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Thermal Conversion of Waste Plastics (HDPE, PP and PS) to Produce Mixture of Hydrocarbons 废塑料(HDPE, PP和PS)热转化生产碳氢化合物混合物
Pub Date : 2012-12-01 DOI: 10.5923/J.AJEE.20120205.03
M. Sarker, M. M. Rashid, M. Molla, Muhammad Sadikur Rahman
Thermal conversion process was applied with three types of waste plastic mixture and waste plastics mixture to liquid hydrocarbon fuel production in present of o xygen under laboratory Labconco fu me hood without adding any kind of catalyst. Utilization of the process described can reduce the impact of waste plastics significantly. Thermal decomposition of the most co mmon plastics such as high density polyethylene (HDPE), polypropylene (PP) and polystyrenes (PS) has been conducted to produces a mixture of hydrocarbons. The thermal process applied of mixed waste plastics using a steel reactor at 25- 430℃ has been investigated. The reactor was connected with standard condensation unit with water circulator system. Waste plastics are broken down into shorter chain hydrocarbon compounds from long chains during the thermal conversion process without adding catalyst or chemical. Produced fuel was analysis by using GC/M S, FT-IR and DSC and fro m GC/MS analysis result showed hydrocarbon chain range C3 to C28 into fuel and produce fuel can be use as feed stock refinery or power plant for electricity generation or can use for internal co mbustion engine.
在不添加任何催化剂的情况下,将三种废塑料混合物和废塑料混合物在实验室Labconco富氧罩下进行热转化工艺,用于无氧条件下的液态烃燃料生产。利用所描述的工艺可以显著减少废塑料的影响。最常见的塑料,如高密度聚乙烯(HDPE),聚丙烯(PP)和聚苯乙烯(PS)的热分解已经进行,以产生碳氢化合物的混合物。研究了混合废塑料在25 ~ 430℃的钢反应器中的热处理过程。反应器与带水循环系统的标准冷凝机组连接。废塑料在热转化过程中由长链分解为短链碳氢化合物,无需添加催化剂或化学品。用GC/M - S、FT-IR和DSC对所得燃料进行了分析,从GC/MS分析结果可以看出,C3 ~ C28烃链范围内的燃料可以作为炼油厂或发电厂的原料发电或内燃机使用。
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引用次数: 17
Biosorption Studies of Cr(VI) Ions from Electroplating Wastewater by Walnut Shell Powder 核桃壳粉对电镀废水中Cr(VI)离子的生物吸附研究
Pub Date : 2012-12-01 DOI: 10.5923/J.AJEE.20120206.07
A. Farhan, N. Salem, A. Al-Dujaili, Akl M. Awwad
Biosorption of Cr(VI) ions from aqueous solutions and electroplating wastewater by walnut shell powder has been investigated in a batch biosorption process. The biosorption of Cr(VI) ions was found to be dependent pH, initial chromiu m ion concentrations, biosorbent dose, contact time and temperature. The experimental equilib riu m biosorption data were analy zed by Lang muir, Freundlich, and Temkin isotherm models. The Lang muir model gave a better fit than the Freundlich and Temkin models. The maximu m biosorption capacity calculated from the Langmu ir isotherm was 138.89 mg/g at optimu m conditions. The kinetic studies indicated that the biosorption process of the chromiu m ions fo llo wed well pseudo-second-order model. The negative values of ∆G o (-3.51 kJ/ mo l) and positive value of ∆H o (12.95 kJ/ mol) revealed that the biosorption process was spontaneous and endothermic. Biosorption process was successfully applied to the treatment of an electroplating wastewater sample, where the concentration of chro miu m (VI) ions, organic materials and COD were effectively reduced. According to the sorption capacity, walnut shell powder considered as an effective, low cost, and environmentally friendly biosorbent for the removal of Cr(VI) ions fro m aqueous solution and electroplating wastewater.
