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Calculating the temperature and degree of cross-linking for liquid silicone rubber processing in injection molding 液态硅橡胶注射成型过程中交联温度和交联度的计算
Pub Date : 2020-11-02 DOI: 10.1002/amp2.10072
Dennis F. Weißer, Daniel Walz, Johannes Schmid, Dennis Mayer, Matthias H. Deckert

Processing of liquid silicone rubber (LSR) in the injection molding process has a high economic potential. Since there are some fundamental differences compared to classical thermoplastic injection molding, up to now there is a lack of well-founded knowledge of the process which allows an estimation of the cycle time. Because, in addition to reverse temperature control, LSR processing also involves an irreversible temperature- and time-dependent chemical reaction. In this paper, the complex cross-linking reaction is first modelled phenomenologically using dynamic differential scanning calorimetry (DSC) measurements and the well-fitting Kamal-Sourour model. Afterwards, a temperature and cross-linking simulation is set up, which reliably simulates the time- and travel-dependent temperature profile and degree of cross-linking in the mold. Therefore, the released exothermic cross-linking heat is also taken into account. The simulated temperature values are verified with measurements in the cavity during the injection molding process. The measured values correspond very well with the simulated values at different mold temperatures. It is shown that the influence of the cross-linking heat on the overall temperature profile in the LSR component during the injection molding process is relatively low. Nevertheless, the model is necessary to determine the degree of cross-linking - it can be used to calculate the cycle time at which the component of a certain cross-section can be ejected at a known tool temperature and is fully cross-linked. With this knowledge, existing processes can be optimized in terms of mold temperature and curing time, but also new components can be calculated economically.

液态硅橡胶(LSR)在注射成型工艺中的加工具有很高的经济潜力。由于与经典的热塑性注塑成型相比有一些根本的区别,到目前为止,还缺乏对该工艺有充分根据的知识,因此可以估计周期时间。因为,除了反向温度控制外,LSR处理还涉及不可逆的温度和时间依赖的化学反应。本文首先利用动态差示扫描量热法(DSC)测量和拟合良好的Kamal-Sourour模型对复杂交联反应进行了现象学模拟。然后,建立了温度和交联仿真,可靠地模拟了模具中随时间和行程变化的温度分布和交联程度。因此,还考虑了释放的放热交联热。模拟的温度值与注射成型过程中型腔内的测量结果进行了验证。在不同的模具温度下,实测值与模拟值吻合良好。结果表明,交联热对注射成型过程中LSR部件整体温度分布的影响相对较小。然而,该模型对于确定交联的程度是必要的——它可以用来计算在已知的工具温度下,某一截面的组件可以弹出并完全交联的周期时间。有了这些知识,现有的流程可以在以下方面进行优化
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引用次数: 3
Design of ethylene oxide production process based on adaptive design of experiments and Bayesian optimization 基于实验自适应设计和贝叶斯优化的环氧乙烷生产工艺设计
Pub Date : 2020-09-24 DOI: 10.22541/au.160091365.52756748
Ryo Iwama, H. Kaneko
In process design, the values of design variables X for equipment and operating conditions should be optimized for entire processes, including all unit operations, such as reactors and distillation columns, to consider effects between unit operations. However, as the number of X increases, many more simulations are required to search for the optimal X values. Furthermore, multiple objective variables Y, such as yields, make the optimization problem difficult. We propose a process design method based on adaptive design of experiments and Bayesian optimization. Optimization of X values that satisfy target values of multiple Y variables are searched, and simulations for the optimized X values are then repeated. Therefore, X will be optimized by a small number of simulations. We verify the effectiveness of this method by simulating an ethylene oxide production plant.
在工艺设计中,应针对整个工艺,包括反应器、精馏塔等所有单元操作,优化设备和操作条件的设计变量X的值,以考虑单元操作之间的影响。然而,随着X数量的增加,需要更多的模拟来搜索最优的X值。此外,多个目标变量Y,如产量,使优化问题变得困难。提出了一种基于实验自适应设计和贝叶斯优化的工艺设计方法。搜索满足多个Y变量目标值的X值优化,并对优化后的X值进行重复仿真。因此,X将通过少量模拟进行优化。通过对环氧乙烷生产装置的仿真,验证了该方法的有效性。
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引用次数: 17
Production and characterization of copper periodic open cellular structures made by 3D printing-replica technique 利用3D打印复制技术制备铜周期开孔结构及表征
Pub Date : 2020-08-23 DOI: 10.1002/amp2.10068
Riccardo Balzarotti, Alessandra Bisaccia, Maria Celeste Tripi, Matteo Ambrosetti, Gianpiero Groppi, Enrico Tronconi

