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Valorisation of coffee husk as replacement of sand in alkali-activated bricks 用咖啡壳替代碱活性砖中的沙子的价值评估
IF 6.5 2区 工程技术 Q2 Materials Science Pub Date : 2024-06-19 DOI: 10.1016/j.cscm.2024.e03440
Sourav Biswas , Nabil Hossiney , Mothi Krishna Mohan , Srinidhi Lakshmish Kumar

The coffee industry is known to generate voluminous amount of waste during its production process. Different types of waste such as coffee hush ash and spent coffee ground, to name a few, have been extensively researched as a substitute in the construction industry. However, the utilization of coffee husk as a substitute for construction materials has seen limited exploration. In particular, there are no studies which investigate the utilization of waste coffee husk (WCH) in alkali-activated bricks. Therefore, in this research WCH was employed as a substitute to sand in alkali-activated bricks. Alkali-activated bricks were synthesized with ground granulated blast furnace slag (GGBFS), fly ash (FA), sand, and sodium silicate solution (SS). Sand was replaced with WCH at replacement rates of 0 %, 5 %, 10 %, 15 %, 20 %, and 30 % by volume. The developed bricks were evaluated for strength, density, water absorption, porosity, and efflorescence. Additionally, structural and morphological characteristics of bricks were assessed by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Thermogravimetric analysis (TGA), and Scanning electron microscopy (SEM) analysis. The results indicate that bricks with WCH improve the compressive strength with a maximum value of 15.7 MPa, and reduce the density with a minimum value of 1509 kg/m3 for composites with 30 % WCH, respectively. The water absorption and porosity of bricks increased with incorporation of WCH due to porous structure of WCH. The physico-chemical analysis of the bricks shows effective geopolymerization in the composite system with WCH, and further the bricks with 30 % WCH depict thermal stability with insignificant weight loss at 575 ℃. Finally, the composites with 30 % WCH classify as good quality bricks as per IS 1077: 1992 specifications, and this will improve practical feasibility of such materials in the construction industry.

众所周知,咖啡业在生产过程中会产生大量废物。不同类型的废物,如咖啡灰和咖啡渣等,已被广泛研究用作建筑业的替代品。然而,将咖啡渣用作建筑材料替代品的研究还很有限。特别是,还没有任何研究调查了废咖啡渣(WCH)在碱活性砖中的利用情况。因此,在这项研究中,咖啡渣被用作碱活性砖中沙子的替代品。碱活性砖是用磨细高炉矿渣(GGBFS)、粉煤灰(FA)、沙子和硅酸钠溶液(SS)合成的。沙子用 WCH 替代,替代率按体积分别为 0%、5%、10%、15%、20% 和 30%。对开发的砖块进行了强度、密度、吸水性、孔隙率和风化评估。此外,还通过傅立叶变换红外光谱(FTIR)、X 射线衍射(XRD)、热重分析(TGA)和扫描电子显微镜(SEM)分析评估了砖的结构和形态特征。结果表明,添加了 WCH 的砖块可提高抗压强度(最大值为 15.7 MPa),并降低密度(30% WCH 复合材料的密度最小值为 1509 kg/m3)。由于 WCH 的多孔结构,砖的吸水率和孔隙率随着 WCH 的加入而增加。砖块的物理化学分析表明,在含有 WCH 的复合材料体系中,土工聚合效果显著,此外,含有 30% WCH 的砖块在 575 ℃ 下具有热稳定性,重量损失不明显。最后,根据 IS 1077:1992 的规范,含有 30% WCH 的复合材料被列为优质砖,这将提高此类材料在建筑业中的实用性。
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引用次数: 0
Synergistic effects of nano and micro silica on fresh and hardened properties of self-consolidating concrete 纳米和微米二氧化硅对自密实混凝土新拌和硬化性能的协同效应
IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-06-19 DOI: 10.1016/j.cscm.2024.e03443
Saeed Bozorgmehr Nia , Behrouz Shafei

