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Mechanistic influence of water chemistry on cement hydration through acidity–alkalinity interactions governing strength and durability 水化学通过酸碱相互作用调控水泥强度和耐久性对水泥水化的机理影响
IF 6.6 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2026-01-05 DOI: 10.1016/j.cscm.2026.e05758
Anurag Angoth , Reddy Babu Gude , Srinivasulu Vemu
The chemical composition of mixing water plays a critical yet often overlooked role in governing cement hydration, microstructure formation, and long-term durability. This study systematically investigates the influence of water chemistry covering acidic (S2), bicarbonate (S3), hydroxide (S4), and saline (S5) waters against potable control (S1) on the performance of ordinary Portland cement-based mortar and concrete. Experimental evaluation included fresh properties, mechanical strength, pore solution pH evolution, transport properties and microstructural characterization using SEM–EDS. Results revealed that water chemistry significantly altered hydration kinetics and matrix densification. Acidic water (S2) delayed setting and caused strength reductions exceeding 30 % relative to control, whereas hydroxide-rich water (S4) accelerated hydration, yielding the highest 90-day compressive (47 MPa) and flexural (6 MPa) strengths. Pore solution analysis confirmed stable alkalinity for S4 and S1 (pH > 12.3 at 365 days), moderate decline for S3 (12.5 → 12.0), and severe depletion for S2 and S5 (11.9 → 11.1 and 12.1 → 11.4). Correspondingly, carbonation depth increased from 5 mm (S1) to 12 mm (S2), while S4 remained lowest (< 3 mm). Hydroxide alkalinity produced the densest microstructure (porosity < 7 %, absorption 2.3 %), whereas acidic and saline systems exceeded 12 % porosity and 5 % absorption. Chloride profiling further confirmed that S4 limited chloride ingress (< 0.1 % by cement mass at 30 mm depth) compared with S5, which surpassed corrosion thresholds (> 0.45 %). SEM–EDS observations validated these trends: hydroxide-rich mixes exhibited compact C–S–H morphology, while acidic and saline waters induced microcracking, carbonate precipitation, and salt crystallization. Findings confirm that pH alone cannot define water suitability for concrete. Instead, the combined effects of mineral acidity, CO₂ acidity, and hydroxide/bicarbonate alkalinity govern hydration efficiency, pore stability, and long-term durability providing essential criteria for using non-potable or recycled waters in sustainable construction.
混合水的化学成分在控制水泥水化、微观结构形成和长期耐久性方面起着至关重要的作用,但往往被忽视。本研究系统地研究了酸性水(S2)、碳酸氢盐水(S3)、氢氧化物水(S4)和盐水(S5)对普通硅酸盐水泥基砂浆和混凝土性能的影响。实验评价包括新鲜性能、机械强度、孔隙溶液pH演变、输运性能和SEM-EDS显微结构表征。结果表明,水化学显著改变了水化动力学和基质致密化。与对照相比,酸性水(S2)延迟了凝结时间,强度降低超过30% %,而富氢氧化物水(S4)加速了水化,产生了最高的90天压缩强度(47 MPa)和弯曲强度(6 MPa)。孔溶液分析证实,S4和S1的碱度稳定(365天pH >; 12.3), S3的碱度中度下降(12.5→12.0),S2和S5的碱度严重下降(11.9→11.1和12.1→11.4)。相应的,碳酸化深度从5 mm (S1)增加到12 mm (S2), S4最低(3 mm)。氢氧碱化体系产生了最致密的微观结构(孔隙度<; 7 %,吸收率2.3 %),而酸性和盐水体系的孔隙度超过12 %,吸收率超过5 %。氯化物分析进一步证实,与S5相比,S4限制了氯化物的进入(30 mm深度的水泥质量为<; 0.1 %),超过了腐蚀阈值(> 0.45 %)。SEM-EDS观察证实了这些趋势:富含氢氧化物的混合物表现出致密的C-S-H形态,而酸性和盐水会引起微裂化、碳酸盐沉淀和盐结晶。研究结果证实,仅靠pH值不能确定混凝土的适水性。相反,矿物酸度、CO 2酸度和氢氧化物/碳酸氢盐碱度的综合影响决定了水化效率、孔隙稳定性和长期耐久性,这为在可持续建筑中使用非饮用水或循环水提供了基本标准。
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引用次数: 0
Experimental study on the bonding strength of rebars in seawater sea-sand concrete under chloride erosion and freeze–thaw cycles 氯离子侵蚀和冻融循环作用下海水海砂混凝土中钢筋粘结强度试验研究
IF 6.6 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2026-01-03 DOI: 10.1016/j.cscm.2026.e05754
Yao Xiao, Yiwen Qu, Siyuan Wang, Jianghao Liu
This study experimentally investigated the bond behavior between reinforcement and seawater sea-sand concrete (SSC) under the combined actions of chloride-induced corrosion and freeze–thaw (F–T) cycles. The coupled environmental effects were simulated through a slow freezing test and an accelerated electrification corrosion method. In the test program, the number of F–T cycles (0, 15, 25, and 50) and the chloride ion concentrations (3.5 %, 7 %, and 10 %) were used as key environmental variables. The bond–slip behavior between rebars and SSC was then examined by push-out tests, taking into account the F–T cycles, salt solution concentration, rebar type (plain and deformed), and concrete strength grades. The results achieved in this study indicate that the interfacial bond strength between the rebars and SSC decreased with the increase in F-T cycles. After 50 F–T cycles, the bond strength of the specimens was reduced by more than 19 % compared with that of the uncycled specimens. The variation trend of bond properties of specimens under the coupling effect of F-T cycles and chloride corrosion was related to the F-T cycles. The bonding slip strength exhibited a pattern of initial increase followed by a gradual decline with increasing F-T cycles. Finally, A theoretic bond-slip curve between rebars and SSC after chloride salt F-T cycles is proposed and is in good agreement with the experimental results.