Additive manufacturing by 3D printing comprises a set of methods for production of 3D objects starting from a CAD file. Advantages of additive manufacturing combine high manufacturing resolution, a reduction of waste material, and the possibility of computer-aided design (CAD). When applied to the manufacturing of structured catalyst substrates, the latter enables the optimization of transport properties of the catalyst support. Despite several methods have been introduced for a variety of materials, copper, well known for its high thermal conductivity, is still difficult to be handled. In this work, a novel approach for the additive manufacturing of copper periodic open cellular structures (POCS) is proposed and investigated. It consists in the use of the replica manufacturing procedure starting from resin supports produced by 3D printing stereolithography. Micrometric high purity copper powder was effectively dispersed using a liquid medium based on organic components; the resulting slurry was used for the washcoat deposition on the resin supports. Structures with diamond unit cell shape (cell size of 2.5 mm and void fractions in the 0.8-0.9 range) were washcoated by dip-spin coating. Homogeneous washcoat layers were obtained without occurrence of cell clogging phenomena. Optimized thermal treatment procedure was assessed for sintering the copper POCS. The resulting matrices preserved the morphology of the original structure, reaching a resolution in the range of 70 to 120 μm. These materials can eventually be used as catalyst supports for heat-transfer limited applications (eg, steam reforming of methane), where copper-based substrates were demonstrated to be an effective solution for process intensification.

3D打印的增材制造包括一套从CAD文件开始生产3D对象的方法。增材制造的优势结合了高制造分辨率、减少废料和计算机辅助设计(CAD)的可能性。当应用于制造结构催化剂基板时,后者能够优化催化剂载体的传输特性。尽管对各种材料已经引入了几种方法,但以其高导热性而闻名的铜仍然难以处理。本文提出并研究了一种新型的铜周期开孔结构(POCS)的增材制造方法。它包括使用从3D打印立体光刻生产的树脂支架开始的复制品制造程序。采用以有机成分为基础的液体介质对微米级高纯铜粉进行了有效分散;所得浆液用于树脂支架上的水洗涂层沉积。采用浸渍自旋涂层对具有金刚石单元胞形状(胞尺寸为2.5 mm,孔隙分数在0.8 ~ 0.9之间)的结构进行水洗涂层。得到了均匀的洗衣层,没有发生细胞堵塞现象。对烧结铜POCS的最佳热处理工艺进行了评价。得到的基体保留了原始结构的形貌,分辨率在70 ~ 120 μm之间。这些材料最终可以用作热传递有限应用的催化剂支撑(例如,甲烷的蒸汽重整),其中铜基衬底被证明是过程强化的有效解决方案。
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引用次数: 6
Online composition analysis of phase separation solvent for carbon dioxide capture using ATR-FT-IR ATR-FT-IR在线分析二氧化碳捕集相分离溶剂的组成
Pub Date : 2020-07-13 DOI: 10.1002/amp2.10067
Miho Sato, Khuyen Viet Bao Tran, Tsuyoshi Yamaguchi, Hiroshi Machida, Koyo Norinaga

