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The Impact of Anthropogenic Activities on the Fosu Lagoon in the Central District of Cape Coast: Integrated Assessment of Heavy Metal Contamination 人为活动对开普海岸中部Fosu泻湖的影响:重金属污染的综合评估
Pub Date : 2017-01-10 DOI: 10.9734/BJAST/2017/31275
George Adjei, C. K. Adokoh, J. K. Bentum, G. Hadzi, E. Ameho
Effluents from humans and industrial discharges into the environment pose a serious threat to human health and aquatic life. In view of this, levels of some heavy metals Zn, Pb, Cu, Ti, V and Mn were determined in sediment samples collected from one of the most polluted water bodies (Fosu Lagoon) in the central region of Ghana using Atomic Absorption Spectrophotometer (AAS) - (Varian Short Research Article – AA240 FS). The average concentrations of lead (Pb), zinc (Zn), manganese (Mn), copper (Cu), Titanium (Ti) and Vanadium (V), from the various sites ranged from 138.75 mgkg -1 (Ti) to 4.90 mgkg -1 (Zn). Among the concentrations of heavy metals found in the sediment samples, Ti recorded the highest concentration of 4600 mgkg -1 followed by Mn (290.00 mgkg -1 ) and then Cu (235.93 mgkg -1 ). The sequence of distribution followed Ti>Mn ˃ V>Cu>Pb ˃ Zn. The mean concentration of Mn, Cu, Ti and V exceeded the USEPA and WHO standard guideline whiles Pb and Zn were below the standard regulation limits. The Pearson correlation analysis between the heavy metals at the various sampling points was generally weak, with both positive and inverse correlations demonstrating that heavy metals may be coming from different anthropogenic sources. Comparing results from this study with previous works in the same Lagoon showed increased anthropogenic activities around the lake which pose potential pollution threats to the lagoon especially, the heavy metal pollutants which may be toxic to humans and aquatic life.
人类和工业排放到环境中的污水对人类健康和水生生物构成严重威胁。鉴于此,使用原子吸收分光光度计(AAS) - (Varian Short Research Article - AA240 FS)测定了从加纳中部地区污染最严重的水体之一(Fosu泻湖)收集的沉积物样品中某些重金属Zn、Pb、Cu、Ti、V和Mn的含量。不同地点的铅(Pb)、锌(Zn)、锰(Mn)、铜(Cu)、钛(Ti)和钒(V)的平均浓度从138.75 mgkg -1 (Ti)到4.90 mgkg -1 (Zn)不等。沉积物样品中重金属含量最高的是Ti (4600 mgkg -1),其次是Mn (290.00 mgkg -1)和Cu (235.93 mgkg -1)。分布顺序为Ti>Mn→V>→Cu>→Pb→Zn。Mn、Cu、Ti和V的平均浓度超过了USEPA和WHO的标准指导值,Pb和Zn的平均浓度低于标准规定限值。各采样点重金属之间的Pearson相关分析普遍较弱,存在正相关和负相关,表明重金属可能来自不同的人为来源。本研究结果与以往在同一泻湖的研究结果进行了比较,结果表明,湖泊周围的人为活动增加,对泻湖造成了潜在的污染威胁,特别是重金属污染物可能对人类和水生生物有毒。
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引用次数: 3
Geochemical Analysis of the Groundwater Quality along the Vrishabhavathi River Basin Vrishabawathi河流域地下水水质的地球化学分析
Pub Date : 2017-01-10 DOI: 10.9734/BJAST/2017/32406
G. Manohar, M. Raju, D. Janardhan
work carried out in collaboration between authors GNM and MHR. Author GNM performed the field work and chemical analysis in the laboratory, wrote the protocol and the first draft of the manuscript. Authors GNM and MHR designed the study and author MHR supervised the chemical analysis in the laboratory. Author DJ helped in the statistical study. All the three authors read and approved the final manuscript. ABSTRACT Aim: The Results: The detailed study of all the water quality variables is discussed in the paper. LSI calculation indicates that majorly 53% of the water samples are classified under the class ‘D’ [Slightly scale forming and corrosive] and 40% of the water samples fall under the group ‘E’ [Scale forming but non-corrosive]. Piper trilinear plot reveals that majorly Ca ++ and Mg ++ are the dominant cations and HCO 3- and Cl - are the dominant anions. Statistical measures such as Mean, SD, SE of sample means, coefficients of Skewness and Kurtosis have been computed using the statistical package to assess the characteristics of the selected water quality variables. Further, 95% confidence intervals have been obtained for the true means of these variables and water quality variables crossing the permissible limits of WHO [1993] have been identified using these confidence limits. Correlation study has been done to estimate the significance of the linear relationship between the pairs of variables at a given level of significance and thereby the set of water quality variables which are interlinked have been identified. Conclusion: The water quality variables which have/have the tendency to cross the permissible limits set by WHO [1993] have been identified using the confidence intervals. Through the Piper plot and LSI calculation, we can conclude that the groundwater samples are alkaline in nature and are not suitable for consumption.