The escalating demand for methods to diminish cement usage without compromising the strength and durability of concrete mixtures has led to an intensified exploration of alternative mixture ingredients. Nano silica has emerged as a prominent supplementary cementitious material, recognized for its capability to partially substitute cement. Despite this potential, there was a gap in the literature on the effects of nano silica on the concrete’s fresh and hardened properties, particularly when used in conjunction with silica fume. This gap motivated the current investigation, aiming to capture and compare the effects of incrementally substituting silica fume with nano silica in self-consolidating concrete (SCC). For this purpose, four nano silica dosages—1%, 2%, 3%, and 5%— were considered as replacements for silica fume. A range of experiments, including slump flow, T50 time, and L-box tests, were conducted to assess the workability of the developed SCC mixtures. Subsequent analyses focused on key mechanical attributes, including the static modulus of elasticity, compressive strength, and tensile strength. The research further encompassed water absorption, penetration depth, and electrical resistivity evaluations to understand the durability characteristics of the developed mixtures. The scanning electron microscopy (SEM) analyses complemented these tests, offering a microstructural perspective to further explain the outcomes. This investigation’s findings offer novel insights into leveraging nano silica’s distinctive properties to achieve the desired SCC properties while reducing the environmental impact of this class of mixtures.

随着人们对在不影响混凝土混合物强度和耐久性的前提下减少水泥用量的方法的需求不断增长,人们开始加强对替代混合物成分的探索。纳米二氧化硅已成为一种重要的胶凝补充材料,其部分替代水泥的能力已得到认可。尽管具有这种潜力,但关于纳米二氧化硅对混凝土新拌和硬化性能的影响,特别是与硅灰一起使用时的影响,文献中还存在空白。这一空白激发了当前的研究,旨在捕捉和比较在自密实混凝土(SCC)中用纳米二氧化硅逐步替代硅灰的效果。为此,我们考虑了四种纳米二氧化硅用量--1%、2%、3% 和 5%--作为硅灰的替代品。为评估所开发的 SCC 混合物的工作性,进行了一系列实验,包括坍落度流动、T50 时间和 L 型箱试验。随后的分析侧重于关键的机械属性,包括静态弹性模量、抗压强度和抗拉强度。研究还包括吸水性、渗透深度和电阻率评估,以了解所开发混合物的耐久性特征。扫描电子显微镜(SEM)分析与这些测试相辅相成,从微观结构的角度进一步解释了测试结果。这项研究的结果为利用纳米二氧化硅的独特性能实现所需的 SCC 特性提供了新的见解,同时减少了这类混合物对环境的影响。
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引用次数: 0
A case study on early-age cracking of high-strength concrete construction by coupled thermal-mechanical analysis and field monitoring 通过热力学耦合分析和现场监测对高强度混凝土建筑早期开裂的案例研究
IF 6.2 2区 工程技术 Q2 Materials Science Pub Date : 2024-06-18 DOI: 10.1016/j.cscm.2024.e03436
Tzu-Han Wen , Terry Y.P. Yuen , Victor K.S. Li , Albert T. Yeung

The use of high-strength concrete (HSC) in constructing high-rise reinforced concrete buildings and their deep foundations is becoming more popular because of the significant reduction in member size and, thus, self-weight in structural members. However, the higher cement content in HSC may result in increased heat of hydration and autogenous shrinkage, growing concerns about forming early-age cracks in HSC structural members. This case study assessed the early-age cracking of HSC in bored pile construction of high-rise buildings. A nonlinear transient coupled thermal-mechanical response analysis was performed to evaluate the potential of early-age cracking caused by the heat of hydration generated in the HSC using ABAQUS and two subprograms, USDFLD and UEXPAN. A 3-D finite element model was developed considering thermal effects, time-dependent evolution of early-age strength and stiffness of HSC, crack strain development, autogenous shrinkage, and stress-relaxation in the analysis. Field measurements were carried out on a 3-m diameter bored pile constructed using Grade C50/60 HSC (fck,cube = 60 MPa) for a high-rise building project in Hong Kong to evaluate the validity of the numerical model. Optical fiber sensors were used to monitor the temperature changes of the pile for approximately 380 hours after casting. The temporal and spatial temperature distributions measured in the field measurements agree well with the simulations. Large thermal gradients and high tensile stress zones were observed across the horizontal cross-sections of the pile, resulting in the formation of vertical annular cracks. Based on the results of the analysis, the maximum crack widths were predicted and compared with the durability crack width limits.

