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Determination of Some Heavy Metals in Roadside Soils from Some Major Roads in Maiduguri, Borno State, Nigeria 尼日利亚博尔诺州迈杜古里主要道路路边土壤重金属含量测定
Pub Date : 2019-11-18 DOI: 10.11648/j.ns.20190403.11
Mohammed Kyari Dikwa, J. Akan, A. Adamu
Heavy metal concentration in road side soils with its potential ecological effects draws much attention in the developing countries. This necessitates the study of their accumulation in the road side soils of Maiduguri (longitude 11° 13’ N; latitude 13° 05’ E), to ensure effective protection of soil from the potential loss of its fertility. In this study, roadside soil samples from major roads (Baga road, Bama road, Ngala road and Kano/Jos road) of Maiduguri were collected and determined the levels of heavy metals (As, Cr, Mn, Fe, Ni, Pb, Zn, Cd, and Cu) in the roadside soil using the Perkin-Elmer analyst 300 Atomic Absorption Spectroscopy (AAS). The results showed that in all the sampling locations, Mn, Zn, Fe and Pb have higher concentration of 137.4±0.04 mg/kg, 392.11±0.07 mg/kg, 13491.70±0.07 mg/kg and 928.50±0.04 mg/kg respectively in roadside soil as compared with Cd of concentration ranges from 0 to maximum of 0.87±0.04mg/kg in Ngala road. The concentrations of Pb and Cd in the soil samples were higher than the recommended value of 48 mg/kg and 5.0 mg/kg respectively. The higher concentration of these metals in the roadside soil samples may be attributed to human activities and traffic volume. Therefore, there is need to further study the concentrations of such heavy metals in agricultural soil, plants and vegetables grown in that area, animals that fed on the plants and any other source that directly or indirectly link to the source of food of the populace.
公路边土壤重金属浓度及其潜在的生态效应一直是发展中国家关注的问题。这就需要研究它们在迈杜古里(经度11°13′N;纬度13°05′E),以确保有效保护土壤,防止其肥力的潜在丧失。本研究收集了迈杜古里主要道路(Baga路、Bama路、Ngala路和Kano/Jos路)的路边土壤样本,并利用perkins - elmer分析仪300原子吸收光谱(AAS)测定了路边土壤中重金属(As、Cr、Mn、Fe、Ni、Pb、Zn、Cd和Cu)的含量。结果表明:在所有采样点,路边土壤中Mn、Zn、Fe和Pb的浓度分别为137.4±0.04 mg/kg、392.11±0.07 mg/kg、13491.70±0.07 mg/kg和928.50±0.04 mg/kg,高于Ngala路0 ~ 0.87±0.04mg/kg的Cd浓度。土壤样品中Pb和Cd的浓度分别高于推荐值48 mg/kg和5.0 mg/kg。路边土壤样品中这些金属的较高浓度可能与人类活动和交通流量有关。因此,有必要进一步研究这类重金属在农业土壤、该地区种植的植物和蔬菜、以这些植物为食的动物以及与民众食物来源直接或间接有关的任何其他来源中的浓度。
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引用次数: 2
Improved Numerical Generalization of the Bethe-Weizsäcker Mass Formula for Prediction the Isotope Nuclear Mass, the Mass Excess Including of Artificial Elements 119 and 120 预测同位素核质量,包括人造元素119和120的质量过剩的Bethe-Weizsäcker质量公式的改进数值推广
Pub Date : 2019-07-26 DOI: 10.11648/J.NS.20190402.11
Mavrodiev Strachimir Chterev, V. Alexander
George Gamow’s liquid drop model of the nucleus can account for most of the terms in the formula and gives rough estimates for the values of the coefficients. Its semi-numerical equation was first formulated in 1935 by Weizsacker and in 1936 Bethe [1, 2], and although refinements have been made to the coefficients over the years, the structure of the formula remains the same today. Their formula gives a good approximation for atomic masses and several other effects, but does not explain the appearance of magic numbers of protons and neutrons, and the extra binding-energy and measure of stability that are associated with these numbers of nucleons. Mavrodiev and Deliyergiyev [3] formalized the nuclear mass problem in the inverse problem framework. This approach allowed them to infer the underlying