研究了核桃壳粉对水溶液和电镀废水中Cr(VI)离子的生物吸附。Cr(VI)离子的生物吸附与pH、初始浓度、生物吸附剂剂量、接触时间和温度有关。采用Lang muir、Freundlich和Temkin等温线模型分析了生物吸附实验平衡数据。Lang muir模型比Freundlich和Temkin模型拟合得更好。在最佳条件下,由朗木等温线计算得到的最大生物吸附量为138.89 mg/g。动力学研究表明,铬离子的生物吸附过程符合准二阶模型。∆G o为负值(-3.51 kJ/ mol),∆H o为正值(12.95 kJ/ mol),表明生物吸附过程为自发吸热过程。将生物吸附法应用于某电镀废水样品的处理中,有效地降低了铬离子、有机物和COD的浓度。根据核桃壳粉的吸附能力,认为核桃壳粉是一种有效、低成本、环保的生物吸附剂,可用于去除水溶液和电镀废水中的Cr(VI)离子。
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引用次数: 36
Isolation and Screening of Dye Degrading Micro-organisms from the Effluents of Dye and Textile Industries at Surat 苏拉特染料和纺织工业废水中染料降解微生物的分离与筛选
Pub Date : 2012-12-01 DOI: 10.5923/J.AJEE.20120206.02
M. C. Thakur, A. Khan, H. Doshi
Text ile dyes have been used since the Bronze Age. They also constitute a prototype 21 st -century speciality chemicals market. Effluent and soil samp les were collected fro m textile industry at Surat. The pH, temperature, BOD, COD, Nitrate and Nitrite values were co mpared with the values given by the Bureau of Indian Standards. The culture med iu m was designed and standardized in the laboratory for the isolation and degradation of the dyes. Pure cultures were screened on the basis of colony morphology. Three different types of unique cultures were selected and named as isolates S1, S2 & S3. Out of 12 dyes used, isolate S1 showed degradation on the maximu m nu mber of dyes (five) in co mparison to other isolates (isolates S2 and S3). Thus, isolate S1 was used for the further studies. The isolate S1 was used for the study of the amount of dye to be degraded. For this study Red BB dye was chosen. Because, isolate S1 showed maximu m degradation on Red BB dye within less time of incubation in comparison with other dyes. Almost all isolates showed the positive results in some of the biochemical tests. Thus most of the isolates can have the capacity to produce the enzyme tryptophanase, indole production, citrate permease (citrate as carbon and energy source), catalase enzy me, degradation of glucose oxidatively as well as fermentatively, urease, gelatinase, production of acid and gas (allo w to ferment lactose and/or sucrose) and fermentation of sugar, lactose, sucrose, mannitol and glucose. Total cellu lar fatty acids profiling has been considered to be one of the important and ideal tool for identification of microorganis ms. On the basis of fatty acid pro filing of isolate S1 the similarity index indicated as Bacillus cereus GC subgroup A (similarity index 0.825), B. thuringiensis sub sp. israelensis (similarity index 0.552) and for B. thuringiensis sub sp. Kurstakii (similarity index 0.511). The isolate S1 was assumed to be B. cereus GC subgroup A. Thus this isolates can be used to degrade harmful azo dyes utilized by the dye, text ile, paper, in k industries etc.
