择性衍射。由此产生的装置是弹性光栅耦合器,与类似的标量电磁耦合器相比,具有额外的功能,因为弹性耦合器具有通过选择性负折射分裂和独立重定向矢量弹性系统中存在的两个体波的能力:压缩(P)和剪切垂直(SV)弹性波。设计范例和解释是通过无量纲化传递矩阵方法获得等频轮廓来辅助的。
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引用次数: 1
Topological Transition in Spiral Elastic Valley Metamaterials 螺旋弹性谷超材料的拓扑跃迁
Pub Date : 2020-11-12 DOI: 10.1103/PHYSREVAPPLIED.15.014058
Shuaifeng Li, Jinkyu Yang
Elastic valley metamaterials offer an excellent platform to manipulate elastic waves and have potential applications in energy harvesting and elastography. Here we introduce a series of strategies to realize topological transition in spiral elastic valley metamaterials by parameter modulations. We show the evolution of Berry curvature and valley Chern number as a function of inherent parameters of spiral, which further results in a general scheme to achieve topological valley edge states. Our strategy leverages multiple degrees of freedom in spiral elastic valley metamaterials to provide enhanced opportunities for desired topological states.
弹性谷材料提供了一个很好的平台来操纵弹性波,在能量收集和弹性成像方面具有潜在的应用前景。本文介绍了一系列通过参数调制实现螺旋弹性谷超材料拓扑跃迁的策略。我们将Berry曲率和谷Chern数的演化作为螺旋固有参数的函数,从而得到了实现拓扑谷边状态的一般方案。我们的策略利用螺旋弹性谷超材料的多个自由度,为所需的拓扑状态提供增强的机会。
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引用次数: 7
期刊
arXiv: Applied Physics
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