model parameters from experimental observation, rather than to predict the observations from the model parameters. They formulated the inverse problem for the numerically generalized semi-empirical mass formula of Bethe and von Weizsacker going step-by-step through the AME2012 [4] nuclear database. The resulting parameterization described the measured nuclear masses of 2564 isotopes with a maximal deviation of less than 2.6 MeV, starting from the number of protons and number of neutrons equal to 1. The unknown functions in the generalized mass formula was discovered in a step-by-step way using the modified procedure realized in the algorithms developed by Aleksandrov [5-7] to solve nonlinear systems of equations via the Gauss-Newton method. In the presented herein article we describe a further development of the obtained by [3] formula by including additional factors,- magic numbers of protons, neutrons and electrons. This inclusion is based the well-known experimental data on the chemically induced polarization of nuclei and the effect of such this polarization on the rate of isotope decay. It allowed taking into account resonant interaction of the spins of nuclei and electron shells. As a result the maximal deviation from the measured nuclear masses of less than 1.9 MeV was reached. This improvement allowed prediction of the nuclear characteristics of the artificial elements 119 and 120.
乔治·伽莫夫的核液滴模型可以解释公式中的大部分项,并给出系数值的粗略估计。它的半数值方程是由Weizsacker和Bethe于1935年和1936年首次提出的[1,2],尽管多年来对系数进行了改进,但公式的结构今天仍然保持不变。他们的公式为原子质量和其他几种效应提供了一个很好的近似,但不能解释质子和中子的神奇数量的出现,以及与这些核子数量相关的额外结合能和稳定性测量。Mavrodiev和Deliyergiyev[3]在反问题框架中形式化了核质量问题。这种方法使他们能够从实验观测中推断出潜在的模型参数,而不是从模型参数中预测观测结果。他们逐步通过AME2012[4]核数据库,为Bethe和von Weizsacker的数值广义半经验质量公式制定了反问题。所得到的参数化描述了2564种同位素的测量核质量,最大偏差小于2.6 MeV,从质子数和中子数等于1开始。利用Aleksandrov[5-7]开发的利用高斯-牛顿法求解非线性方程组的算法所实现的改进程序,逐步发现了广义质量公式中的未知函数。在本文中,我们描述了由[3]得到的公式的进一步发展,包括额外的因素,质子、中子和电子的幻数。这种包含是基于众所周知的关于原子核的化学诱导极化以及这种极化对同位素衰变速率的影响的实验数据。它允许考虑原子核自旋和电子壳层的共振相互作用。结果表明,在小于1.9 MeV的情况下,得到了与实测核质量的最大偏差。这一改进可以预测人造元素119和120的核特性。
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引用次数: 1
Evaluating of Simulating the Transportation of Electron in Intelligent Information Systems and High-Tech Applicants 智能信息系统中电子传输模拟的评价及高技术应用
Pub Date : 2019-07-09 DOI: 10.11648/J.NS.20190401.12
Afroditi Skafida, Katherina Dalaka
The interest to study electron transport in semiconductor devices at very high electric field has been increased in the last decades and assessment of Monte Carlo simulation of electron transport in ZnO diode in intelligent information systems is of high significance. The Monte Carlo method as applied to semiconductor transport is a simulation of the trajectories of individual Carriers as they move through a device under the influence of external forces and subject to random scattering events. Monte Carlo simulation is performed to study quasi-ballistic transport of electrons in n+nn+ ZnO diode. In this simulation, the spatial motion of the electrons is semi classical and the scattering mechanisms taken into account are those due to acoustic phonons, non-polar optical phonons, polar optical phonons and ionized impurities. The simulation results are reported for different temperatures and voltages. It is also found that the transient properties of ZnO-made diode are not much sensitive to environment temperature changes, and thus the use of this substance is highly recommended in manufacture of electronic equipment.
