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The connection between plasmon decay dynamics and the surface enhanced Raman spectroscopy background: Inelastic scattering from non-thermal and hot carriers 等离子体衰变动力学与表面增强拉曼光谱背景之间的联系:非热和热载流子的非弹性散射
Pub Date : 2020-10-14 DOI: 10.1063/5.0032763
Shengxian Wu, Oscar Hsu-Cheng Cheng, B. Zhao, Nicki Hogan, An-Tse Lee, D. Son, M. Sheldon
Recent studies have established that the anti-Stokes Raman signal from plasmonic metal nanostructures can be used to determine the two separate temperatures that characterize carriers inside the metal -- the temperature of photoexcited "hot carriers" and carriers that are thermalized with the metal lattice. However, the related signal in the Stokes spectral region has historically impeded surface enhanced Raman spectroscopy (SERS), as the vibrational peaks of adsorbed molecules are always accompanied by the broad background of the metal substrate. The fundamental source of the metal signal, and hence its contribution to the spectrum, has been unclear. Here, we outline a unified theoretical model that describes both the temperature-dependent behavior and the broad spectral distribution. We suggest that the majority of the Raman signal is from inelastic scattering directly with non-thermal carriers that have been excited via damping of the surface plasmon. In addition, a significant spectral component (~ 1%) is due to a sub-population of hot carriers in an elevated thermal distribution. We have performed temperature and power-dependent Raman experiments to show how a simple fitting procedure reveals the plasmon dephasing time, as well as the temperatures of the hot carriers and the metal lattice, in order to correlate these parameters with quantitative Raman analysis of chemical species adsorbed on metal surface.
最近的研究已经证实,等离子体金属纳米结构的反斯托克斯拉曼信号可以用来确定金属内部载流子的两个不同温度——光激发“热载流子”的温度和与金属晶格热化的载流子的温度。然而,Stokes光谱区域的相关信号历来阻碍了表面增强拉曼光谱(SERS),因为吸附分子的振动峰总是伴随着金属衬底的宽背景。金属信号的基本来源,以及它对频谱的贡献,一直不清楚。在这里,我们概述了一个统一的理论模型,描述了温度依赖的行为和广谱分布。我们认为,大部分拉曼信号是直接与非热载流子的非弹性散射,这些载流子是通过表面等离子体激元的阻尼激发的。此外,显著的光谱成分(~ 1%)是由于热分布中热载流子的亚群。我们进行了温度和功率相关的拉曼实验,展示了一个简单的拟合程序如何揭示等离子体脱相时间,以及热载流子和金属晶格的温度,以便将这些参数与吸附在金属表面的化学物质的定量拉曼分析联系起来。
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引用次数: 6
An Investigation On Neck Extensions For Single and Multi-Degree Of Freedom Acoustic Helmholtz Resonators 单自由度和多自由度声学亥姆霍兹谐振器颈部延伸的研究
Pub Date : 2020-10-12 DOI: 10.2514/6.2021-2206
A. Gautam, A. Celik, M. Azarpeyvand
The effect of neck extensions in single and multi-degree of freedom Helmholtz resonator based acoustic liners is studied both experimentally and numerically and the resulting transmission coefficient and resonance frequencies are examined. It has been shown that a single degree of freedom liner with increasing neck extension lengths leads to the resonance frequencies being pushed to lower frequency values, however, this shift to lower frequencies is not linear with increasing length. A study on including neck extensions for the primary and/or secondary neck within a double degree of freedom liner is also presented. It is shown that both neck extension concepts lead to an increase in bandwidth of sound absorption by a double degree of freedom Helmholtz resonator.
本文通过实验和数值方法研究了基于单自由度和多自由度亥姆霍兹谐振腔的声衬垫中颈部伸长的影响,并对由此产生的透射系数和共振频率进行了分析。研究表明,随着颈部延伸长度的增加,单自由度线性线性管会导致共振频率被推到较低的频率值,然而,这种向较低频率的转移并不是随着长度的增加而线性的。本文还研究了在双自由度衬垫内对主颈和/或次颈进行颈部延伸的方法。结果表明,两种伸长颈的概念都会导致双自由度亥姆霍兹谐振器吸声带宽的增加。
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引用次数: 2
Thermodynamic driving force of transient negative capacitance of ferroelectric capacitors 铁电电容器瞬态负电容的热力学驱动力
Pub Date : 2020-10-07 DOI: 10.1063/5.0039246
Yuanyuan Zhang, Xiaoqing Sun, Junshuai Chai, Hao Xu, Xueli Ma, J. Xiang, Kai Han, Xiaolei Wang, Wenwu Wang
This paper investigates the thermodynamic driving force of transient negative capacitance (NC) in the series circuit of the resistor and ferroelectric capacitor (R-FEC). We find that the widely used Landau-Khalatnikov (L-K) theory, that is, the minimum of the Gibbs free energy, is inapplicable to explain the transient NC. The thermodynamic driving force of the transient NC phenomenon is the minimum of the difference between the elastic Gibbs free energy and the electric polarization work. The appearance of the transient NC phenomenon is not due to the widely accepted view that the ferroelectric polarization goes through the negative curvature region of elastic Gibbs free energy landscape (Ga). Instead, the transient NC phenomenon appears when the energy barrier of Ga disappears. The transient NC is dependent on both the intrinsic ferroelectric material parameters and extrinsic factors in the R-FEC circuit.