在建造高层钢筋混凝土建筑及其深基础时使用高强度混凝土(HSC)正变得越来越流行,因为这样可以显著减小构件尺寸,从而减轻结构构件的自重。然而,高强混凝土中较高的水泥含量可能会导致水化热和自生收缩的增加,从而增加了对高强混凝土结构构件形成早期裂缝的担忧。本案例研究评估了高层建筑钻孔灌注桩施工中使用的 HSC 早期开裂情况。使用 ABAQUS 和两个子程序 USDFLD 和 UEXPAN 进行了非线性瞬态热-机械耦合响应分析,以评估由 HSC 中产生的水化热引起的早期开裂的可能性。建立的三维有限元模型在分析中考虑了热效应、HSC 早期强度和刚度随时间的变化、裂缝应变发展、自生收缩和应力松弛。在香港的一个高层建筑项目中,使用 C50/60 级 HSC(fck,cube = 60 兆帕)对直径 3 米的钻孔灌注桩进行了实地测量,以评估数值模型的有效性。在浇注后的约 380 小时内,使用光纤传感器监测桩身的温度变化。现场测量所测得的时间和空间温度分布与模拟结果十分吻合。在桩的水平横截面上观察到了较大的热梯度和高拉伸应力区,从而形成了垂直环形裂缝。根据分析结果预测了最大裂缝宽度,并与耐久性裂缝宽度限制进行了比较。
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引用次数: 0
Durability of concrete-embedded GFRP bars after 20 years of tidal zone exposure: Correlation with accelerated aging tests 混凝土预埋 GFRP 钢筋在潮汐区暴露 20 年后的耐久性:与加速老化试验的相关性
IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-06-18 DOI: 10.1016/j.cscm.2024.e03435
Mesfer M. Al-Zahrani

The application of non-metallic glass fiber-reinforced polymer (GFRP) bars as embedded reinforcement in reinforced concrete (RC) has been of great interest among researchers and practicing engineers alike, owing to its properties such as high strength-to-weight ratio and corrosion resistance. This study investigated the long-term performance of ribbed (RB) and sand-coated (SC) GFRP bars embedded in concrete columns exposed to harsh seawater conditions for approximately 20 years. The bars extracted from the concrete elements were tested to evaluate strength retention based on ASTM standard transverse and interlaminar shear strength tests. After the long-term field exposure, the ribbed and sand-coated GFRP bars exhibited 82.5 % and 79.4 % transverse shear strength retention, and 84.4 % and 78.1 % interlaminar shear strength retention, respectively, which corresponds to approximately 5 months of exposure in the accelerated solution specified by ACI 440.3R-12 guide. Scanning electron microscopy analyses revealed the extent of damage in the fibers, the matrix, and their interface, which validated the degradation in the mechanical strength of the exposed GFRP bars. Finally, correlations between long-term and accelerated exposure test conditions were developed to predict transverse and interlaminar shear strength in the field based on laboratory conditioning investigations.

由于非金属玻璃纤维增强聚合物(GFRP)钢筋具有高强度重量比和耐腐蚀性等特性,因此将其作为钢筋混凝土(RC)中的预埋钢筋一直备受研究人员和实际工程师的关注。本研究调查了嵌入混凝土柱中的带肋 (RB) 和涂砂 (SC) GFRP 钢筋在恶劣海水条件下约 20 年的长期性能。根据 ASTM 标准横向和层间剪切强度测试,对从混凝土构件中提取的钢筋进行了强度保持性测试。经过长期现场暴露后,带肋和砂涂层 GFRP 钢筋的横向剪切强度保持率分别为 82.5% 和 79.4%,层间剪切强度保持率分别为 84.4% 和 78.1%,相当于在 ACI 440.3R-12 指南规定的加速溶液中暴露约 5 个月。扫描电子显微镜分析显示了纤维、基体及其界面的损坏程度,验证了暴露的 GFRP 棒材机械强度的下降。最后,在实验室条件调查的基础上,建立了长期和加速暴露试验条件之间的相关性,以预测现场的横向和层间剪切强度。
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引用次数: 0
Study on the pore blocking characteristics and cleaning methods of permeable asphalt mixtures based on accelerated clogging simulation experiments 基于加速堵塞模拟实验的透水性沥青混合料孔隙堵塞特性及清理方法研究
IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-06-18 DOI: 10.1016/j.cscm.2024.e03438
Yin An , Lizhi Du , Wenting Dai , Kai Zhang , Yong Wang , Wei Guo

