{"title":"Élections régionales en Occitanie, 20-27 juin 2021","authors":"Julien Audemard","doi":"10.3917/blue.002.0054","DOIUrl":"https://doi.org/10.3917/blue.002.0054","url":null,"abstract":"","PeriodicalId":9337,"journal":{"name":"Blue-Green Systems","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89674446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Maria Vitória Ribeiro Gomes, B. P. Battemarco, L. F. Guimarães, A. Oliveira, Victória de Araújo Rutigliani, Felipe Manoel Cabral, Ronan de Oliveira Pereira Bezerra, Ianic Bigate Lourenço, O. Rezende, P. Magalhães, M. Miguez, A. P. Veról
This article investigates how to make the implementation of blue-green infrastructure (BGI) more attractive to solve urban problems in densely occupied watersheds that lack flood control and environmental quality protection infrastructure. Considering the obstacles related to implementing multifunctional solutions in developing countries, measuring its co-benefits (in addition to flood control) may influence greater public and political acceptance. Thus, the paper uses a multifunctional design approach using the urban open space system and combining the blue-green and gray infrastructure. A hydrodynamic model was used to support flood mapping. This approach also increases the land value and the environmental quality of the urban spaces. Two quantitative aspects support this evaluation. The first one represents the land value increase as a positive effect, while the second one assesses the environmental quality of the urban space using the Environmental Quality Assessment Index (EQAI). The results obtained from the urban and environmental evaluation proved that blue and green corridors could promote multiple co-benefits for consolidated urban areas. The increased environmental quality and land value were only possible due to the combined use of BGI and gray infrastructure since BGI can add benefits that the gray infrastructure is not capable of providing.
{"title":"The use of blue-Green infrastructure as a multifunctional approach to watersheds with socio-environmental vulnerability","authors":"Maria Vitória Ribeiro Gomes, B. P. Battemarco, L. F. Guimarães, A. Oliveira, Victória de Araújo Rutigliani, Felipe Manoel Cabral, Ronan de Oliveira Pereira Bezerra, Ianic Bigate Lourenço, O. Rezende, P. Magalhães, M. Miguez, A. P. Veról","doi":"10.2166/bgs.2021.119","DOIUrl":"https://doi.org/10.2166/bgs.2021.119","url":null,"abstract":"\u0000 This article investigates how to make the implementation of blue-green infrastructure (BGI) more attractive to solve urban problems in densely occupied watersheds that lack flood control and environmental quality protection infrastructure. Considering the obstacles related to implementing multifunctional solutions in developing countries, measuring its co-benefits (in addition to flood control) may influence greater public and political acceptance. Thus, the paper uses a multifunctional design approach using the urban open space system and combining the blue-green and gray infrastructure. A hydrodynamic model was used to support flood mapping. This approach also increases the land value and the environmental quality of the urban spaces. Two quantitative aspects support this evaluation. The first one represents the land value increase as a positive effect, while the second one assesses the environmental quality of the urban space using the Environmental Quality Assessment Index (EQAI). The results obtained from the urban and environmental evaluation proved that blue and green corridors could promote multiple co-benefits for consolidated urban areas. The increased environmental quality and land value were only possible due to the combined use of BGI and gray infrastructure since BGI can add benefits that the gray infrastructure is not capable of providing.","PeriodicalId":9337,"journal":{"name":"Blue-Green Systems","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2021-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49375178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Phosphorus circulation in Taihu Lake has attracted extensive attention, but the contribution of Microcystis to phosphorus circulation in this area is unknown. In this study, the phosphorus concentrations in algal samples collected from the lake in 2015–2016 were determined in the laboratory. From the concentration data, the total quantity of algal phosphorus was calculated and the seasonal variations in algal phosphorus were examined. The results indicated that the intracellular phosphorus content of Microcystis in Taihu varied from 0.044 to 0.130 pg/cell and tended to be high in spring and low in summer. The total amount of algal phosphorus in Taihu Lake ranged between 7.78 and 97.32 t over the study period. Algal phosphorus only accounted for between 1.5 and 18.5% of the phosphorus stock in the water. Because Microcystis accumulated downwind, there was a tendency for the total phosphorus concentrations to be low in the east of the lake and high in the west of the lake. This new information about the spatial and temporal distribution of algal phosphorus contributes to our understanding of how phosphorus in Microcystis contributes to phosphorus circulation in Taihu Lake.