本文研究了电阻器与铁电电容器串联电路中瞬态负电容(NC)的热力学驱动力。我们发现广泛使用的Landau-Khalatnikov (L-K)理论,即Gibbs自由能的最小值,并不适用于瞬态NC的解释。瞬态数控现象的热力学驱动力是弹性吉布斯自由能与电极化功之差的最小值。瞬态NC现象的出现并不是因为人们普遍认为铁电极化经过弹性吉布斯自由能区(Ga)的负曲率区。相反,当Ga的能垒消失时,会出现瞬态NC现象。在R-FEC电路中,瞬态NC既取决于铁电材料的固有参数,也取决于外在因素。
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引用次数: 1
Experimental validation of differential evolution indicators for ultrasonic imaging in unknown backgrounds 未知背景下超声成像差分演化指标的实验验证
Pub Date : 2020-10-05 DOI: 10.1016/j.ymssp.2021.108029
Fatemeh Pourahmadian
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引用次数: 5
Laser-processing of grinded and mechanically abraded Nb-surfaces 研磨和机械研磨铌表面的激光加工
Pub Date : 2020-09-30 DOI: 10.2351/7.0000160
V. Porshyn, P. Rothweiler, D. Lützenkirchen-Hecht
The effect of pulsed laser polishing on rough niobium surfaces was investigated. We created different well-defined roughness profiles with standard emery papers and subsequently remelted random surface areas with a size of about 2x2 mm^2 with nanosecond laser pulses (wavelength of 1064 nm, pulse length of 10 ns). Pristine as well as laser-treated surfaces were investigated using optical profilometry and atomic force microscopy, and the surface topography was described by means of correlation functions. Uniformly rough and highly smooth surface geometries were achieved for fractals above and below 7 {mu}m, respectively. Moreover, the behavior of foreign particles during the laser processing was investigated in detail. The polishing procedure was also monitored point by point by detecting electrical signals, i.e., sample charging, which resulted from the intense laser illumination. The measured electrical charges were found to be correlated with the local surface texture. Thus, regions with initially high roughness profiles and regions with extensive laser-induced defects could be directly identified from the detected electrical signals.
研究了脉冲激光抛光对铌表面粗糙度的影响。我们用标准金刚砂纸创建了不同的明确定义的粗糙度轮廓,随后用纳秒激光脉冲(波长1064 nm,脉冲长度10 ns)重熔了大小约为2x2 mm^2的随机表面区域。利用光学轮廓术和原子力显微镜对原始表面和激光处理表面进行了研究,并用相关函数描述了表面形貌。在7 {mu}m以上和7 {mu}m以下的分形分别获得了均匀粗糙和高度光滑的表面几何形状。此外,还详细研究了激光加工过程中外来粒子的行为。抛光过程还通过检测由强激光照射产生的电信号,即样品充电,逐点监测。测量的电荷被发现与局部表面织构相关。因此,最初具有高粗糙度轮廓的区域和具有广泛激光诱导缺陷的区域可以直接从检测到的电信号中识别出来。
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引用次数: 0
A hybrid optoelectronic Mott insulator 一种混合光电莫特绝缘体
Pub Date : 2020-09-28 DOI: 10.1063/5.0044066
Henry Navarro, J. D. Valle, Y. Kalcheim, N. Vargas, C. Adda, Min-Han Lee, P. Lapa, A. Rivera‐Calzada, I. Zaluzhnyy, Erbin Qiu, O. Shpyrko, M. Rozenberg, A. Frano, I. Schuller
The coupling of electronic degrees of freedom in materials to create hybridized functionalities is a holy grail of modern condensed matter physics that may produce novel mechanisms of control. Correlated electron systems often exhibit coupled degrees of freedom with a high degree of tunability which sometimes lead to hybridized functionalities based on external stimuli. However, the mechanisms of tunability and the sensitivity to external stimuli are determined by intrinsic material properties which are not always controllable. A Mott metal-insulator transition, which is technologically attractive due to the large changes in resistance, can be tuned by doping, strain, electric fields, and orbital occupancy but cannot be, in and of itself, controlled externally with light. Here we present a new approach to produce hybridized functionalities using a properly engineered photoconductor/strongly-correlated hybrid heterostructure, showing control of the Metal-to-Insulator transition (MIT) using optical means. This approach combines a photoconductor, which does not exhibit an MIT, with a strongly correlated oxide, which is not photoconducting. Due to the close proximity between the two materials, the heterostructure exhibits large volatile and nonvolatile, photoinduced resistivity changes and substantial photoinduced shifts in the MIT transition temperatures. This approach can potentially be extended to other judiciously chosen combinations of strongly correlated materials with systems which exhibit optically, electrically or magnetically controllable behavior.