Clogging in permeable asphalt pavements compromises their functional properties. Understanding clogging characteristics and developing appropriate maintenance methods is crucial. This study integrates indoor accelerated clogging simulations with Grey Relational Analysis to investigate the factors influencing clogging behavior. Computer tomography scanning and seepage model simulations are utilized to examine the distribution of clogging materials, seepage properties, and changes in pore parameters in permeable asphalt mixtures before and after clogging. Additionally, variable frequency vibration tests are conducted to evaluate the impact of vibration frequency on clog removal efficiency. Findings show that the cementation hardening effect of clay progressively seals pores, with sand particles of 0.15 mm diameter exerting the most significant influence on clogging. Wet-dry cycles lead to an accumulation of clay cementation, resulting in a 26.1 % and 72.4 % decrease in pore channel length and volume, respectively, at depths of 0–4.2 cm. The area within this depth range is most prone to clogging, increasing pore tortuosity. Seepage behavior is primarily determined by several main interconnected pores. Vibration test outcomes indicate that frequencies between 100 and 400 Hz are optimal for disrupting cementation blockages.

透水性沥青路面的堵塞会影响其功能特性。了解堵塞特征并制定适当的维护方法至关重要。本研究将室内加速堵塞模拟与灰色关系分析相结合,研究影响堵塞行为的因素。利用计算机断层扫描和渗流模型模拟来研究堵塞前后透水性沥青混合料中堵塞材料的分布、渗流特性和孔隙参数的变化。此外,还进行了变频振动试验,以评估振动频率对堵塞清除效率的影响。研究结果表明,粘土的胶结硬化效应会逐渐封闭孔隙,直径为 0.15 毫米的砂粒对堵塞的影响最大。干湿循环导致粘土胶结累积,使 0-4.2 厘米深度的孔道长度和体积分别减少了 26.1% 和 72.4%。该深度范围内的区域最容易发生堵塞,从而增加孔隙迂回度。渗流行为主要由几个相互连接的主要孔隙决定。振动测试结果表明,频率在 100 到 400 赫兹之间的振动最适合破坏胶结堵塞。
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引用次数: 0
Examining the rheological and adhesion performance of asphalt: Insights into the influence of SARA components 研究沥青的流变和粘附性能:深入了解 SARA 成分的影响
IF 6.5 2区 工程技术 Q2 Materials Science Pub Date : 2024-06-17 DOI: 10.1016/j.cscm.2024.e03427
Hongfei Zhang , Yuanfa Li , Jiupeng Zhang , Zhe Li , Zixuan Chen , Jianzhong Pei , Ming Wang

The role of chemical components is pivotal in determining the rheological and adhesion performance of asphalt binders. In this study, the saturate, aromatic, resin, and asphaltene (SARA) components were directly blended with the original asphalt in specific proportions, enabling a direct assessment of their influence on critical asphalt properties. Various tests, including frequency sweep, temperature sweep, and multiple stress creep and recovery tests, were conducted, followed by the utilization of master curves to analyze the rheological properties of SARA-doped asphalt. Additionally, binder bond strength tests were performed to evaluate the adhesion properties of SARA-doped asphalt binders. The research outcomes revealed that the complex modulus, rutting factor, creep and recovery behaviors increased with higher asphaltene and resin proportions, while diminishing with elevated saturate and aromatic proportions. Analysis of the Glover–Rowe (G-R) parameter variation indicated that increasing the proportion of aromatic and saturate components can enhance cracking resistance, with the aromatic component playing a particularly significant role in this enhancement. Furthermore, augmenting the proportion of heavy components was found to enhance the adhesion performance between asphalt and commonly used aggregates. Notably, the pattern of interfacial failure transitioned from cohesive failure to adhesive failure gradually with rising proportions of heavy components.