{"title":"Spatial and temporal variations in algal phosphorus in Taihu Lake","authors":"Yu Zhang, Wei Zhu, Ruochen Wang, G. Feng, Zongpu Xue, Shuai Zhao, Yiyan Lv","doi":"10.2166/bgs.2021.013","DOIUrl":"https://doi.org/10.2166/bgs.2021.013","url":null,"abstract":"\u0000 Phosphorus circulation in Taihu Lake has attracted extensive attention, but the contribution of Microcystis to phosphorus circulation in this area is unknown. In this study, the phosphorus concentrations in algal samples collected from the lake in 2015–2016 were determined in the laboratory. From the concentration data, the total quantity of algal phosphorus was calculated and the seasonal variations in algal phosphorus were examined. The results indicated that the intracellular phosphorus content of Microcystis in Taihu varied from 0.044 to 0.130 pg/cell and tended to be high in spring and low in summer. The total amount of algal phosphorus in Taihu Lake ranged between 7.78 and 97.32 t over the study period. Algal phosphorus only accounted for between 1.5 and 18.5% of the phosphorus stock in the water. Because Microcystis accumulated downwind, there was a tendency for the total phosphorus concentrations to be low in the east of the lake and high in the west of the lake. This new information about the spatial and temporal distribution of algal phosphorus contributes to our understanding of how phosphorus in Microcystis contributes to phosphorus circulation in Taihu Lake.","PeriodicalId":9337,"journal":{"name":"Blue-Green Systems","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2021-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46254446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tamer Almaaitah, Madison Appleby, Howard Rosenblat, J. Drake, D. Joksimovic
Blue-Green Infrastructure (BGI) consists of natural and semi-natural systems implemented to mitigate climate change impacts in urban areas, including elevated air temperatures and flooding. This study is a state-of-the-art review that presents recent research on BGI by identifying and critically evaluating published studies that considered urban heat island mitigation and stormwater management as potential benefits. Thirty-two records were included in the review, with the majority of studies published after 2015. Findings indicate that BGI effectively controls urban runoff and mitigates urban heat, with the literature being slightly more focused on stormwater management than urban heat island mitigation. Among BGI, the studies on blue- and blue-green roofs focused on one benefit at a time (i.e. thermal or hydrologic performance) and did not consider promoting multiple benefits simultaneously. Two-thirds of the selected studies were performed on a large urban scale, with computer modelling and sensor monitoring being the predominant assessment methods. Compared with typical Green Infrastructure (GI), and from a design perspective, many crucial questions on BGI performance, particularly on smaller urban scales, remain unanswered. Future research will have to continue to explore the performance of BGI, considering the identified gaps.
{"title":"The potential of blue-Green infrastructure as a climate change adaptation strategy: a systematic literature review","authors":"Tamer Almaaitah, Madison Appleby, Howard Rosenblat, J. Drake, D. Joksimovic","doi":"10.2166/bgs.2021.016","DOIUrl":"https://doi.org/10.2166/bgs.2021.016","url":null,"abstract":"\u0000 Blue-Green Infrastructure (BGI) consists of natural and semi-natural systems implemented to mitigate climate change impacts in urban areas, including elevated air temperatures and flooding. This study is a state-of-the-art review that presents recent research on BGI by identifying and critically evaluating published studies that considered urban heat island mitigation and stormwater management as potential benefits. Thirty-two records were included in the review, with the majority of studies published after 2015. Findings indicate that BGI effectively controls urban runoff and mitigates urban heat, with the literature being slightly more focused on stormwater management than urban heat island mitigation. Among BGI, the studies on blue- and blue-green roofs focused on one benefit at a time (i.e. thermal or hydrologic performance) and did not consider promoting multiple benefits simultaneously. Two-thirds of the selected studies were performed on a large urban scale, with computer modelling and sensor monitoring being the predominant assessment methods. Compared with typical Green Infrastructure (GI), and from a design perspective, many crucial questions on BGI performance, particularly on smaller urban scales, remain unanswered. Future research will have to continue to explore the performance of BGI, considering the identified gaps.","PeriodicalId":9337,"journal":{"name":"Blue-Green Systems","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2021-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42283431","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In recent years, sponge city has been booming in China aiming to alleviate urban flooding and improve water quality of natural water bodies. LID/green infrastructure has been gradually introduced to urban planning and urban water system planning. Efficient deployment of LID facilities is critical, which requires modeling and evaluation to develop rational planning. A case study of Guian New Area was presented to show the application of SWMM and the planning methods in sponge-city-based urban water system planning for water quality sensitive new areas development. Based on SWMM, two river network water quality models, the Dongmenqiao River and the Chetian River, were established through a systematic analysis of the case study area. Baseline scenarios were simulated and analyzed, and assimilation capacities of the two river basins were calculated by a trial-and-error method. Finally, two LID scenarios were carefully designed, simulated, and analyzed to support the planning. The simulations showed that in order to meet the strict water quality requirements in Guian New Area, large scales of LID facilities are required to cut down the rainfall-runoff pollution. Moreover, measures such as more frequent cleaning to reduce pollutants accumulation on the ground should also be taken to mitigate the maximum buildups of pollutants.