近几十年来,人们对半导体器件在甚强电场下的电子输运研究越来越感兴趣,对智能信息系统中ZnO二极管电子输运的蒙特卡罗模拟进行评估具有重要意义。应用于半导体输运的蒙特卡罗方法是模拟单个载流子在外力影响下通过器件并受到随机散射事件时的轨迹。采用蒙特卡罗模拟方法研究了n+nn+ ZnO二极管中电子的准弹道输运。在这个模拟中,电子的空间运动是半经典的,考虑了声子、非极性光学声子、极性光学声子和电离杂质的散射机制。给出了不同温度和电压下的仿真结果。研究还发现,zno二极管的瞬态特性对环境温度变化不太敏感,因此在电子设备的制造中强烈推荐使用该物质。
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引用次数: 0
Linearity Test for Harshaw TLD (Type: TLD-100H) Base on Individual Calibration Method Harshaw TLD(型号:TLD- 100h)基于单独校准法的线性测试
Pub Date : 2019-06-11 DOI: 10.11648/J.NS.20190401.11
Luay Abdulsahib Rasool, Naashat Raheem Al-Ataby, Alaa Fadil Hashim
The testing of the individual monitoring instruments is important to demonstrate the performance of the instruments to give accurate measurements in workplace environment. In this research, 18 Thermoluminescence dosimetry (TLD) units were calibrated individually at surface water phantom and exposed with 60Co source at block 32 in Malaysia Nuclear Agency. The TLD were exposed at 5.00 meter distance from the source. The exposed TLD in terms of Personal Dose Equivalent at 10mm depth tissue, (Hp (10)) equal to 2.00mSv. The exposed TLD then be measured using winRems software from Harshaw TLD reader 6600 plus for defining the calibration factor in term of mSv/nC. After that all the 18 unit TLD were tested using linearity testing method and 18 TLD units were exposed with different dose that were 1mSv, 5mSv, 7mSv, 10mSv, 15mSv, and 20mSv. The research is conducted to satisfy two main objectives which was to obtain linear regression coefficient R2 ~ 1 and to show that the ratio of measured value over standard values are within ICRP trumpet acceptance limit curve, which are within (-33% to +50%).
单个监测仪器的测试是重要的,以证明仪器的性能,以提供准确的测量工作环境。在这项研究中,18个热释光剂量计(TLD)单元在马来西亚核机构32区块的地表水幻影中单独校准,并暴露于60Co源。TLD暴露在距离辐射源5.00米的地方。以个人剂量当量(Hp(10))计算,暴露于10mm深度组织的TLD等于2.00mSv。然后使用Harshaw TLD阅读器6600 plus的winRems软件测量暴露的TLD,以mSv/nC定义校准因子。然后对18个TLD单元进行线性检测,分别以1mSv、5mSv、7mSv、10mSv、15mSv、20mSv的不同剂量照射18个TLD单元。本研究的主要目的是获得线性回归系数R2 ~ 1,并表明实测值与标准值的比值在ICRP小号接受极限曲线范围内(-33% ~ +50%)。
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引用次数: 2
Nuclear Forensics and Development of Non-Destructive Scrutiny Facility (NDSF) for the Kingdom of Saudi Arabia 沙特阿拉伯王国核取证和非破坏性审查设施(NDSF)的发展
Pub Date : 2019-05-31 DOI: 10.11648/J.NS.20180304.11
S. Khan
In this paper, theoretical model for nuclear forensics is developed and the Kingdom of Saudi Arabia (KSA) is considered as the case study. The main objective of this research is the development of procedure for nuclear forensics and infrastructure for non-destructive scrutiny facility (NDSF). In this study, various assumptions and parameters were discussed including the development strategies, technical evaluations, capabilities and current scenarios. The prime objective is to gain insight to the threat and unexpected issues regarding the race of nuclear technology in Middle East and North Africa (MENA) region and to safer the KSA region.