试验研究了氯化物腐蚀和冻融循环共同作用下海水海砂混凝土(SSC)与钢筋的粘结行为。通过慢冻结试验和加速电蚀法模拟了环境耦合效应。在测试程序中,以F-T循环次数(0、15、25和50)和氯离子浓度(3.5 %、7 %和10 %)作为关键环境变量。然后,考虑到F-T循环、盐溶液浓度、钢筋类型(普通和变形)以及混凝土强度等级,通过推出试验检查了钢筋与SSC之间的粘结滑移行为。研究结果表明,随着F-T循环次数的增加,钢筋与SSC之间的界面结合强度降低。经过50次F-T循环后,与未循环的试件相比,试件的粘结强度降低了19. %以上。在F-T循环和氯化物腐蚀耦合作用下,试件粘结性能的变化趋势与F-T循环有关。随着F-T循环次数的增加,粘结滑移强度呈现先增加后逐渐下降的规律。最后,提出了氯盐F-T循环作用下钢筋与SSC粘结滑移的理论曲线,该曲线与试验结果吻合较好。
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引用次数: 0
Decoding Roman construction techniques through a multiproxy study of pozzolanic mortars from the Brick Amphitheater of Nola (Campania, Southern Italy) 通过对来自诺拉(意大利南部坎帕尼亚)砖砌圆形剧场的火山灰迫击炮的多代理研究,解读罗马建筑技术
IF 6.6 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2026-01-03 DOI: 10.1016/j.cscm.2026.e05753
Serena Spadavecchia , Giovanna Montesano , Concetta Rispoli , Martina Mercurio , Mario Cesarano , Assunta Campanile , Barbara Liguori , Paola Petrosino , Piergiulio Cappelletti
The long-lasting performance of ancient pozzolanic mortars highlights the advanced expertise of Roman builders. By intentionally mixing lime with specific volcanic materials, like ash or sand, the Romans developed hydraulic mortars and concretes that could harden even underwater and exhibit high mechanical strength. Furthermore, these pozzolanic additives accelerated the setting process via hydraulic reactions, offering a faster alternative to the slow carbonation of pure slaked lime. This study provides the first integrated reconstruction of the technological choices and historical evolution of the Brick Amphitheater of Nola by linking the provenance and compositional variability of volcanic aggregates to its different building phases. Due to the site's complex historical stratigraphy and multiple construction phases, a targeted, non-invasive sampling strategy was adopted. Eighteen bedding mortar samples from the Amphitheater structures and adjoining Late Antique walls were analyzed using an integrated analytical including Polarized Optical Microscopy, X-Ray Powder Diffraction, Field Emission Scanning Electron Microscopy with Energy-Dispersive X-Ray Spectroscopy, Mercury Intrusion Porosimetry, Differential Thermal Analysis and Thermogravimetric Analysis. The research aims to distinguish construction phases and trace the evolution of building techniques by i) identifying the geological provenance of raw materials, ii) analyzing the mortar mix design, and iii) reconstructing the site's chronology. Results confirmed that raw materials were locally sourced, employing aggregates from Somma-Vesuvius district, as well as recycled Neapolitan Yellow Tuff, highlighting the Roman builders' expertise in selecting and combining local volcanic aggregates with hydrated lime to produce natural hydraulic mortars. The observed hydraulicity is attributed to the binder-aggregate interaction, evidenced by reaction rims and the formation of calcium-aluminum-silicate-hydrate (C-A-S-H) gels. Mortars from the Amphitheater structures display optimized binder-aggregate ratios and well-compacted pore networks, contrasting with the greater heterogeneity, increased porosity and mixed aggregate origins of mortars from Late Antique walls. These findings reflect intentional and consistent material selection and formulation, also reflecting chronological and functional evolution of the site.