An amine solvent that undergoes phase change after absorption of CO2 has been studied to reduce the energy consumed during the CO2 capture process. Depending on the components of the solvent, the CO2-rich phase can be separated for the regeneration step or the component in CO2-lean phase accelerates the regeneration step in the solvent that undergoes liquid-liquid phase change. Since the homogeneous solvent separates into two liquid phases after CO2 absorption, an analysis method to track the change in chemical species during the absorption process, especially at the phase separation time, is necessary to illuminate the phenomenon. To establish an online method to analyze the components of the solvent, a Fourier-transform infrared (FT-IR) spectrometer equipped with an attenuated total reflection (ATR) probe was used during the CO2 absorption of phase separation solvent composed of amine, ether, and water. The calibration samples of amines, ethers, and CO2-loaded solutions were used to develop the partial least square regression model. The consumption of reactants, as well as the formation of products, can be monitored quantitatively using the FT-IR spectra. Utilizing this information, the changes in the chemical species shed light on the phase separation mechanism of this solvent: ether was pushed out of the solvent to form a CO2-lean phase due to its hydrophobicity, while CO2 and its products along with amine and water remain in the CO2-rich phase. Without sampling, this rapid and high-accuracy method is suitable for closed processes, especially for a high-pressure process.

已经研究了在吸收CO2后经历相变的胺溶剂,以减少CO2捕获过程中消耗的能量。根据溶剂的组分,富CO2相可以被分离用于再生步骤,或者贫CO2相中的组分在经历液-液相变的溶剂中加速再生步骤。由于均匀溶剂在吸收CO2后分离成两个液相,因此有必要采用分析方法来跟踪吸收过程中,特别是在相分离时化学物质的变化,以阐明这一现象。为了建立一种在线分析溶剂成分的方法,在由胺、醚和水组成的相分离溶剂吸收CO2的过程中,使用配备衰减全反射(ATR)探针的傅立叶变换红外(FT-IR)光谱仪。胺、醚和CO2负载溶液的校准样品用于开发偏最小二乘回归模型。反应物的消耗以及产物的形成可以使用FT-IR光谱进行定量监测。利用这些信息,化学物质的变化揭示了这种溶剂的相分离机制:醚由于其疏水性而被挤出溶剂,形成贫CO2相,而CO2及其产物与胺和水一起保持在富CO2相中。无需采样,这种快速、高精度的方法适用于封闭过程,尤其是高压过程。
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引用次数: 1
Comparing reusable to disposable products: Life cycle analysis metrics 可重复使用产品与一次性产品的比较:生命周期分析指标
Pub Date : 2020-07-05 DOI: 10.1002/amp2.10065
Fadhel Alshqaqeeq, Evan Griffing, Janet Twomey, Michael Overcash

This research is to produce the first quantitative evaluation, using global warming potential (GWP, kg CO2 eq), of all published cradle-to-gate life cycle studies that compare reusable vs single-use products. We seek to determine whether there are consistent and fundamental factors that differentiate disposable and reusable products. A comparative assessment was made of the cradle-to-gate life cycle analyses of all published comparisons of reusable and single-use products from 1990 to 2016. A literature search found only 20 products in which a full life cycle analysis of cradle-to-gate (supply chain, manufacturing, reprocessing, and packaging of the reusable item) and supply chain plus manufacturing for the disposable had been published. GWP or carbon footprint was used as the environment comparison metric to which we added energy for the product manufacturing metrics. In this diverse set of products, the reusable product was consistently lower in cradle-to-gate energy use and global warming potential than the comparable single-use product. However, no apparent product characteristic appeared to govern the extent by which the reusable had a lower carbon footprint. These compelling results were compared with two other references in which disposable products were reported as better. However, when the data were reviewed with those authors, they reevaluated and found errors in calculations and corrected the results to then identify the lower reusable GWP impact compared to the respective disposable. The diversity of products studied and the consistently lower GWP impact of reusable products herein may suggest that products with reusable/disposable options could be predicted to show that the reusable is better than the single-use option.