化学成分在决定沥青胶结料的流变和粘附性能方面起着关键作用。在这项研究中,饱和组分、芳烃组分、树脂组分和沥青烯(SARA)组分按特定比例直接与原沥青混合,从而可以直接评估它们对沥青关键性能的影响。我们进行了各种试验,包括频率扫描、温度扫描、多应力蠕变和恢复试验,然后利用主曲线分析了掺有 SARA 的沥青的流变特性。此外,还进行了粘结强度试验,以评估掺 SARA 沥青粘结剂的粘结性能。研究结果表明,复合模量、车辙系数、蠕变和恢复行为随着沥青烯和树脂比例的增加而增加,而随着饱和度和芳烃比例的增加而减少。Glover-Rowe(G-R)参数变化分析表明,提高芳香组分和饱和组分的比例可增强抗裂性,其中芳香组分在增强抗裂性方面的作用尤为显著。此外,增加重组分的比例还能提高沥青与常用集料之间的粘附性能。值得注意的是,随着重组分比例的增加,界面破坏模式从内聚破坏逐渐过渡到粘附破坏。
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引用次数: 0
Synergy of devulcanized rubber and rock asphalt for asphalt modification 脱硫橡胶和岩石沥青在沥青改性中的协同作用
IF 6.5 2区 工程技术 Q2 Materials Science Pub Date : 2024-06-17 DOI: 10.1016/j.cscm.2024.e03432
Yue Zhou , Qingbing Lu , Zhiqiang Cheng , Jie Wang , Jingtao Zhong , Qingqing Lu , Shengjia Xie , Baoshan Huang

Rock asphalt (RA) has gradually been recognized as a green and efficient asphalt modifier. However, the weakness of low-temperature performance and fatigue resistance for RA modified asphalt limited its application and popularization in asphalt pavement. To overcome the above shortcomings, this study aimed to synergistically apply devulcanized rubber powder (DRP) with American rock asphalt (ARA) for asphalt modification. Multiple experiments such as dynamic shear rheology (DSR) and bending beam rheology (BBR) were conducted to evaluate the rheological properties and road performance of composite modified asphalt (CMA). Cigar tube test (CTT) was applied to assess storage stability of CMA. In addition, Fourier transform infrared spectrometer (FTIR) and microscopic test (MT) were used to investigate the modification mechanisms. The results showed that CMA modified by DRP and ARA exhibited comparable storage stability, low-temperature performance and rutting resistance as SBS modified asphalt. ARA tended to cause aging problems of asphalt, but the addition of DRP effectively improved the aging resistance performance of modified binder blends, especially long-term aging resistance. The mixing of DRP, ARA and base asphalt is a physical process without chemical reactions. Even though the ash in ARA slightly lowered its storage stability, it significantly improved dispersion and homogenous interface of DRP in asphalt.

岩石沥青(RA)作为一种绿色、高效的沥青改性剂已逐渐得到认可。然而,岩石沥青改性沥青在低温性能和抗疲劳性能方面的弱点限制了其在沥青路面中的应用和推广。为克服上述不足,本研究旨在将脱硫化橡胶粉(DRP)与美国岩石沥青(ARA)协同应用于沥青改性。通过动态剪切流变学(DSR)和弯梁流变学(BBR)等多种实验,对复合改性沥青(CMA)的流变特性和道路性能进行了评估。应用雪茄管试验(CTT)评估了 CMA 的储存稳定性。此外,还使用傅立叶变换红外光谱仪(FTIR)和显微测试(MT)研究了改性机理。结果表明,经 DRP 和 ARA 改性的 CMA 在储存稳定性、低温性能和抗车辙性能方面与 SBS 改性沥青相当。ARA容易引起沥青的老化问题,但添加DRP能有效改善改性混合料的抗老化性能,尤其是长期抗老化性能。DRP、ARA 和基质沥青的混合是一个物理过程,没有化学反应。尽管 ARA 中的灰分略微降低了其储存稳定性,但却显著改善了 DRP 在沥青中的分散性和均匀界面。
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引用次数: 0
Influence of additional components on mechanical and shrinkage properties of high performance cementitious grouting materials 附加成分对高性能水泥基灌浆材料的机械性能和收缩性能的影响
IF 6.2 2区 工程技术 Q2 Materials Science Pub Date : 2024-06-17 DOI: 10.1016/j.cscm.2024.e03425
Peng Du , Junchao Yang , Honghai Chu , Xiaolei Lu , Xin Cheng