古代火山灰砂浆的持久性能突出了罗马建筑商的先进技术。罗马人故意将石灰与火山灰或沙子等特定的火山物质混合,开发出了水力砂浆和混凝土,即使在水下也能硬化,并表现出很高的机械强度。此外,这些火山灰添加剂通过水力反应加速了凝固过程,为纯熟石灰缓慢的碳化提供了一个更快的选择。本研究通过将火山聚集物的来源和成分变化与不同的建筑阶段联系起来,首次对诺拉砖砌圆形剧场的技术选择和历史演变进行了综合重建。由于场地复杂的历史地层和多个施工阶段,采用了有针对性的非侵入性采样策略。采用偏光显微镜、x射线粉末衍射、场发射扫描电镜和能量色散x射线光谱学、汞侵入孔隙学、差热分析和热重分析等综合分析方法,对圆形剧场结构和邻近的晚期古董墙的18个层理砂浆样品进行了分析。该研究旨在区分施工阶段,并通过1)确定原材料的地质来源,2)分析砂浆混合设计,3)重建遗址的年代来追踪建筑技术的演变。结果证实,原材料来自当地,采用了索玛-维苏威火山地区的骨料,以及回收的那不勒斯黄色凝灰岩,突出了罗马建筑商在选择和结合当地火山骨料与水合石灰生产天然水力砂浆方面的专业知识。观察到的水力归因于粘合剂-聚集体相互作用,反应边缘和钙-铝-硅酸盐水合物(C-A-S-H)凝胶的形成证明了这一点。圆形剧场结构的砂浆显示出优化的粘结料比和良好的孔隙网络,与晚期古董墙砂浆的更大的异质性、更高的孔隙率和混合骨料来源形成对比。这些发现反映了有意和一致的材料选择和配方,也反映了遗址的时间和功能演变。
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引用次数: 0
Manganese zinc ferrite composite graphene oxide improves the macroscopic and microscopic properties of cement paste 锰锌铁氧体复合氧化石墨烯改善了水泥浆体的宏观和微观性能
IF 6.6 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2026-01-02 DOI: 10.1016/j.cscm.2025.e05751
Suhui Yu , Aoyang Li , Jian Yuan , Zhaoguang Li , Yan Wang , Shaohui Zhang
Graphene oxide (GO) had great potential in improving the performance of cement-based materials. However, the strong interaction between GO sheets was easy to cause agglomeration, which seriously limited the full play of its enhancement effect. To address this issue, this study proposed a novel strategy using manganese-zinc ferrite (MZF) to assist the dispersion of GO, aiming to solve the key problems of uneven dispersion and poor stability of GO in cement-based materials. In this study, MZF@GO materials with different composite ratios (MZF: GO = 2:1, 5:1, 10:1) were prepared. The dispersion behavior of MZF@GO was discussed. The effects of MZF@GO on the hydration process, macroscopic properties, and microstructure of cement composites were systematically studied. The results showed that MZF formed strong interfacial bonding with GO through chemical coordination, exhibiting excellent dispersion stability in simulated cement pore solution. After adding cement, MZF@GO accelerated the hydration heat release of cement, and the peak heat flow of MZF-5@GO was the highest (2.1 mW/g). Compared with the JZ group (curing 28 days), the compressive strength of MZF-2@GO, MZF-5@GO, and MZF-10@GO samples increased by 9.39 %, 16.18 %, and 8.87 %, respectively, while the flexural strength increased by 22.67 %, 32.86 % and 26.03 %, respectively. Meanwhile, the total porosity of the MZF-5@GO group decreased by about 13.26 %, indicating that the dispersed GO could effectively promote the growth of hydration products and reduce harmful pores, whereas MZF primarily contributed through physical filling. MZF@GO did not significantly reduce the resistivity of cement composites. Overall, MZF served as an effective dispersing medium for GO and provided a new approach for its efficient application in cement-based materials.