这项研究将利用全球变暖潜能值(GWP,kg CO2当量),对所有已发表的从摇篮到门的生命周期研究进行首次定量评估,这些研究比较了可重复使用的产品和一次性产品。我们试图确定是否存在区分一次性产品和可重复使用产品的一致性和基本因素。对1990年至2016年所有已发表的可重复使用和一次性产品的比较进行了从摇篮到门的生命周期分析的比较评估。文献检索发现,只有20种产品发表了从摇篮到门(可重复使用物品的供应链、制造、再加工和包装)以及一次性用品的供应链加制造的全生命周期分析。GWP或碳足迹被用作环境比较指标,我们为产品制造指标添加了能源。在这套多样化的产品中,可重复使用的产品在从摇篮到大门的能源使用和全球变暖潜力方面一直低于可比的一次性产品。然而,似乎没有明显的产品特征来控制可重复使用的碳足迹降低的程度。这些令人信服的结果与另外两篇报道一次性产品更好的参考文献进行了比较。然而,当与这些作者一起审查数据时,他们重新评估并发现了计算中的错误,并更正了结果,以确定与各自的一次性相比,可重复使用的全球升温潜能值影响较低。本文研究的产品多样性和可重复使用产品的全球变暖潜能值影响持续较低,这可能表明,可以预测具有可重复使用/一次性选项的产品,表明可重复使用的产品比一次性选项更好。
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引用次数: 1
Rapid development and deployment of high-volume vaccines for pandemic response 为大流行应对快速开发和部署大容量疫苗
Pub Date : 2020-06-29 DOI: 10.1002/amp2.10060
Zoltán Kis, Cleo Kontoravdi, Antu K. Dey, Robin Shattock, Nilay Shah

Overcoming pandemics, such as the current Covid-19 outbreak, requires the manufacture of several billion doses of vaccines within months. This is an extremely challenging task given the constraints in small-scale manufacturing for clinical trials, clinical testing timelines involving multiple phases and large-scale drug substance and drug product manufacturing. To tackle these challenges, regulatory processes are fast-tracked, and rapid-response manufacturing platform technologies are used. Here, we evaluate the current progress, challenges ahead and potential solutions for providing vaccines for pandemic response at an unprecedented scale and rate. Emerging rapid-response vaccine platform technologies, especially RNA platforms, offer a high productivity estimated at over 1 billion doses per year with a small manufacturing footprint and low capital cost facilities. The self-amplifying RNA (saRNA) drug product cost is estimated at below 1 USD/dose. These manufacturing processes and facilities can be decentralized to facilitate production, distribution, but also raw material supply. The RNA platform technology can be complemented by an a priori Quality by Design analysis aided by computational modeling in order to assure product quality and further speed up the regulatory approval processes when these platforms are used for epidemic or pandemic response in the future.

克服大流行,如当前的Covid-19疫情,需要在几个月内生产数十亿剂疫苗。考虑到临床试验的小规模生产、涉及多个阶段的临床试验时间表以及大规模原料药和药品生产的限制,这是一项极具挑战性的任务。为了应对这些挑战,监管流程得到了快速跟踪,并使用了快速响应制造平台技术。在此,我们评估当前的进展、未来的挑战以及以前所未有的规模和速度为大流行应对提供疫苗的潜在解决方案。新兴的快速反应疫苗平台技术,特别是RNA平台,提供了估计每年超过10亿剂的高生产力,生产面积小,资本成本低。自扩增RNA (saRNA)药品成本估计在1美元/剂以下。这些制造过程和设施可以分散,以方便生产,分销,以及原材料供应。RNA平台技术可辅以辅以计算建模的先验设计质量分析,以确保产品质量,并在将来将这些平台用于流行病或大流行病应对时进一步加快监管审批程序。
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引用次数: 42
Enhancing operational performance and productivity benefits in breweries through smart manufacturing technologies 通过智能制造技术提高啤酒厂的运营绩效和生产力效益
Pub Date : 2020-06-20 DOI: 10.1002/amp2.10064
Sachin Nimbalkar, Sarang D. Supekar, Will Meadows, Thomas Wenning, Wei Guo, Joseph Cresko