本文以沙特阿拉伯王国为研究对象,建立了核取证的理论模型。本研究的主要目的是发展核取证程序和无损检查设施基础设施。在本研究中,讨论了各种假设和参数,包括发展战略、技术评估、能力和当前情景。主要目标是深入了解中东和北非(MENA)地区核技术竞赛的威胁和意想不到的问题,并使KSA地区更加安全。
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引用次数: 1
Improvement in Optical Properties of Nuclear Track Detector 核径迹探测器光学性能的改进
Pub Date : 2019-01-01 DOI: 10.11648/j.ns.20190402.12
Doaa Hassan Shabaan, Tayseer Ibrahim AL-Naggar
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引用次数: 0
Low Activation-Modified High Manganese-Nitrogen Austenitic Stainless Steel for Fast Reactor Pressure Vessel Cladding 快堆压力容器包覆用低活化改性高锰氮奥氏体不锈钢
Pub Date : 2018-11-23 DOI: 10.11648/J.NS.20180303.14
A. Saeed, Raed Mohmed El-Shazly, S. Ghali, S. El-Khamisy, S. El-fiki, M. Eissa
Low and free nickel austenitic stainless steel alloys were developed successfully and proposed to be used as a liquid sodium coolant fast reactor pressure vessel cladding. A standard austenitic stainless steel SS316L (AISI 316L) was produced as a reference sample. The nickel content was partially or totally replaced by manganese and nitrogen. The microstructure of the produced stainless steel alloys was investigated using Schaeffler diagram, optical microscopy and X-ray diffraction patterns (XRD). Mechanical properties of the developed stainless steel grads were investigated using Vickers hardness, impact and tensile tests at room temperature. Sodium chloride was used to study the corrosion rate of the investigated alloys by open circuit potential technique. Slow and total slow neutrons removal cross sections were measured using 241 Am-Be neutron source and highly calibrated He-3 detector. Eight gamma ray lines which emitted from 60 Co and 232 Th radioactive sources and HPGe detector were used to study the attenuation parameters of the produced alloys. Metallography, Schaeffler diagram and XRD results showed that all the produced stainless steels are mainly of austenite phase with a small ferrite phase. The developed manganese-nitrogen stainless steels showed higher hardness, yield and ultimate tensile strength than SS316L. The elongation of developed stainless steels is relatively lower than the standard SS316L. The impact toughness was reduced with replacement of Ni by Mn. The developed manganese stainless steels have a higher total slow removal cross section than SS316L. On the other hand, the slow neutron and gamma rays have nearly the same behavior for all studied stainless steels.