氧化石墨烯在改善水泥基材料性能方面具有很大的潜力。然而,氧化石墨烯片间的强相互作用容易造成团聚,严重限制了其增强效果的充分发挥。针对这一问题,本研究提出了一种使用锰锌铁氧体(MZF)辅助氧化石墨烯分散的新策略,旨在解决氧化石墨烯在水泥基材料中分散不均匀和稳定性差的关键问题。本研究制备了不同复合比例(MZF: GO = 2:1, 5:1, 10:1)的MZF@GO材料。讨论了MZF@GO的色散行为。系统研究了MZF@GO对水泥复合材料水化过程、宏观性能和微观结构的影响。结果表明,MZF与GO通过化学配位形成了强界面键合,在模拟水泥孔隙溶液中表现出优异的分散稳定性。加入水泥后,MZF@GO加速了水泥的水化热释放,其中MZF-5@GO的峰值热流最高(2.1 mW/g)。相比生理组(养护28天),MZF-2@GO的抗压强度,MZF-5@GO,和MZF-10@GO样本 %增加了9.39,16.18 %,和8.87 %,分别在挠曲强度增加了22.67 %,分别32.86 %和26.03 %。同时,MZF-5@GO组的总孔隙率降低了约13.26 %,说明分散的氧化石墨烯能够有效地促进水化产物的生长,减少有害孔隙,而MZF主要通过物理填充来贡献。MZF@GO并没有显著降低水泥复合材料的电阻率。综上所述,MZF作为一种有效的氧化石墨烯分散介质,为其在水泥基材料中的高效应用提供了新的途径。
{"title":"Manganese zinc ferrite composite graphene oxide improves the macroscopic and microscopic properties of cement paste","authors":"Suhui Yu ,&nbsp;Aoyang Li ,&nbsp;Jian Yuan ,&nbsp;Zhaoguang Li ,&nbsp;Yan Wang ,&nbsp;Shaohui Zhang","doi":"10.1016/j.cscm.2025.e05751","DOIUrl":"10.1016/j.cscm.2025.e05751","url":null,"abstract":"<div><div>Graphene oxide (GO) had great potential in improving the performance of cement-based materials. However, the strong interaction between GO sheets was easy to cause agglomeration, which seriously limited the full play of its enhancement effect. To address this issue, this study proposed a novel strategy using manganese-zinc ferrite (MZF) to assist the dispersion of GO, aiming to solve the key problems of uneven dispersion and poor stability of GO in cement-based materials. In this study, MZF@GO materials with different composite ratios (MZF: GO = 2:1, 5:1, 10:1) were prepared. The dispersion behavior of MZF@GO was discussed. The effects of MZF@GO on the hydration process, macroscopic properties, and microstructure of cement composites were systematically studied. The results showed that MZF formed strong interfacial bonding with GO through chemical coordination, exhibiting excellent dispersion stability in simulated cement pore solution. After adding cement, MZF@GO accelerated the hydration heat release of cement, and the peak heat flow of MZF-5@GO was the highest (2.1 mW/g). Compared with the JZ group (curing 28 days), the compressive strength of MZF-2@GO, MZF-5@GO, and MZF-10@GO samples increased by 9.39 %, 16.18 %, and 8.87 %, respectively, while the flexural strength increased by 22.67 %, 32.86 % and 26.03 %, respectively. Meanwhile, the total porosity of the MZF-5@GO group decreased by about 13.26 %, indicating that the dispersed GO could effectively promote the growth of hydration products and reduce harmful pores, whereas MZF primarily contributed through physical filling. MZF@GO did not significantly reduce the resistivity of cement composites. Overall, MZF served as an effective dispersing medium for GO and provided a new approach for its efficient application in cement-based materials.</div></div>","PeriodicalId":9641,"journal":{"name":"Case Studies in Construction Materials","volume":"24 ","pages":"Article e05751"},"PeriodicalIF":6.6,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145921673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing tensile strength and microstructural properties of solidified high-moisture dredged sediment through solid waste-based binder stabilization and basalt fiber reinforcement 通过固体废物基粘结剂稳定和玄武岩纤维增强,提高高水分疏浚泥固化物的抗拉强度和微观结构性能
IF 6.6 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2026-01-02 DOI: 10.1016/j.cscm.2025.e05752
Hongwei Wang , Jiahui Zhang , Longjun Dong , Rachid Zentar , Ying Shi , Daoyuan Sun
The study of materials with good mechanical properties for backfilling Urban Underground Spaces (UUS), such as abandoned underground spaces and ground subsidence, has important practical significance for achieving urban safety. A binder developed with solid waste materials was employed to solidify dredged sediment, transforming it into a Liquefied Stabilized Backfill Material (LSBM) for UUS. This study investigates the reinforcing effect of Basalt Fibers (BF) on the Splitting Tensile Strength (STS) behavior of solidified dredged sediment treated with a waste-based binder. A comprehensive experimental program was conducted to assess the influence of BF content, BF length, curing time, initial moisture content, and binder dosage on both STS and stress-strain responses. The results indicate that the optimal BF contents for maximizing STS at 3, 7, and 28 days were 0.1%, 0.1%, and 0.2%, respectively. Meanwhile, the corresponding STS values were 182.20 kPa, 191.98 kPa, and 242.74 kPa, representing STS increases of 120.9%, 65.2%, and 31.3% compared to the solidified sediment without BF. A fiber length of 3 mm yielded the best reinforcing effect on the tensile strength behavior of LSBM, with the STS reaching peak values of 104.47 kPa, 183.12 kPa, and 260.89 kPa at the curing times of 3, 7, and 28 days, respectively. Moreover, BF incorporation significantly