This article uses case studies to demonstrate the potential of smart manufacturing (SM) and Internet of Things (IoT) technologies to enhance operational performance and productivity in industry. The analysis highlights benefits such as cost reduction, production flexibility, shorter product time-to-market, energy/water efficiency and environmental impact reduction, and increased productivity. To illustrate the effectiveness of SM and IoT approaches, the authors sought out manufacturers currently implementing or seeking to implement SM and IoT technologies. The authors identified beer brewing (NAICS Code 312120) as a rapidly expanding industry whose members appear eager to implement SM technologies to optimize production lines by revealing bottlenecks and identifying performance-reducing nodes. This article presents two case studies based on SM and IoT technologies in breweries. It briefly describes a systematic framework introduced elsewhere by the authors and uses it to assess the energy productivity and competitiveness of SM applications in breweries. This article addresses questions concerning the information and communications technology infrastructure needed to build smart breweries and how corporations simplify the installation and deployment of SM and IoT components. This article was originally published in the Proceedings of the 2019 ACEEE Summer Study on Energy Efficiency in Industry.

本文通过案例研究来展示智能制造(SM)和物联网(IoT)技术在提高行业运营绩效和生产力方面的潜力。该分析强调了降低成本、生产灵活性、缩短产品上市时间、降低能源/水效率和环境影响以及提高生产力等好处。为了说明SM和物联网方法的有效性,作者寻找了目前正在实施或寻求实施SM和物联技术的制造商。作者将啤酒酿造(NAICS Code 312120)确定为一个快速扩张的行业,其成员似乎急于实施SM技术,通过揭示瓶颈和确定性能降低节点来优化生产线。本文介绍了啤酒厂基于SM和物联网技术的两个案例研究。它简要描述了作者在其他地方介绍的一个系统框架,并用它来评估SM在啤酒厂应用的能源生产率和竞争力。本文解决了有关建立智能啤酒厂所需的信息和通信技术基础设施的问题,以及企业如何简化SM和物联网组件的安装和部署。这篇文章最初发表在《2019年ACEEE夏季工业能效研究论文集》上。
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引用次数: 5
A systematic approach to define flexibility in chemical engineering 定义化工柔性的系统方法
Pub Date : 2020-06-20 DOI: 10.1002/amp2.10063
Bastian Bruns, Felix Herrmann, Maria Polyakova, Marcus Grünewald, Julia Riese

Increasing economic and environmental challenges leads to the need for changes in the chemical industry. In this context, a promising approach is utilizing flexible apparatuses and flexible plants to react to changing boundary conditions. However, the concept of flexibility in chemical engineering, which originated in manufacturing, still lacks a comprehensive organization and categorization of different types of flexibility. Thus, in this work, the origin of flexibility in manufacturing is traced, and a literature overview on flexibility in chemical engineering is provided. Based on a subsequent cluster analysis, four types of flexibility are identified and defined. Furthermore, this work enables research on flexibility to be integrated into a general and consistent definition of flexibility. The definitions are applied to examples from literature to achieve comparability. While enabling the qualitative assessment of flexibility, this work identifies open research gaps regarding the quantification of flexibility.