材料中电子自由度的耦合以创造杂化功能是现代凝聚态物理学的圣杯,它可能产生新的控制机制。相关电子系统通常表现出具有高度可调性的耦合自由度,这有时会导致基于外部刺激的杂化功能。然而,可调性的机制和对外部刺激的敏感性是由材料的固有特性决定的,而这些特性并不总是可控的。Mott金属-绝缘体转变,由于电阻的巨大变化,在技术上很有吸引力,可以通过掺杂、应变、电场和轨道占用来调节,但本身不能用光来控制外部。在这里,我们提出了一种使用适当设计的光导体/强相关杂化异质结构产生杂化功能的新方法,显示了使用光学手段控制金属到绝缘体的转变(MIT)。这种方法结合了不表现出MIT的光导体和不具有光导电性的强相关氧化物。由于两种材料之间的距离很近,异质结构表现出较大的挥发性和非挥发性,光致电阻率变化和大量的MIT转变温度的光致位移。这种方法可以潜在地扩展到其他明智地选择强相关材料与表现出光学、电或磁可控行为的系统的组合。
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引用次数: 8
Deployable Tensegrity Lunar Tower 可展开的张拉整体月球塔
Pub Date : 2020-09-27 DOI: 10.1061/9780784483374.100
Muhao Chen, R. Goyal, M. Majji, R. Skelton
A tensegrity tower design to support a given payload for the moon mining operation is proposed in this paper. A non-linear optimization problem for the minimal-mass structure design is posed and solved, subject to the yielding constraints for strings and yielding and buckling constraints for bars in the presence of lunar gravity. The optimization variables for this non-linear problem are structural complexity and pre-stress in the strings. Apart from local failure constraints of yielding and buckling, global buckling is also considered. The structure designed as a deployable tower is a TnD1 tensegrity structure. A case study demonstrates the feasibility and advantage of the tower design. The principles developed in this paper are also applicable for building other structures on the Earth or other planets.
提出了一种支持月球采矿作业给定载荷的张拉整体塔设计。提出并求解了在月球重力作用下,受弦屈服约束和杆屈服屈曲约束的最小质量结构非线性优化问题。该非线性问题的优化变量为结构复杂度和预应力。除了屈服和屈曲的局部破坏约束外,还考虑了整体屈曲的破坏约束。结构设计为可展开塔,为TnD1张拉整体结构。实例分析证明了该塔设计的可行性和优越性。本文提出的原则也适用于在地球或其他行星上建造其他结构。
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引用次数: 10
Outgassing rate comparison of seven geometrically similar vacuum chambers of different materials and heat treatments 不同材料和热处理的七个几何形状相似的真空室的放气率比较
Pub Date : 2020-09-22 DOI: 10.1116/6.0000657
J. Fedchak, J. Scherschligt, S. Avdiaj, D. Barker, S. Eckel, B. Bowers, Scott OConnell, Perry A. Henderson
We have measured the water and hydrogen outgassing rates of seven vacuum chambers of identical geometry but constructed of different materials and heat treatments. Chambers of five different materials were tested: 304L, 316L, and 316LN stainless steels; titanium; and aluminum. In addition, chambers constructed of 316L and 316LN stainless steel were subjected to a vacuum-fire process, where they were heated to approximately 950 °C for 24 hours while under vacuum. These latter two chambers are designated as 316L-XHV and 316LN-XHV. Because all the chambers were of identical geometry and made by the same manufacturer, a relative comparison of the outgassing rates among these chambers can be made. Water outgassing rates were measured as a function of time using the throughput technique. The water outgassing results for the 316L, 316LN, 316L-XHV, 316LN-XHV were all similar, but lower than those of 304L by a factor of 3 to 5 lower at 10,000 s. The water outgassing results for Ti and Al chambers were closer to that of 304L, Ti being slightly lower. Hydrogen outgassing rates were measured using the rate-of-rise method and performed after a low-temperature bake of 125 °C to 150 °C for a minimum of 72 hours. The Ti, Al, 316L-XHV, and 316LN-XHV chambers all have ultra-low specific outgassing rates below 1.0E-11 Pa L s-1 cm-2 and are a factor of 100 or better than the 304L chamber. The 304L, 316L, and 316LN chambers with no vacuum-fire heat treatment have larger hydrogen outgassing rates than the other chambers, with determined specific outgassing rates ranging between 4.0E-11 Pa L s-1 cm-2 and 8.0E-11 Pa L s-1 cm-2. We conclude that Ti, Al, 316L-XHV, and 316LN-XHV have hydrogen outgassing rates that make them excellent choices for ultra-high vacuum (UHV) and extreme-high vacuum (XHV) applications, the choice depending on cost and other material properties.