improved the ductility of the solidified matrix. A regression model with a high coefficient of determination (R2=0.947) was developed, enabling effective analysis and estimation of STS from the given parameters under comparable conditions. Additionally, a strong linear relationship between the STS and Unconfined Compressive Strength (UCS) for the LSBM samples was established. Microstructural analysis revealed that the BF enhances tensile performance by increasing interfacial friction and filling pores via associated hydration products, thereby facilitating a broader stress distribution within the dense matrix. Additionally, a simplified economic and environmental benefit analysis demonstrated that per 100 kPa of STS, the 28d solidified sediment with 0.2% BF exhibited a 7.3% reduction in cost and a 15.7% reduction in CO2 emissions per ton compared with the solidified sediment backfill material without BF. Overall, the findings of this study demonstrate that BF-reinforced, waste binder-treated dredged sediment presents a technically viable and environmentally sustainable solution for UUS backfilling.
研究具有良好力学性能的城市地下空间(如废弃地下空间和地面沉降)回填材料,对实现城市安全具有重要的现实意义。采用固体废物开发的粘结剂对疏浚后的沉积物进行固化,将其转化为UUS液化稳定回填材料(LSBM)。研究了玄武岩纤维(BF)对废基粘结剂处理的固化疏浚泥沙劈裂抗拉强度(STS)行为的增强作用。采用综合试验方案,评估了BF含量、BF长度、固化时间、初始含水率和粘结剂用量对STS和应力-应变响应的影响。结果表明,发酵第3、7、28 d时,最大限度提高STS的最佳BF添加量分别为0.1%、0.1%、0.2%。相应的STS值分别为182.20 kPa、191.98 kPa和242.74 kPa,分别比未加BF的固化沉积物STS增加了120.9%、65.2%和31.3%。当纤维长度为3 mm时,对LSBM拉伸强度的增强效果最好,在养护3、7和28 d时,STS分别达到104.47 kPa、183.12 kPa和260.89 kPa的峰值。此外,高炉的加入显著提高了固化基体的延展性。建立了具有较高决定系数(R2=0.947)的回归模型,可在可比条件下根据给定参数对STS进行有效分析和估计。此外,建立了LSBM样品的STS与无侧限抗压强度(UCS)之间的强线性关系。微观结构分析表明,BF通过增加界面摩擦和通过相关水化产物填充孔隙来提高拉伸性能,从而促进致密基体内更广泛的应力分布。此外,简化的经济和环境效益分析表明,与不含BF的固化沉积物回填材料相比,每100 kPa的STS,添加0.2% BF的固化沉积物28d的成本降低了7.3%,每吨二氧化碳排放量减少了15.7%。总的来说,这项研究的结果表明,bf增强、废物粘合剂处理的疏浚沉积物为UUS回填提供了一种技术上可行、环境上可持续的解决方案。
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引用次数: 0
Experimental investigation on the restrained shrinkage of internally cured concrete with combined use of superabsorbent polymers, nanosilica and basalt fibers 高吸水聚合物、纳米二氧化硅和玄武岩纤维联合使用内固化混凝土抑制收缩的试验研究
IF 6.6 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2026-01-02 DOI: 10.1016/j.cscm.2025.e05736
Said Mirgan Borito , Zhao Bo , Han Zhu , Yasser E. Ibrahim , Sadi Ibrahim Haruna
Superabsorbent polymers (SAP) are widely used in concrete to mitigate autogenous shrinkage by absorbing and releasing water when internal humidity drops. However, SAP can negatively affect concrete's mechanical properties, particularly compressive strength, due to pore formation after water release. To address this issue, this study systematically investigates the effects of superabsorbent polymers (SAP), nanosilica (NS), and basalt fibers (BF) on the mechanical properties, shrinkage behavior, and cracking resistance of concrete. The addition of NS mitigates the pore formation caused by SAP by enhancing hydration and filling voids, while BF improves tensile strength and crack resistance by bridging microcracks, especially under shrinkage restraint conditions. The experimental program focused on analyzing the performance of concrete mixtures with SAP, NS, and BF, specifically addressing restrained shrinkage and its impact on early-age cracking. The results reveal that SAP significantly reduces shrinkage and delays cracking by providing internal curing, thereby mitigating moisture loss during the early curing phase. However, the addition of SAP was found to decrease compressive strength and modulus of elasticity due to pore formation within the matrix. In contrast, the inclusion of NS and BF compensated for the strength reduction, improving both compressive strength and tensile resistance, as well as providing limiting crack propagation under restraint. The combined incorporation of 0.3 % SAP, 0.9 % NS, and 1.2 % BF (NSBF-ICC mix) demonstrated the best overall performance, offering improved shrinkage resistance and cracking behavior while maintaining mechanical integrity. Specifically, the NSBF-ICC mix exhibited an 11.2 % increase in compressive strength and a 16.8 % improvement in tensile strength compared to the control mix, while also showing a 30 % reduction in shrinkage strain relative to the control mix and a 25 % reduction in shrinkage strain compared to the SAP-only mixture. The synergy between SAP, NS, and BF significantly mitigated the negative effects of SAP alone, providing a balanced solution for internally cured concrete. These findings highlight the potential for optimizing the use of hybrid additive systems to improve concrete durability without compromising strength, offering valuable insights for future research into hybrid cementitious mixtures in applications like concrete pavements and bridge decks that require enhanced durability.