日益增长的经济和环境挑战导致化学工业需要变革。在这种情况下,一种很有前途的方法是利用柔性设备和柔性植物对不断变化的边界条件做出反应。然而,起源于制造业的化工柔性概念,仍然缺乏对不同类型柔性的全面组织和分类。因此,在这项工作中,追溯了制造业柔性的起源,并提供了化学工程柔性的文献综述。基于随后的聚类分析,确定并定义了四种类型的灵活性。此外,这项工作使对灵活性的研究能够整合到灵活性的通用和一致的定义中。将这些定义应用于文献中的例子,以实现可比性。在能够对灵活性进行定性评估的同时,这项工作确定了在灵活性量化方面存在的研究空白。
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引用次数: 19
Advanced manufacturing and processing in the time of COVID-19 新型冠状病毒肺炎时代的先进制造加工
Pub Date : 2020-06-14 DOI: 10.1002/amp2.10061
Matthew Realff, Jan Lerou, Michael Rinker

The COVID-19 pandemic has exposed fragilities and reinforced the resiliency of different elements of our manufacturing and processing systems. Food processing, in particular meat packing, currently a very labor-intensive operation, experienced significant disruption and the car industry implemented shutdowns which will ripple through supply chains in the coming months. It became clear that packaging supply chains are bottlenecks as producers tried to divert food stuffs from restaurants to consumer stores, and shifts in demand for paper products caused persistent consumer outages. The basic chemicals and fuels industry did not see significant disruption, but wild price fluctuations did occur as reduced demands and an unfortunately timed production increase caused available storage capacity to be strained. Recycling industries saw, and will continue to experience, both ends of the disruption as their consuming industries reduced demand and their providers stockpiled material or diverted it to trash. The beverage industry has significant inventory in public venues that has expired. Boutique level hand sanitizer production has resulted as these beverage production systems have been reconfigured and the rules surrounding the grade of alcohol relaxed.[1]

We are sure there are many of you who have worked long hours to innovate your manufacturing and processing systems to cope with the challenges of COVID-19 and we would welcome articles and commentaries on how advanced manufacturing can play a role in our collective response. In this issue of JAMP we share a commentary on the rapid manufacturing of vaccines as our contribution to understanding how our community might respond to COVID-19,[2] and we would like to encourage you to consider other ways in which our manufacturing systems will change in response to the pandemic. However, much as there is a need to address the short-term disruptions caused by a pandemic, and to understand how research can respond to create advanced manufacturing and processing systems with flexibility and resilience in the future, we also need to continue to push forward with efforts that provide new foundations for those features and we have curated articles that we hope fulfill that goal.

Process intensification remains a key approach to advanced manufacturing enabling more nimble and responsive systems. This issue provides two examples tackling a variety of processes: the epoxidation of vegetable oils and the manufacturing of butyl acrylate.

Rahim et al.[3] show that by using a mesoscale oscillating baffled reactor the process can be converted from a batch operation to a continuous one and in the process they estimate that the new reactor is approximately 144 times smaller than the batch reactor operating at the same production rate.