Semi-flexible pavement is a new type of pavement technology with excellent mechanical and road performance. Grouting materials play a crucial role in filling and reinforcing semi-flexible pavements as an important component. In this study, based on sulphoaluminate cement, the effect of mineral admixtures on rheological properties of grouting materials was studied by introducing rheology. High-performance grouting materials for semi-flexible pavements were prepared by varying the ratio of water-cement ratio, early-strength agent and mineral admixture, and their optimal ratios were determined. The research findings indicate that, the grouting materials with the best mechanical properties can be obtained when the water-to-binder ratio is 0.5, and the dosages of lithium carbonate, silica fume, microspheres, and granulated blast furnace slag are 0.2 %, 1.6 %, 5.0 %, and 5.0 %, respectively. The optimal dosage for shrinkage-reducing agents to improve the shrinkage behavior of grouting materials is in the range of 0.10–0.15 %. The accelerated early hydration reaction and improved compactness of the material matrix are the main reasons for the rapid development of the mechanical properties of the grouting materials. Mineral admixtures can undergo a hydration reaction similar to that of cement to produce a rigid gel consisting of very small particles with a laminar structure, which has a positive effect on the development of grouting material properties. The improvement in shrinkage behavior is achieved through the filling effect of silica fume and the micro-expansion effect of plasticizing expanders, which generate small and uniform bubbles.

半柔性路面是一种新型路面技术,具有优异的机械性能和路面性能。灌浆材料作为半柔性路面的重要组成部分,在路面的填充和加固中起着至关重要的作用。本研究以硫铝酸盐水泥为基础,通过引入流变学,研究了矿物掺合料对灌浆材料流变性能的影响。通过改变水灰比、早强剂和矿物掺合料的配比,制备了用于半柔性路面的高性能灌浆材料,并确定了其最佳配比。研究结果表明,当水灰比为 0.5,碳酸锂、硅灰、微球和粒化高炉矿渣的用量分别为 0.2 %、1.6 %、5.0 % 和 5.0 % 时,灌浆材料的力学性能最佳。为改善灌浆材料的收缩性能,减缩剂的最佳用量为 0.10-0.15%。早期水化反应的加速和材料基体密实度的提高是灌浆材料力学性能快速发展的主要原因。矿物掺合料可以发生与水泥类似的水化反应,产生由极小颗粒组成的刚性凝胶,具有层状结构,这对灌浆材料性能的发展具有积极作用。硅灰的填充效应和塑化膨胀剂的微膨胀效应可产生均匀的小气泡,从而改善收缩性能。
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引用次数: 0
Enhancing the performance of alkali-activated slag using KH-550 as a multi-functional admixture 使用 KH-550 作为多功能外加剂提高碱活性渣的性能
IF 6.2 2区 工程技术 Q2 Materials Science Pub Date : 2024-06-17 DOI: 10.1016/j.cscm.2024.e03434
Menglong Yu , Jin Li , Cheng Zhao , Weibo Tan , Xiangkun Li , Peiyuan Chen

This study proposes using KH-550 as a multifunctional admixture for improving the performance of alkali-activated slag (AAS). The hydrolysis products of KH-550 were characterized, and the influence of KH-550 on the fresh properties, hydration kinetics, pore structure, capillary water absorption, hydration products, compressive strength and micro-mechanical properties of AAS were investigated. The results showed that the addition of KH-550 improved the fresh properties of AAS. By adding 2.5 % KH-550, the initial and final setting time of AAS were prolonged by 105.1 % and 60.3 %, respectively, and the fluidity was increased by 10.26 %. The analysis of hydration kinetics showed that although the added KH-550 retarded the AAS hydration at early ages, the nucleation effect of KH-550 nanoparticles accelerated the hydration of AAS at later ages. Moreover, the addition of KH-550 improved the pore structure of the mortars, resulting in a denser microstructure of AAS, which was beneficial for capillary water absorption and compressive strength of AAS. Consequently, the capillary water absorption was reduced by 1.7—11.5 %, and the 28 d compressive strength was increased by 4.8—34.3 %.