作者GNM和MHR合作开展的工作。作者GNM进行了野外工作和实验室化学分析,撰写了方案和稿件初稿。作者GNM和MHR设计了这项研究,作者MHR监督了实验室的化学分析。作者DJ协助统计研究。三位作者都阅读并批准了最后的手稿。【摘要】目的:结果:对各水质变量进行了详细的研究。LSI计算表明,53%的水样属于“D”类(轻度结垢和腐蚀),40%的水样属于“E”类(轻度结垢但无腐蚀)。Piper三线性图显示,阳离子以ca++和mg++为主,阴离子以hco3 -和Cl -为主。使用统计软件包计算了样本均值的Mean、SD、SE、偏度系数和峰度系数等统计度量,以评估所选水质变量的特征。此外,已经为这些变量的真实均值获得了95%的置信区间,并且使用这些置信区间确定了超过WHO[1993]允许范围的水质变量。相关研究是为了估计变量对之间的线性关系在给定显著性水平上的显著性,从而确定了相互关联的水质变量集。结论:使用置信区间确定了有/有超过WHO[1993]规定的允许限度趋势的水质变量。通过派珀图和大规模集成电路计算,可以得出地下水样品属于碱性,不适合消费的结论。
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引用次数: 0
Application of Multiple Ecological Risk Indices for the Assessment of Heavy Metal Pollution in Soils in Major Mechanic Villages in Abuja, Nigeria 多重生态风险指数在尼日利亚阿布贾主要机械村土壤重金属污染评价中的应用
Pub Date : 2017-01-10 DOI: 10.9734/BJAST/2017/30779
C. Ekeocha, C. Ogukwe, Joy Nikoro
Heavy metal contamination has become a serious environmental problem due to their negative effects on humans, organisms, soil quality, underground water and ecosystem. This research was targeted at the use of multiple ecological risk indices approach in assessing the ecological risk associated with heavy metal contamination in soils in some mechanic villages in Abuja, central Nigeria. To achieve this set objective, four pollution indices models namely: contamination factor (C f ), ecological risk factor (E r ), degree of contamination (C D ) and potential ecological risk index (PERI) were explored. Fifteen soil samples were randomly collected with a hand dug auger to a depth range of 0-15 cm with five sample points from each of the three investigated mechanic villages. A control sample was also collected from a distance of 100 km where neither commercial nor industrial activities take place. The sampled soils were further subjected to standard chemical analysis. The automated Atomic Absorption Spectrophotometer (AAS) was used for this purpose. The results of the chemical analysis revealed that concentrations of heavy metals in Apo, Kugbo and Zuba mechanic villages followed a trend of Cu > Zn > Cr > Fe > Pb > Ni > Cd; Zn > Cu > Cr > Ni > Fe > Pb > Cd and Zn > Cr > Cu > Fe > Pb > Ni > Cd respectively. The multiple ecological risk indices models explored in the study showed various ecological risk level associated with heavy metal contamination of soils from the investigated sites with classes ranging from low to very high ecological risks. This could be traceable to anthropogenic activities like indiscriminate discharge of heavy metal containing waste in soil and poor waste management practice in the mechanic villages. This calls for urgent measure in curtailing indiscriminate waste discharge and the introduction of environmental friendly waste management in the mechanic villages so as to avert epidemics and environmental degradation due to heavy metal pollution.