高吸水性聚合物(SAP)广泛应用于混凝土中,通过吸收和释放内部湿度下降时的水分来减缓混凝土的自收缩。然而,由于水释放后孔隙的形成,SAP会对混凝土的力学性能,特别是抗压强度产生负面影响。为了解决这一问题,本研究系统地研究了高吸水聚合物(SAP)、纳米二氧化硅(NS)和玄武岩纤维(BF)对混凝土力学性能、收缩行为和抗裂性的影响。添加NS可以通过增强水化和填充空隙来减轻SAP引起的孔隙形成,而BF通过桥接微裂纹来提高拉伸强度和抗裂性,特别是在收缩约束条件下。该试验项目侧重于分析SAP、NS和BF混合料的混凝土性能,特别是抑制收缩及其对早期开裂的影响。结果表明,SAP通过提供内部固化显著减少收缩和延迟开裂,从而减轻了早期固化阶段的水分损失。然而,SAP的加入降低了抗压强度和弹性模量,这是由于基体内部形成了孔隙。相反,NS和BF的加入弥补了强度的降低,提高了抗压强度和抗拉性能,并在约束下提供了极限裂纹扩展。含有0.3 % SAP、0.9 % NS和1.2 % BF (NSBF-ICC混合料)的复合材料表现出最佳的综合性能,在保持机械完整性的同时提高了抗收缩率和开裂性能。具体来说,与对照混合物相比,NSBF-ICC混合物的抗压强度增加了11. %,抗拉强度提高了16.8 %,同时与对照混合物相比,收缩应变减少了30 %,收缩应变减少了25 %。SAP, NS和BF之间的协同作用显著减轻了SAP单独的负面影响,为内固化混凝土提供了平衡的解决方案。这些发现突出了优化混合添加剂系统使用的潜力,在不影响强度的情况下提高混凝土耐久性,为未来研究混合胶凝混合物在混凝土路面和桥面等需要增强耐久性的应用中提供了有价值的见解。
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引用次数: 0
Experimental investigation on the mechanical performance of 3D-printed concrete-glued laminated timber composite beams 3d打印混凝土-层压木材组合梁力学性能试验研究
IF 6.6 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.cscm.2025.e05749
Xiaoyue Zhang , Zhengren Chen , Xinting Zhou , Zheng Li , Xuhong Zhou
This study presents a novel, reinforcement-free prefabricated composite beam system integrating 3D-printed concrete (3DPC) slabs and glued laminated timber (GLT) beams. The system employs an ultra-high-performance concrete (UHPC)-filled notch-screw shear connector to address the interfacial bonding challenge between the two materials. Push-out tests on the connector demonstrated that its load-bearing capacity and slip stiffness increased with notch depth and length, while the shear length ahead of the notch had a minor influence. For the critical 3DPC-UHPC interface, three failure modes were identified, with performance governed by matrix interlayer properties and interface morphology. The X-interface with an original 3DPC surface was optimal, and adding polyoxymethylene fiber further enhanced performance. Connectors with a vertical printing path showed superior performance, with approximately 8 % higher load capacity than those with a horizontal path. Bending tests on composite beams clarified the influence of cross-sectional mesh configuration and printing material. Beams with a transverse mesh exhibited 28.8 % greater initial stiffness than those with a top-surface mesh. Crucially, the system achieved satisfactory structural performance without traditional steel reinforcement, validating the feasibility of the proposed reinforcement-free, prefabricated approach. Finally, predictions for bending stiffness and interface shear capacity based on the gamma method showed good agreement with experimental values.