本研究提出使用 KH-550 作为多功能外加剂来改善碱活性矿渣(AAS)的性能。对 KH-550 的水解产物进行了表征,并研究了 KH-550 对 AAS 的新鲜性能、水化动力学、孔隙结构、毛细吸水率、水化产物、抗压强度和微观力学性能的影响。结果表明,添加 KH-550 改善了 AAS 的新鲜特性。添加 2.5 % 的 KH-550 后,AAS 的初凝时间和终凝时间分别延长了 105.1 % 和 60.3 %,流动性提高了 10.26 %。水化动力学分析表明,虽然添加的 KH-550 会延缓 AAS 在早期龄期的水化,但 KH-550 纳米粒子的成核效应会加速 AAS 在后期龄期的水化。此外,KH-550 的添加还改善了砂浆的孔隙结构,使 AAS 的微观结构更加致密,有利于 AAS 的毛细吸水率和抗压强度。因此,毛细吸水率降低了 1.7-11.5%,28 d 抗压强度提高了 4.8-34.3%。
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引用次数: 0
Effect of waste engine oil and warm mix additive on the physical, rheological, and short-term aging attributes of Styrene–Butadiene Rubber-modified asphalt binders 废机油和温拌添加剂对丁苯橡胶改性沥青胶结料的物理、流变和短期老化属性的影响
IF 6.5 2区 工程技术 Q2 Materials Science Pub Date : 2024-06-17 DOI: 10.1016/j.cscm.2024.e03433
Ahmed Eltwati , Mohd Rosli Hainin , Fares Tarhuni , Euniza Jusli , Mohammed Alamri

Styrene-butadiene rubber (SBR) latex is used widely to increase the low-temperature resistance of asphalt binders. However, the high content of butadiene copolymer in SBR-treated asphalt causes oxidation and aging. Furthermore, following the SBR modification, the compatibility and thermal storage stability of SBR-modified asphalt is not satisfactory. Therefore, the best approach to improve the quality of short-term aged SBR-modified asphalt is to lower the manufacturing temperatures of the SBR-modified asphalt mixture. In this study, to reduce the preparation temperatures of SBR-modified asphalt mixes and improve their performance after short-term aging, several additives i.e., waste engine oil (WEO), warm mix agent i.e., ZycoTherm, and WEO/ZycoTherm combination (WEO+ ZycoTherm) were selected. The rheological properties and aging performance of binder samples were evaluated through the rational viscosity, dynamic shear rheometer, bending beam rheometer and Fourier transform infrared spectroscopy tests. The results showed that adding WEO together with ZycoTherm into an SBR-modified binder contributed to reducing the compaction and mixing temperatures. The chemical analysis showed that the three additives i.e., WEO, ZycoTherm, and ZycoTherm/WEO declined the aromaticity and chemical aging indicators of aged SBR-modified binders. Furthermore, it was demonstrated that both the ZycoTherm and WEO/ZycoTherm improved the asphalt resistance to rutting at elevated temperatures in both conditions i.e., before and after short-term aging. In addition, the findings revealed ZycoTherm /WEO compound yielded the best performance to improve the minimal-temperature cracking resistance of the SBR-modified binder, resulting in lower short-term aging temperatures. In summary, this study highlights the necessity of lowering preparation temperatures in asphalt mixes containing SBR to enhance binder resistance to rutting and cracking and reduce susceptibility to oxidation during short-term aging.

丁苯橡胶(SBR)胶乳被广泛用于提高沥青胶结料的耐低温性能。然而,SBR 处理的沥青中丁二烯共聚物含量较高,会导致氧化和老化。此外,SBR 改性后,SBR 改性沥青的相容性和热储存稳定性也不尽如人意。因此,改善短期老化 SBR 改性沥青质量的最佳方法是降低 SBR 改性沥青混合料的生产温度。在本研究中,为了降低 SBR 改性沥青混合料的制备温度并改善其短期老化后的性能,选择了几种添加剂,即废机油(WEO)、温拌剂(ZycoTherm)和 WEO/ZycoTherm 组合(WEO+ ZycoTherm)。通过合理粘度、动态剪切流变仪、弯曲梁流变仪和傅里叶变换红外光谱测试,对粘结剂样品的流变特性和老化性能进行了评估。结果表明,在 SBR 改性粘合剂中添加 WEO 和 ZycoTherm 有助于降低压实和混合温度。化学分析显示,WEO、ZycoTherm 和 ZycoTherm/WEO 这三种添加剂降低了老化 SBR 改性粘合剂的芳香度和化学老化指标。此外,研究还表明,ZycoTherm 和 WEO/ZycoTherm 在短期老化前和短期老化后两种条件下都能提高沥青在高温下的抗车辙能力。此外,研究结果表明,ZycoTherm /WEO 复合物在改善 SBR 改性粘结剂的最小温度抗裂性方面表现最佳,从而降低了短期老化温度。总之,本研究强调了降低含有丁苯橡胶的沥青混合料制备温度的必要性,以提高粘结剂的抗车辙和抗开裂能力,并降低短期老化过程中的氧化敏感性。
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Case Studies in Construction Materials
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