{"title":"Sponge-city-based urban water system planning: a case study of water quality sensitive new area development in China","authors":"Yijian Xu, Yanhong Kong","doi":"10.2166/bgs.2021.022","DOIUrl":"https://doi.org/10.2166/bgs.2021.022","url":null,"abstract":"\u0000 In recent years, sponge city has been booming in China aiming to alleviate urban flooding and improve water quality of natural water bodies. LID/green infrastructure has been gradually introduced to urban planning and urban water system planning. Efficient deployment of LID facilities is critical, which requires modeling and evaluation to develop rational planning. A case study of Guian New Area was presented to show the application of SWMM and the planning methods in sponge-city-based urban water system planning for water quality sensitive new areas development. Based on SWMM, two river network water quality models, the Dongmenqiao River and the Chetian River, were established through a systematic analysis of the case study area. Baseline scenarios were simulated and analyzed, and assimilation capacities of the two river basins were calculated by a trial-and-error method. Finally, two LID scenarios were carefully designed, simulated, and analyzed to support the planning. The simulations showed that in order to meet the strict water quality requirements in Guian New Area, large scales of LID facilities are required to cut down the rainfall-runoff pollution. Moreover, measures such as more frequent cleaning to reduce pollutants accumulation on the ground should also be taken to mitigate the maximum buildups of pollutants.","PeriodicalId":9337,"journal":{"name":"Blue-Green Systems","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2021-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42060912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Strategic placement of water-sensitive urban design (WSUD) is essential in optimising its performance and maximising co-benefits. However, little is known about the current placement and interconnectedness between WSUD assets and the performance of current planning strategies. We evaluated the placement of existing WSUDs in a highly urbanised catchment in Sydney, Australia. We used a three-step process: (1) compiling a comprehensive spatial asset database, (2) performing spatial correlation analysis between asset locations and biophysical, urban form and socioeconomic variables and (3) using a novel approach to facilitate holistic understanding through analysing asset locations compared with the outcome of the spatial suitability analysis tool (SSANTO). WSUD coverage was generally low, with clustering in some municipalities. Placement was constrained by physical variables, such as slope, limited space and varying land uses. However, placement was not detectably influenced by most socioeconomic variables. SSANTO's suitability score at asset locations was only slightly higher than average, suggesting that the placement of existing WSUD was opportunistic, rather than strategically planned. Further development and implementation of tools able to account for spatial constraints will help guide future WSUD placement as a component of green urban stormwater management.