自青铜器时代以来,人们就开始使用染料。它们也构成了21世纪特种化学品市场的雏形。收集了苏拉特纺织工业的废水和土壤样品。将pH值、温度、BOD、COD、硝酸盐和亚硝酸盐值与印度标准局给出的值进行比较。在实验室设计并标准化了培养基,用于分离和降解染料。根据菌落形态筛选纯培养物。选择三种不同类型的独特培养物,分别命名为分离物S1、S2和S3。在使用的12种染料中,与其他分离物(分离物S2和S3)相比,分离物S1对染料的降解最多(5种)。因此,分离物S1被用于进一步的研究。分离物S1用于染料降解量的研究。本研究选用红色BB染料。因为,与其他染料相比,分离物S1在更短的孵育时间内对红BB染料表现出最大的降解。几乎所有分离株在部分生化试验中均呈阳性。因此,大多数分离株能够产生色氨酸酶、吲哚生产酶、柠檬酸渗透酶(柠檬酸作为碳和能量来源)、过氧化氢酶、氧化降解葡萄糖以及发酵、脲酶、明胶酶、生产酸和气体(允许发酵乳糖和/或蔗糖)以及发酵糖、乳糖、蔗糖、甘露醇和葡萄糖的能力。总细胞脂肪酸谱分析被认为是鉴定微生物ms的重要而理想的工具之一。在分离物S1脂肪酸谱分析的基础上,相似指数显示蜡样芽孢杆菌GC亚群A(相似指数0.825)、苏云金芽孢杆菌以色列亚群(相似指数0.552)和苏云金芽孢杆菌库尔斯塔基亚群(相似指数0.511)。分离物S1被认为是蜡样芽孢杆菌GC亚群a,因此该分离物可用于降解染料、文本、纸张等工业中使用的有害偶氮染料。
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引用次数: 18
Advantages of Trichloro Iso Cyanuric Acid over Commercially Available Liquid Chlorine for Sanitation of Swimming Pools in Nagpur Region 三氯异氰尿酸相对于市售液氯在那格浦尔地区游泳池卫生中的优势
Pub Date : 2012-12-01 DOI: 10.5923/J.AJEE.20120206.05
Lanjewar Prashant S. Smt Radhika, D. Parbat, P. T. Kosankar
This research paper highlights on disinfection and sanitation studies on swimming pools based on several experiments carried out in different swimming pools including water parks in Nagpur and Suburbs. It also suggests practical and effective methods of swimming pool sanitation using TCCA in lieu of existing Liquid chlorine sources. Once implemented, the pool management could have savings potential up to Rs 4,000 per month per ONE Lakh litre capacity pool.
本研究论文重点介绍了游泳池的消毒和卫生研究,该研究基于在那格浦尔和郊区的不同游泳池(包括水上公园)进行的几项实验。提出了用TCCA代替现有液氯源进行泳池卫生的实用有效方法。一旦实施,每个10万升容量的游泳池每月可以节省4000卢比。
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引用次数: 0
Decolorization of Anaerobically Digested Molasses Spentwash by Coagulation 厌氧消化糖蜜渣的混凝脱色研究
Pub Date : 2012-08-31 DOI: 10.5923/J.AJEE.20120201.03
M. Chauhan, A. Dikshit
Treatment of molasses spentwash has always posed a challenge to the environmental engineers. Problem becomes more difficult in the countries like India where more harsh environmental parameters of spentwash on one hand and limitation of treatment cost on the other is crude reality. Inability to grow micro-organisms in undiluted spentwash further limits the options. In this work, various options of coagulation were tried as primary treatment to make spentwash fit for further biological treatment without dilution. Poly aluminium chloride(PAC) was found to be the best coagulant.