我们测量了七个几何形状相同但材料和热处理方式不同的真空室的水和氢放气率。测试了五种不同材料的腔室:304L, 316L和316LN不锈钢;钛;和铝。此外,由316L和316LN不锈钢制成的腔室经受真空火处理,在真空下加热到大约950°C 24小时。后两个室被指定为316L-XHV和316LN-XHV。由于所有的腔室都是相同的几何形状,由同一制造商制造,因此可以对这些腔室的放气速率进行相对比较。利用通量技术测量出水率作为时间的函数。316L、316LN、316L- xhv、316LN- xhv的脱气结果相似,但在10000 s时比304L的脱气结果低3 ~ 5倍。Ti和Al气室的放水结果与304L气室的放水结果接近,Ti气室的放水结果略低。在125°C至150°C的低温烘烤至少72小时后,使用上升速率法测量氢气放气率。Ti、Al、316L-XHV和316LN-XHV气室都具有低于1.0E-11 Pa L s-1 cm-2的超低比放气率,比304L气室低100倍或更好。没有真空火热处理的304L、316L和316LN燃烧室比其他燃烧室有更大的氢气放气速率,确定的比放气速率在4.0E-11 Pa L s-1 cm-2和8.0E-11 Pa L s-1 cm-2之间。我们得出的结论是,Ti, Al, 316L-XHV和316LN-XHV具有氢气放气率,使其成为超高真空(UHV)和极高真空(XHV)应用的绝佳选择,选择取决于成本和其他材料性能。
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引用次数: 7
Magnon-mediated spin currents in Tm3Fe5O12/Pt with perpendicular magnetic anisotropy 垂直磁各向异性Tm3Fe5O12/Pt中磁介子介导的自旋电流
Pub Date : 2020-09-22 DOI: 10.1063/5.0023242
G. Vilela, J. E. Abrão, E. Santos, Y. Yao, J. Mendes, R. L. Rodríguez-Suárez, S. Rezende, W. Han, A. Azevedo, J. Moodera
The control of pure spin currents carried by magnons in magnetic insulator (MI) garnet films with a robust perpendicular magnetic anisotropy (PMA) is of great interest to spintronic technology as they can be used to carry, transport and process information. Garnet films with PMA present labyrinth domain magnetic structures that enrich the magnetization dynamics, and could be employed in more efficient wave-based logic and memory computing devices. In MI/NM bilayers, where NM being a normal metal providing a strong spin-orbit coupling, the PMA benefits the spin-orbit torque (SOT) driven magnetization's switching by lowering the needed current and rendering the process faster, crucial for developing magnetic random-access memories (SOT-MRAM). In this work, we investigated the magnetic anisotropies in thulium iron garnet (TIG) films with PMA via ferromagnetic resonance measurements, followed by the excitation and detection of magnon-mediated pure spin currents in TIG/Pt driven by microwaves and heat currents. TIG films presented a Gilbert damping constant {alpha}~0.01, with resonance fields above 3.5 kOe and half linewidths broader than 60 Oe, at 300 K and 9.5 GHz. The spin-to-charge current conversion through TIG/Pt was observed as a micro-voltage generated at the edges of the Pt film. The obtained spin Seebeck coefficient was 0.54 {mu}V/K, confirming also the high interfacial spin transparency.