{"title":"Are we planning blue-green infrastructure opportunistically or strategically? Insights from Sydney, Australia","authors":"M. Kuller, David J. Reid, V. Prodanovic","doi":"10.2166/bgs.2021.023","DOIUrl":"https://doi.org/10.2166/bgs.2021.023","url":null,"abstract":"\u0000 Strategic placement of water-sensitive urban design (WSUD) is essential in optimising its performance and maximising co-benefits. However, little is known about the current placement and interconnectedness between WSUD assets and the performance of current planning strategies. We evaluated the placement of existing WSUDs in a highly urbanised catchment in Sydney, Australia. We used a three-step process: (1) compiling a comprehensive spatial asset database, (2) performing spatial correlation analysis between asset locations and biophysical, urban form and socioeconomic variables and (3) using a novel approach to facilitate holistic understanding through analysing asset locations compared with the outcome of the spatial suitability analysis tool (SSANTO). WSUD coverage was generally low, with clustering in some municipalities. Placement was constrained by physical variables, such as slope, limited space and varying land uses. However, placement was not detectably influenced by most socioeconomic variables. SSANTO's suitability score at asset locations was only slightly higher than average, suggesting that the placement of existing WSUD was opportunistic, rather than strategically planned. Further development and implementation of tools able to account for spatial constraints will help guide future WSUD placement as a component of green urban stormwater management.","PeriodicalId":9337,"journal":{"name":"Blue-Green Systems","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2021-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45497557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jiayu Chen, Tianjiao Dai, Z. Lei, K. Shimizu, Donghui Wen, Zhenya Zhang
Given that long-term treated wastewater discharge may alter the microbial community of the recipient coast, it is important to evaluate whether and how the community's stability is impacted. We constructed microcosms using coastal sediments with (near-coast) and without (far-coast) a wastewater disposal history and compared the communities’ responses to p-chloroaniline (PCAN, a typical organic pollutant) in low (10 mg/L) and high (100 mg/L) concentrations. Compared to the far-coast community, the near-coast community drove faster PCAN attenuation and nitrate generation. More significant negative correlations were observed between the alpha-diversity indices and PCAN concentrations in the far-coast communities than the near-coast ones. The community turnover rate, represented by the slopes of the time–decay curves, was slower for the near-coast community (−0.187) than that for the far-coast community (−0.233), but only when the PCAN was added in low concentration. Our study revealed that the long-term wastewater disposal may cause the sediment bacterial community to be less sensitive and more stable in response to a future disturbance, demonstrating a significant historical effect of environmental context on the coastal microbial community's stability.
{"title":"Historical exposure to wastewater disposal reinforces the stability of sediment bacterial community in response to future disturbance","authors":"Jiayu Chen, Tianjiao Dai, Z. Lei, K. Shimizu, Donghui Wen, Zhenya Zhang","doi":"10.2166/bgs.2021.017","DOIUrl":"https://doi.org/10.2166/bgs.2021.017","url":null,"abstract":"\u0000 Given that long-term treated wastewater discharge may alter the microbial community of the recipient coast, it is important to evaluate whether and how the community's stability is impacted. We constructed microcosms using coastal sediments with (near-coast) and without (far-coast) a wastewater disposal history and compared the communities’ responses to p-chloroaniline (PCAN, a typical organic pollutant) in low (10 mg/L) and high (100 mg/L) concentrations. Compared to the far-coast community, the near-coast community drove faster PCAN attenuation and nitrate generation. More significant negative correlations were observed between the alpha-diversity indices and PCAN concentrations in the far-coast communities than the near-coast ones. The community turnover rate, represented by the slopes of the time–decay curves, was slower for the near-coast community (−0.187) than that for the far-coast community (−0.233), but only when the PCAN was added in low concentration. Our study revealed that the long-term wastewater disposal may cause the sediment bacterial community to be less sensitive and more stable in response to a future disturbance, demonstrating a significant historical effect of environmental context on the coastal microbial community's stability.","PeriodicalId":9337,"journal":{"name":"Blue-Green Systems","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2021-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42749636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wenwen Chen, Huan-fang Huang, Haixiang Li, Jianhua Cao, Qiang Li, Yingjie Chen, B. Bai, H. Zeng
Carbonate bedrock regions represent that 14% of Earth's continental surface and carbon (C) sink in karst water plays an important role in the global C cycle due to the CO2 consumption during carbonate mineral weathering. Intensive agriculture and urbanization have led to the excessive input of nitrogen (N) into aquatic systems, while the high concentrations of inorganic C in the karst water might affect the N cycle. This paper summarized the characteristics of water in karst regions and discussed the N transformation coupled with the C cycle in the condition of high Ca2+ content, high pH, and high C/N ratios. Carbonates can consume more atmospheric and pedologic CO2 than non-carbonates because of their high solubility and high rate of dissolution, resulting in the higher average CO2 sink in karst basins worldwide than that in non-karst basins. Therefore, carbonate mineral weathering and aquatic photosynthesis are the two dominant ways of CO2 absorption, which are termed as coupled carbonate weathering. As the alkalinity and high C/N content of karst water inhibit the denitrification and mineralization processes, the karst aquatic environment is also served as the N sink.