本研究提出了一种新型的无钢筋预制组合梁系统,该系统集成了3d打印混凝土(3DPC)板和胶合层压木材(GLT)梁。该系统采用了超高性能混凝土(UHPC)填充的缺口螺钉剪切连接器,以解决两种材料之间的界面粘合问题。对接头的推出试验表明,其承载能力和滑移刚度随缺口深度和长度的增加而增加,而缺口前的剪切长度影响较小。对于临界3DPC-UHPC界面,确定了三种失效模式,其性能受基体层间特性和界面形态的影响。以原始3DPC表面的x界面为最优,添加聚甲醛纤维进一步增强了性能。具有垂直打印路径的连接器表现出优越的性能,其负载能力比具有水平路径的连接器高约8 %。组合梁的弯曲试验阐明了截面网格结构和打印材料对组合梁弯曲性能的影响。采用横向网格的梁的初始刚度比采用顶面网格的梁高28.8 %。关键是,该系统在没有传统钢筋加固的情况下取得了令人满意的结构性能,验证了所提出的无钢筋预制方法的可行性。最后,基于伽玛法的抗弯刚度和界面抗剪承载力预测值与实验值吻合较好。
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引用次数: 0
Seismic performance enhancement of precast bridge pier using ultrahigh-performance concrete jacket 采用超高性能混凝土护套提高预制桥墩抗震性能
IF 6.6 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.cscm.2025.e05750
Jiuhong Fan , Xiuhua Li , Bowen Xiao , Ying Lu , Jin Di , Fengjiang Qin
The application of precast bridge piers is becoming increasingly widespread due to its significant time-saving advantages. To enhance the seismic performance of the bridge piers, ultrahigh-performance concrete (UHPC) jackets was set in the plastic hinge of the precast bridge piers with socket connection. Quasi-static tests were conducted on five specimens to investigate the influence of the height and thickness of the UHPC jacket on the seismic behavior of precast bridge piers. When the UHPC jacket height was too low or the thickness was too great, the plastic hinge region of the pier shifted upward, reducing the ductility and cumulative energy dissipation of the pier, which adversely affected its seismic performance. Based on the numerical analysis results, a bending moment enhancement coefficient was regressed and the dimension design method of UHPC jacket was proposed. This study provides a reference for designing UHPC jackets to enhance the seismic performance of bridge piers.
预制桥墩由于具有显著的省时优势,其应用越来越广泛。为提高桥墩抗震性能,采用承插式连接方式在预制桥墩塑性铰处设置超高性能混凝土护套。通过5个试件的拟静力试验,研究了UHPC护套高度和厚度对预制桥墩抗震性能的影响。当UHPC护套高度过低或厚度过大时,墩台塑性铰区域向上位移,降低了墩台的延性和累积耗能,对其抗震性能产生不利影响。在数值分析结果的基础上,回归了弯矩增强系数,提出了UHPC夹套的尺寸设计方法。该研究为设计提高桥墩抗震性能的超高压混凝土护套提供了参考。
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引用次数: 0
Prediction of the hydration heat, temperature distribution and thermal stress of mass concrete 大体积混凝土水化热、温度分布及热应力预测
IF 6.6 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2025-12-31 DOI: 10.1016/j.cscm.2025.e05748
Guowen Sun , Haorui Zheng , Liguo Wang , Liang Peng , Haitao Yang , Yifan Li
Thermal cracks induced by hydration heat are one of the primary factors affecting the durability of mass concrete structures. To accurately predict the early-age temperature rise and thermal stress of mass concrete, a hydration heat prediction model for Portland cement was established based on the Parrot-Killoh hydration kinetic model, considering the effects of water-cement ratio, cement fineness, relative humidity and temperature. Subsequently, taking the predicted hydration heat as the internal heat source, a finite element analysis model for the temperature and thermal stress fields of mass concrete was constructed. The influence laws of key parameters including water-cement ratio, cement fineness and curing temperature on the core temperature and thermal stress were systematically investigated. The results indicate that reducing the water-cement ratio or using finer cement significantly increases the peak core temperature and peak compressive stress of concrete; an increase in curing temperature accelerates the hydration reaction, raises the peak temperature and reduces the late-age tensile stress. Furthermore, a thermo-mechanical-damage coupled model based on the Mazars damage criterion was employed to simulate the early-age damage evolution process, revealing that damage tends to occur on the surface and edge regions within 24 h after casting. The multi-scale prediction method proposed in this study provides a reliable theoretical tool and engineering reference for temperature control and crack prevention design of mass concrete.