研制成功了低镍和游离镍奥氏体不锈钢合金,并提出将其用作快堆压力容器包壳的液态钠冷却剂。制作了标准奥氏体不锈钢SS316L (AISI 316L)作为参考样品。镍含量部分或全部被锰和氮所取代。采用舍弗勒图、光学显微镜和x射线衍射图(XRD)对制备的不锈钢合金的显微组织进行了研究。采用维氏硬度、冲击和室温拉伸试验研究了所研制的不锈钢梯度的力学性能。采用开路电位法,用氯化钠对合金的腐蚀速率进行了研究。利用241 Am-Be中子源和高度校准的He-3探测器测量了慢中子和总慢中子去除截面。利用60 Co和232 Th放射源发射的8条伽马射线线和HPGe探测器研究了所制备合金的衰减参数。金相、舍弗勒图和XRD结果表明,所制备的不锈钢以奥氏体相为主,铁素体相较少。所研制的锰氮不锈钢的硬度、屈服强度和极限抗拉强度均高于SS316L。开发的不锈钢的延伸率相对低于标准的SS316L。Mn取代Ni后,合金的冲击韧性降低。开发的锰不锈钢具有比SS316L更高的总缓慢去除截面。另一方面,慢中子和伽马射线对所有被研究的不锈钢具有几乎相同的行为。
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引用次数: 7
Design of Vacuum Compatible Automatic Targets Feeding System 真空兼容自动送料系统的设计
Pub Date : 2018-11-14 DOI: 10.11648/j.ns.20180303.13
M. Curuia, S. Soare, C. Jianu, M. Varlam
The present paper presents the design of a vacuum compatible automatic targets feeding system (VCATFS) that can be used to introduce targets inside the interaction chambers for accelerators, laser beams and others research plants. As a first application, the system is to be used within the Extreme Light Infrastructure - Nuclear Physics (ELI-NP) project, to load target frames in the interaction chamber without losing the vacuum. The target frames will be inserted and retracted into/from the interaction chamber individually with high accuracy of positioning. Up to three target frames can be used during one experiment. This number of targets is a consequence of several severe spatial constraints where the system will be installed, but for other situations it can be increased. Also, a new technique of moving the target frames is proposed, two horizontal translations in two parallel planes and two vertical translations also in two parallel planes. VCATFS is divided into two main sub-systems: mechanical (includes kinematics, high precision components and systems, vacuum chamber), and a dedicated command and control system (transducers - high accuracy absolute linear encoders, stepper motors and associated electric drives unit, interfaces and proprietary software). Additionally, a dedicated vacuum system was designed. This approach will further be developed as prototype level. This paper will focus on the design of mechanical sub-system, the remaining ones will be the subject of future documents that would be made publicly available in the future.
本文介绍了一种真空兼容自动靶标馈送系统(VCATFS)的设计,该系统可用于在加速器、激光束和其他研究装置的相互作用室内引入靶标。作为第一个应用,该系统将在极光基础设施-核物理(ELI-NP)项目中使用,在不失去真空的情况下加载相互作用室中的目标框架。目标框架将单独插入和从交互室中取出,定位精度高。在一次实验中最多可以使用三个目标帧。目标的数量是由于安装系统的几个严格的空间限制,但在其他情况下可以增加目标的数量。此外,还提出了一种新的目标帧移动技术,即在两个平行平面上进行两次水平平移和在两个平行平面上进行两次垂直平移。VCATFS分为两个主要子系统:机械(包括运动学,高精度组件和系统,真空室)和专用命令和控制系统(传感器-高精度绝对线性编码器,步进电机和相关的电力驱动单元,接口和专有软件)。此外,还设计了专用真空系统。这种方法将进一步发展为原型级。本文将重点介绍机械子系统的设计,其余部分将在未来公开的文件中进行。
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引用次数: 0
Revealing 226 Ra Alpha Peak by a Multi-Pixel Photon Counter 用多像素光子计数器揭示226 Ra α峰
Pub Date : 2018-11-13 DOI: 10.11648/J.NS.20180303.12
E. E. Ermiş, C. Celiktas
226 Ra alpha peak was revealed by a Multi-Pixel Photon Counter (MPPC) through a developed spectrometer. MPPC is consisted of silicon photomultipliers (Si-PM) which can be used for photon detection and measurement. It is one of the new generation counter types. It has been used in many research areas such as radiation detection and optics. So, this type detector was chosen so that this study is up-to-date. Main goal of the study is to obtain pure alpha energy spectrum because no study was found in the literature about the neat alpha spectrum by the MPPC. For this reason, coincidence gate method was used in the presented study to acquire the spectrum. In the first section, alpha spectrum was recorded directly via MPPC module. This spectrum had too much electronic noise. The spectrum was secondly obtained through the developed spectrometer. This second spectrum had not almost all noise components. Then, the obtained spectra were compared with each other at the final section. The asserted spectrometer was highly successful in obtaining neat alpha spectrum by reducing the most noise components. It has been realized that the neat source spectra of other radioactive sources can be achieved by using this spectrometer with MPPC. Additionally, students who work about radiation detection can use the suggested spectrometer in their experiments.
