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Nuclear H2 production – a utility perspective 核能制氢——从实用角度看
Pub Date : 2010-01-01 DOI: 10.1787/9789264087156-34-EN
D. Keuter
Entergy is the second largest nuclear owner/operator in the United States with five nuclear units in the south operating under a cost of service structure and an additional six units in the Northeast and Midwest operating as merchant generating facilities. As a major nuclear operator in the merchant sector, Entergy wears the risk of nuclear operations – revenues are directly dependent upon operational performance. Our investment in merchant nuclear operations reflects our belief that use of nuclear energy in the competitive merchant environment can be an economically viable business venture.
Entergy是美国第二大核电所有者/运营商,在南部有5个核电机组,按服务成本结构运行,另外在东北部和中西部有6个机组作为商业发电设施运行。作为商业领域的主要核运营商,Entergy承担着核运营的风险——收入直接取决于运营绩效。我们对商业核运营的投资反映了我们的信念,即在竞争激烈的商业环境中使用核能可以成为一项经济上可行的商业投资。
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引用次数: 0
Status of the INERI sulphur-iodine integrated-loop experiment INERI硫碘集成环路实验现状
Pub Date : 2010-01-01 DOI: 10.1787/9789264087156-19-EN
B. Russ, R. Moore, M. Hélie
In an International Nuclear Energy Research Initiative (INERI) project supported by the US DOE Office of Nuclear Energy, Sandia National Labs (SNL) has teamed with the Commissariat a l'Energie Atomique (CEA) in France, and industrial partner General Atomics (GA) to construct and operate a closed-loop device for demonstration of hydrogen production by the S-I process. The Integrated Lab Scale (ILS) experiment is being conducted at General Atomics’ San Diego facility. This presentation will summarise project goals, work done to date, current status and scheduled future work on the INERI S-I integrated-loop experiment.
在美国能源部核能办公室支持的国际核能研究倡议(INERI)项目中,桑迪亚国家实验室(SNL)与法国原子能委员会(CEA)和工业合作伙伴通用原子公司(GA)合作,建造并运行一个闭环装置,用于S-I过程制氢的演示。综合实验室规模(ILS)实验正在通用原子公司的圣地亚哥工厂进行。本报告将总结项目目标,迄今为止所做的工作,目前的状态和计划的未来工作在INERI S-I集成环路实验。
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引用次数: 7
Status of the Korean nuclear hydrogen production project 韩国核电制氢事业现状
Pub Date : 2010-01-01 DOI: 10.1787/9789264087156-7-EN
Jonghwa Chang, W. Lee
The rapid climate changes and the heavy reliance on imported fuel in Korea have motivated interest in the hydrogen economy. The Korean government has set up a long-term vision for transition to the hydrogen economy. To meet the expected demand of hydrogen as a fuel, hydrogen production using nuclear energy was also discussed. Recently the Korean Atomic Energy Committee has approved nuclear hydrogen production development and demonstration which will lead to commercialisation in late 2030s. An extensive research and development programme for the production of hydrogen using nuclear power has been underway since 2004 in Korea. During the first three years, a technological area was identified for the economic and efficient production of hydrogen using a VHTR.
韩国迅速的气候变化和对进口燃料的严重依赖激发了人们对氢经济的兴趣。韩国政府制定了向氢经济过渡的长期愿景。为了满足对氢作为燃料的预期需求,还讨论了利用核能制氢。最近,韩国原子能委员会(Korean Atomic Energy Committee)批准了核氢生产的开发和示范,将在本世纪30年代末实现商业化。自2004年以来,韩国一直在进行利用核能生产氢气的广泛研究和开发计划。在头三年,确定了一个技术领域,以经济和有效地利用超低温热源生产氢气。
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引用次数: 4
Causes of degradation in a solid oxide electrolysis stack 固体氧化物电解堆中降解的原因
Pub Date : 2010-01-01 DOI: 10.1787/9789264087156-16-EN
J. Carter, Jennifer R. Mawdsley, A. J. Kropf
Steam electrolysis experiments conducted at Idaho National Laboratory (INL) have demonstrated an efficient process to generate hydrogen using waste heat and electricity from a nuclear power plant. However, the hydrogen output was observed to decrease significantly over time. Solid oxide stack components from the INL studies were analysed at Argonne National Laboratory to elucidate the degradation mechanisms of electrolysis. After probable regions of degradation were identified by surface techniques, Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS) were used to further characterise the causes of degradation by examining cross-sections of stack components.