糖蜜废料的处理一直是环境工程师面临的一个挑战。在印度这样的国家,问题变得更加困难,一方面是更苛刻的环境参数,一方面是处理成本的限制,这是残酷的现实。无法在未稀释的洗涤液中培养微生物进一步限制了选择。在这项工作中,各种选择的混凝作为初级处理,使废洗适合进一步的生物处理而不稀释。聚氯化铝(PAC)是最佳混凝剂。
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引用次数: 6
Sustainable Electronic Waste Management and Recycling Process 可持续的电子废物管理和回收过程
Pub Date : 2012-08-31 DOI: 10.5923/J.AJEE.20120201.05
S. Chatterjee
Electronics waste is becoming a major global issue. Huge accumulation of e-waste and their recycling through primitive means for extraction of precious metals are real concern in the developing countries due to presence of hazardous materials in e-waste. Recycling of e-waste through appropriate technologies is, however, considered to be a profitable business as the printed circuit boards (PCBs) contain the precious metals (including gold, silver etc.). The present recycling cost in developed country is, however, not viable, and thereby, huge volume of e-waste is being exported to the developing countries like India, China, Brazil etc., where manpower is in-expensive and enforcement of environmental laws is not so stringent. This article has proposed an outsourcing model where equal participation of the organised and unorganised sector is ensured to make the e-waste management business a profitable one. The main motivation of the units in unorganised sector is to extract the precious metals like gold, silver and copper from the printed circuit board (PCB). The unscientific and unhy- gienic methods, used for extracting the metals, are harmful to the workers and the environment. This practice needs to be discouraged by providing alternative earning mechanism of the unorganised operators for the collected materials. In the proposed approach, unorganised operators will concentrate on collection, disassembly, segregation of e-waste, whereas, organised sector will concentrate on processing the PCBs to extract precious metals. The 95-97% of the e-waste by weight contains metal, glass and plastics, which can easily be dissembled and segregated manually without damaging environment; whereas, the rest 3-5% by weight of e-waste actually consists of PCBs/connectors, need environmentally friendly recycling techniques to manage. The major segregated materials from e-waste include metals, glass and plastic parts can be managed through the conventional recycling practices used in municipality waste management by organized smelters and re-processors. The segregated PCB and connectors will be pulverized by professional agency to make homogenous powder and assessment of assay content of the powder will be done to know the worth of the PCBs. Once the right price is decided, unorganised sector can sell the PCBs to the organised recyclers for further process. This approach will allow the organised recyclers to concentrate only on processing PCBs, which requires technologies, specialized skills and expertise. The said approach will eradicate the unhygienic practice prevailing in unorganised units in developing countries and thereby will stop polluting environment, soil, water, and will also protect the health of the worker. Once the outsourced model is established, the recycling of e-waste business will again be viable. It will also ensure the higher yield of metal recovery from e-waste as well as minimum landfill.