重金属污染对人类、生物、土壤质量、地下水和生态系统的负面影响已成为一个严重的环境问题。本研究旨在利用多重生态风险指数方法评估尼日利亚中部阿布贾一些机械村土壤重金属污染的生态风险。为了实现这一既定目标,研究了四种污染指数模型,即污染因子(C f)、生态风险因子(E r)、污染程度(C D)和潜在生态风险指数(PERI)。用手挖螺旋钻随机采集15个土壤样本,深度0 ~ 15 cm,在调查的3个机械村各取5个采样点。对照样本也从100公里以外既没有商业活动也没有工业活动的地方收集。采样土壤进一步进行标准化学分析。采用自动原子吸收分光光度计(AAS)测定。化学分析结果表明,Apo、Kugbo和Zuba机械村重金属浓度呈现Cu b> Zn b> Cr b> Fe b> Pb > Ni > Cd的趋势;Zn > Cu > Cr > Ni > Fe > Pb > Cd和Zn > Cr > Cu > Fe > Pb > Ni > Cd。研究建立的多重生态风险指数模型显示了调查点土壤重金属污染的不同生态风险等级,生态风险等级从低到极高。这可以追溯到人为活动,如在土壤中随意排放含有重金属的废物,以及机械村的废物管理不善。这就要求采取紧急措施,减少随意排放废物,并在技工村实行环境友好型废物管理,以避免因重金属污染造成的流行病和环境退化。
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引用次数: 3
Time Period in Which Radiation Workers Completed the 20 mSv Annual Limit 辐射工作人员完成每年20毫西弗限值的时间段
Pub Date : 2017-01-10 DOI: 10.9734/bjast/2017/30802
S. Memon, Naeem Ahmed Laghari
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引用次数: 0
Theoretical Model of the Electric Field of Stray Currents in Underground Installations in Urban Environments 城市地下设施杂散电流电场的理论模型
Pub Date : 2017-01-10 DOI: 10.9734/BJAST/2017/31690
S. Bjelić, Bojan L. Jovanović, Z. Bogićević, N. Marković, Igor S. Bjelić
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引用次数: 2
Minerals and Nutrient Variations as Influenced by Harvesting Stages in selected African Leafy Vegetables Grown in Busia, Kenya 在肯尼亚布西亚种植的精选非洲叶菜中受收获阶段影响的矿物质和营养变化
Pub Date : 2017-01-10 DOI: 10.9734/bjast/2017/32437
M. Grace, O. Owuor, O. David
collaboration between authors. Author MG designed the study, performed the statistical analysis, wrote the protocol, managed the literature searches and wrote the first of the manuscript. Authors OO and OD managed the analyses of the study. All authors read and approved the final manuscript. ABSTRACT Proper nutrition contributes to declines in under-five mortality rates and improves the productivity of adults. Addressing nutritional problems requires adequate information on decreased from 6 to 10 WAE. The Fe levels increased from 4 to 6 WAE while the increase from 6 to 10 WAE was not significant. Magnesium levels significantly (P ≤ 0.05) increased from 4 to 8 WAE then decreased, while Mn and Na levels did not vary with harvesting stage. Harvesting the ALVs from 4 to 6 WAE for the supply of P, K, Ca and Zn, 4 to 8 WAE for Mg and 4 to 10 WAE for the supply of Na and Mn is recommended.
作者之间的合作。作者MG设计研究,进行统计分析,撰写方案,管理文献检索,撰写第一篇稿件。作者OO和OD管理了这项研究的分析。所有作者都阅读并批准了最终的手稿。适当的营养有助于降低五岁以下儿童的死亡率,提高成年人的生产力。解决营养问题需要关于从6到10的WAE的充分信息。4 ~ 6 WAE Fe水平升高,6 ~ 10 WAE Fe水平升高不显著。4 ~ 8 WAE期间,镁含量先升高后降低(P≤0.05),Mn和Na含量随收获期变化不大。建议在4至6 WAE范围内收获alv,以供应P、K、Ca和Zn, 4至8 WAE范围内收获Mg, 4至10 WAE范围内收获Na和Mn。
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引用次数: 0
On the Riesz Integral Representation of Additives Set-Valued Maps (I) 关于附加集值映射的Riesz积分表示(I)
Pub Date : 2017-01-10 DOI: 10.9734/BJAST/2017/30901
Lakmon Kodjovi, S. Kenny, Ayassou Emmanuel, Tchariè Kokou
In this paper we generalize the Riesz integral representation for continuous linear maps associated with additive set-valued maps with values in the set of all closed bounded convex non-empty subsets of any Banach space. We deduce the Riesz integral representation results for set-valued maps, for vector-valued maps of Diestel-Uhl and for scalar-valued maps of Dunford-Schwartz.