在爱达荷国家实验室(INL)进行的蒸汽电解实验证明了利用核电站的废热和电力生产氢的有效过程。然而,观察到氢气输出随着时间的推移而显著减少。来自INL研究的固体氧化物堆组分在阿贡国家实验室进行了分析,以阐明电解的降解机制。在通过表面技术确定可能的降解区域后,使用扫描电子显微镜(SEM)和能量色散x射线光谱学(EDS)通过检查堆叠组件的横截面进一步表征降解的原因。
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引用次数: 0
Experimental study of the vapour-liquid equilibria of HI-I2-H2O ternary mixtures HI-I2-H2O三元混合物气液平衡的实验研究
Pub Date : 2010-01-01 DOI: 10.1787/9789264087156-21-EN
D. Doizi, B. Larousse, V. Dauvois, J. Roujou, Y. Zanella, P. Fauvet, P. Carles
In the framework of the massive production of hydrogen using the sulphur-iodine thermochemical cycle, the design of the reactive distillation column, chosen by CEA for the HIx section, requires the knowledge of the partial pressures of the gaseous species (HI, I2, H2O) in thermodynamic equilibrium with the liquid phase of the HI-I2-H2O ternary mixture in a wide range of concentrations up to 270°C and 50 bar. The experimental devices which enable the measurement of the total pressure and concentrations of the vapour phase (and thus the knowledge of the partial pressures of the different gaseous species) for the HI-I2-H2O mixture in the 20-250°C range and up to 35 bar are described.
在使用硫-碘热化学循环大规模生产氢气的框架中,CEA为HIx部分选择的反应精馏塔的设计需要了解气态物质(HI, I2, H2O)在热力学平衡中的分压,以及HI-I2-H2O三元混合物的液相在270°C和50 bar的浓度范围内的分压。描述了能够测量20-250°C范围内高达35 bar的HI-I2-H2O混合物的总压力和气相浓度(从而了解不同气体种类的分压)的实验装置。
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引用次数: 4
A Uranium Thermochemical Cycle for Hydrogen Production 铀热化学循环制氢
Pub Date : 2010-01-01 DOI: 10.1787/9789264087156-50-EN
C. Forsberg, J. Collins, L. Dole, J. J. Ferrada, M. J. Haire, R. Hunt, J. Ladd-Lively, B. Lewis, R. Wymer
A modelling and experimental effort has identified a new uranium thermochemical cycle (UTC) for the production of hydrogen from water. The peak temperature within the cycle is below 700°C – a temperature achievable with existing high temperature nuclear reactors and some solar systems using commercially available materials. This paper describes the new process and some of the experimental work. It is an early report of chemical feasibility. Much work will be required to determine engineering and economic viability.
建模和实验工作已经确定了一种新的铀热化学循环(UTC),用于从水中生产氢。循环内的峰值温度低于700°C——现有的高温核反应堆和一些使用商用材料的太阳能系统可以达到这个温度。本文介绍了新工艺和一些实验工作。这是一份化学可行性的早期报告。需要做大量的工作来确定工程和经济可行性。
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引用次数: 1
Possibility of active carbon recycle energy system 活性炭循环能源系统的可能性
Pub Date : 2010-01-01 DOI: 10.1787/9789264087156-40-EN
Y. Kato
A new energy transformation system based on carbon recycle use was discussed. A concept of an Active Carbon Neutral Energy System (ACRES) was proposed. Carbon dioxide is regenerated artificially into hydrocarbons by using a heat source with non-carbon dioxide emission, and the regenerated hydrocarbon is re-used cyclically as an energy carrier media in ACRES. Feasibility of ACRES was examined thermodynamically in comparison with hydrogen energy system. Carbon monoxide was the most suitable for a recycle carbon media in ACRES because of relatively high energy density in comparison with hydrogen, and high acceptability to conventional chemical, steel and high-temperature manufacturing industries. A high-temperature gas reactor was a good power source for ACRES. ACRES with carbon monoxide as recycle media was expected to be one of the efficient energy utilisation systems for the reactor.