电子垃圾正在成为一个重大的全球性问题。由于电子废物中存在有害物质,电子废物的大量积累及其通过原始手段提取贵金属的回收是发展中国家真正关注的问题。然而,通过适当的技术回收电子废物被认为是一项有利可图的业务,因为印刷电路板(pcb)含有贵金属(包括金,银等)。然而,目前发达国家的回收成本是不可行的,因此,大量的电子垃圾被出口到印度、中国、巴西等发展中国家,这些国家的人力成本很高,环境法的执行也不那么严格。本文提出了一种外包模式,确保有组织和无组织部门的平等参与,使电子废物管理业务成为有利可图的业务。无组织部门的单位的主要动机是从印刷电路板(PCB)中提取贵金属,如金,银和铜。金属的提取方法不科学、不卫生,对工人和环境都有危害。需要通过为无组织的经营者提供收集材料的替代收入机制来阻止这种做法。在拟议的方法中,无组织的运营商将专注于收集、拆卸、分离电子废物,而有组织的部门将专注于处理多氯联苯以提取贵金属。按重量计算,95-97%的电子垃圾含有金属、玻璃和塑料,可以很容易地人工拆解和分离,而不会破坏环境;然而,其余3-5%的电子垃圾实际上是由pcb /连接器组成的,需要环保的回收技术来管理。从电子废物中分离出来的主要材料包括金属、玻璃和塑料部件,可以通过有组织的冶炼厂和再加工商在市政废物管理中使用的传统回收做法进行管理。分离的PCB和连接器将由专业机构粉碎,制成均匀的粉末,并对粉末的含量进行评估,以了解PCB的价值。一旦确定了合适的价格,无组织部门可以将pcb出售给有组织的回收商进行进一步处理。这种方法将使有组织的回收商只专注于处理多氯联苯,这需要技术、专业技能和专业知识。上述办法将消除发展中国家无组织单位中普遍存在的不卫生做法,从而将停止污染环境、土壤和水,并将保护工人的健康。一旦外包模式建立起来,电子垃圾回收业务将再次可行。它还将确保从电子垃圾中回收更高的金属产量,以及最少的垃圾填埋。
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引用次数: 53
Experimental Study of Influencing Factors and Kinetics in Catalytic Removal of Methylene Blue with TiO 2 Nanopowder 纳米二氧化钛粉体催化去除亚甲基蓝的影响因素及动力学实验研究
Pub Date : 2012-08-31 DOI: 10.5923/J.AJEE.20120201.01
Marziyeh Salehi, H. Hashemipour, M. Mirzaee
In this research, degradation of methylene blue as a dye pollutant was investigated in the presence of TiO2 nanopowders using photolysis and sonolysis systems separately and simultaneously. Effect of different parameters such as catalyst dosage, initial concentration of dye, UV power, pH and type of catalyst on the removal efficiency was ascertained. The results showed that basic pH is proper for the photocatalytic removal of the dye. Furthermore higher UV power and lower initial concentration of dye leads to higher removal percent. Moreover TiO2 showed more photocatalytic activity than ZnO in the nanopowder form. The experimental kinetic data followed the pseudo-first order model in both photocatlytic and sonophotocatalytic processes but the rate constant of sonophotocatalysis is higher than it at photocatalysis process. Fi- nally the reaction order of the rate law respect to nanocatalyst dosage in photocatalysis process is obtained 1.45. High acti- vation energy of this process shows its high sensitivity to temperature.
在本研究中,研究了TiO2纳米粉末存在下,分别使用光解和声解系统同时降解亚甲基蓝作为染料污染物。考察了催化剂用量、染料初始浓度、UV功率、pH值和催化剂种类等参数对去除率的影响。结果表明,碱性pH适合光催化脱除染料。此外,较高的紫外线功率和较低的染料初始浓度可以提高去除率。此外,纳米粉末形式的TiO2比ZnO表现出更强的光催化活性。光催化和声光催化的实验动力学数据均符合准一级模型,但声光催化的速率常数高于光催化的速率常数。最后得到光催化过程中纳米催化剂用量对反应速率规律的影响顺序为1.45。该工艺活化能高,表明其对温度的敏感性高。
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引用次数: 120
Effects of Some Selected Spices on Some Biochemical Profile of Wister Albino Rats 几种香料对白化病大鼠生化指标的影响
Pub Date : 2012-08-31 DOI: 10.5923/J.AJEE.20120201.02
N. E. O, Igbinobaro O.
The influences on the biochemical profiles by three medicinal plant parts used by pregnant women in the southern part of Nigeria, Tetrapleura tetraptera, Piper guineense, and Xylopia aethiopica were evaluated through a feeding study using Albino Whistar rats. The study revealed that extracts decreased the plasma cholesterol and triglyceride levels in treated rats and is attributable to the presence of hypolipidemic agent in the extracts. This shows that the extracts could reduce cardiovascular risk factor. Also, plasma levels of Potassium statistically decreased in the rats treated with T. tetraptera, P. guineense, and X. Aethiopica. This finding is suggestive of a hypokalaemic effect. Two major liver enzymes, ALT and AST plasma levels significantly decreased in the order X. Aethiopica > T. Tetraptera > P. Guineense and P. Guineense > X. Aethiopica > T. Tetraptera for ALT and AST respectively. These findings suggest effective potential to lower hepatotoxic effects by the spices.