{"title":"Coupled nitrogen transformation and carbon sink in the karst aquatic system: a review","authors":"Wenwen Chen, Huan-fang Huang, Haixiang Li, Jianhua Cao, Qiang Li, Yingjie Chen, B. Bai, H. Zeng","doi":"10.2166/bgs.2021.120","DOIUrl":"https://doi.org/10.2166/bgs.2021.120","url":null,"abstract":"\u0000 Carbonate bedrock regions represent that 14% of Earth's continental surface and carbon (C) sink in karst water plays an important role in the global C cycle due to the CO2 consumption during carbonate mineral weathering. Intensive agriculture and urbanization have led to the excessive input of nitrogen (N) into aquatic systems, while the high concentrations of inorganic C in the karst water might affect the N cycle. This paper summarized the characteristics of water in karst regions and discussed the N transformation coupled with the C cycle in the condition of high Ca2+ content, high pH, and high C/N ratios. Carbonates can consume more atmospheric and pedologic CO2 than non-carbonates because of their high solubility and high rate of dissolution, resulting in the higher average CO2 sink in karst basins worldwide than that in non-karst basins. Therefore, carbonate mineral weathering and aquatic photosynthesis are the two dominant ways of CO2 absorption, which are termed as coupled carbonate weathering. As the alkalinity and high C/N content of karst water inhibit the denitrification and mineralization processes, the karst aquatic environment is also served as the N sink.","PeriodicalId":9337,"journal":{"name":"Blue-Green Systems","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2021-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41299545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yan Tian, Guifeng Liu, Ying-xia Gao, Yaru Wang, Jun Zhang, Yali Fang, Zongqiang Zhu, H. Deng
Arsenic pollution prevails in rivers and reservoirs in nonferrous metal mining areas, especially in lead–zinc mining areas, which affects the health of the people residing in such areas. Arsenic usually exists as As(III) and As(V) in water, and the adsorption of As(III) and As(V) changes with the type of adsorbent used. In this work, we report a novel adsorbent Fe/Mn–CO3-layered double hydroxide (Fe/Mn–CO3-LDH) composite that can efficiently remove both As(III) and As(V) from water. When the initial concentrations of As(III) and As(V) were 5, 10 and 50 mg/L, the adsorption capacities were 10.12–53.90 and 10.82–48.24 mg/g in the temperature range of 25–45 °C, respectively. The adsorption kinetics conformed well to the pseudo-second-order kinetic model, with all of the fitted correlation coefficients being above 0.998 for all the three initial concentrations (5, 10 and 50 mg/L) tested, suggesting a chemisorption-dominated process. The adsorption isotherms of As(III) and As(V) by Fe/Mn–CO3-LDHs conformed better to the Freundlich model than to the Langmuir one, indicating a heterogeneous reversible adsorption process. The theoretical maximum adsorption capacity increased with the increase in temperature. During adsorption, As(III) was partially converted to As(V), which was further interacted with intralayer anions. While the electrostatic attraction played an important role in the adsorption of As(V).