通过研制的多像素光子计数器(MPPC)揭示了226 Ra α峰。MPPC由硅光电倍增管(Si-PM)组成,可用于光子探测和测量。它是新一代计数器类型之一。它已被应用于辐射探测和光学等许多研究领域。所以,选择这种类型的探测器是为了使这项研究是最新的。由于文献中未见MPPC对纯α能谱的研究,本研究的主要目的是获得纯α能谱。为此,本研究采用重合门法获取频谱。在第一部分中,通过MPPC模块直接记录α光谱。这个频谱有太多的电子噪音。利用研制的光谱仪进行二次光谱分析。第二个频谱几乎没有所有的噪声成分。然后,在最后一段对得到的光谱进行比较。所述光谱仪通过减少大部分噪声分量,获得了整齐的α光谱。利用该光谱仪与MPPC结合,实现了其他放射源的整齐源光谱。此外,从事辐射检测工作的学生可以在他们的实验中使用建议的光谱仪。
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引用次数: 0
Natural Radionuclides Concentrations and Annual Effective Dose in Seasonal Fruits of Bangladesh 孟加拉国时令水果中的天然放射性核素浓度和年有效剂量
Pub Date : 2018-11-09 DOI: 10.11648/j.ns.20180303.11
Rumman Mustakim, J. Ferdous, A. Begum, A. Islam
The aim of the present study was to investigate the activity concentrations of natural radionuclides in different seasonal fruits of Bangladesh. In total 20 samples of 16 different kinds of fruits were collected from the local markets of Bangladesh. The radioactivity of these samples was measured by using Gamma Spectrometry System. The radioactivity of natural radionuclides in the studied seasonal fruit samples were found to be ranged from BDL to 31.13±10.63 Bqkg -1 with an average 10.95 Bqkg -1 due to 238 U, from 1.55±0.73 to 34.59±7.43 Bqkg -1 with an average 6.68 Bqkg -1 due to 232 Th and from BDL to 733.25±61.17 Bqkg -1 with an average 308 Bqkg -1 due to 40 K. Artificial radionuclide was not found in the studied fruit samples. The maximum activities of 238 U, 232 Th and 40 K were observed, respectively in coconut, jujube and papaya. However, the average concentrations of all radionuclides mentioned above in the studied samples were found to be less than the world average. The total annual internal effective dose from the consumption of radioactive fruits was found to be 8.39 μSv/y. The value the annual effective dose in all samples in this study was lower than ICRP 72; therefore, the values natural radioactivity and annual effective dose in the seasonal fruits are found to be safe and no health-hazards are createdfor the population of Bangladesh.
本研究的目的是调查孟加拉国不同时令水果中天然放射性核素的活性浓度。总共从孟加拉国当地市场收集了16种不同水果的20个样本。用伽马能谱法测定了样品的放射性。所研究的时令水果样品中天然放射性核素的放射性范围为:BDL ~ 31.13±10.63 Bqkg -1,平均为10.95 Bqkg -1; BDL ~ 733.25±61.17 Bqkg -1,平均为40k,平均为308 Bqkg -1;在所研究的水果样本中未发现人工放射性核素。其中,238 U、232 Th和40 K在椰子、大枣和木瓜中活性最高。然而,研究样本中上述所有放射性核素的平均浓度被发现低于世界平均水平。食用放射性水果产生的年总内有效剂量为8.39 μSv/y。本研究所有样品的年有效剂量值均低于ICRP 72;因此,时令水果的天然放射性值和年有效剂量值是安全的,不会对孟加拉国人民的健康造成危害。
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引用次数: 4
期刊
Nuclear science abstracts
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