The Simulated Moving Bed Reac

2019冠状病毒病大流行暴露了我们制造和加工系统中不同要素的脆弱性,并增强了它们的弹性。食品加工,特别是肉类包装,目前是一个非常劳动密集型的操作,经历了严重的中断,汽车行业实施停工,这将在未来几个月波及供应链。很明显,包装供应链是瓶颈,因为生产商试图将食品从餐馆转移到消费者商店,而纸制品需求的变化导致消费者持续停电。基本化学品和燃料行业没有出现重大中断,但由于需求减少和不幸的时间生产增加导致可用存储能力紧张,价格确实出现了剧烈波动。回收行业看到了,并将继续经历破坏的两端,因为他们的消费行业减少了需求,他们的供应商囤积材料或将其转移到垃圾中。饮料行业在公共场所有大量已经过期的库存。随着这些饮料生产系统的重新配置和围绕酒精等级的规则的放松,精品级洗手液的生产已经产生。我们相信,你们中有许多人长时间工作,创新制造和加工系统,以应对2019冠状病毒病的挑战,我们欢迎有关先进制造业如何在我们的集体应对中发挥作用的文章和评论。在本期《JAMP》中,我们分享了一篇关于快速生产疫苗的评论,作为我们对了解我们的社区如何应对COVID-19的贡献,我们希望鼓励您考虑我们的生产系统将以其他方式改变以应对大流行。然而,正如有必要解决大流行造成的短期中断,并了解研究如何应对未来具有灵活性和弹性的先进制造和加工系统一样,我们也需要继续努力为这些功能提供新的基础,我们已经策划了一些文章,希望能够实现这一目标。过程强化仍然是实现更灵活和响应更快的系统的先进制造的关键方法。本期提供了两个解决各种工艺的例子:植物油的环氧化和丙烯酸丁酯的制造。Rahim等人表明,通过使用中尺度振荡折流板反应器,该过程可以从间歇操作转换为连续操作,并且在该过程中,他们估计新反应器比在相同生产速率下运行的间歇反应器大约小144倍。模拟移动床反应器(SMBR)技术几十年来一直是过程强化的一个例子。Constantino等人将该技术与膜渗透蒸发相结合,创造了一个模拟移动床膜反应器,减少了生产丙烯酸丁酯的操作段数量,同时减少了洗脱液的消耗,提高了生产率。本文对所有工艺指标进行了完整的分析。人工智能(AI)在化学过程工业中的应用正在以新的方式进行,这对该行业应该考虑采用和部署工业4.0的方式提出了挑战,而工业4.0在其他业务领域已经无处不在。Colegrove[5]讨论了保护数据作为关键智力资本的重要性,以及人工智能供应商社区中有多少人不了解数据对流程工业的价值。该评论提供了对化学工程师和数据科学家密切合作的需求的见解,以解决技术和操作问题,这些问题需要分析比过程数据更广泛的数据,以及基本模型失效的地方。鉴于2019冠状病毒病的社会和经济影响,本评论对增强韧性更加重要。
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引用次数: 0
A high-efficiency novel IGCC-OTM carbon capture power plant design 一种高效新型IGCC-OTM碳捕获发电厂设计
Pub Date : 2020-06-09 DOI: 10.1002/amp2.10059
Xiao-Yu Wu, Lili Cai, Xuefeng Zhu, Ahmed F. Ghoniem, Weishen Yang

Coal power plants play an important role in supplying affordable and reliable electricity. It is necessary to develop high-efficiency and low-cost carbon capture (CC) technologies to mitigate the associated global warming. Using H2S-tolerant oxygen transport membranes (OTMs) for hydrogen production and CO2 separation can significantly reduce the energy penalty of CC in integrated gasification combined cycle (IGCC) power plants. We carried out system-level analysis to investigate a novel IGCC-CC power plant design using OTMs. We studied the impacts of various operating parameters on the overall efficiency and energy penalty. This novel IGCC-OTM system has an overall efficiency 3.2%-point lower than the same system without CC, much lower than the IGCC with water-gas shift reactors and acid gas removal units (IGCC-WGS) of 6.8%-point drop. The specific primary energy consumption for CO2 avoided (SPECCA) of this novel technology is 1.08 MJ kgCO2−1, which is 59.4% lower than that of the IGCC-WGS.

煤电厂在提供负担得起和可靠的电力方面发挥着重要作用。有必要开发高效、低成本的碳捕获技术来缓解相关的全球变暖。在整体煤气化联合循环(IGCC)发电厂中,使用耐H2S的氧气输送膜(OTM)进行氢气生产和CO2分离可以显著降低CC的能量损失。我们进行了系统级分析,以研究一种使用OTM的新型IGCC-C发电厂设计。我们研究了各种操作参数对整体效率和能量损失的影响。这种新型IGCC-OTM系统的总效率比没有CC的相同系统低3.2%,比具有水煤气变换反应器和酸性气体去除装置(IGCC-WGS)的IGCC低6.8%。该新技术的CO2避免比一次能耗(SPECCA)为1.08 MJ kgCO2−1,比IGCC-WGS低59.4%。
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引用次数: 10
期刊
Journal of advanced manufacturing and processing
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