{"title":"Comparative study on As(III) and As(V) adsorption by CO32--intercalated Fe/Mn-LDHs from aqueous solution","authors":"Yan Tian, Guifeng Liu, Ying-xia Gao, Yaru Wang, Jun Zhang, Yali Fang, Zongqiang Zhu, H. Deng","doi":"10.2166/bgs.2021.010","DOIUrl":"https://doi.org/10.2166/bgs.2021.010","url":null,"abstract":"\u0000 Arsenic pollution prevails in rivers and reservoirs in nonferrous metal mining areas, especially in lead–zinc mining areas, which affects the health of the people residing in such areas. Arsenic usually exists as As(III) and As(V) in water, and the adsorption of As(III) and As(V) changes with the type of adsorbent used. In this work, we report a novel adsorbent Fe/Mn–CO3-layered double hydroxide (Fe/Mn–CO3-LDH) composite that can efficiently remove both As(III) and As(V) from water. When the initial concentrations of As(III) and As(V) were 5, 10 and 50 mg/L, the adsorption capacities were 10.12–53.90 and 10.82–48.24 mg/g in the temperature range of 25–45 °C, respectively. The adsorption kinetics conformed well to the pseudo-second-order kinetic model, with all of the fitted correlation coefficients being above 0.998 for all the three initial concentrations (5, 10 and 50 mg/L) tested, suggesting a chemisorption-dominated process. The adsorption isotherms of As(III) and As(V) by Fe/Mn–CO3-LDHs conformed better to the Freundlich model than to the Langmuir one, indicating a heterogeneous reversible adsorption process. The theoretical maximum adsorption capacity increased with the increase in temperature. During adsorption, As(III) was partially converted to As(V), which was further interacted with intralayer anions. While the electrostatic attraction played an important role in the adsorption of As(V).","PeriodicalId":9337,"journal":{"name":"Blue-Green Systems","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2021-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49236179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study examined the effects of two substrates (SOIL and COMMERCIAL) and grass on the green roof runoff quality in Singapore. Ten events were sampled over a 9-month period. Rainfall and green roof runoff from grass and bare experimental configurations were tested for total organic carbon (TOC), nitrogen and phosphorus nutrients (N, NH4+-N and PO43−-P), cations/anions and trace metals (Fe, Cu, Zn, Cd and Pb). All configuration units neutralised acid rainfall and removed metals except Fe despite their proximity to an industrial area. Concentrations decrease over the monitoring period for most water quality variables. The COMMERCIAL (COM) configurations elevated Cl− (3.8–10.8 ppm), SO42− (1.5–32.4 ppm), NO3−-N (7.8–75.6 ppm) and NH4+-N (22.0–53.1 ppm) concentrations in the runoff. Concentrations of NO3−-N (4.5–67.7 ppm) and NH4+-N (14.7–53.0 ppm) remained high at the end of the monitoring period for the COMgrass configuration, even with dilution from monsoon rainfall, making it suitable as an irrigation water source and a fertiliser substitute. The SOIL substrate retained N-nutrients, TOC and trace metals with concentrations comparable or below rainfall inputs. This substrate is suitable for widespread green roof applications in Singapore and other tropical cities. We recommend substrate testing before their approval for use on green roofs and encourage the long-term monitoring of these systems.
{"title":"Water quality impacts of young green roofs in a tropical city: a case study from Singapore","authors":"H. Lim, E. Segovia, A. Ziegler","doi":"10.2166/bgs.2021.007","DOIUrl":"https://doi.org/10.2166/bgs.2021.007","url":null,"abstract":"\u0000 This study examined the effects of two substrates (SOIL and COMMERCIAL) and grass on the green roof runoff quality in Singapore. Ten events were sampled over a 9-month period. Rainfall and green roof runoff from grass and bare experimental configurations were tested for total organic carbon (TOC), nitrogen and phosphorus nutrients (N, NH4+-N and PO43−-P), cations/anions and trace metals (Fe, Cu, Zn, Cd and Pb). All configuration units neutralised acid rainfall and removed metals except Fe despite their proximity to an industrial area. Concentrations decrease over the monitoring period for most water quality variables. The COMMERCIAL (COM) configurations elevated Cl− (3.8–10.8 ppm), SO42− (1.5–32.4 ppm), NO3−-N (7.8–75.6 ppm) and NH4+-N (22.0–53.1 ppm) concentrations in the runoff. Concentrations of NO3−-N (4.5–67.7 ppm) and NH4+-N (14.7–53.0 ppm) remained high at the end of the monitoring period for the COMgrass configuration, even with dilution from monsoon rainfall, making it suitable as an irrigation water source and a fertiliser substitute. The SOIL substrate retained N-nutrients, TOC and trace metals with concentrations comparable or below rainfall inputs. This substrate is suitable for widespread green roof applications in Singapore and other tropical cities. We recommend substrate testing before their approval for use on green roofs and encourage the long-term monitoring of these systems.","PeriodicalId":9337,"journal":{"name":"Blue-Green Systems","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2021-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45654055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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