通过对白化惠斯鼠的饲养研究,评价了尼日利亚南部孕妇使用的三种药用植物四胸草(Tetrapleura tetratraptera)、几内亚胡椒(Piper guineense)和埃塞俄比亚木犀(Xylopia aethiopica)对生化指标的影响。研究表明,提取物降低了治疗大鼠血浆胆固醇和甘油三酯水平,这是由于提取物中存在降血脂剂。说明其提取物具有降低心血管危险因素的作用。此外,经四翅虫、几内亚弓形虫和埃塞俄比亚弓形虫治疗的大鼠血浆钾水平也有统计学上的下降。这一发现提示了低钾效应。血浆中两种主要肝酶ALT和AST水平分别显著降低了P. Aethiopica > T. Tetraptera > P. Guineense和P. Guineense > X. Aethiopica > T. Tetraptera。这些发现表明香料具有降低肝毒性作用的有效潜力。
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引用次数: 22
Insights into the Invasiveness of Non-Native Plants under Atmospheric Nitrogen Deposition 大气氮沉降对外来植物入侵的影响
Pub Date : 2012-08-31 DOI: 10.5923/J.AJEE.20110101.03
Cong-yan Wang, Lei Wang, Yan-na Lv, Chuncan Si, Hong-guang Xiao, D. Du
Increasing human activities are causing global changes, such as elevated atmospheric nitrogen deposition and increased biological invasions. Both atmospheric nitrogen deposition and biological invasions are recognized as increasingly prominent features of ecological landscapes throughout the world, and their interactions affect the structure and function of global ecosystems. Thus, there is considerable interest in understanding the mechanism of the invasion of non-native plants under atmospheric nitrogen deposition, specifically in terms of global nitrogen cycling and its potential contribution to the ongoing global change in coming decades. We reviewed the invasiveness of non-native plants under atmospheric nitrogen deposition. We discuss gaps in this research topic in an effort to guide further research.
人类活动的增加正在引起全球变化,例如大气氮沉降增加和生物入侵增加。大气氮沉降和生物入侵是全球生态景观日益突出的特征,它们之间的相互作用影响着全球生态系统的结构和功能。因此,了解非本地植物在大气氮沉降下的入侵机制,特别是在全球氮循环及其对未来几十年全球变化的潜在贡献方面具有相当大的兴趣。本文综述了大气氮沉降下外来植物的入侵。我们讨论了这一研究课题的空白,以努力指导进一步的研究。
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引用次数: 11
Metal Leaching Potential in Coal Fly Ash 粉煤灰中金属浸出电位的研究
Pub Date : 2012-08-31 DOI: 10.5923/J.AJEE.20110101.04
K. Shivpuri, Lokeshappa B., Deepak A. Kulkarni, Anil Kumar Dikshit
Thermal power plants are the major source of electricity generation in India and most of them use pulverized coal as the fuel producing enormous quantities of coal fly ash every year. The method of disposal adopted is by wet sluicing in on-site fly ash ponds. This disposal in the form of dilute slurry has a high potential for leaching into the surrounding soil and groundwater. The coal fly ash contains trace metals like As, Cr, Zn, Cd, etc which are toxic in nature and thus, the wet disposal of coal fly ash has serious environmental concerns. This paper assesses the leaching potential of coal fly ash from six thermal power plants in Maharashtra, India. The maximum leachable quantities of some trace metals present in coal fly ash are computed by a Sequential Extraction Procedure (SEP) and results are compared with values obtained by Toxicity Characteristics Leaching Procedure(TCLP).
火力发电厂是印度发电的主要来源,大多数发电厂使用煤粉作为燃料,每年产生大量的粉煤灰。采用现场粉煤灰池湿式泄水处理。这种以稀浆形式处理的方式极有可能渗入周围的土壤和地下水。粉煤灰中含有As、Cr、Zn、Cd等具有毒性的微量金属,湿法处理粉煤灰具有严重的环境问题。本文评估了印度马哈拉施特拉邦6个火力发电厂煤飞灰的浸出潜力。采用顺序萃取法(SEP)计算了粉煤灰中某些微量金属的最大可浸出量,并与毒性特征浸出法(TCLP)进行了比较。
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引用次数: 26
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American journal of environmental engineering
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