本文推广了连续线性映射与加性集值映射相关的Riesz积分表示,其值在任意Banach空间的所有闭有界凸非空子集的集合中。我们推导了集合值映射、Diestel-Uhl的向量值映射和Dunford-Schwartz的标量值映射的Riesz积分表示结果。
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引用次数: 0
Geochemical Characterization and Protolith of the Migmatite-Gneisses of Tandama Area, Katsina State, NW Nigeria 尼日利亚西北部卡齐纳州Tandama地区混合岩片麻岩的地球化学特征和原岩
Pub Date : 2017-01-10 DOI: 10.9734/BJAST/2017/30117
Idzi Alaku, O. Moshood, A. Agbor, A. Amos
Migmatite-gneisses, which include migmatite, granite gneiss, and augen gneiss, underlie more than 70% of Tandama area, in North-western Nigeria. They are associated with schists, and are intruded by granites and pegmatites. These rocks are thought to have undergone a reworking during the Pan-African Orogeny. The aim of this research is to present results of geochemical investigation of Migmatite-gneiss Complex in the study area with a view to determine their geochemical characteristics and petrogenesis. Whole rock geochemical analyses have been used to evaluate the characteristics, petrogenesis and mode of emplacement of the protoliths. Geochemically, these rocks show granitic affinities. They are metaluminous to weakly peraluminous I-type, with S-type characteristic, magnesian to ferroan and alkali calcic and calcic. The protoliths could have been derived from the partial melting of tonalitic to granodioritic crustal rocks at low pressure, thus, producing metaluminous to slightly peraluminous high-silica, ferroan, alkali-calcic to calc-alkali melts, which is why it has some S-type character. These varying features are an indication that the protoliths are derived from mainly crustal melt mingled with mantle-derived component. The varying REEs and trace elements pattern displayed by the rocks is typical signature of arc rocks or continental crustal materials: the LREEs and LILE enrichment along with Rb, K, Pb, and negative Nb, Ta, Ti are evident of this signature. The incompatible trace elements show similarity to those of continental crustal rocks as indicated by the ratios in Th/U (2.21 12.4), Th/Yb (2.60 – 90.95), Ta/Yb (0.03 - 1.43), Ce/Pb (mainly 0.30 – 29.23) and high Ba/Nb (8.56 – 2402), the values of Sr/Y are generally<100, which is an indication of subduction-related rocks,the trend in Sr/Y ratio relative to Y contents in the rocks reflects essentially two types of felsic protolith namely crustal melts and slab melts. Similarly, the magnesian characteristic indicates close affinity to relatively hydrous, oxidizing melts, which is broadly typical of settings related to subduction. The high-K nature is characteristics of crustal rocks derived from remelting and differentiation of arc-accretionary complex crust. The rare earth element (REE) distribution shows that the migmatite-gneisses are enriched in the lighter rare earth elements (LREE) Sm, Pr, Nd, La and Ce, in that order of increasing abundance, with average values of 4.81 ppm, 7.90 ppm, 27.50 ppm, 38.44 ppm, 68.22ppm, respectively; and relatively depleted in the heavy rare earth elements (HREE) Lu, Tm, Tb, Ho, Yb and Er, with average values ranging 0.28 ppm, 0.30 ppm, 0.58 ppm, 0.65ppm, 1.91 ppm and 1.88 ppm respectively, and they exhibit negative EU anomaly, indicating that the rocks are highly fractionated. REE-chondrite normalized spider plot and plots in the chemical discrimination diagrams including the Y versus Nb plot, show that the protoliths were derived from partial melting