水化热引起的热裂缝是影响大体积混凝土结构耐久性的主要因素之一。为了准确预测大体积混凝土的早期温升和热应力,基于Parrot-Killoh水化动力学模型,考虑水灰比、水泥细度、相对湿度和温度的影响,建立了波特兰水泥水化热预测模型。随后,以预测的水化热为内热源,建立了大体积混凝土温度场和热应力场的有限元分析模型。系统研究了水灰比、水泥细度、养护温度等关键参数对岩心温度和热应力的影响规律。结果表明:降低水灰比或使用细水泥均显著提高混凝土的峰值芯温和峰值压应力;养护温度的升高加速了水化反应,提高了峰值温度,降低了后期拉伸应力。采用基于Mazars损伤准则的热-机-损伤耦合模型模拟了早期损伤演化过程,结果表明,在铸造后24 h内,损伤倾向于发生在表面和边缘区域。本研究提出的多尺度预测方法为大体积混凝土的温控防裂设计提供了可靠的理论工具和工程参考。
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引用次数: 0
Creep failure of alkali activated slag concrete in compression: Effect of loading age and stress level 碱渣混凝土受压蠕变破坏:加载龄期和应力水平的影响
IF 6.6 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2025-12-30 DOI: 10.1016/j.cscm.2025.e05744
Ziyang Zhang , Xianggang Bian , Jianfei Kang , Tengfei Xu
With the rapid advancement of 3D printing, concrete is required to bear significant stress loads during its early-age period. The high stress creep failure behavior is directly associated with the structural stability and build ability requirements of 3D printed concrete elements during layer deposition. Nonlinear creep manifests in concrete subjected to high stresses. This process results in the accumulation of damage, which culminates in creep failure of concrete materials. However, limited information exists on this phenomenon in alkali-activated slag concrete. In this study, the creep failure of alkali-activated slag concrete under high uniaxial stress was investigated, and the creep failure characteristics of alkali-activated slag concrete were obtained. Additionally, the effects of loading age and stress ratio were investigated. The failure mechanism, creep coefficient, and nominal Poisson’s ratio of alkali-activated slag concrete specimens were investigated. Findings indicated that as age increases, the influence of loading age on the nonlinear creep of alkali-activated slag concrete progressively diminishes. Stress levels significantly affect the nonlinear creep of alkali-activated slag concrete. Specifically, when the stress level reached 0.95fc, the alkali-activated slag concrete specimen failed after sustaining the load for a few seconds. During the creep phase, the circumferential creep coefficient and nominal Poisson’s ratio of the specimen exhibited a substantial increase, with the circumferential creep coefficient markedly exceeding the axial creep coefficient. Furthermore, the specimens exhibited significant lateral expansion upon destruction. Non-destructive and crack analyses were conducted to identify the creep-failure mechanism. The creep-failure study indicated that the propagation of microcracks inside the specimen influenced the nonlinear creep and creep-failure characteristics of alkali-activated slag concrete specimens subjected to high sustained compressive stress. The deterioration of the adhesive substance between particles progressively culminated in extensive fractures, which resulted in creep failure.
随着3D打印技术的快速发展,混凝土在早期阶段需要承受较大的应力载荷。高应力蠕变破坏行为直接关系到3D打印混凝土构件在层积过程中的结构稳定性和构建能力要求。混凝土在高应力作用下表现为非线性徐变。这一过程导致损伤的累积,最终导致混凝土材料的蠕变破坏。然而,关于碱活化矿渣混凝土中这种现象的研究资料有限。本研究对高单轴应力作用下碱活化渣混凝土的徐变破坏进行了研究,得出了碱活化渣混凝土的徐变破坏特征。此外,还研究了加载龄期和应力比的影响。对碱活化矿渣混凝土试件的破坏机理、蠕变系数和名义泊松比进行了研究。结果表明:随着龄期的增加,加载龄期对碱渣混凝土非线性徐变的影响逐渐减弱;应力水平对碱渣混凝土的非线性徐变有显著影响。其中,当应力水平达到0.95fc时,碱活化渣混凝土试件在承受荷载数秒后即失效。在蠕变阶段,试件的周向蠕变系数和名义泊松比均显著增大,且周向蠕变系数明显大于轴向蠕变系数。此外,试样在破坏后表现出明显的侧向膨胀。通过无损分析和裂纹分析来确定蠕变破坏机制。蠕变破坏研究表明,高持续压应力作用下碱活化渣混凝土试件内部微裂纹的扩展影响其非线性蠕变和蠕变破坏特性。颗粒间黏附物的劣化逐渐导致大面积断裂,从而导致蠕变破坏。
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引用次数: 0
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Case Studies in Construction Materials
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