具有垂直磁各向异性(PMA)的磁绝缘体(MI)石榴石薄膜中磁振子携带的纯自旋电流的控制是自旋电子技术的重要研究方向,因为它们可用于携带、传输和处理信息。具有PMA的石榴石薄膜具有丰富磁化动力学的迷宫畴磁性结构,可用于更高效的基于波的逻辑和存储计算器件。在MI/NM双层中,纳米是一种提供强自旋-轨道耦合的普通金属,PMA通过降低所需电流和使过程更快,有利于自旋-轨道扭矩(SOT)驱动的磁化开关,这对于开发磁性随机存取存储器(SOT- mram)至关重要。在这项工作中,我们通过铁磁共振测量研究了PMA在铥铁石榴石(TIG)薄膜中的磁各向异性,然后在微波和热流驱动下激发和检测了TIG/Pt中磁非介导的纯自旋电流。TIG薄膜在300 K和9.5 GHz下的吉尔伯特阻尼常数{alpha} 0.01,共振场大于3.5 kOe,半线宽大于60 Oe。通过TIG/Pt观察到自旋到电荷的电流转换,在Pt膜边缘产生微电压。得到的自旋塞贝克系数为0.54 {mu} V/K,也证实了较高的界面自旋透明度。
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引用次数: 8
Cryogenic cleaning of tin-drop contamination on surfaces relevant for extreme ultraviolet light collection 低温清洗与极紫外光收集有关的表面锡滴污染
Pub Date : 2020-09-22 DOI: 10.1116/6.0000501
N. Böwering, C. Meier
Improvement of tool reliability and uptime is a current focus in development of extreme ultraviolet lithography. The lifetime of collection mirrors for extreme ultraviolet light in tin-based plasma light sources is limited considerably by contamination with thick tin deposits that cannot be removed sufficiently fast by plasma etching. For tin droplet splats sticking to large substrates, we have developed and compared several efficient cleaning techniques based on cryogenic cooling. A silicon carbide substrate and different silicon wafer samples with up to 6 inch diameter with the surface uncoated, multilayer-coated, unstructured and grating-structured were tested. After tin dripping onto heated samples, embrittlement of droplet contamination is induced in-situ by stresses during phase transformation, following the initiation of tin pest with seed crystals of gray tin. Conversion of initially adhesive deposits to loose gray tin has been reached in less than 24 hours on all tested surfaces by continuous cooling with cold nitrogen vapor to temperatures in the range of -30 to -50 °C. Alternatively, stress-initiated tin-removal by delamination of beta-Sn droplet splats has been attained via contraction strain induced by strong cooling to temperatures of around -120 °C. Profilometry has been used to analyze the bottom side of tin droplet splats removed from a grating-structured wafer. The in-situ tin cleaning techniques give results comparable to fast ex-situ cleaning that has been achieved either by sample immersion in liquid nitrogen or by splat removal after CO2 snowflake aerosol impact using a hand-held jet-nozzle. The implementation of the in-situ phase-conversion concept for the cleaning of collector mirrors in commercial light sources for lithography is discussed.
提高工具的可靠性和正常运行时间是目前极紫外光刻技术发展的重点。在锡基等离子体光源中,极紫外光收集镜的寿命很大程度上受到厚锡沉积物污染的限制,而厚锡沉积物不能通过等离子体蚀刻足够快地去除。对于粘附在大型衬底上的锡滴片,我们已经开发并比较了几种基于低温冷却的高效清洁技术。测试了碳化硅衬底和直径不超过6英寸、表面未涂覆、多层涂覆、非结构化和光栅结构的硅片样品。锡滴入加热试样后,在相变过程中应力的原位作用下,锡害虫由灰锡种子晶体引发,从而导致锡污染的脆化。在所有测试表面上,通过用冷氮蒸汽连续冷却至-30至-50°C的温度范围,在不到24小时内将最初的粘合剂沉积转化为松散的灰色锡。另一种方法是,通过强烈冷却至-120℃左右的温度引起的收缩应变,通过β - sn液滴薄片分层来实现应力引发的锡去除。用轮廓法分析了从光栅结构晶圆片中取出的锡滴片的底部。原位锡清洗技术提供的结果可与通过将样品浸入液氮或使用手持喷射喷嘴去除CO2雪花气溶胶撞击后的飞溅物来实现的快速非原位清洗相媲美。讨论了用于光刻商业光源集电极镜清洗的原位相变概念的实现。
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引用次数: 2
期刊
arXiv: Applied Physics
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