混辉岩片麻岩,包括混辉岩、花岗片麻岩和奥根片麻岩,占尼日利亚西北部Tandama地区的70%以上。它们与片岩伴生,并被花岗岩和伟晶岩侵入。这些岩石被认为在泛非造山运动期间经历了改造。摘要介绍研究区杂岩片麻岩杂岩地球化学调查结果,探讨其地球化学特征和岩石成因。利用全岩地球化学分析对原岩的特征、成因和侵位方式进行了评价。地球化学上,这些岩石显示出花岗岩的亲和力。它们是铝质到弱过铝质的i型,具有s型特征,镁质到铁质,碱钙和钙。原岩可能是在低压条件下由渐长质到花岗闪长质地壳岩石部分熔融而成,形成了含铝质到略过铝质的高硅、铁、碱钙到钙碱熔体,具有一定的s型特征。这些不同的特征表明原岩主要来源于地壳熔体,并混合有地幔源成分。岩石中稀土元素和微量元素的变化模式是弧岩或大陆地壳物质的典型特征,lree和LILE的富集与Rb、K、Pb和负Nb、Ta、Ti的富集是这一特征的明显体现。不相容微量元素与大陆地壳岩石相似,Th/U(2.21 12.4)、Th/Yb(2.60 ~ 90.95)、Ta/Yb(0.03 ~ 1.43)、Ce/Pb(主要为0.30 ~ 29.23)和Ba/Nb(8.56 ~ 2402)较高,Sr/Y值普遍<100,表明岩石为俯冲相关岩石,岩石中Sr/Y比值与Y含量的变化趋势主要反映了地壳熔体和板块熔体两种长英质原岩类型。同样,镁质特征表明与相对含水的氧化性熔体密切相关,这是与俯冲有关的典型环境。高钾性是弧-增生复合体地壳重熔分异形成的地壳岩石特征。稀土元素(REE)分布表明,杂岩片麻岩富集较轻的稀土元素(LREE) Sm、Pr、Nd、La和Ce,丰度依次递增,平均值分别为4.81 ppm、7.90 ppm、27.50 ppm、38.44 ppm、68.22ppm;重稀土元素(HREE) Lu、Tm、Tb、Ho、Yb和Er相对富集,平均值分别为0.28 ppm、0.30 ppm、0.58 ppm、0.65ppm、1.91 ppm和1.88 ppm, EU呈负异常,表明岩石分选程度较高。ree -球粒陨石归一化蜘蛛图和化学分辨图(包括Y - Nb图)显示,原岩来自于位于火山弧(VAG) -碰撞花岗岩(Syn-COLG)构造背景下的杂化花岗岩岩浆的部分熔融和分异。因此,表明该地区混杂岩片麻岩的火成岩前体来自不同的来源和深度。
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引用次数: 0
Comparative Evaluation of Some Nutrient Contents and Antifungal Properties of Ground Musa paradisiaca (Plantain) Peels and Leaves 芭蕉皮和叶某些营养成分及抗真菌性能的比较评价
Pub Date : 2017-01-10 DOI: 10.9734/bjast/2017/28393
Anthony Cemaluk C. Egbuonu, Wisdom O. Nneji, Chimnonye A. Ukasoanya
Musa paradisiaca (plantain) fruit peels and the plant leaves may have some nutrients and antifungal properties. Thus, millimeter, mm) against Candida albicans, however, the activity of the ethanol extract of the leaves (15.67±0.58) was higher (p<0.05) than that of the ethanol extract of the peels and the aqueous extract of the peels and leaves. The difference in activity against C. albicans between the samples extracts in terms of either the same or the different extracting solvent was significant (p<0.05) but the overall difference between the samples compared to the extracting solvents (±0.67) was the same hence non-significant (p>0.05). A similar trend was recorded for the activity of the ethanol and aqueous extracts of the peels and leaves against P. notatum . Thus, the plantain peels and leaves could be alternative source for vitamin C. The extracts (aqueous and ethanol) had activity against C. albicans and P. notatum hence may be useful in managing such pathogen-induced ailments. Overall negligible difference in activity against either C. albicans or P. notatum in terms of samples and the extracting solvents was suggested and this may be an underlying useful trend for comparing the overall antimicrobial activity of different samples and solvents, hence warrants a follow up.
芭蕉果皮和植物叶片可能具有一定的营养和抗真菌特性。因此,对白色念珠菌的抑制作用(mm, mm),叶乙醇提取物的抑制作用(15.67±0.58)较高(p0.05)。类似的趋势记录了乙醇和水提取物的果皮和叶片的活性对假葡萄。因此,车前草的皮和叶可以作为维生素c的替代来源。提取物(水和乙醇)对白色念珠菌和假单胞菌有活性,因此可能对治疗这些病原体引起的疾病有用。在样品和提取溶剂方面,对白色念珠菌或假单胞菌的活性总体上可以忽略不计,这可能是比较不同样品和溶剂的总体抗菌活性的潜在有用趋势,因此值得后续研究。
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引用次数: 0
Developing an Automatic Switch for Home or Industrial Power Supply Changeover 开发一种用于家庭或工业电源转换的自动开关
Pub Date : 2017-01-10 DOI: 10.9734/BJAST/2017/32785
Bamidele Onipede, S. Joseph, O. Odiba
Continued development of automatic change over switch is a necessary requirement for the principle of energy mix especially in developing countries characterised by insufficient mains power supply. In this paper, we report how we were able to intuitively use basic electronic components to implement an efficient automatic change over switch. In the event of a power failure from the mains supply, this automatic changeover is designed and constructed to switch on a standby generator and transfer the installation load to it (the generator) and vice versa when power is restored. The switching time was calculated and tested to be about 0.88 ms which is sufficient to prevent any noticeable disruption in the power supply to the installation load, whether home or industrial.
自动转换开关的持续发展是能源组合原则的必要要求,尤其是在主电源供应不足的发展中国家。在本文中,我们报告了我们如何能够直观地使用基本的电子元件来实现高效的自动切换开关。在主电源出现电力故障的情况下,这种自动切换的设计和构造是为了打开备用发电机,并在电力恢复时将安装负载转移到它(发电机),反之亦然。经过计算和测试,开关时间约为0.88ms,这足以防止对安装负载(无论是家庭还是工业)的电力供应出现任何明显中断。
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引用次数: 3
期刊
British journal of applied science & technology
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