探讨了一种基于碳循环利用的新型能源转换系统。提出了碳中和能源系统(acre)的概念。利用无二氧化碳排放的热源将二氧化碳人工再生为碳氢化合物,再生的碳氢化合物作为能量载体介质循环再利用。通过与氢能系统的热力学比较,验证了该系统的可行性。与氢气相比,一氧化碳的能量密度相对较高,对常规化工、钢铁和高温制造业的可接受性较高,因此最适合作为acre的回收碳介质。高温气体反应堆是一个很好的动力源。以一氧化碳为循环介质的acro有望成为反应器的高效能源利用系统之一。
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引用次数: 0
Nuclear hydrogen using high temperature electrolysis and light water reactors for peak electricity production 核氢利用高温电解和轻水反应堆进行高峰发电
Pub Date : 2010-01-01 DOI: 10.1787/9789264087156-17-EN
C. Forsberg, M. Kazimi
In a carbon-dioxide-constrained world, the primary methods to produce electricity (nuclear, solar, wind and fossil fuels with carbon sequestration) have low operating costs and high capital costs. To minimise the cost of electricity, these plants must operate at maximum capacity; however, the electrical outputs do not match changing electricity demands with time. A system to produce intermediate and peak electricity is described that uses light water reactors (LWR) and high temperature electrolysis. At times of low electricity demand the LWR provides steam and electricity to a high temperature steam electrolysis system to produce hydrogen and oxygen that are stored. At times of high electricity demand, the reactor produces electricity for the electrical grid. Additional peak electricity is produced by combining the hydrogen and oxygen by operating the high temperature electrolysis units in reverse as fuel cells or using an oxy-hydrogen steam cycle. The storage and use of hydrogen and oxygen for intermediate and peak power production reduces the capital cost, increases the efficiency of the peak power production systems, and enables nuclear energy to be used to meet daily, weekly and seasonal changes in electrical demand. The economic viability is based on the higher electricity prices paid for peak-load electricity.
在一个二氧化碳限制的世界里,主要的发电方法(核能、太阳能、风能和具有碳封存的化石燃料)运营成本低,资本成本高。为了最大限度地降低电力成本,这些发电厂必须以最大容量运行;然而,电力输出不能满足随时间变化的电力需求。介绍了一种利用轻水堆和高温电解技术生产中峰电的系统。在电力需求低的时候,LWR向高温蒸汽电解系统提供蒸汽和电力,以产生储存的氢和氧。在电力需求高的时候,反应堆为电网发电。通过反向操作高温电解装置作为燃料电池或使用氧-氢蒸汽循环,将氢和氧结合在一起产生额外的峰值电力。氢气和氧气的储存和使用可以降低资本成本,提高峰值电力生产系统的效率,并使核能能够用于满足每日、每周和季节性的电力需求变化。经济可行性是基于为高峰负荷电力支付更高的电价。
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引用次数: 14
The development of the Hydrogen Economic Evaluation Program (HEEP) 氢经济评价项目(HEEP)的发展
Pub Date : 2010-01-01 DOI: 10.1787/9789264087156-33-EN
I. Khamis
The International Atomic Energy Agency (IAEA) is developing software to perform economic analysis related to hydrogen production. The software is expected to analyse the economics of the four most promising processes for hydrogen production. These processes are: high and low temperature electrolysis, thermochemical processes including the S-I process, conventional electrolysis and steam reforming.
国际原子能机构(IAEA)正在开发软件,以执行与氢气生产有关的经济分析。该软件预计将分析四种最有前途的制氢过程的经济性。这些过程是:高低温电解,热化学过程包括S-I过程,常规电解和蒸汽重整。
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引用次数: 0
Application of nuclear-produced hydrogen for energy and industrial use 核能产氢在能源和工业上的应用
Pub Date : 2010-01-01 DOI: 10.1787/9789264087156-10-EN
M. Hori
Hydrogen can be produced from water by thermochemical processes using nuclear heat or by electrochemical processes using nuclear electricity, or by "hybrid" processes combining both processes. As these nuclear water-splitting processes make it possible to produce hydrogen without any carbon dioxide emissions, they are mainstream methods to supply hydrogen as an energy carrier or as a feed material for industrial processes.
氢可以通过使用核热的热化学过程或使用核电的电化学过程从水中产生,也可以通过结合这两种过程的“混合”过程。由于这些核水分解过程可以在不排放任何二氧化碳的情况下生产氢气,因此它们是供应氢气作为能源载体或作为工业过程原料的主流方法。
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Nuclear science abstracts
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